CF & Second Step for JEE (Main & Advanced)-2021 E-CAPS : 12 (Chemistry)

CF & SS
JEE (Main)

CF & Second Step for JEE (Main & Advanced)-2021

E-CAPS-12 : CHEMISTRY
(Engineering-Classroom Assessment Practice Sheet)
Topics covered: Introduction; Rates of Chemical Reaction: (i) Rate, (ii) Average and Instantaneous Rate,
(iii) Law of Mass Action, (iv) Rate Law or Rate Equation of a Reaction, (v) Units of Rate of a Reaction, Order and
Molecularity. Integrated Rate Law: (i) Zero Order, (ii) First Order, (iii) Half-life, (iv) nth order, Graphical Method.

Choose the correct answer:

1. 2NO + 2H2  N2 + 2H2O. 5. The rate expression for reaction A (g) + B (g) 
The experimental rate law for above reaction is, C (g) is rate = k [A]1/2 [B]2. What change in rate
Rate = k [NO]2 [H2]. When time is in minute and if initial concentration of A and B increase by factor
the concentration is in mole/L, the units for k are
4 and 2 respectively?
mole3 mole (1) 4 (2) 6
(1) (2)
L3 min. L min.
(3) 8 (4) None of these
mole2 L2 6. Reaction A  B follows second order kinetics,
(3) (4)
L2 min. mole2 min. doubling the concentration of A will increase the
2. The differential rate law equation for the elementary rate of formation of B by a factor of
K
reaction A + 2B   3 C, is
1
d[A] d[B] d[C] (1)
4
(1)    = k[A][B]2
dt dt dt
d[A] 1 d[B] 1 d[C] 1
(2)    = k[A]2[B] (2)
dt 2 dt 3 dt 2
d[A] 1 d[B] 1 d[C]
(3)    = k[A][B]2 (3) 2
dt 2 dt 3 dt
(4) None of these (4) 4
3. For the reaction A  C + D, the initial 7. For the reaction 2NO2  N2O2 + O2, suppose
concentration of A is 0.01 M. After 100 s, the
concentration of A is 0.001 M. The rate constant of d[NO2 ]
the reaction has the numerical value of 9.0. What  = K[NO2]n, where K = 3 × 10–3 mol–1 L
dt
is the unit of the reaction rate constant?
sec –1 . If the rate of formation of oxygen is
(1) M–1s–1 (2) Ms–1
1.5 × 10 –4 mol L –1 sec –1 , then the molar
(3) s–1 (4) M–1.5s–1
concentration of NO2 in mole L–1 is
4. Which of the following statement is incorrect?
(1) 1.5 × 10–4
(1) Unit of k for first order is M–1s–1
(2) Unit of rate of reaction is Ms–1 (2) 0.0151
(3) Unit of rate constant k depends on order of (3) 0.214
reaction
(4) Unit of k for first order reaction is Ms–1 (4) 0.316

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E-CAPS : 12 (Chemistry) CF & Second Step for JEE (Main & Advanced)-2021

8. Decomposition of Hl(g) on Gold surface is zero (3) Molecularity of any reaction is generally  4
order reaction. Initially, few moles of H2 are present
(4) Molecularity of complex reaction has no
in container then which of the following graph is
correct? significance
12. From the following select the incorrect graph of t1/2
(half life) Vs a0(initial concentration of reactant)
[reaction : A  Products]
(1) PH2 (2) PH2

time time
(1) t1/2 (2) t1/2
Zero order First order

a0 lna0
(3) PH2 (4) PH2

time time
(3) t1/2 (4) t1/2 First order
Second order
9. A first order reaction is 75% completed in
100 minute. How long time will it take for its 87.5% 1/a0 a0
completion?
13. Consider the reaction : 3A  Products
(1) 125 minute (2) 150 minute If the concentration of A decreases from 1.8 M to
(3) 175 minute (4) 200 minute 1.2 M in 20 minutes. The average rate of reaction
during this interval is
10. For the zero order reaction A  B + C; initial
concentration of A is 0.1 M. If A = 0.08 M after (1) 0.03 M min–1 (2) 0.02 M min–1
10 minute, then its half-life and completion time are (3) 0.01 M min–1 (4) 0.06 M min–1
respectively: 14. The half-life of a first order reaction is 69.3 seconds.
(1) 10 minute; 20 minute The value of rate constant of the reaction in s–1 is
(2) 2 × 10–3 minute, 10–3 minute _______.

