NCERT-DECODE SERIES

CHEMICAL KINETICS
1. For a first order reaction, t99% = y × t99.90%, 9. In presence of catalyst, heat evolved or
Find value of y. absorbed during reaction on -
1 2 4 (1) Decreases
(1) (2) (3) 3 (4)
3 3 3 (2) Increases
2. The value of rate constant of a pseudo 1st (3) Remains unchanged
order reaction.
(4) May increase or decrease
(1) Depends on the concentration of
10. Which of following statements is incorrect
reactant present in excess.
about the collision theory of chemical
(2) Depend on the concentration of reactant
reaction ?
present in a small amount.
(3) Independent of concentration of reactant. (1) The collision of atoms or molecules
(4) Depends only on temperature. possessing sufficient threshold energy
3. Which of following factor changes with results into product formation.
catalyst. (2) Molecules should collide with sufficient
(1) Gibbs energy of reaction threshold energy and power.
(2) Enthalpy of reaction (3) It considers reacting molecules or atom to
(3) Activation energy of reaction be hard spheres and ignores their
(4) Equation constant structural features.
4. A 1st order reaction takes 40 min for 30%
(4) A number of effective collisions
decomposition calculate t1/2 = ?
determine the rate of reaction.
(1) 84.3 min (2) 75.32 min
11. An Elementary reaction is given below-
(3) 45.3 min (4) 42 min
A + B ⎯→ 2P + 7Q
5. The rate constant of a reaction at 500K &
700K are 0.03 s–1 and 0.09 s–1. Calculate value Find the order of reaction
of Ea in kJ mol–1. (1) 1 (2) 1.5 (3) 2 (4) zero
(1) 16.08 (2) 19.21 12. Consider a reaction A ⎯→ B with
(3) 14.59 (4) 10.90 K = 2.5 × 10–2s–1, calculate the concentration
6. The rate of reaction quadruples when of a remaining after 200 s, if initial
temperature charges from 273 to 293K. If concentration of A is 1 mol L–1
initial rate is 3.2×102Ms–1, final rate is- (1) 6.2 × 10–5 (2) 6.7 × 10–3
(1) 6.4×102 (2) 7.8×102
(3) 5.3 × 10–2 (4) 4.7 × 10–2
(3) 9.5×102 (4) 12.8×102
13. Activation energy is given by ?
7. A reaction is 1st order in A and 2nd order in B,
(1) Always equal to energy of product
write differential rate equation ?
molecules
(1) R=K[A][B] (2) R=K[A]1/2[B]
(3) R=K[A][B]2 (4) R=K[A]2[B] (2) The energy difference between activated
8. The time required for 10% completion of 1st complex and the energy of reactant
order reaction at 298 is equal to that required molecules.
to 25% completion at 318K. If value of A is (3) Always Equal to energy of reactant
2.8×1010s–1. Calculate Ea. molecules.
(1) 39.91 KJ mol–1 (2) 78.32 KJ mol–1 (4) Summation of threshold energy and
(3) 30.07 KJ mol–1 (4) 92.37 KJ mol–1 energy of product molecules

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14. The slope between log (a-x) vs t graph for 1st 15. For 3rd order reaction, unit of rate constant
order reaction is :- (K) is given by :-
(1) –K (2) –2.303 K (1) (mol L–1)–1 Time–1
K K (2) (mol L–1)–2 Time–1
(3) (4) −
2.303 2.303 (3) (mol L–1)0 Time–1
(4) (mol L–1)2 Time–1

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 NCERT-DECODE SERIES
ANSWER KEY
Question 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Answer 2 2 3 2 1 4 3 1 3 1 3 2 2 4 2
SOLUTIONS

1. Ans. (2) 6. Ans. (4)

2.303 A r1 = K[A]n
t 99% = log 0 (log100 = 2)
K At after changing temperature
2.303 100 2.303 r2 = 4 × r1
= log = 2 ...(1)
K 1 K r1 = 3.2 × 102 Ms–1
2.303 100 2.303 r2 = 4 × 3.2 × 102 Ms–1
t 99.9% = log  3 …(2)
K 0.1 K
= 12.8 × 102 Ms–1
(log1000 = 3)
7. Ans. (3)
t 99% 2 2
= y= r = K[A]1[B]2
t 99.9 3 3
8. Ans. (1)
2. Ans. (2) For 1st order reaction
Depends on the concentration of reactant
present in smaller amount. 2.303 a
t= log
3. Ans. (3) K a−x
Lowering the activation energy. 2.303 100 0.1054
At 298 K, t1 = log =
4. Ans. (2) K 90 K1
t30% = 40 min
2.303 100 2.303 100 0.2877
t30% = log At 318K, t2 = log =
K 100 − 30 K 75 K2
2.303 100 Now according to question ; t1 = t2
K= log
40 70 0.1054 0.2877
2.303 =
K= (log10–log7) K1 K2
40
K2
2.303 2.303 = 2.7296
K= (1–0.84)   0.16 K1
40 40
0.693 from Arrhenius equations
t 50% =
K K  Ea  T2 − T1 
log  2  =  
0.693  40  K1  2.303  R  T1T2 
t50% = = 75.32 min
2.303  0.16
5. Ans. (1)
Ea  318 − 298 
log(2.7296) =
2.303  8.314  298  318 
K  Ea  1 1 
log  2  =  −  2.303  8.314  298  318  log(2.7296)
 K1  2.303R  T1 T2  Ea =
318–298
 0.09  Ea  1 1 
log   =  −  = 39.918 J mol–1  39.918 KJ mol–1
 0.03  2.303  8.314  500 700 
Ea 200 9. Ans. (3)
log3 = 
2.303  8.314 500  700 Catalyst will only lower the required
0.48  2.303  8.314  500  700 activation.
Ea = = 16,083.59 Jmol−1
200 Energy for the reaction. So the not change in
−1
= 16.08 kJ mol enthalpy is zero.

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10. Ans. (1) 13. Ans. (2)
The collision of atoms or molecules The energy difference between activated
possessing sufficient threshold energy results complex and the energy of reactant
into product formation. molecules.
11. Ans. (3) 14. Ans. (4)
r = K[A]1[B]1
Order = 1 + 1 = 2 log (a-x) –K/2.303
log a
12. Ans. (2)
t
2.303  a  2.303 A 
K= log   or log  0  K
t a−x  t  At  log (a-x) = log a − t
2.303
2.303  1.0  15. Ans. (2)
2.5 × 10–2 = log  
t  (a − x)  [mol/L]1-n Time–1
[mol/L]1-3 Time–1
 1.0  2.5 10–2  200
log  = [mol/L]–2 Time-1
 At  2.303
 1.0 
log   = 217.10 × 10–2
A
 t 
(At) = 6.7×10–3 M sec–1

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