JEE (Main + Advanced) / Chemistry / Revision DPP-01

Mole & Redox : Revision DPP - 01

Single Correct Questions (01-03)
1. Consider the reaction [JEE (Main) 2022]
4HNO3(l) + 3KCl(s) → Cl2(g) + NOCl(g) + 2H2O(g) + 3KNO3(s)
The amount of HNO3 required to produce 110.0 g of KNO3 is :
(Given : Atomic masses of H, O, N and K are 1, 16, 14 and 39, respectively.)
(1) 32.2 g (2) 69.4 g (3) 91.5 g (4) 162.5 g

2. Production of iron in blast furnace follows the following equation [JEE (Main) 2022]
Fe3O4(s) + 4CO(g) → 3Fe(l) + 4CO2(g)
when 4.640 kg of Fe3O4 and 2.520 kg of CO are allowed to react then the amount of iron (in g) produced
is :
[Given : Molar Atomic mass (g mol –1): Fe = 56 Molar Atomic mass (g mol –1) : 0 = 16
Molar Atomic mass (g mol –1): = C = 12
(1) 1400 (2) 2200 (3) 3360 (4) 4200

3. N2(g) + 3H2(g) 2NH3(g)

20 g 5 g
Consider the above reaction, the limiting reagent of the reaction and number of moles of NH 3 formed
respectively are: [JEE (Main) 2022]
(1) H2, 1.42 moles (2) H2, 0.71 moles (3) N2, 1.42 moles (4) N2, 0.71 moles

Integer Type Questions (04-10)

4. In the given reaction,
X + Y + 3Z XYZ3
if one mole of each of X and Y with 0.05 mol of Z gives compound XYZ3. (Given : Atomic masses of X, Y
and Z are 10, 20 and 30 amu, respectively). The yield of XYZ3 is __________ g.
(Nearest integer)
[JEE (Main) 2022]

5. Consider the following sulphure based oxoacids.

H2SO3, H2SO4, H2S2O8 and H2S2O7.
Amongst these oxoacids, the number of those with peroxo(O-O) bond is______.
[JEE (Main) 2022]

6. The molality of a 10% (v/v) solution of di-bromine solution in CCl4 (carbon tetrachloride) is 'x'.
x = ________ × 10–2 M. (Nearest integer)
[Given : molar mass of Br2 = 160 g mol–1
atomic mass of C = 12 g mol–1
atomic mass of Cl = 35.5 g mol–1
density of dibromine = 3.2 g cm–3
density of CCl4 = 1.6 g cm–3]
[JEE (Main) 2023]

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JEE (Main + Advanced) / Chemistry / Revision DPP-01

7. The oxidation sate of phosphorus in hypophosphoric acid is + ________ .

[JEE (Main) 2023]

8. Sum of oxidation states of bromine in bromic acid and perbromic acid is ________ .
[JEE (Main) 2023]

9. The density of 3 M solution of NaCl is 1.0 g mL-1. Molality of the solution is __________ × 10-2 m.
(Nearest integer).
Given: Molar mass of Na and Cl is 23 and 35.5 g mol-1 respectively.
[JEE (Main) 2023]

10. A sample of a metal oxide has formula M 0.83O1.00 . The metal M can exist in two oxidation states
+2 and + 3 . In the sample of M0.83O1.00 , the percentage of metal ions existing in +2 oxidation state is _____
% (nearest integer)
[JEE (Main) 2023]

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JEE (Main + Advanced) / Chemistry / Revision DPP-01

Answer Key

Question 1 2 3 4 5 6 7 8 9 10
Answer 3 3 3 2 1 139 4 12 364 59

Solutions
1. Ans. (3)
4HNO3( ) + 3KCl (s ) → Cl2 ( g ) + NOCl ( g ) + 2H2O ( g ) + 3KNO3 (g )
x 110
Mole =
63 101
4→3
3
1→
4
x 3 x 110
→  =
63 4 63 101
110  63  4
x= = 91.5gm
101  3

2. Ans. (3)
4.640 103
Moles of Fe3O4 = = 20
232
2.52 103
Moles of CO = = 90
28
So limiting Reagent = Fe3O4
So moles of Fe formed = 60
Weight of Fe = 60 × 56 = 3360 gms

3. Ans. (3)
N2 (g) + 3H2(g) 2NH3(g)
W2 = 20g 5g.

20 5
n=
28 2
Stoichiometric Amount:
20 / 28 20 5/ 2 5
N2 → = H2 → =
1 28 3 6
 N2 is the Limiting Reagent.
20
 n(NH3 ) = 2  n(N2 ) = 2 
28
= 1.42

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JEE (Main + Advanced) / Chemistry / Revision DPP-01

4. Ans. (2)
X + Y + 3Z XYZ3
1mol 1mol 0.05mol

Z is L.R.
0.05
= moles of XYZ3
3
0.05
Mass of XYZ3 =  (10 + 20 + 30  3)
3
= 2g
5. Ans. (1)

O
||
H —O— S—O— H ( H2SO3 )
O
||
H —O— S—O—H ( H2SO4 )
||
O
O O
|| ||
HO— S—O—O— S—OH ( H2S2O8 )
|| ||
O O
O O
|| ||
H —O— S—O— S—OH ( H2S2O7 )
|| ||
O O

6. Ans. (139)
(10 ml solute in 90 ml solvent
mass of solute = 10 × 3.2 = 32g
mass of solvent = 90 × 1.6g
32  1000
m= = 1.388
160  90  1.6
m = 138.8 × 10-2 = 139

7. Ans. (4)
H4P2O6
O O
|| ||
HO— P — P —OH
| |
OH OH
O.S. of P is +4

8. Ans. (12)
HBrO3 (Bromic acid)
Ox. State of Br = +5
HBrO4 (per bromic acid)
OX. State of Br = +7
Sum of Ox. State = 12

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JEE (Main + Advanced) / Chemistry / Revision DPP-01

9. Ans. (364)
1000  M
m=
1000  d − M  M.W of solute
1000  3
= = 3.64
1000  1 − (3  58.5)
= 364 × 10–2

10. Ans. (59)

+2 ⎯→ x
M
+3 ⎯→ (0.83 – x)
2x + 3 ( 0.83 − x ) = 2
x = 0.49
0.49
% M2 + =  100
0.83
= 59%

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