REVIEW TEST-1

C
H E
M I
STRY
Class : XI
Time : 90 min Max. Marks : 75
INSTRUCTIONS
General Remarks:
1. The question paper contain two parts. Part-A contains short question and Part-B contains
subjective questions. All questions are compulsory. Paper contains 10 questions in Part-A and
9 questions in Part-B.
2. You are advised NOT to spend more than 30 minutes in any case for part-A.
3. Each question should be done only in the space provided for it, otherwise the solution will not be
checked.
4. Use of Calculator, Log table and Mobile is not permitted.
5. Legibility and clarity in answering the question will be appreciated.
6. Put a cross ( × ) on the rough work done by you.

Name : ____________________________ Roll No. __________________

Batch Class : XI

Invigilator's Full Name __________________________________________________

USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.4, Ti = 48,
Ba = 137

For Office Use ……………………………. Total Marks Obtained…………………

Part-A Part-B
Q.No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Marks
XI(PQRS) CHEMISTRY REVIEW TEST-1
PART A
Q.1 Rearrange the following (I to IV) in the order of increasing masses [3]
(I) 0.5 mole of O3 (II) 0.5 gm-molecule of N2
(III) 3.011 × 1023 molecules of O2 (IV) 5.6 litre of CO2 at STP
[Sol. I 0.5 mol O3 = 24 g O3
II 0.5 gm molecule of N2 = 14 g N2
3.01110 23
III  32 = 16 g O2
6.023 10 23
5. 6
IV  44 g CO2 = 11 g CO2
22.4
-----------------------------------------------
IV < II < III < I Ans. ]

Q.2 Calculate number of neutrons in 17 g of H2O2. [3]

[Sol. 0.5 mol H2O2 has 8 mol neutrons
 8NA Ans. ]

Q.3 The hydrated salt Na2CO3.xH2O undergoes 63% loss in mass on heating and becomes anhydrous,
calculate the value of x [3]
[Sol. Na2CO3.xH2O (s)  Na2CO3(s) + xH2O (g)
Let 100g of Na2CO3.xH2O be present
100x
 mol of H2O formed
106  18x
100x
 63 = (18)
106  18x
6678 + 1134 = 1800 x
666x = 6678
x = 10.027 Ans.]

Q.4 The vapour density of a mixture containing NO2 & N2O4 is 27.6. Calculate mole fraction of N2O4
in the mixture. [3]
[Sol. Let 1 mol of mixture have x mol N2O4
 2 × 27.6 = x(92) + (1–x) 46
x = 0.2 Ans.]

Q.5 Suppose two elements X and Y combine to form two compounds XY2 and X3Y2 when 0.05 mole
of XY2 weighs 5 g while 3.011 × 1023 molecules of X3Y2 weighs 90 g. Calculate the atomic
masses of X and Y. [3]
5
[Sol. Mol. wt. of XY2 = = 100
0.05
90
Mol. wt. of X2Y3 = ×6.023×1023 = 180
3.0111023
Let molar mass of X and Y are a & b respectively
 a + 2b = 100
2a+3b = 180
a = 40; b = 30 Ans.]
Q.6 Average atomic mass of magnesium is 24.31 a.m.u. This magnesium is composed of 79 mole %
of 24Mg & remaining 21 mole % of 25Mg and 26Mg. Calculate mole % of 26Mg. [3]
[Sol. Let mol% of 26Mg be x
( 21  x ) 25  x ( 26)  79( 24)
 = 24.31
100
x = 10% Ans.]

Q.7 What is the molarity of SO 24 ion in aqueous solution that contain 34.2 ppm of Al2(SO4)3 [Assume
complete dissociation & density of solution 1 g/ml) [3]
mass of Al 2 (SO 4 )3
[Sol. × 106 = 34.2
mass of water
1 Lt. solution contains 1000 g of water
34.2 1000
 In 1 Lt. solution mass of Al2 (SO4)3 = = 34.2 mg
10 6
34.2  10 3
molarity of Al2(SO4)3 = M
342
= 10–4 M
Al2(SO4)3 (aq)  2Al3+(aq) + 3SO 24 (aq)
10–4 M 2×10–4 M 3×10–4 M
3 × 10–4 M Ans.]

