Oct/Nov 2021 variant 2

May/June 2022 variant 1

Question Answer Marks

4(a) M1 measuring cylinder (1) 2

M2 pipette (1)

4(b) make sure the concentration is even / equal 1

4(c) to show when the reaction is complete / finished / ended / to find the end point 1

4(d) 4.96 1
Question Answer Marks
4(e) 0.0258 1
4(g) M1 final = 35.7 and initial = 4.2 (1) 2
4(f) 0.103 1
M2 volume = 31.5 (1)

4(h) M1 tick in boxes 2, 3, 4 (1) 2

M2 all values within 0.2 (1)

4(i) 30.8 1

4(j) 0.00258 1

4(k) 0.00775 1

4(l) 0.252 1

4(m)(i) M1 moles of NaOH = 0.252  25 / 1000 = 0.0063 (1) 2

M2 moles of Fe(OH)2 = 0.0063 ÷ 2 = 0.00315 (1)

OR
If value of 0.255 is used
M1 moles of NaOH = 0.252  25 / 1000 = 0.0063 (1)
M2 moles of FeSO4 = 0.0063 ÷ 2 = 0.00315 (1)

4(m)(ii) green 1
 Question Answer Marks

5(a) pipette is more accurate ORA 1

5(b) volumetric flask / graduated flask / standard flask 1

5(c) L 1

5(d)(i) to see the colour change of the indicator clearly 1

5(d)(ii) yellow to orange / red / pink 1

Oct/Nov2022 variant 1
specimen
paper

Question Answer
1(a) initial and final readings completed correctly
all readings to 1 decimal place
differences completed correctly
at least one volume used within 2% of supervisor’s
1(b) initial, final reading and volume used completed correctly
volume used within 2% of supervisor’s
1(c) yellow / orange to red
1(d) bubbles / fizzing / effervescence
I gas given off
1(e) Experiment 2
1(f) effect on volume used: none
reason: no change in concentration
1(g)(i) 2 : 1 (answer to nearest whole numbers)
1(g)(ii) 1 : 2 (answer to nearest whole numbers)
A ECF from (g)(i)
1(h) rinse burette
with solution B
1(i) (repeat until) similar results obtained
calculate mean of similar results
2(a) solid C: green AND solid D: white
 2023 May/June variant 2

Question Answer Marks

2(a) M1 final and initial readings completed correctly. 3

M2 volume used completed correctly.

M3 all readings to 1 decimal place

2(b) final and initial readings and volume used completed correctly. 1

2(c) to enable the colour change / end-point to be observed more accurately 1

2(d) 15.1 cm3 and 34.8 cm3 1

2(e) M1 0.5  15.1 / 1000 = 0.00755 2
M2 0.302 correct to 3 sig. fig.
Question Answer Marks

2(f) M1 0.00755 (mol) 2

M2 0.18(1) dm3

2(g) 0.418 / 0.42 dm3 1

2(h) Any two from: 2

Some water remains in burette
Hydrochloric acid is diluted
The volume needed for titration is greater / reading on burette is greater

2(i) Does not have a clear end-point / the colour change would not be as clear 1