REVIEW TEST-3

C
H E
M I
STRY
Class : XI (PQRS)
Time : 90 min Max. Marks : 75
INSTRUCTIONS
General Remarks:
1. The question paper contain 15 questions. All questions are compulsory.
2. Each question should be done only in the space provided for it, otherwise the solution will not be
checked.
3. Use of Calculator, Log table and Mobile is not permitted.
4. Legibility and clarity in answering the question will be appreciated.
5. Put a cross ( × ) on the rough work done by you.
6. Write your answer(s) in the box given in the last of each question. Otherwise Makrs will not be awarded.

Name ________________________________ Father's Name ____________________________

Class : __________ Batch : B.C. Roll No. ___________

Invigilator's Full Name __________________________________________________

USEFUL DATA

Atomic weights: Mg = 24, Cl = 35.5, O = 16, H = 1, N = 14, I = 127, K=39, C = 12, Ca = 40; He = 4.
Useful constant : g = 10 m/sec2, NA = 6 × 1023, R = 8.314 J/(mol-K) = 0.082 lt-atm/(mol-K)

For Office Use ……………………………. Total Marks Obtained…………………

Q.No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Marks
XI(PQRS)
Q.1 Match the column
Column I
(A) Atomic theory of matter
(B) Quantization of charge
(C) Quantization of energy
1/3
(D) Size of nucleus (R = RoA )
CHEMISTRY REVIEW TEST-3
[4]
Column II
(P) Rutherford scattering experiment
(Q) Millikan's oil drop experiment
(R) Planck's Quantum Theory
(S) Law of chemical combination

C olumn I A B C D
Ans.
C olumn II
[Ans. (A) – S, (B) – Q, (C) – R, (D) – P]
Q.2 Match the description in Column I with graph provided in Column II. For n moles of ideal gas at
temperature 'T'. [4]
Column I Column II

P
(A) vs P (P)
V

P
(B) vs V (Q)
V

V
(C) vs P–2 (R)
P

P
(D) log   vs log P (S)
V

C olumn I A B C D
Ans.
C olumn II
[Ans. (A) – S, (B) – R, (C) – Q , (D) – P]
Q.3 Calcium and magnisium ion from a 105 litre of sample of hard water was quantitatively precipitated as
carbonates and weight of ppt. obtained was found to be 568 gm. If the ppt. lost 264 gm of wt. on strong
heating. [2 + 2]
(a) Find the hardness of water in ppm (in terms of wt. of CaCO3)
(b) Molarity of Ca2+ and Mg2+ ions in hard water.
MgCO3  MgO + CO2
CaCO3  CaO + CO2

[Ans. (a) 6 ppm, (b) [Mg2+] = 2 × 10–5 M; [Ca2+] = 4 × 10–5 M]

[Sol.(a) consider 105 litre hard water sample 
MgCO3  MgO + CO2
CaCO3  CaO + CO2
 264
Moles of CO2 lost = =6
44
Moles of CaCO3 + MgCO3 = 6 mole
Wt. of eq. quantity of CaCO3 = 600 gm
600106
= 6 ppm
108
(b) Also (6 – X) 100 + 84 X = 568
 X=2
 MgCO3 = 2 mole in 10–5 litres
CaCO3 = 4 mole in 10–5 litres
[Ca2+] = 4 × 10–5 M
[Mg2+] = 2 × 10–5 M ]
88
Q.4 The Vander Waal's constant 'b' of a gas is 10  4 L/mol. How near can the centres of the two
7
molecules approach each other? [Use NA = 6 × 1023] [4]
4
[Sol. b=4× × r3 × NA
3
88 4 22
 10  4 × 1000 = 4 × × × r3 × 6 × 1023
7 3 7
8 .8 4 22
=4× × × r3 × 6 × 1023
7 3 7
r = 5 × 10–9 cm
Distance of closest approach = 2r = 10–8 cm ]

Q.5 Calculate the minimum volume of a hot air balloon, which can lift a payload of 1000 kg. The density of
air is 1 gm/litre. The temperature of air 300 K and air inside the balloon can be heated upto 400 K. The
mass of balloon is 0.2 kg/m3. [4]
[Ans. 2 × 104 m3]

[Sol: Let the volume of balloon is Vm3

 V × damb = mass of balloon + mass of gas filled + payload ...............(1)
Here damb = 1gm/lt = 1kg/m3
P ×M = 1 × R × 300 ...........(2)
& P ×M = dhot × R × 400 ...........(3)
3
Divide (2) by (3) dhot = kg/m3
4
 mass of balloon = (0.2 V) kg
3 
mass of gas filled =  V  kg
4 
& payload = 1000 kg
from (1) (V × 1) = 0.2 V + (0.75V) + 1000
1000
V= = 2 × 104 m3 ]
0.05
Q.6 100 gm of KClO3 when heated gives 14.90 gm KCl and 41.55 gm KClO4 [2+2]
3
KClO3  KCl + O ...(1)
2 2
4KClO3  KCl + 3KClO4 ...(2)
(a) Find the weight of KClO3 remaining indecomposed.
W1 Weight of KClO 3 used in 1st Reaction
(b) Ratio =
W2 Weight of KClO 3 used in 2 nd Reaction
[Ans. 38.75 gm; 1:4]
41.55
[Sol: (a) moles of KClO4 = = 0.3
138.5
 moles of KClO3 used in (2) reaction = 0.4
moles of KCl formed from (2) reaction = 0.1
14.9
total moles of KCl formed = = 0.2
74.5
therefore, moles of KCl from (1) reaction = 0.2 – 0.1 = 0.1
 moles of KClO3 used in (1) reaction = 0.1
total moles of KClO3 used = 0.4 + 0.1 = 0.5
wt. of KClO3 decomposed = 0.5 × 122.5 = 61.25 gm
 wt. of KClO3 remaining underdecompoased = 100 = 61.25 = 38.75 gm
w1 wt . of KClO3 used in (1) reaction
(b) ratio w2 = wt . of KClO3 used in (2) reaction

