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oxygen. It is also very likely that some of the fuel will not get burned when there is a de-
ficiency of oxygen. This unburned fuel ends up as pollution in the exhaust of the engine.
Various terminology is used for the amount of air or oxygen used in combustion:
where
when
SI engines normally operate with an equivalence ratio in the range of 0.9 to 1.2,
depending on the type of operation.
Example Problem 1
Isooctane is burned with 120% theoretical air in a small three-cylinder turbocharged automobile
engine.
Calculate:
1. air–fuel ratio
2. fuel–air ratio
3. equivalence ratio
Stoichiometric reaction is
148
Thermochemistry and Fuels
products. In addition, there is some oxygen and additional nitrogen in the products (the excess air).
(1) Equation (1) is used to find the air–fuel ratio:
= 18.16
Even when the flow of air and fuel into an engine is controlled exactly at stoi-
chiometric conditions, combustion will not be “perfect,” and components other than
CO2, H 2O, and N2 are found in the exhaust products. One major reason for this is the
extremely short time available for each engine cycle, which often means that less than
complete mixing of the air and fuel is obtained. Some fuel molecules do not find an
oxygen molecule to react with, and small quantities of both fuel and oxygen end up in
the exhaust. SI engines have a combustion efficiency in the range of 95% to 98% for
lean mixtures and lower values for rich mixtures, where there is not enough air to react
with all the fuel (see Fig. 1). CI engines operate lean overall and typically have com-
bustion efficiencies of about 98%.
Chemical Equilibrium
If a general chemical reaction is represented by
nAA + nBB : nCC + nDD (3)
where A and B represent all reactant species, whether one or two or more, and C and
D represent all products, regardless of number, then nA, nB, nC, and nD represent the
stoichiometric coefficients of A, B, C, and D.
Equilibrium composition for this reaction can be found if one knows the
chemical equilibrium constant
Ke = [1NCnCNDnD2>1NAnANBnB2]1P>Nt2¢n (4)
where
¢n = nC + nD - nA - nB
Ni = number of moles of component i at equilibrium
Nt = total number of moles at equilibrium
P = total absolute pressure in units of atmospheres
149
Air and Fuel Induction
ENGINE SPEED
2000 rpm
5 3000 rpm
4000 rpm
5000 rpm
4
7000 rpm
B.M.E.P. kg/cm2
0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
DELIVERY RATIO
21
FIGURE 25
Brake mean effective pressure as a function of delivery ratio for two-stroke cycle
SI motorcycle engine of 0.347 L displacement. Reprinted with permission from
SAE Paper No. 750908 © 1975 SAE International, [229].
Example Problem 8
An experimental six-cylinder, two-stroke cycle, SI automobile engine has a delivery ratio of 0.88
when operating at 3700 RPM. At this speed, when the exhaust slots close during the cycle, there
is an air–fuel mass of 0.000310 kg in each cylinder, plus a 5.3% exhaust residual from the pre-
ceding cycle. The engine has a bore of 7.62 cm and a stroke of 8.98 cm.
Calculate:
1. charging efficiency
2. trapping efficiency
3. scavenging efficiency
4. relative charge
Vd = 1p>42B2S
= 1p>4217.62 cm2218.98 cm2 = 409.5 cm3 = 0.4095 L = 0.0004095 m3
(2) Equation (22) is used to find mass of air–fuel ingested into cylinder:
245
Air and Fuel Induction
= 0.728 = 72.8%
(3) Total mass of air–fuel in cylinder, plus exhaust residual is
lrc = mtc>Vdra
= lce>lse = 10.000326 kg2>[10.0004095 m3211.181 m32] = 10.6412>10.9512
= 0.674 = 67.4%
246
Fluid Motion within Combustion Chamber
FIGURE 6
Schematic showing relationships among swirl, injection
duration, and number of orifice holes in the fuel nozzle
of a CI engine. Proper design, as given in Eq. (5),
assures good fuel distribution throughout the entire
combustion chamber.
Example Problem 1
A four-cylinder, 3.2-liter engine running at 4500 RPM has a swirl ratio of 6 as defined by Eq. (1).
The stroke and bore are related as S = 1.06 B.
