n b

Csystollizalion PAGE NO.

DATE:

arsameteis mpin caysdalllzaHon

DCoystal stsuctuse
Yaatcle SIzeshapeappeonance
ssaluxlen Reveise af issoluton
EnthalryLnesq assoclated
sAunity
6Concentsatton
7 Meling poin (In ase ot MP cystalizathon)
Wates ot cnystallization
Sasoluten solub1l
Mf(k)
-Cheso 304
16 2 85

CDeso T5 38

O-xjlene 248
m-ylene 412 225
P-xylene 4 236

Fo sepasaticn-o this mixtuxe distilaton can_

be used But as dttesence A 8Pis low, yalue of
o i l l _he la no: oSHps jacsease This caus
incaease in equisement_and in tuan
Cos hus distllatien is less _efiective hexe
solids
Casatoli zaion

Waahin}
ML
Moha uquo
 PAGE NOO.
DATE

Caystalization can be hatch os Continuos

Ancha amlatos clase cle arßance impelle

a T
iosminqon the dalls, heat Kansies e-ftr
is eduCed Lo Ais
by scsapnq t
seactox Scalina is avcide
sshds attached tor ual_

Solubility Maximum amountot solute that car

be dissolved in a Ca
sollent> Homogeno iqud
FeA
FesOu
/ kclo3_
ka solute
ookq ales

Gatusohon Soluian io equillibaium with uD

Solule

SupessatusatiorD canc highe thoo 5aubbi l i t

tqen T
Tt _drsiviaq05a ioK C&ystalzation-
 w
DAIR

NaC
Mius o joc
Kq satuk n)
5,01vent

T
cbtaun atse Nac coystals
To
Cvaposatnqsadvent 33Nca
ndroarohe (ponet 11tt
Cocho9 hep o 5at ou tue

Supesatursakd

S
E

1o kg solvent
B
T

mcpeT)
A8 CoohDq
A DE Fyapobahicn(S: mA
 PAGE NO.
DATE:
suferssdrsadtoo

M a s a k

Vnsab)e.
Cenc o
Soute.
Stable
Zone

A Nucleatica
To stast the cystalizahoni, a
oohith pastHcley attach and fom nu.cley is T
H
Spontaneo No seeolina is eeLuised.
Bejond metaetable 2one uns table
20ne) spante
nucleatien take place.
2) Noa-spanBaneay When We have to
adelcextie
Coustals ot same makesia (seadinq) o shant
CAystalkizaton /Nueleakon Seedinq_needsn
dene io metasable Zone
LRaleo ystalliaahen)-
ast Slo Cystallization- coolinq
Fast Slo
Monenucder lem nude
Small s i e biq sizL
CAs it is cooled iasles,_
cystals as tosmed
hut thesL is less ime
fo qodth of cyslal
 PAGE NOp.

DATE
H o m n o g e n o u s
on
n u c l e a t o n

Nucle a Omed
t O h e saluhon

need helesoo
heksoqeno
us_ NNuclei
die Suara
Hekoqeno

d) sidesof thevesse/aqitaBox
Avaid helesogenou nucleatio

Vse ot sCiapess

Tncseasethe
hespeed ct agiiatos:
ceslan
ma nucleatlon -Nude ase osmed as
toehes:_Dfha need et extesnal
mass comes
Such shea 0qitatpn
achoss
Secondasy nucleaHon s h Eernal fosce is Seqused
to nucleatian-

3ystzd Griot
-e6stae
CA

Conc

Abulk conc in
liqud
C1nkrit ace ConC
Conc_of ot satusated
sauHen,
esheld be Conc. ateren toK maK a l e s to
hoen
 PAGE NO.
DATE: |

Dusidn ConVective makstKansteK om bu

to Sustace.

|DepaiHod Sutac de inltgsadion of saut

CA- C appaseot
supessatusatio
CA- Cg concents cuhion
anse ditfeintaresponsibleokon ma
CgC Concdttesence eaised o oveKcDe
Kesistante a inkestate

dM DA LCACce
ot

2) M kACB-Cs

A Suxtaco Asea o custals.

D Dittusivik
M Mass ot makesial depsiltd
sg Hhicknes b in time
mass atu laye
layei
Eliminale Ce om @
ACCA ACas
CA&Q) =K C-Ls
 DACCA Cs)
S8 D PAGE NO.

CA C6): EAG8r_kACDATE
QAN kAt DA.
CeKiC DA_CA
dM DA CA kACst CAA
dt kA+ DA
DA KACA tCA DA k 0A CA
OB
KA DA
A K: A_CA Cs
k: A D:A

DAk CCA-Cs)
K tDD_

A A k AkA CB-k AC
C A DA = 12A CA tA L

M D.A CA- M Cs
di kA
DA DA CA C s )
k 68
DA CACs J

dM
DAKCa -Cs)
 PAGE NO.
DATE:
Yield ot Caystals
W 1niha mass oSoluent
w tnal mas of salvene
yield ct cxsta
R=Mw_hdate
MW otanhjdKauy

Mass s solvent evaposaBtd

Mass ot inia ssiveot
oital Conc of sstution
Lnital mass o anhydou
Mass of sslvt
C = inal_conc: o soluHian
to SalenB dalei)

) | w=Wt9 (R-L + wE
Tital ina watt of Wett ost in
LaAt ma
Chstalizokin cAAtlahisn

R
Eliminate

w C (R-1)+ Wt
RC2
 PACE NO.
DATE
CR-1
C - wE
E

y CR-1)
RC

C2 (R-1 1C
R L C2 ( E) C
C C8-1) 2
wRLC C-E) -
200X 2 26
C2 (R):1 o O39 (1-o o2)-02
C CatcE 0 o13(1. 26)- 1
y wR
7

SA soln ot Soo kaNa, S04 10 2500 kqin lDot

s is Cooled fínm 333 k o 283 K hs pxocess
sisdone in _an_agitatd veneof majs ZO Ea
LPSe= 0:KTk K At 283 k, the stablk
OStCline phase is Nag50 0 HO-
LpLsluhep) 6 KIk K 1 duinq #psace
ass of laBeis1t by evaparatHon
atield_of cutols haat to be semaved
Saubilha i ankdsau salt at 283 k is 9:4
OD ka
udolt andHeat solsol 78S00 ET|Ese
2S00 kq Mw:of anhydsow
24SO
Mo E
ka.
sAe
eYap oKattd SO_ f: 0**
Mas of inta 2 SOO
31

2 CESoo
2

26 o 89
89 s
-0
2 C2 10Og
 Suok cal
PAGE NO.
DATE:
2 00 2960 0039 0'02
0 09922G-090
717: GR8 ka
Heat Meeds to_beKemoved fsom-
Cooin SoluHan CSo042s00)x 3:6x SO= Su0000 K
T Coolidlg.Vesse) 7So OS*SO= 137O
-fhesgylkE Waes eNaposahio = mX2 00 x T
240
CastadlizahBon:18S0OA 00
322.
12 00
17504O me

heat xemoved 2 Shoooot 187SO -

13000170
C267go kT
620 7K\o3 kT
Hw :|Assu o eiapohahion i noh happenin
otqJen TA