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  • Isomersim Part 1 Definition and Degree of Unstauration

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    Dishant Gupta
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    The document discusses different types of isomers: 1) Compounds with the same molecular formula but different structural features are called structural isomers. 2) Isomers that differ in the arrangement of atoms in space are called stereoisomers. 3) The main types of isomers discussed are chain isomers, positional isomers, functional isomers, metamers, ring-chain isomers, tautomers, configurational isomers, conformational isomers, and geometrical isomers.

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    16347_1620394269_isomersim-part-1-definition-and-degree-of-unstauration

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    The document discusses different types of isomers: 1) Compounds with the same molecular formula but different structural features are called structural isomers. 2) Isomers that differ in the arrangement of atoms in space are called stereoisomers. 3) The main types of isomers discussed are chain isomers, positional isomers, functional isomers, metamers, ring-chain isomers, tautomers, configurational isomers, conformational isomers, and geometrical isomers.

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    © All Rights Reserved
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    7 views11 pages

    Isomersim Part 1 Definition and Degree of Unstauration

    Uploaded by

    Dishant Gupta
    The document discusses different types of isomers: 1) Compounds with the same molecular formula but different structural features are called structural isomers. 2) Isomers that differ in the arrangement of atoms in space are called stereoisomers. 3) The main types of isomers discussed are chain isomers, positional isomers, functional isomers, metamers, ring-chain isomers, tautomers, configurational isomers, conformational isomers, and geometrical isomers.

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    © All Rights Reserved
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    of 11

    If the

    Different If the compounds


    compounds compounds differ in their
    having the differ in their properties due
    same properties to the
    due to the
    Isomerism
    molecular difference in
    formula are difference in the
    called structural arrangement
    isomers. features, they of atoms in
    are called space, they
    structural are called
    isomers. stereoisomers.
    Chain Isomers Positional Functional Metamers Ring-Chain Tautomers
    Isomers Isomers Isomers
    Chain Isomers Positional Functional Metamers Ring-Chain Tautomers Configurational Conformational
    Isomers Isomers Isomers Isomers Isomers
    Chain Isomers Positional Functional Metamers Ring-Chain Tautomers Configurational Conformational
    Isomers Isomers Isomers Isomers Isomers

    Geometrical Optical Isomers


    Isomers
    Also known as the Index of If a compound has a formula
    Hydrogen Deficiency or Double 𝑪𝒂 𝑯𝒃 𝑵𝒄 𝑶𝒅 𝑿𝒆
    bond equivalent. 𝟏
    𝑫𝑼 = 𝒂 + 𝟏 − (𝒃 + 𝒆 − 𝒄)
    𝟐

    It is the number of Hydrogen 𝑪𝟔 𝑯𝟔


    molecules required to 𝟏
    convert a compound into a 𝑫𝑼 = 𝟔 + 𝟏 − 𝟔 =𝟒
    𝟐
    saturated open chain
    compound.

    𝑫𝑼 = 𝒏𝒐. 𝒐𝒇 𝝅 𝒃𝒐𝒏𝒅𝒔 Not workable for 3D fused


    + 𝒏𝒐. 𝒐𝒇 𝒓𝒊𝒏𝒈𝒔 Rings.
    If atoms other than Carbon, Nitrogen, Hydrogen,
    Oxygen or Halogen are present then:

    𝟏
    𝑫𝑼 = 𝟏 + ෍ 𝒏𝒊 (𝒗𝒊 − 𝟐)
    𝟐

    Where 𝒏𝒊 = 𝒏𝒐. 𝒐𝒇 𝒂𝒕𝒐𝒎𝒔 𝒘𝒊𝒕𝒉 𝒗𝒂𝒍𝒆𝒏𝒄𝒚 𝒗𝒊


    𝟏
    𝑫𝑼 = 𝟖 + 𝟏 − 𝟖 =𝟓
    𝟐
    𝟏
    𝑫𝑼 = 𝟔 + 𝟏 − 𝟔 =𝟒
    𝟐

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