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Unit#9 Test#9 Date:

Q.1: Tick the correct Option. [5]

1. Aromatic hydrocarbons are the derivative of :

(a) (b) (c) (d)

Paraffin’s

2. bond length in benzene is:

(a) (b) (c) (d)

3. The resonating contributing structures of Benzene are:

(a) (b) (c) (d)

4. Which one is not a meta directing group?

(a) (b) (c) (d)

5. The conversion of n-hexane into benzene by heating in the presence of Pt is called:

(a) (b) (c) (d)

Q.2: Give answer to any eight short questions of the following. [16]
1. What are polycyclic aromatic hydrocarbons?
2. Describe X-ray structure of benzene.
3. What objections were raised on the kelule’s structure for benzene molecule?
4. How is the straight chain structure of benzene ruled out?
5. How do you justify that is the resonance energy of benzene?
6. Write down mechanism for Halogenation of benzene.
7. Give reaction of benzene
8. What happened when chlorine is passed through benzene in sunlight?
9. Benzene is less reactive than Alkene, why?
10. What is meant by nitration of benzene? Write its reaction.
Q.3: Give answer to any two questions of the following. [9]
(a) Write down four methods for preparation of benzene.
(b) Explain the structure of Benzene on the basis of atomic orbital treatment.

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