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Yakeen NEET 2.0 (Alpha)

Chemical Kinetics DPP-01

1. For a gaseous reaction, the rate of reaction may be 6. For the reaction A + B → Products, it is observed
expressed in the units: that
(1) atm (2) atm s I) On doubling the initial concentration of A only,
(3) atm/s (4) atm/s2 the rate of reaction is also doubled and
II) On doubling the initial concentration of both A
2. In a reaction, 2X + Y → X2Y, the X disappears at: and B, there is a change by a factor of 8 in the
(1) Half the rate as that of disappearance of Y rate of the reaction.
(2) The same rate as that of disappearance of Y The rate of this reaction is given by:
(3) The same rate as that of appearance of X2Y (1) Rate = k [A] [B]2
(4) Twice the rate as that of appearance of X2Y (2) Rate = k [A]2 [B]2
(3) Rate = k [A] [B]
3. For the reaction N2 + 3H2 → 2NH3, the rate of (4) Rate = k [A]2 [B]
change of concentration for hydrogen is
–0.3 × 10–4 Ms–1. The rate of change of 7. The rate of a reaction is expressed as
concentration of ammonia is: 1 [C] 1 [D] 1  [A]   [B] 
+ = = − = −
(1) –0.2 × 104 (2) 0.2 × 10–4 2 t 3 t 4  t   t 
–4
(3) 0.1 × 10 (4) 0.3 × 10–4 Then reaction is:
(1) 4A + B → 2C + 3D
4. For the given reaction:
(2) B + 3D → 4A + 2C
N2 + 3H2 → 2NH3
(3) A + B → C + D
Rate of formation of ammonia is 2 × 10–4 mol. L–1 s–
1 (4) B + D → A + C
then find rate of disappearance of hydrogen?
(1) 3 × 10–4 mol. L–1 s–1
8. For a reaction A + B → products, the rate of reaction
(2) 2 × 10–4 mol. L–1 s–1
was doubled when concentration of A was doubled.
(3) 4 × 10–4 mol. L–1 s–1
When concentration of A and B both was doubled,
(4) 6 × 10–4 mol. L–1 s–1
the rate was again doubled, order of reaction w.r.t. A
and B are:
5. In the reaction:
(1) 1, 1
BrO3− (aq) + 5Br–(aq) + 6H+ → 3Br2(I) + 3H2O(I) (2) 2, 0
The rate of appearance of bromine (Br2) is related to (3) 1, 0
rate of disappearance of bromide ions as following. (4) 0, 1
d(Br2 ) 5 d(Br − )
(1) =−
dt 3 dt 9. The overall order of reaction between X & Y is 3.
d(Br2 ) 5 d(Br − ) Which of the following rate equation must be
(2) =
dt 3 dt correct, if on doubling the concentration of X, the
d(Br2 ) 3 d(Br − ) rate of reaction gets doubled?
(3) = (1) r = K[X]2 [Y]0
dt 5 dt
(2) r = K[X]1[Y]2
d(Br2 ) 3 d(Br − )
(4) =− (3) r = K[X]1[Y]3
dt 5 dt
(4) r = K[X]2[Y]1
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10. For a reaction between A and B the order with (1) K2 = 2K1 and K3 = ½K1
respect to A is 2 and the order with respect to B is 3. (2) K1 = 2K2 and K3 = 2K1
The concentrations of both A and B are doubled, the (3) K1 = K2 = K3
rate will increase by a factor of: (4) K1 = 2K2 = 3K3
(1) 12 (2) 16
(3) 32 (4) 10 15. N2O5 decomposes are as follows:
1
N2O5 → 2NO2 + O2
11. Which one of the following statements for the order 2
of a reaction is incorrect? d[N2O5 ]
(1) Order can be determined only experimentally. If, – = k1[N2O5 ];
dt
(2) Order is not influenced by stoichiometric
d[NO2 ]
coefficient of the reactants. = k 2 [N2O5 ];
dt
(3) Order of a reaction is sum of power to the
d[O2 ]
concentration terms of reactants to express the = k3[N2O5 ];
rate of reaction. dt
(4) Order of reaction is always whole number. Which one of the following is correct for k1, k2 and
k3?
12. The rate of reaction between two reactants A and B (1) k1 + k2 = k3
decreases by a factor of 4 if the conc. of reactant B is (2) k1 = k2 + k3
doubled. The order of this reaction with respect to (3) k1 = 2k2 + ½K3
reactant B is: (4) 2k1 = k2 = 4k3
(1) 2 (2) –2
(3) 1 (4) –1 16. Consider the reaction: 2N2O4 ⇌ 4NO2
d[N2O4 ] d[NO2 ]
If − = k and = k ' then
13. For the reaction A + B → products, it is observed dt dt
that (1) 2k’ = k
(i) on doubling the initial concentration of A only, (2) k’ = 2k
the rate of reaction is also doubled and (3) k’ = k
(ii) on doubling the initial concentration of both A 1
(4) k = k’
and B, there is a change by a factor of 8 in the 4
rate of the reaction.
The rate of this reaction is given by: 17. For the reaction H2(g) + Br2(g) → 2HBr(g), the
(1) rate = k[A] [B]2 experimental data suggests, Rate = K [H2] [Br2]1/2.
(2) rate = k[A]2 [B]2 The order for this reaction is:
(3) rate = k[A] [B] 1
(4) rate = k[A]2 [B] (1) 2 (2) 1 2
1
14. Dinitrogen pentaoxide decomposes as (3) 1 (4) 2 2
2N2O5 → 4NO2 + O2
The rate can be given in three ways 18. Order of reaction can be:
–d[N2O5 ] d[NO2 ] (1) 0
= K1[N2O5], = K2[N2O5],
dt dt (2) Fraction
d[O2 ] (3) Whole number
= K3[N2O5] (4) Integer, fraction, zero
dt
The relation between the rate constant K1, K2 and K3
is:
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19. The order of a reaction is said to be 2 with respect to d  A

= k1 A ;
2
a reactant X. when: 20. For the reaction 2A → B + 3C; if −
dt
(1) The rate of the reaction is proportional to
d B 2 d C
= k 2  A ; = k3 A the correct relation
2
[X]
dt dt
(2) The rate of the reaction is proportional to
between k1, k2 and k3 is:
[X]2
(1) k1 = k2 = k3
(3) Two molecules of X are present in the
stoichiometric equation (2) 2k1 = k2 = 3k3
(4) The reaction occurs in two steps. (3) 4k1 = k2 = 3k3
k1 k
(4) = k2 = 3
2 3
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (3) 11. (4)
2. (4) 12. (2)
3. (2) 13. (1)
4. (1) 14. (1)
5. (4) 15. (4)
6. (1) 16. (2)
7. (1) 17. (2)
8. (3) 18. (4)
9. (2) 19. (2)
10. (3) 20. (4)

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