Q.8 Concentration of aq. NaOH solution is 3.0 Molal and it's density is 1.1 gm/ml. What is the Molarity
of the solution? [3]
[Sol. 3 mol NaOH in 1000 g water
3 mol NaOH in [1000 + 40 × 3] g solution
1000  40  3 
3 mol NaOH in   L solution
 1100 
3
1000  120 3300
molarity = = = 2.94 M Ans. ]
1100 1120

Q.9 What volume of 90% alcohol by weight (d = 0.80 g/cm3) must be used to prepare 150 cm3 of 30%
alcohol by weight (d = 0.90 g/cm3) [3]
[Sol. Let V ml of alcohol be required
 mass of alcohol is same in both solutions
90 30
 ×0.8 ×V = × 0.9 × 150
100 100
V = 56.25 mL Ans.]
Q.10 1.44 gram of Titanium (Ti) reacted with excess of O2 and produced x gram of non-stoichiometric
compound Ti1.44O. Find the value of x. [3]
[Sol. Ti + O2  Ti1.44O or by balancing reaction
1.44 x
mol 48 (1.44)  16 mol 1.44 Ti + 1/2O2  Ti1.44O
48
1.44 1.44x
P.O.A.C. on Ti  =
48 48(1.44)  16
x = 1.77 g Ans.]

PART B

Q.11(i) Find the value of x in Nicotine, C10H14Nx? (Given: mol. mass of Nicotine is 162 amu.)
(ii) If an atom of 12C had been assigned a relative value of 24.0 a.m.u., what would be the atomic
weight of hydrogen relative to this mass. [2 + 2]
[Sol. (i) 10 × 12 + 14 × 1 + x ×14 = 162
 x = 2 Ans.
(ii) New atomic mass of hydrogen = 2 amu Ans.]

Q.12 (i) How many millilitres of a 0.45 M BaCl2 aq. solution contain 15.0 g of BaCl2?
(ii) Consider the balanced equation for the formation of 1 mole of Fe2(CO3)3
2Fe(NO3)3 + 3Na2CO3  Fe2(CO3)3 + 6NaNO3
How many oxygen atoms are on each side of the equation? [2 + 2]
[Sol. (i) Let volume is V ml
 V  15
  ×0.45 =
 1000  137  2  35.5
V = 160. 26 ml Ans.

(ii) 2Fe(NO3)3 + 3Na2CO3  Fe2(CO3)3 + 6NaNO3

No. of O-atom each side = 18 + 9 = 27 Ans. ]

Q.13 An aq. solution of H2SO4 contain 196 g acid per litre; solution has density 1.24 g/ml.
Calculate
(i) wt % of H2SO4 in solution (ii) mole % of H2SO4 in solution [4]
[Sol. Assume 1000 ml solution
wt. of solution = 1000 × 1.24 gm
196
(i) % wt. of H2SO4 = ×100
1000  1.24
= 15.81 % Ans.
 nH
2SO 4
(ii) Mole % of H2SO4 = ×100
nH  nH
2SO 4 2O

 196 
 
 98 
= 196  1240  196  ×100
 
98  18 

2
= ×100 = 3.33 % Ans.]
2  58

Q.14
(i) In the decomposition of impure KClO3 9.8 g of it gave 1.49 g of KCl and 0.03 mol of O2 gas.
Calculate percent purity of KClO3 with the help of law of conservation of mass.
(ii) Phosphorus (V) chloride reacts with water to give phosphoric acid and hydrogen chloride according
to the following equation (not balanced)
PCl5 + H2O H3PO4 + HCl
In an experiment 0.36 mole of PCl5 was reacted to 2.88 mole of water
(a) Which reactant was the limiting reagent.
(b) Calculate the theoretical yields (in moles) of H3PO4 and HCl. [2+3]

[Sol. (i) 2KClO3  2KCl + 3O2
9.8 gm 1.49 gm 0.03 ×32 = 0.96 gm
Total mass of product = 1.49 + 0.96
= 2.45 gm
Then the mass of KClO3 (pure)= 2.45 gm
2.45
% purity of KClO3 = ×100 = 25 % Ans.
9.8
(ii) PCl5 + 4H2O  H3PO4 + 5HCl (Balanced reaction)
0.36 mol 2.88 mol
Li2
(a) PCl5 is the L.R.
(b) Theoretical yield of H3PO4 = 0.36 mole Ans.
Theoretic yield of HCl = 5 × 0.36
= 1.8 mole Ans. ]
Q.15 A mixture of NH4NO3 & (NH4)2HPO4 showed the mass percent of nitrogen to be 30.40%. What
is the mass ratio of the two components in the mixture? [5]
[Sol. x gm y gm
NH NO  ( NH ) HPO
4 3 424
Total ( x  y ) gm

x y
 2 14   2 14
28  4  48 2 18  1  31  64 ×100 = 30.4
xy

28x 28y

 80 132 ×100 = 30.4
xy
0.35x + 0.212y = 0.304 x + 0.304 y
 0.046 x = 0.092 y
x
= 2 Ans. ]
y

