GASES IDENTIFICATION OF GASES 1. HYDROGEN EXPERIMENT OBSERVATION INFERENCE
A piece of The evolved gas is The gas is Hydrogen.
Magnesium wire is colourless, taken in a clean and odourless and dry test tube. neutral to litmus. Equation: Add a few drops of It burns with a blue dil.hydrochloric acid. flame and pop Mg +2HCl MgCl2 +H2 sound when a burning splinter is brought near it. IDENTIFICATION OF GASES 2. OXYGEN EXPERIMENT OBSERVATION INFERENCE
A few grams of The evolved gas is The gas is Oxygen.
Potassium colourless, chlorate is taken odourless and in a clean and dry neutral to litmus. test tube and a It rekindles a Equation : pinch of glowing splinter. 2KClO3 2KCl + 3O2 Manganese dioxide is added (Catalyst – MnO2) and then heated. IDENTIFICATION OF GASES 3. CARBON DIOXIDE EXPERIMENT OBSERVATION INFERENCE
Take a few grams The gas is The gas is Carbon dioxide.
of Sodium colourless and carbonate in a odourless clean and dry test It turns moist blue tube.Add a few litmus faint red. Equation : drops of dil.HCl It turns lime water acid. Na2CO3 + 2HCl 2NaCl milky when gas is +H2O + CO2 passed through lime water. IDENTIFICATON OF GASES 4. CHLORINE EXPERIMENT OBSERVATION INFERENCE
Add a few drops The gas is The gas identified is
of conc.HCl to a greenish yellow Chlorine. few grams of having a sharp MnO2 taken in a pungent odour. clean and dry The gas turns Equation: test tube. Heat moist blue litmus red and then MnO2 +4HCl MnCl2 + the mixture. bleaches it. 2H2O +Cl2 It decolourises Potassium permanganate solution. IDENTIFICATION OF GASES 5. HYDROGEN CHLORIDE EXPERIMENT OBSERVATION INFERENCE
To a few grams The gas is The gas is Hydrogen
of NaCl taken in colourless with a chloride. a clean and dry pungent choking test tube add a odour. few drops of The gas turns conc.H2SO4 and moist blue litmus gently heat for a red. Equation : few seconds. If the rod dipped NaCl + H2SO4 NaHSO4 + in Ammonia HCl solution is brought near it , dense white fumes of NH Cl are formed. IDENTIFICATION OF GASES 6. SULPHUR DIOXIDE EXPERIMENT OBSERVATION INFERENCE
Add a few drops of The gas is colourless The gas is Sulphur
dil.HCl to a few with a suffocating dioxide. grams of Sodium smell of burning sulphite taken in a sulphur. clean and dry test It turns moist blue tube. Equation : litmus red. Na2SO3 +2HCl It turns golden yellow solution of 2NaCl + H2O + SO2 Potassium dichromate green. IDENTIFICATION OF GASES 7. HYDROGEN SULPHIDE EXPERIMENT OBSERVATION INFERENCE
In a clean and dry The gas is The gas is Hydrogen
test tube take a colourless having a sulphide. few grams of ZnS foul smell of rotten and add a few eggs. drops of dil.HCl and It turns moist blue warm if necessary. Equation : litmus red. ZnS + 2HCl ZnCl2 + It turns lead acetate paper H2S silvery black. IDENTIFICATION OF GASES 8. AMMONIA EXPERIMENT OBSERVATION INFERENCE
Heat a mixture of The gas is colourless The gas is Ammonia.
