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SAKUNTHALA
ENGINEERING COLLEGE
DEPARTMENT OF SCIENCE AND HUMANITIES
QUESTION BANK
DEGREE : BE/B.TECH
SUBJECT : ENGINEERING CHEMISTRY SEMESTER :I
SUBJECT CODE : YEAR : I
2 Find the number of electrons transferred in the equation Cu(s) + CO2.1 CL1
2Ag+(aq) → Cu2+(aq) + 2Ag(s).
a) 4
b) 3
c) 2
d) 1
3 The standard reduction electrode potentials of four metals are A = CO2.1 CL2
-0.250 V, B = -0.140 V, C = -0.126 V, D = -0.402 V. The metal that
displaces A from its aqueous solution is:
(a) A
(b) B
(c) C
(d) D
4 The layer formed between the interfaces of the electrolyte and the CO2.1 CL1
solid electrode is known as ……………
a) liquid junction potential
b) Helmholtz electrical double layer
c) semipermeable membrane
d) cellulose
5 …………………..is used to eliminate liquid junction potential. CO2.1 CL1
a) Anode
b) Cathode
c) Salt bridge
d) Cell voltage
6 The standard electrode potential of zinc ion is 0.76 V. Find the CO2.1 CL3
potential of 2M solution at 300 K from the following.
a) 0.769V
b) 0.796V
c) 0. 8901V
d)0.9801V
7 The standard reduction potential value of the three metallic CO2.1 CL2
cations X, Y and Z are 0.52, -3.03 and -1.18 V respectively, the
order of reducing power of the corresponding metals is ……
a) Y > Z > X
b) X > Y > Z
c) Z > Y > X
d) Z > X > Y
8 Mercury covered by a layer of mercurous chloride which is in CO2.2 CL1
contact with a solution of saturated potassium chloride is a
description of ………………...
a) Hydrogen Electrode
b) Platinum Electrode
c) Calomel Electrode
d) Glass Electrode
9 ………………. is also called as primary reference electrode. CO2.2 CL1
a) Ion selective Electrode
b) Calomel Electrode
c) Glass Electrode
d) Standard Hydrogen Electrode
10 Pick out the incorrect working condition of standard hydrogen CO2.2 CL1
electrode which is not true for a primary reference electrode.
a) The hydrogen ion concentration is 1 M
b) The temperature maintained is 25oC
c) Pressure of hydrogen is 1 atmosphere
d) It contains a metallic conductor which does not absorb
hydrogen
11 In combination electrode, which of the following electrodes are CO2.2 CL1
built together?
a) Primary electrode, secondary reference electrode
b) Primary reference electrode, glass electrode
c) Glass electrode, secondary reference electrode
d) Glass electrode with another glass electrode
12 The electrolytic solution present in the glass electrode of the pH CO2.2 CL1
meter is ………….
a) saturated KCl
b) concentrated HCl
c) dilute KCl
d) dilute HCl
13 Identify the gas passed through the unmarked component of CO2.2 CL1
Standard Hydrogen Electrode.
a) Hydrogen at 1 atm
b) Hydrogen at 10 atm
c) Helium at 1 atm
d) Helium at 10 atm
14 The reduction potential for the half cell reaction at 25o C: CO2.3 CL3
Heavy water used in the nuclear reactor to slow down the speed of
neutrons is………..
a) Highly purified water CO3.8 CL1
b) A compound of oxygen and deuterium
30
c) Water having dissolved salts of heavy metals
d) None of these
…….Among the following part in a nuclear reactor minimizes the
neutron leakage.
a) Shield CO3.8 CL1
b) Control rods
31
c) Reflector
d) Moderator
Select the desirable property of a moderator is…………….
a) Moderator should absorb neutrons but slow down the neutrons
as early as possible CO3.8 CL1
b) It should have low thermal conductivity for better heat transfer
32
c) It shouldn’t be chemically unstable
d) It should have low resistance to corrosion
In the following reactor…………is fertile material converted into
initial fissile material?
a) Breeder reactor CO3.9 CL1
b) Fast reactor
33
c) Burner reactor
d) Thermal reactor
The following the number of constituting particles from two to several thousand------
1 CO5.1 CL1
a) Atom/molecule b) Nanomaterials c) Bulk materials d)None of the above
2 ……………… property of nanomaterials make them suitable to be used for elimination of CO5.1 CL1
pollutants?
a)High purity b) Better thermal conductivity c)
Enhanced chemical activity d) Small size
………………… is one of the following options comes under physical property of
3 nanoparticles. CO5.1 CL2
a) Melting point b) Hardness c) Strength d) Capacity of tensile deformation
…………..is one of the following example of top-down approach for the preparation of
nanomaterials.