Q.16 In the preparation of iron from haematite (Fe2O3) by the reaction with carbon
Fe2O3 + C  Fe + CO2
(a) Balance the equation
(b) How much 80% pure iron could be produced from 120 kg of 90% pure Fe2O3 [5]
3C 3
[Sol. (a) Fe2O3 +  2Fe + CO2
2 2
or 2F2O3 + 3C  4Fe + 3CO2 Ans.
 120  1000  90
(b) no. of moles of Fe2O3 =  
 2  56  48  100
120  1000  0.9 2  56
Amount of 80% pure iron =  = 94500 gram Ans.
2  56  48 0.8
= 94.5 kg Ans. ]

Q.17(i) The actual mass of the atomic mass unit is 1.66 × 10–24 g using this value, calculate the mass in
grams of 10 atoms of 12C.
(ii) A gaseous compound is composed of 85.7% by mass carbon and 14.3% by mass hydrogen. It's
density is 2.28 g/litre at 300K and 1.0 atm pressure. Determine the molecular formula of the
compound. [2+4]
[Sol. (i) 1 amu = 1.66 × 10 gm–24

Mass of 10 atoms of 12C = 10×12 amu

= 10×12×1.66×10–24
= 1.992 ×10–22 gm Ans.
PM dRT 2.28  0.0821 300
(ii) d= M= =
RT P 1
= 56.15 gm/mol
85.7 14.3
E.F. : : = 7.14 : 14.3 = 1 : 2
12 1
E.F.  CH2
 56.15
M.F. = (CH2)n where n = =4
12  2
M.F. C4H8 Ans. ]
M
Q.18(i) Calculate volume of water to be added to 300 ml of HNO3 solution so that its new strength
5
M
becomes .
15
(ii) It is known that when 1 mole of carbon reacted with 1 mole of oxygen (C + O2  CO2),
1
95 Kcal heat liberated & when 1 mole carbon reacted with 0.5 mole of O2 (C + O  CO),
2 2
24 Kcal heat liberated. When 12.0 g of carbon reacted with oxygen to form CO & CO2, 80.8 Kcal
of heat liberated and no carbon remained. Calculate the mass of oxygen which reacted. [2 + 4]
[Sol. (i) Let V ml of H2O is added
300 1 V 1
 = mol of HNO3 = ×
1000 5 1000 15
 V = 900 ml
water added = 900 – 300 = 600 ml Ans.
(ii) Let x mole of carbon is reacted with O2 and form x mole of CO2
C + O2  CO2, heat liberated = 95 Kcal
x x x
1
C + O  CO, heat liberated = 24 Kcal
2 2
1–x (1–x)/2 1–x
x × 95 + (1–x) × 24 = 80.8
 71x + 24 = 80.8
x = 0.8 mol
1 x
 Mol of O2 used = x +
2
1 0.8
= 0.8 + = 0.8 + 0.1 = 0.9 mol
2
 Mass of O2 reacted = 0.9 × 32
= 28.8 gm Ans.]
Q.19 8KI + 5H2SO4 100
%yield
 4K2SO4 + 4I2 + H2S + 4H2O
H2SO4 + 2NaOH 100
%yield
 Na2SO4 + 2H2O

I2 + 2Na2S2O3 50
%yield
 2NaI + Na2S4O6
I2 + 2KCl 50 %yield
 2KI + Cl2
100 ml of a sample of dilute H2SO4 of specific gravity 1.47 is treated with a 10 g sample of
impure KI. The final mixture had to be treated with 20 ml of 4% (w/V) NaOH solution to neutralize
left H2SO4. Iodine liberated was trapped and divided into two parts. One part on passing through
20 ml. Na2S2O3 solution yielded 0.3 g of NaI and the other part of I2 sample on treatment with
excess KCl yielded 0.497 g of Cl2.Calculate,
(i) molarity of Na2S2O3 solution.
(ii) % (w/W) of H2SO4 sample
(iii) % purity of KI sample [6]
0. 3
[Sol. (i) no. of mole of NaI =  0.002
23  127
100 0.004
no.of mole of Na2S2O3 required  0.002 ×  Molarity = ×1000
50 20
= 0.2 M Ans.

(ii) Initial mass of H2SO4  100 ×1.47  147gm

0.02
mass of unreacted H2SO4  moles of NaOH used   0.01
2
100 ml  4 g
4
20 ml  ×20  0.8 gm
100
0. 8
nNaOH = = 0.02
40
 0.497   0.3  1
Total moles of I2 formed   × 2 +   ×2×
 71   150  2
 0.014 + 0.002  0.016
5
Moles H2SO4  × 0.016  0.02
4
Total initial moles of H2SO40.02+0.010.03Mass of H2SO4 = 0.03 × 98 = 2.94 gm
w 2.94
% = × 100 = 2 % Ans.
W 147

8
(iii) Moles of KI reacted with H2SO4  × 0.02  0.032
5
Mass of KI  0.032 × (127 + 32)  5.312 g
5.312
% purity  × 100  53.12 % Ans.]
10