slaked lime and with a sharp pungent ammonium characteristic smell. chloride in a clean It turns moist red and dry test tube. Equation : litmus blue. Ca(OH)2 + 2NH4Cl If the rod dipped in conc.HCl is brought CaCl2 + 2H2O + 2NH3 near it , dense white fumes of NH4Cl are formed. IDENTIFICATION OF GASES 9. WATER VAPOUR EXPERIMENT OBSERVATION INFERENCE
Heat a few crystals A clear liquid forms The gas is water
of Copper sulphate on the cooler parts vapour. in a dry test tube. of the test tube, which turns anhydrous copper sulphate (white) to Equation : blue. CuSO4 .5H2O It is neutral to litmus. CuSO4 + 5H2O IDENTIFICATION OF GASES 10. NITROGEN DIOXIDE EXPERIMENT OBSERVATION INFERENCE
Add a few drops of The gas is reddish The gas is Nitrogen
conc.Nitric acid to a brown in colour dioxide. few grams of Copper having an irritating turnings taken in a odour. clean and dry test It turns KI paper tube. Equation : yellow. Heat the mixture. Cu + 4HNO3 It turns blue litmus red. Cu(NO3)2 + 2H2 O +2NO2 TEST FOR ANIONS USING DILUTE SULPHURIC ACID 1.TEST FOR CARBONATE 2- (CO3 ) EXPERIMENT OBSERVATION INFERENCE
A small quantity of Brisk effervescence Carbonate may be
salt is taken in a test occurs and present. tube and a little colourless odourless amount of dil.H2SO4 gas evolves.It is added to it. Warm extinguishes a if there is no action glowing splinter. It in cold. turns moist blue litmus red. Carbonate is It turns lime water confirmed. Pass the gas through milky. lime water. . Equation : The white ppt Na2CO3 + H2SO4 To the above ppt, dissolves to form 2.TEST FOR SULPHIDE 2- (S ) EXPERIMENT OBSERVATION INFERENCE
A small quantity of A colourless gas with Sulphide may be
salt is taken in a test a rotten egg smell is present. tube and a little given out. amount of dil.H2SO4 It turns blue litmus is added to it. red. A filter paper dipped Sulphide is in moist lead acetate The moist lead confirmed. is brought near the acetate paper turns Equation : mouth of the test silvery black. tube. ZnS + H2SO4 ZnSO4 + H2S 3.TEST FOR SULPHITE (SO3 2-)
EXPERIMENT OBSERVATION INFERENCE
A small quantity of A colourless gas with Sulphite may be
salt is taken in a test a suffocating odour present. tube and a little of burnt suphur is amount of dil.H2SO4 given out. is added to it. The gas turns blue litmus red.
A moist filter paper The orange colour of
the paper turns Sulphite is confirmed. with acidified green. Equation : potassium dichromate is Na2SO3 + H2SO4 brought near the Na2SO4 + H2 O +SO2 TEST FOR ANIONS USING CONCENTRATED SULPHURIC ACID 1.TEST FOR CHLORIDE - (Cl ) EXPERIMENT OBSERVATION INFERENCE
A small quantity of A colourless gas with Chloride may be
salt is taken in a a pungent odour is present. test tube and a little given out. amount of conc. It turns blue litmus H2SO4 is added to it. red. It is warmed gently. A glass rod dipped Chloride is confirmed. in Ammonium Dense white fumes of hydroxide is brought Hydrogen chloride are Equation : near the gas formed. NaCl + H2SO4 evolved. NaHSO4 + HCl NH3 + HCl NH4Cl 2.TEST FOR NITRATE (NO3 -)
EXPERIMENT OBSERVATION INFERENCE
A small quantity Reddish brown Nitrate may be present.
of salt is taken in fumes are a test tube and a evolved. Nitrate is confirmed. few drops of Conc.H2SO4 are Equation : KNO3+H2SO4KHSO4+ carefully poured along the side of HNO3 the test tube. 2HNO3+3 H2SO4+6FeSO4 An equal volume A brown ring 3Fe2(SO4)3 + 4 H2 O + 2NO of freshly prepared ferrous appears at the sulphate solution junction of the FeSO4 + NO FeSO4.NO is added to the two liquids. (brown ring) TEST FOR ACID RADICAL 1.TEST FOR SULPHATE(SO4 2-)
EXPERIMENT OBSERVATION INFERENCE
A small quantity White precipitate Sulphate is confirmed.
of salt is taken in is obtained which a test tube and a remains insoluble solution is in dil.nitric acid. prepared. To one part dilute nitric acid and then Barium chloride solution is added. White ppt is formed which is Sulphate is confirmed. To the other part of the solution soluble in excess add acetic acid of Ammonium Equation : and lead acetate acetate solution Na2SO4 + BaCl2 2NaCl solution. TEST FOR CATIONS 1.TEST FOR AMMONIUM + (NH4 ) EXPERIMENT OBSERVATION INFERENCE
A small quantity of Colourless gas Ammonium may be
salt is taken in a with a pungent present. test tube and a smell is evolved. Equation : little amount of It turns moist red NH4Cl + NaOH NaCl + NaOH is added to litmus blue. it and warmed H2O + NH3 It gives dense gently. white fumes of A glass rod is NH4Cl with a rod Ammonium is confirmed. dipped in conc.HCl Equation : dipped in conc. and brought near HCl. NH3 + HCl NH4Cl the evolved gas. (white fumes) 2.TEST FOR LEAD (Pb2+) EXPERIMENT OBSERVATION INFERENCE
A small quantity of A white ppt. of Lead may be present.