4 CO5.2 CL2
a)Gas Phase agglomeration b) Molecular Self-assembly
c) Mechanical grinding d) Molecular beam epitaxy
The creating of nanoscale materials by chemically or physically breaking down the
5 larger materials is known as ------------ approach in nanotechnology? CO5.2 CL2
a)Top down b) Bottom up c) Bottom – down d)None of the above
……………………….is a tubular form of carbon used as catalyst in chemical industries.
6 CO5.2 CL1
a) Carbon nanotube b) Poly carbon c) Carbon fibre d) Fullerene
Statement (I): A carbon nano-tube consists of a single sheet of graphite rolled into a
tube.
Statement (II): The carbon nanotube electrically behaves as a semiconductor.
a) Both Statement (I) and Statement (II) are individually true and Statement (II) is the
7 correct explanation of Statement (I). CO5.3 CL2
b) Both Statement (I) and Statement (II) are individually true, but Statement (II) is not
the correct explanation of Statement (I).
c) Statement (I) is true, but Statement (II) is false.
d) Statement (I) is false, but Statement (II) is true.
Consider the following statements regarding carbon nanotubes (CNTs):
1. CNTs are described as a sheet of graphite rolled into a cylindrical form, constructed
from hexagonalrings of carbon.
2. CNTs have one or multiple layers.
8 CO5.3 CL2
3. Choice of the rolling axis relative to the hexagonal network of graphite sheet, gives
three differentstructures, namely: Armchair, Zig Zag, and chiral.
Which of the above statements are correct?
a) 1 and 2 only b) 1 and 3 only c) 2 and 3 only d) 1, 2 and 3
The carbon nanotubes, graphene, and fullerenes are the ____________ based
9 nanoparticles? CO5.3 CL1
a) Organic b) Inorganic c) Carbon based d) None of the above
-------- is the primary process used to convert raw materials into carbon fibers?
13 CO5.3 CL1
a) Spinning b) Extrusion c) Pultrusion d) Carbonization
The following properties makes carbon fibers an ideal material for use in aerospace
and defense applications --------.
14 CO5.3 CL2
a) High conductivity b) High strength-to-weight ratio
c) High flexibility d) High transparency
Graphene was first isolated in the lab, technology did the researchers use-------
15 a) Atomic Force Microscopy (AFM) b) Scotch tape CO5.4 CL2
c) Hammer and chisel d)Ultrasensitive planing and milling machine
…………..can be used as an alternative to silicon or Indium tin oxide for the manufacture
17 of photo voltaic (PV) cells. CO5.4 CL2
a) Graphene b) CNTs c)Cabon fibers d)Nano composites
The following material is used as a Nano sensor to detect microscopic contaminants in
18 water-------- CO5.4 CL2
a) Carbon Nano tubes b) Carbon fibers c) Graphene d) Graphite
25 Match the solid oxide fuel cell components in column I with the electrode materials in CO5.6 CL2
column II.
Column I Column II
i. Anode a) Lanthanum nikelate strontium doped Nanopowder
ii.Cathode b) Cerium oxide praseodymium doped Nano powder
iii. Electrolyte c) Hydrogen
iv. Fuel d) Nickel oxide – Scandia stabilized Zirconia
a. (i) ---- (d) (ii) ------(b) (iii) -----(a) (iv) ------ (c)
b. (i)----- (c) (ii)------(a) (iii) ----- (b) (iv) ----- (d)
c. ( i)-----(b) (ii) ----- (a) (iii)----- (d) (iv) ---- (c)
d. ( i)-----(d) (ii) ---- (a) (iii) ------(b) (iv) ---- (c)
The solid solvents which possess ion transport properties are called……………..
27 a) polymer alloys b) polymer blends CO5.6 CL1
c) polymer electrolytes d) polymer nanocomposites
The process of combining two or more distinct polymer molecules to form a new
30 product with different characteristics is called as…………… CO5.8 CL1
a) binding b) stabilizing c) filling d) blending
The physical mixture of two or more polymers that are not linked by covalent bond is
32 called……. CO5.8 CL1
a) polymerization b) poly blend c) dendrimer d) copolymer
The following material is used for making electronic printers and type writers----a)ABS-
33 CO5.8 CL2
PC alloy b) ABS- PVC alloy c) PPE- PA alloy d) Poly Blend
Polymer of……… doped polyvinyl carbazole films are good photoluminescent material.
34 CO5.9 CL2
a) C40 b) C30 c) C60 d) C20
PART-B (4 Marks)
UNIT II -ELECTROCHEMISTRY
PART-B (4 Marks)
List out the major advantages and disadvantages of fuel cells over CO3.5 CL2
5 other power conversion devices.
6 Fuel cell is better than the conventional methods of energy CO3.5 CL2
generation. Justify.
7 Elaborate the principle of a super capacitor. CO3.6 CL2
8 Illustrate the super critical mass and sub-critical mass of nuclear CO3.7 CL2
reaction.
9 Sketch the diagram of nuclear power reactor and label the parts. CO3.8 CL3
10 List out the advantages and disadvantages of Nuclear power CO3.8 CL3
reactor.