Calculate:
1. angular velocity of gas mixture in the cylinder using the paddle wheel model
2. swirl ratio as defined by Eq. (2)
266
Combustion
Maximum
Pressure
Pressure, P
Ignition
EVO
Negative Positive
Work Work
FIGURE 1
Cylinder pressure in the combustion chamber of an SI engine as a function of crank angle.
The increase in pressure rise is very slow after ignition during the flame development
period. This results in a slow pressure force increase on the piston and a smooth engine
cycle. Maximum pressure occurs 5° to 10° aTDC. Adapted from [93].
286
Combustion
of reaction and flame speed, and combustion ends by slowly dying away. Although
very little additional work is delivered by the piston during this flame termination pe-
riod due to the slow reaction rate, it is still a desirable occurrence. Because the rise in
cylinder pressure tapers off slowly towards zero during flame termination, the forces
transmitted to the piston also taper off slowly, and smooth engine operation results.
During the flame termination period, self-ignition will sometimes occur in the
end gas in front of the flame front, and engine knock will occur. The temperature of the
unburned gases in front of the flame front continues to rise during the combustion
process, reaching a maximum in the last end gas. This maximum temperature is often
above self-ignition temperature. Because the flame front moves slowly at this time, the
gases are often not consumed during ignition delay time, and self-ignition occurs. The
resulting knock is usually not objectionable or even noticeable. This is because there is
so little unburned air–fuel left at this time that self-ignition can only cause very slight
pressure pulses. Maximum power is obtained from an engine when it operates with
very slight self-ignition and knock at the end of the combustion process. This occurs
when maximum pressure and temperature exist in the combustion chamber and knock
gives a small pressure boost at the end of combustion.
Example Problem 1
The spark plug is fired at 18° bTDC in an engine running at 1800 RPM. It takes 8° of engine ro-
tation to start combustion and get into flame propagation mode. Flame termination occurs at 12°
aTDC. Bore diameter is 8.4 cm, and the spark plug is offset 8 mm from the centerline of the
cylinder. The flame front can be approximated as a sphere moving out from the spark plug. Cal-
culate the effective flame front speed during flame propagation.
Rotational angle during flame propagation is from 10° bTDC to 12° aTDC, which equals 22°.
Time of flame propagation is
Example Problem 2
The engine in Example Problem 1 is now run at 3000 RPM. As speed is increased in this engine,
greater turbulence and swirl increase the flame front speed at a rate such that Vf r 0.85 N.
Flame development after spark plug firing still takes 8° of engine rotation. Calculate how much
ignition timing must be advanced such that flame termination again occurs at 12° aTDC.
Flame speed is
294
Exhaust Flow
cylinder along with the air–fuel charge. This results in a larger exhaust residual during
the rest of the cycle. This backflow of exhaust gases is a greater problem at low engine
speeds, being worst at idle conditions. At most low engine speeds, the intake throttle is
at least partially closed, creating low pressure in the intake manifold. This creates a
greater pressure differential, forcing exhaust gas back into the intake manifold. Cylin-
der pressure is about one atmosphere, while intake pressure can be quite low. In addi-
tion, real time of valve overlap is greater at low engine speed, allowing more backflow.
Some engines are designed to use this small backflow of hot exhaust gas to help va-
porize the fuel that has been injected directly behind the intake valve face.
Some engines have a one-way reed valve at the exhaust port to keep exhaust gas
from flowing back from the exhaust manifold into the cylinder and intake system dur-
ing valve overlap.
Engines equipped with turbochargers or superchargers often will have intake
pressures above one atmosphere and are not subject to exhaust backflow.
Another negative result of valve overlap is that some intake air–fuel mixture can
short-circuit through the cylinder when both valves are open, with some fuel ending up
as pollution in the exhaust system.
Variable valve timing, which is becoming common in automobile engines, de-
creases the problem of valve overlap. At low engine speeds, the exhaust valve can be
closed earlier and the intake valve can be opened later, resulting in less overlap.
If the exhaust valve is closed too early, an excess of exhaust gases is trapped in the
cylinder. Also, cylinder pressure will go up near the end of the exhaust stroke, causing
loss of net work from the engine cycle. If the exhaust valve is closed late, there is an ex-
cess of overlap, with more backflow of exhaust gas into the intake.
