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LAKSHYA JEE AIR (2025)

Chemical Kinetics DPP-02

SINGLE CORRECT QUESTIONS

k = 0.1M min−1 4. If decomposition reaction A(g) → B(g) follows
1. Consider a reaction A(g) ⎯⎯ ⎯ ⎯ ⎯→ 2B(g) . If
first order kinetics then the graph of rate of
initial concentration of A is 0.5M then select
formation (R ) of B against time t will be:
correct graph.

(1) (2)
(1) (2)

(3) (4)
(3) (4)

5. Consider the plots, given below, for the types of

reaction
2. Decomposition of NH 4 NO 2 (aq) into N 2 (g) and nA → B + C

2H 2 O(l) is first order reaction. Which of the

following graph is correct?

These plots respectively correspond to the reaction

(1) (2) orders:
(1) 0, 1, 2
(2) 1, 2, 0
(3) 1, 0, 2
(4) None of these

(3) (4) 6. What will be the order of reaction for a chemical

change having log t1/2 vs log a ? (where a = initial
concentration of reactant; t1/2 = half-life)

3. Consider the plots for the types of reaction

nA → B + C

(1) Zero order

These plots respectively correspond to the reaction (2) First order
orders: (3) Second order
(1) 0, 2, 1 (2) 0, 1, 2 (4) None of these
(3) 1, 1, 2 (4) 1, 0, 2
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7. In the reaction A → B + C , rate constant is 12. For the reactions

0.001M s −1 . If we start with 1 M of A then (i) A ⎯⎯KI
→P
(ii) B ⎯⎯→ Q , following observation is made.
K II

concentration of A and B after 10 minutes are

respectively:
(1) 0.5M, 0.5M (2) 0.6M, 0.4M
(3) 0.4M, 0.6M (4) none of these

−1
k r = 0.6M min
8. For a reaction A ⎯⎯ ⎯ ⎯ ⎯⎯ → 2B KI
Calculate , where KI and KII and rate constant
starting with 1 M of 'A' only, concentration of B K II
for the respective reaction.
(in M) after 100 sec. and 200 sec. is respectively?
(1) 2.303 (2) 1
(1) 2 and 4 (3) 0.36 (4) 0.693
(2) 1 and 2
13. Two first order reaction have half-lives in the ratio
(3) 2 and 3
8 : 1. Calculate the ratio of time intervals t1 : t 2 .
(4) None of these th
1
The time t1 and t 2 are the time period for  
4
9. For the zero order reaction A → B + C , initial th
3
concentration of A is 0.1 M. If [A] = 0.08M after and   completion.
4
10 minutes, then its half-life and completion time (1) 1 : 0.301 (2) 0.125 : 0.602
are respectively: (3) 1 : 0.602 (4) None of these
(1) 10 min, 20 min
14. Reaction A+B→C+D follows rate law,
–3 –3
(2) 2×10 min, 4 × 10 min r = k[A] [B] . Starting with 1 M of A and B
1/2 1/2

(3) 25 min, 50 min each, what is the time taken for concentration of A
become 0.1 M?
(4) 250 min, 500 min
[Given : k = 2.303  10 −2 sec −1 ]
(1) 10 sec (2) 100 sec
10. A first order reaction is 75% completed in 100 (3) 1000 sec (4) 434 sec
minutes. How long time will it take for its 87.5%
15. For the two reactions I : A → B; II : C → D
completion? following graph is obtained.
(1) 125 min (2) 150 min
(3) 175 min (4) 200 min

11. Rate constant k = 2.303 min −1 for a particular

reaction. The initial concentration of the reactant is
1 mol / litre then rate of reaction after 1 minute is: Which of the following is true?
(1) 2.303 M min −1 (1) If [B] = [A] then at that time [D] = 0.75M
(2) If [C] = [A] then at that time [B]  [D]
(2) 0.2303 M min −1
(3) ( t100% ) Reaction I = ( t100% ) Reaction II
(3) 0.1 M min–1
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(4) none of these (4) [A] = [C] at t = min .
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Answer Key
1. (3) 9. (3)
2. (4) 10. (2)
3. (4) 11. (2)
4. (3) 12. (4)
5. (3) 13. (3)
6. (1) 14. (2)
7. (3) 15. (1)
8. (4)

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