salt is taken in a Lead hydroxide is Equation : test tube and a formed. Pb(NO3)2+ NaOH NaNO3 little amount of NaOH is added to + Pb(OH) 2 it. It is soluble in Add excess of excess of NaOH. Lead is confirmed. NaOH to the ppt. Equation : formed. Pb(OH) 2 + 2NaOH Na2PbO2 + 2H2O 3.TEST FOR COPPER(Cu2+) EXPERIMENT OBSERVATION INFERENCE
A small quantity of A pale blue ppt. Copper may be present.
salt is taken in a of Copper CuSO4+ 2NH4OH test tube and a hydroxide is little amount of formed. Cu(OH)2 + (NH4)2SO4 NH4OH is added to it. Add excess of It is soluble in Copper is confirmed. NH4OH to the ppt. excess of NH4OH Equation : formed. forming azure Cu(OH)2 + (NH4)2SO4+ blue solution. 2NH4OH H2O + Cu(NH3)4SO4 4.TEST FOR ZINC (Zn2+) EXPERIMENT OBSERVATION INFERENCE
A small quantity of A gelatinous Zinc may be present.
salt is taken in a white ppt. of Zinc Equation : test tube and a hydroxide is ZnSO4+ 2NaOH Na2SO4 little amount of formed. NaOH is added to + Zn(OH) 2 it. It is soluble in Add excess of excess of NaOH. Zinc is confirmed. NaOH to the ppt. Equation : formed. Zn(OH) 2 + 2NaOH Na2ZnO2 + H2O 5.TEST FOR FERROUS (Fe2+) EXPERIMENT OBSERVATION INFERENCE
A small quantity of A dirty green ppt. Ferrous may be present.
salt is taken in a of Ferrous test tube and a hydroxide is little amount of formed. NaOH is added to it. Ferrous is confirmed. It is insoluble in Add excess of excess of NaOH. Equation : NaOH to the ppt. FeSO4 + 2NaOH formed. Fe(OH) 2 + Na2 SO4 6.TEST FOR FERRIC (Fe3+) EXPERIMENT OBSERVATION INFERENCE
A small quantity of A reddish brown Ferric may be present.
salt is taken in a ppt. of Ferric test tube and a hydroxide is little amount of formed. NaOH is added to it. Ferric is confirmed. It is insoluble in Add excess of excess of NaOH. Equation : NaOH to the ppt. FeCl3+ 3NaOH Fe(OH)3 formed. + 3NaCl 7.TEST FOR CALCIUM(Ca2+) EXPERIMENT OBSERVATION INFERENCE
A small quantity of No ppt.is Calcium may be present.
salt is taken in a obtained even in test tube and a excess of NH4OH . little amount of NH4OH is added to it. White ppt. is Calcium is confirmed. A small quantity of obtained which is salt is taken in a Equation : sparingly soluble test tube and a Ca(NO3)2 +2NaOH in excess of little amount of NaOH . Ca(OH) 2 +2Na NO3 NaOH is added to it. DISTINCTION BETWEEN COPPER OXIDE AND MANGANESE DIOXIDE 1. DISTINCTION BETWEEN COPPER OXIDE AND MANGANESE DIOXIDE TEST COPPER OXIDE MANGANESE DIOXIDE Conc.HCl is Green colour solution is Greenish yellow added to the obtained.No gas is evolved. coloured gas which CuO+HCl CuCl2+H2O bleaches moist blue black powder litmus is evolved. and warmed. Filtrate is green in colour. The gas is Chlorine. The above A pale blue ppt. is obtained solution is which is soluble in excess Filtrate is light brown filtered. of NH4OH giving an Azure in colour. Ammonium blue solution. hydroxide is added to the CuCl2+ NH4OH Cu(OH) 2 No ppt.is formed. filtrate. +2NH4Cl MnO2+4HCl Cu(OH) 2 + NH4OH MnCl2+2H2O+Cl2 [Cu(NH ) ](OH) + 4 H O DISTINCTION BETWEEN COLOURLESS SOLUTIONS OF ACIDS AND ALKALIS 1. DISTINCTION BETWEEN COLOURS SOLUTIONS OF ACIDS AND ALKALIS TEST ACIDIC SOLUTION ALKALINESOLUTION 1. Moist Litmus Blue turns red. Red turns blue. paper
2. Methyl orange Orange turns red. Yellow colour is obtained.
3. Colour does not Colourless solution turns
Phenolphthal change. pink. ein Carbon dioxide No reaction. evolves, turns lime 4. Addition of water milky.