Figure 2 shows the flow of gases through the exhaust valve out of the cylinder.
When the valve is first opened, blowdown occurs with a very high flow rate due to the
large pressure differential. Choked flow will occur (sonic velocity) at first, limiting the
maximum flow rate. By the time the piston reaches BDC, blowdown is complete, and
flow out of the exhaust valve is now controlled by the piston during the exhaust stroke.
The piston reaches maximum speed about halfway through the exhaust stroke, and this
is reflected in the rate of exhaust flow. Towards the end of the exhaust stroke, near
TDC, the intake valve opens and valve overlap is experienced. Depending on engine
operating conditions, a momentary reverse flow of exhaust gas back into the cylinder
can occur at this point.
Example Problem 1
A 6.4-liter V8 engine with a compression ratio of 9:1 operates on an air-standard cycle and has
the exhaust process shown in Fig. 1. Maximum cycle temperature and pressure are 2550 K and
11,000 kPa when operating at 3600 RPM. The exhaust valve effectively opens at 52° bBDC.
Calculate:
331
Exhaust Flow
Exhaust
Stroke
Valve
Overlap
0
FIGURE 2
Exhaust gas flow out of cylinder through the exhaust valve(s), showing
blowdown and exhaust stroke. Possible reverse flow back into the cylinder may
occur during valve overlap. Adapted from [28].
(1) Blowdown will occur between 52° bBDC and BDC. This is 52>360 = 0.1444 of a
revolution.
Clearance volume is
332
Exhaust Flow
At the end of blowdown, gases are at hypothetical state 7, but volume is V4 or V1:
P7 = Po = 101 kPa
T7 = T31P7>P321k - 12>k = 12550 K21101>11,000211.35 - 12>1.35 = 756 K
VBDC = V4 = V1 = 1Vc + Vd2 = 10.0001 + 0.00082 = 0.0009 m3
m7 = PV>RT = 1101 kPa210.0009 m32>10.287 kJ>kg-K21756 K2
= 0.00042 kg
1¢m2blowdown = mEVO - m7 = 0.00150 - 0.00042 = 0.00108 kg
This is the same result as the one obtained previously. Calculation of the
amount of mass in the cylinder would be the same using any point along process line
3–4. This means that the same percentage of the exhaust flow must occur during blow-
down regardless of when the exhaust valve is opened. Size of the exhaust valve(s) and
the corresponding mass flow rate through the valve(s) then dictate when the valve
should be opened.
(3) If flow is choked at the start of blowdown, velocity will be sonic. Using Eq. (2)
yields,
VEVO = c = 1kRTEVO = 111.3521287 J>kg-K211244 K2 = 694 m>sec
3 EXHAUST VALVES
Exhaust valves are made smaller than intake valves, although the same amount of mass
must flow through each. The pressure differential across the intake valves of a natural-
ly aspirated engine is less than one atmosphere, while the pressure differential across
the exhaust valves during blowdown can be as high as three or four atmospheres. In ad-
dition, if and when choked flow is occuring, sonic velocity through the exhaust valve is
higher than sonic velocity through the intake valve. This can be seen in Eq. (2), with the
exhaust gas being much hotter than the intake air–fuel mixture. We have for intake
A i = 1constant2B21Up2max>ci (4)
where
A i = area of inlet valve1s2
1Up2max = average piston speed at maximum engine speed
333
Heat Transfer in Engines
Water
Jacket
A
q X
Y
FIGURE 10
Cooling of piston. The face of a piston (A) is one of the hotter
surfaces in a combustion chamber. Cooling is done mainly by
Y convection to the lubricating oil on the back side of the piston
face, by conduction through the piston face, by conduction
through the piston rings in contact with the cylinder walls, and
by conduction down the connecting rod to the oil reservoir.
High conduction resistance occurs because of lubricated
surfaces at cylinder walls (X) and rod bearings (Y).
an engine ages, deposits slowly build up on the walls of the cylinders, due to impurities
in the air and fuel, imperfect combustion, and lubricating oil in the combustion cham-
ber. These deposits create a thermal resistance and cause higher wall temperatures. Ex-
cessive wall deposits also slightly decrease the clearance volume of the cylinder and
cause a rise in the compression ratio.
