CHEM 145 Honors General Chemistry I

2021-08-17

# Gas
| Kinetic Theory of Gas

Quantity Unit Definition

Pressure

Mole fraction of -

Partial pressure of

Pressure-volume work

Compressibility of gas -

Description Equations

Ideal gas law

Ideal gas constant and Boltzmann constant

Average kinetic energy of one gas molecule

Root mean square speed gas

Mean speed of gas

Most probable speed of gas

Maxwell-Boltzmann speed distribution

Van der Waals equation of state

Lennard-Jones potential

| Molecular Collisions and Rate Processes

Description Equations

Molecule collision rate with wall

Graham’s law of effusion

Molecule-molecule collision rate

Mean free path

 Description Equations

Mean square displacement of diffusion in 3D

Gas diffusion constant

| Intermolecular Interactions

Quantity Unit Definition

Electrostatic force

Electrostatic potential energy

Dipole moment

Polarizability

Induced dipole moment

Description Equations

Ion-ion interactions

Ion-dipole interactions

Dipole-dipole interactions

Induced-dipole-induced-dipole (London)

Dipole-induced-dipole

Rotating fixed dipole (Keesom)

# Thermodynamics
| First law of thermodynamics

Quantity Unit Definition

Specific heat capacities

Heat capacity

Molar heat capacities

Enthalpy

Description Equations

First law of thermodynamics

Enthalpy change
 Description Equations

Molar heat capacity of monoatomic ideal gas at constant

volume

Molar heat capacity of any ideal gas at constant pressure

Internal energy change of any ideal gas

Enthalpy change of any ideal gas

Hess’s law

Molality

Boiling point elevation

( is vant’s Hoff dissociation factor)

Freezing point depression

( is vant’s Hoff dissociation factor)

Reversible isothermal process of ideal gas

Reversible adiabatic process of ideal gas

| Second law of thermodynamics

Description Equations

Entropy

Entropy change

for reversible isothermal process

for reversible isothermal process -

compression/expansion of ideal gas

for reversible isothermal process - phase

transitions
 Description Equations

for reversible adiabatic process

for reversible isochoric process

for reversible isobaric process

Entropy change of surrounding

Second law of thermodynamics

Enthalpy of spontaneous process

Standard molar entropy

Gibbs free energy for reaction at constant temperature

Efficiency of Carnot engines

Relationship between heat and temperature in Carnot

cycle

Work done by Carnot cycle in one cycle

# Equilibrium

Description Equations

Law of mass action - partial pressure

Law of mass action - concentration

Gibbs free energy of isothermal reactions

Equilibrium expression: relationship between Gibbs free

energy and equilibrium constant (gas phase reaction)

Equilibrium expression: alternative form

Change in Gibbs free energy at non-standard conditions

 Description Equations

Reaction quotient - partial pressure

Reaction quotient - concentration

vant’s Hoff equation

temperature dependence of equilibrium constant of a
reaction

Clapeyron equation
for two phase in equilibrium, construct phase diagram by
finding change of pressure as a function of temperature

Clausius-Clapeyron equation
temperature dependence of vapor pressure for condensed
phase and gas phase in equilibrium

Clausius-Clapeyron equation

for