(3) 25 minute; 50 minute
(4) 250 minute; 500 minute
11. From the following select the correct statement
(1) Molecularity of elementary reaction has no
significance
(2) Molecularity of complex reaction is equal to
the molecularity of the slowest elementary
reaction
15. The rate of a gaseous reaction is given by the
expression K[A][B]. If volume of the reaction vessel
1
is suddenly reduced to th of the initial volume, the
4
ratio of reaction rate to the original rate will be_____.
16. Hydrogenation of vegetable oil at 25°C reduces the
pressure of H2 from 2 atm to 1.2 atm in 40 min.
Calculate the average rate of disappearance of H2 in
terms of pressure per minute.

ˆ ˆ ˆ

Aakash Educational Services Limited - Regd. Office: Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456
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 CF & SS
JEE (Main)

CF & Second Step for JEE (Main & Advanced)-2021

E-CAPS-12 : CHEMISTRY
(Engineering-Classroom Assessment Practice Sheet)
Topics covered: Introduction; Rates of Chemical Reaction: (i) Rate, (ii) Average and Instantaneous Rate,
(iii) Law of Mass Action, (iv) Rate Law or Rate Equation of a Reaction, (v) Units of Rate of a Reaction, Order and
Molecularity. Integrated Rate Law: (i) Zero Order, (ii) First Order, (iii) Half-life, (iv) nth order, Graphical Method.

ANSWERS

1. (4) 2. (3) 3. (1) 4. (4) 5. (3)

6. (4) 7. (4) 8. (2) 9. (2) 10. (3)
11. (4) 12. (2) 13. (3) 14. (0.01) 15. (16)

16. (0.02)

HINTS & SOLUTIONS

3. Answer (1) d
– [NO2 ] = 2 × 1.5 × 10–4
For second order, dt

1 1 1  = 3 × 10–4
–
t  A A 0  = k
 = K[NO2]2
3 × 104 = 3 × 10–3[NO2]2
1
1000 – 100 = 9 [NO2]2 =
1
100 10
2nd order rate constant. [NO2] = 0.316
7. Answer (4) 10. Answer (3)
Given expression,
–[0.08 – 0.1] 0.02
Zero order Rate = k = =
–d 10 10
[NO2 ] = K[NO ]n ...(i)
dt 2
A0
t1/2 =
From units of constant it is second reaction. 2k
We know, 0.1  10
= = 25 min.
2  0.02
1 d d
– [NO2 ] = [O ]
2 dt dt 2
C0 0.1  10
Completion time = = 50 min.
= 1.5 × 10–4 k 0.02

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E-CAPS : 12 (Chemistry) CF & Second Step for JEE (Main & Advanced)-2021

11. Answer (4) 15. Answer (16)

Molecularity of complex reaction has no significance x x 

r  K[A][B]  K    
VV
12. Answer (2)
1
If volume is reduced to
For 1st order reaction half life is independent of initial 4
concentration.
 x  x   x  x 
13. Answer (3) r   K     16 K   
V V  V  V 
1   A    
Average Rate of reaction =  4  4 
3 t

1 1.2  1.8  0.6 16 times

=  = = 0.01 M min–1
3 20 3  20 16. Answer (0.02)
14. Answer (0.01)
change in pressure 2  1.2
Rate  
0.693 0.693 1 time in min 40
K    0.01 s1
t 1/2 69.3 100  2.0  102 atm min1

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Edition: 2020-21