ALLEN TARGET:JEE (MAIN)/13-08-2023

PART-2 : CHEMISTRY 9. Ans ( D )

SECTION-I i) nNaOH = 5 : w : 200g, = 1200 – 200 =
1000g
1. Ans ( B ) ii) 5 mole NaOH in 1200 g solution
5 member chelation is more stable.
⇒ in 1000g, nNaOH = 4.167
2. Ans ( D ) ⇒ WNaOH = 166.68 g
= 833.35 g
iii)
= ⇒ 18n + 40 n = 1000

WNaOH = 689.65 g
3. Ans ( A )
FACTUAL (iv) WNaOH = 5g
4. Ans ( A )
FACTUAL 10. Ans ( B )
Electrical conductivity ∝ number of ions
5. Ans ( B )
+ M of O > S
11. Ans ( C )
So more stable carbocation in case of

12. Ans ( D )
6. Ans ( C ) Factual
Graphite
13. Ans ( B )
7. Ans ( C )
Both have the same configurations
8. Ans ( C )
C. CO2 : linear sp.
XeF2 : linear sp3d.
14. Ans ( D )
Factual
15. Ans ( C )
Factual
16. Ans ( A )
Factual
17. Ans ( C )
(1) & (2) are SN1 and (3) & (4) are SN2
18. Ans ( D )
Large deviations required to form an azeotrope.

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19. Ans ( B ) PART-2 : CHEMISTRY
SECTION-II
(A)
1. Ans ( 400 )

MF =C4nD3nH4n
Moles of O2 available from 1 mole organic
Compound = 3n/2
48 gram methane ⇒ mole
(B) CH4 + 2O2 ⇒ CO2 + H2O
∴ needed = 6 mole = 3n/2
⇒n=4
∴ MF = C16O12H16
∴ G.M.M. = 400
2. Ans ( 80 )
(C) σ *1s 20(x) – 20 ( l – x ) = – 12

⇒ form = 0.8 = 80%

3. Ans ( 18 )
Pd has 18 electrons is its outermost shell
4. Ans ( 8 )
NCERT data based
(D)
5. Ans ( 4 )

20. Ans ( D )
Dehydration of alcohol

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6. Ans ( 900 ) 8. Ans ( 60 )
[CoBr2(CN)(NO2) (H2O) (NH3)]
NO2 – and CN−both are ambidentate ligands.
⇒ 0.9 Kg Ice
7. Ans ( 46 )
X = Cubic, Tetragonal , Orthorhombic,
Monoclinic = 4
Y = All except Triclinic = 6

Br− at trans position (optically inactive).

Br− at cis position (optical active complex)

The number of geometrical isomers
keeping Br− at cis position is 6 and all of them
are optically active.
So there are twelve cis isomers.
∴ X=12
Y=3 (optical inactive complex)
∴ X+ Y = 12 +3 =15
Also, CN – and NO2 – are both ambidentate
ligands.
∴ 4 possibilities for each case.
∴ Answer = 15 × 4 = 60

9. Ans ( 4 )
HS-8/16 (A), (B),(C) and (D) 7650CJA101029230025
10. Ans ( 36 )
EAN of Fe = 26+10(from five CO) = 36