11 Elucidate the reactions of fissionable and non fissionable materials CO3.9 CL3
in breeder reactor.
6 Illustrate the condensation polymerization of Nylon 66 and mention its CO4.3 CL2
applications.
7 Elaborate the role of additives in polymer compounding. CO4.3 CL2
8 Differentiate between stepwise and chain growth polymerization CO4.3 CL2
reactions with examples.
9 Identify the factors affecting glass transition temperature. CO4.4 CL2
10 Describe the polymerization process by injection moulding technique CO4.6 CL2
with a schematic diagram.
11 Elaborate in energy storage application the solid polymer electrolytic fuel cells CO5.7 CL2
produces electrical energy with high efficiency.
12 Discuss factors affecting the miscibility and compatibility of polymer blends CO5.8 CL2
and alloys.
13 Compare polymer blends and polymer alloys with respect to their structure, CO5.8 CL2
property and use.
14 The polymer is used as a good insulating material, Justify the statement with its CO5.9 CL2
properties.
5 Identify the metal ions present in water sample with the help of (CO1.7)
AAS and describe the principle and components with a neat CL3
sketch.
Demonstrate the working principle, components and (CO1.8) CL2
6 instrumentation of Flame Emission Spectroscopy and discuss the
identification of Na, K, Ca and Mg present in the water sample
with the help of FES.
Compare the principle and applications of Emission spectra with
7 Absorption spectra with a special reference of trace element (CO1.8) CL4
analysis in water sample.
8 Recognize the trace metal ions present in water sample with the (CO1.9) CL3
help of Inductively Coupled Plasma Mass Spectroscopy and
describe the components with a neat sketch.
UNIT II -ELECTROCHEMISTRY
S.NO QUESTIONS CO
1 Describe the following electrodes with diagram, electrode notation and CO2.2 CL1
electrode reactions.
(i) Standard Hydrogen Electrode (ii) Calomel Electrode
2 (i) Derive Nernst equation, giving the emf of a cell in terms of CO2.3 CL2
concentrations of reactants and products of the cell reaction (6 Marks)
(ii) Find the oxidation potential of zinc electrode at 250C. The standard
oxidation potential of Zn/Zn2+ is 0.763 V. [Given Zn/Zn2+ =0.2 M] (6 Marks)
3 (i)A zinc rod is placed in 0.1M ZnSO4 solution at 298K. Write the electrode CO2.3 CL3
reaction and calculate the potential of the electrode. E0 Zn= - 0.7V (6
marks)
(ii) Calculate the emf of the cell: Ni/Ni2+(1M)// Pb2+(1M)/Pb at 25oC.
Write down its cell reactions. Standard electrode potential of nickel and
lead are -0.24V and -0.13V respectively at 25oC. (6 marks)
4 (i) Enumerate the applications of emf series and indicate the standard CO2.4 CL3
reduction potential of the following electrodes (Li+/Li, Zn2+/Zn, Fe2+/Fe,
Cu2+/Cu, Ag+/Ag and F2/F-) in hydrogen scale. (8 Marks)
(ii) Differentiate standard electrode potential and single electrode
potential. (4 Marks)
5 Compare and contrast the working principle and electrode reactions of CO2.5 CL2
Galvanic cells with Concentration cells. Comment their applications in
everyday life.
6 (i) Construct a Galvanic cell and write its oxidation and reduction CO2.5 CL3
electrode potential by applying Nernst equation.(6 marks)
(ii) Calculate the emf of a concentration cell at 25ᵒC consisting of two Zn
electrodes immersed in solutions of Zn2+ ions of 0.1 M and 0.01M
concentrations. (6 marks)
7 (i) By applying the Nernst equation, calculate the reduction potential for CO2.7 CL3
the reduction of O2 at pH=7. Given partial pressure of O2 [ρO2]=0.20bar and
E0=1.229V at pH=7. (6 marks)
(ii) Enumerate the measurement of pH of a given solution using an ion
selective electrode. (6 marks)
8 Sketch the titration curve for the following redox reaction and describe CO2.8 CL2
the working principle and emf measurement of potentiometric titrations.
Cr2O72- + 6 Fe2+ + 14 H+ 2 Cr3+ + 6 Fe3+ + 7 H2O
9 Plot a curve for the conductometric titration of strong acid with a strong CO2.9 CL2
base and show that the conductivity of solution rises quickly after the
equivalence point with an example.
1 Illustrate the constructing of the alkaline battery and its anode and CO3.2 CL2
cathode reaction.
7 Super capacitor is an Electric Double Layer Capacitor (EDLC) with CO3.6 CL2
higher capacity compared to normal capacitor. Illustrate this
concept with suitable description.
8 Demonstrate the construction and working of a light water nuclear CO3.8 CL2
power plant with a neat sketch mentioning the components.