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Yakeen NEET 2.0 (Alpha)

Chemical Kinetics DPP-03

1. Consider the following in respect of zero order 7. The graph of t1/2 versus initial concentration ‘a’ is
reaction. for
I. t1/2 is directly proportional to the initial
concentration.
II. Time taken for the completion of the reaction
is twice its t1/2
III. Concentration of the reactant decreases (1) First order (2) Second order
linearly with time (3) Zero order (4) Can’t predict
Which of the statements given above are correct?
(1) I & II only (2) I & III only 8. For a reaction, A → B, it has been found that the
(3) II & III only (4) I, II & III order of the reaction is zero with respect to A.
Which of the following expressions correctly
describes the reaction?
2. If initial concentration is reduced to 1/4th in a zero
2.303 [A ]
order reaction, the time taken for half the reaction (1) K = log 0
to complete t [A]
(1) Remains same (2) [A]0 – [A] = Kt
(2) Becomes 4 times 0.693
(3) t1/ 2 =
(3) Becomes one-fourth K
(4) Doubles 1
(4) t1/ 2 
[A]0
3. If initial concentration of the reactants is doubled,
the time for half reaction is also doubled, the order 9. A sample of a radioactive substance undergoes
of the reaction is 80% decomposition in 345 minutes. Its half-life is
(1) Zero (2) One ______ minutes.
(3) Two (4) Three ln 2 ln 5
(1)  345 (2)  345
ln 5 ln 2
4. For a 1st order reaction, a straight line is obtained if ln 5 ln 4
you plot (3)  345 (4)  345
(1) Log conc. Vs. time ln 4 ln 5
(2) Conc. vs. time 10. 99% of a first order reaction, was completed in 32
(3) 1/conc. vs. time minute. When will 99.9% of the reaction
(4) Log conc. vs. 1/time complete?
(1) 50 minute (2) 46 minute
5. A substance (initial concentration ‘a’) reacts (3) 49 minute (4) 48 minute
according to zero order kinetics. The time it takes
for the completion of the reaction is 11. A first order reaction is 50% completed in
1.26 × 1014 s. How much time would it take for
a a 100% completion?
(1) (2)
k 2k (1) 1.26 × 1015 s (2) 2.52 × 1014 s
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k 2k (3) 2.52 × 10 s (4) Infinite
(3) (4)
a a 12. A first order reaction has a specific reaction rate of
10–2 sec–1. How much time will it take for 20 g of
6. Which order reaction obeys the expression the reactant to reduce to 5 g?
t1/2  1/[A] ? (1) 138.6 sec (2) 346.5 sec
° (3) 693.0 sec (4) 238.6 sec
(1) First (2) Second
(3) Third (4) Zero
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13. The decomposition of phosphine (PH3) on tungsten 19. The rate constant for a first order reaction is
at low pressure is a first order reaction. It is because 4.606 × 10–3 s–1. The time required to reduce 2.0 g
the of the reactant to 0.2 g is
(1) Rate is proportional to the surface coverage (1) 100 s (2) 200 s
(2) Rate is inversely proportional to the surface (3) 500 s (4) 1000 s
coverage
(3) Rate is independent of the surface coverage 20. A chemical reaction involves two reacting species.
(4) Rate of decomposition is very slow. The rate of reaction is directly proportional to the
concentration of one of them and inversely
14. The rate constant of the reaction proportional to the concentration of the other. The
A → B is 0.6 × 10–3 mol. L–1 s–1. If the order of reaction is:
concentration of A is 5 M, then concentration of B (1) 1
after 20 minute is (2) 2
(1) 3.60 M (2) 0.36 M (3) Zero
(3) 0.72 M (4) 1.08 M (4) Unpredictable

15. A reaction is 50% complete in 2 hours and 75% 21. For the reaction H2(g) + Br2(g) → 2HBr(g), the
complete in 4 hours. The order of reaction is experimental data suggests, Rate = K [H2] [Br2]1/2.
(1) 1 (2) 2 The order for this reaction is:
(3) 3 (4) 0 1
(1) 2 (2) 1 2
16. If 60% of a first order reaction was completed in 60 1
minutes, 50% of the same reaction would be (3) 1 (4) 2
2
completed in approximately
(log 4 = 0.60, log 5 = 0.69)
22. For the chemical reaction
(1) 45 minutes
5Br–+ BrO3– + 6H+ → 3Br2 + 3H2O
(2) 60 minutes
(3) 40 minutes Rate = k[Br–][BrO3–][H+]2
(4) 50 minutes The molecularity and order of reaction with
respect to [Br–] is
17. In a first-order reaction A → B, if k is rate constant (1) 5, 1 (2) 1, 5
and initial concentration of the reactant A is 0.5 M, (3) 1, 1 (4) 6, 2
then the half-life is
log 2 23. Which is incorrect
(1)
k (1) Half-life of a first order reaction is independent
log 2 of initial concentration
(2)
k 0.5 (2) Rate of reaction is constant for first order
ln 2 reaction
(3) (3) Unit of K for second order reaction is Mol–1 lit
k
0.693 sec–1
(4) (4) None
0.5k

18. For a first-order reaction, the half-life period is 24. 75% of a first order reaction was found to complete in
independent of 32 min. When will 50% of the same reaction complete –
(1) First power of final concentration (1) 24 min
(2) Cube root of initial concentration (2) 16 min
(3) Initial concentration (3) 8 min
(4) Square root of final concentration (4) 4 min
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27. Which of the following curves represents a 1st order

25. The rate constant for a first order reaction whose half- reaction
life is 480 sec:
(1) 1.44 × 10–3 sec–1 (1)
(2) 1.44 × sec–1
(3) 0.72 × 10–3 sec–1
(4) 2.88 × 10–3 sec–1

26. Which of the following represents the expression for

3 (2)
th life of first order reaction?
4
k 4
(1) log
2.303 3
2.303 3
(2) log
k 4 (3)
2.303
(3) log 4
k
2.303
(4) log 3
k (4) 1 and 3 both

28. In a first order reaction, the concentration of

reactant, decreases from 0.8 M to 0.4 M is 15
minutes. The time taken for the concentration to
change from 0.1 M to 0.025 M is
(1) 7.5 min (2) 15 min
(3) 30 min (4) 60 min
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (4) 15. (1)
2. (3) 16. (1)
3. (1) 17. (3)
4. (1) 18. (3)
5. (1) 19. (3)
6. (2) 20. (3)
7. (1) 21. (2)
8. (2) 22. (1)
9. (1) 23. (2)
10. (4) 24. (2)
11. (4) 25. (1)
12. (1) 26. (3)
13. (1) 27. (4)
14. (3) 28. (3)

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