Some modern engines use heat pipes to help cool internal hot regions that are in-
accessible to normal cooling by conduction or coolant flow. With one end of the heat
pipe in the hot interior of the engine, the other end can be in contact with the circulat-
ing coolant or exposed to external air flow.
Example Problem 1
A 3.0 liter, 5-cylinder, 4-stroke cycle SI engine, with a volumetric efficiency of 82%, operates at 3000
RPM using gasoline with a lambda value of 0.91. Bore and stroke are related as S = 1.08 B. At a
certain point in the engine cycle, the gas temperature in the combustion chamber is Tg = 2100°C
while the cylinder wall temperature is Tw = 190°C. Calculate the approximate convection heat
transfer rate to the cylinder wall at this instant.
Bore can be calculated as follows:
401
Heat Transfer in Engines
The mass flow rate of air into one cylinder of the engine is
#
ma = hvraVdN>n
= 10.82211.181 kg>m32[10.003 m3>cycle2>15 cylinders2]13000>60 rev>sec2>12 rev>cycle2
= 0.01453 kg>sec
The mass flow rate of fuel into one cylinder of the engine is
# # #
mf = ma>1AF2act = ma>[l1AF2stoich] = 10.01453 kg>sec2>[10.912114.62] = 0.00109 kg>sec
Equation (8) gives the Nusselt number and convection heat transfer coefficient (ref. [40] sug-
gests C1 = 0.035 and C2 = 0.80):
Equation (6) gives convection heat transfer rate at combustion chamber wall at this instant:
#
q = hg1Tg - Tw2 = 128.44 W>m2-K212373 - 4632K = 54,320 W>m2 = 54.32 kW>m2
402
Friction and Lubrication
30
ENGINE IDLING
20 BMEP LOAD
40 BMEP LOAD
20 30 BMEP LOAD
Fmep, psi
10
0
800 1000 1200 1400 1600 1800 2000 2200 2400
RPM
FIGURE 6
Friction mean effective pressure as a function of engine speed and load for six-cylinder CI engine.
Pressure in psia. Reprinted with permission from SAE Paper No. 730150 © 1973 SAE
International, [158].
10
0
800 1000 1200 1400 1600 1800 2000 2200 2400
RPM
FIGURE 7
Comparison of friction mean effective pressure of a motored engine vs. fired engine. Engine is a six-
cylinder CI engine. Pressure in psia. Reprinted with permission from SAE Paper No. 730150 © 1973
SAE International, [158].
Example Problem 1
A five-cylinder, in-line engine has an 8.15-cm bore, a 7.82-cm stroke, and a connecting rod length
of 15.4 cm. Each piston has a skirt length of 6.5 cm and a mass of 0.32 kg. At a certain engine
speed and crank angle, the instantaneous piston speed is 8.25 m/sec, and clearance between the
piston and cylinder wall is 0.004 mm. SAE 10W-30 motor oil is used in the engine, and at the tem-
perature of the piston–cylinder interface, the dynamic viscosity of the oil is 0.006 N-sec/m2. Cal-
culate the friction force on one piston at this condition.
440
Friction and Lubrication
30
12:1 COMPRESSION RATIO
7:1 COMPRESSION RATIO
25
20 FRICTION
MEP
15
10
PUMPING
0
0 20 40 60 80 100 120 140
LOAD, BMEP
Friction and pumping work versus load at two compression ratios
FIGURE 8
Friction mean effective pressure (fmep) and pumping mean effective pressure (pmep) as a
function of brake mean effective pressure (bmep) for two compression ratios. Engine is a
four-cylinder, 3.25 liter, SI engine, with 9.53 cm bore and 11.40 cm stroke, operating at 1600
RPM. Pressures in psia. Reprinted with permission from SAE Transactions © 1958 SAE
International, [177].
ts = m1dU/dy2 = m1¢U/¢y2
= 10.006 N-sec/m22[18.25 m/sec2/10.000004 m2] = 12,375 N/m2
441