0.1  122.5 1
= 0.4  122.5  4 ]

Q.7 Find the mole fraction of N2 and O2 in air at 8314 meter height from surface of earth on the basis of
following assumptions. [5]
I. Composition of air on the surface of earth is 20% O2 and 80% N2 by moles and P = 1 atm.
II. Temperature of atmosphere is constant at 300 K upto 8314 meter height.
III. Take acceleration due to gravity to be constant and equal to 10 m/s2.
IV. No turbulance in air to make the composition of gases non–uniform
[Use e1 / 15 ] [Ans. 82.1%, 17.9%]

  28  g  h  10 3 
[Sol. PN = P exp  
2 N2
 RT 

  32  g  h 10 3 
PO = P exp  
2 O2
 RT 

PN 8  (32  28)g·h  10 3  8  4  10  8314  10 3 

2
= exp   = exp  
PO
2
2  8.314  300  2  8.314  300 

4 2
= 4exp   = 4exp   = 4 × (1.07)2 = 4.58
 30  15 
 1
yO2 = = 0.179  0.18
5.58
and y N 2 = 1 – 0.18 = 0.82 ]
Q.8 A container having very small orifice contained Helium gas at pressure of 2000 mmHg. The Helium gas
leaked slowly and it took 5000 second, when the pressure of He gas dropped to 1000 mmHg. How
much time it will take for pressure of methane gas to drop from 2000 mmHg to 1500 mmHg if filled in
same container under identical conditions. Consider effect of variation of pressure on rate of diffiusion.
Pi K
Use equation ln = t [5]
Pf M
[Given log 3 = 0.5 & log 2 = 0.3]
[Sol. For Helium
Pi K
ln = ·t
Pf M

 2000  K
 ln   = ·(5000)
 1000  2
2ln 2
 k=
5000
For Methane
Pi K
ln = ·t
Pf 16

 2000  2ln 2
 ln   = ·t
 1500  4  5000
4 ln 2
 ln   = ·t
 3  2  5000
 2ln 2  ln 3 
 t = (5000 × 2)  
 ln 2 
 log3 
 t = 10000 2  
 log 2 
 t = 3333.33 sec ]

Q.9 In an experiment 0.15 gm of a biological sample containing amino acid glycene (NH2CH2COOH) was
treated with nitrous acid [5]
NH2CH2COOH + HNO2  HO–CH2–COOH + H2O + N2
The nitrogen gas thus produced is collected over water at 300 K, (vapour pressure of H2O at 300 K is
28 torr) at a total pressure of 700 torr. The volume of gas measured as 15.2 ml. Find the percentage of
glycene in biological sample.
(15.2  10 3 )(672)  273
[Sol. moles of Amino acid(n) = = 2 × 273 × 10–6 = 5.46 × 10–4 moles
760  22.4  300
 Wt. of Amino acid = n × (24 + 32 + 5 + 14) = n × 75 = (5.46 × 10–4 × 75) gm
5.46  10 4  75
% of glycene is sample = × 100 = 27.3% ]
0.15

Q.10 The compressibility factor for nitrogen at 220 K and 800 atm is 1.90 and at 380 K and 200 atm is 1.10.
A certain mass of N2 occupies a volume of 1 dm3 at 220 K and 800 atm. Calculate volume occupied by
same quantity of N2 gas at 380 K and 200 atm. [5]
[Ans. 4 litre]
PV
[Sol. Z=
nRT
1 800
1.90 =
n  0.0821 220
800
n=
1.90  R  220
V  200
Z = 1.10 =
n  R  380
V  200  1.90  R  220
1.10 =
800  R  380
1.10  800  380
V= = 4 litre ]
200  1.90  220

Q.11 1023 gas molecules each of mass 10–25 kg are taken in a container of volume 1 dm3. The root mean
square speed of gas molecules is 1 km sec–1. Find [2 + 3]
(a) Pressure exerted by gas molecules
(b) Temperature of gas molecules
1
[Sol.(a) PV = N·m·vrms2
3

N·m·vrms
2
1023 1025  (103 ) 2 1 1
P= = 3 = × 1023 × 10–25 × 106 × 103 = × 107 = 0.333 × 107
3V 3 10 3 3
6
= 3.33 × 10 Pa
3RT
(b) 1000 =
M
1/ 2
 3  8 . 314  T 
103 =   25
 10  6  10 23 

10 6  10  25  6  10 23 6
T= = × 104 = 2403 K ]
3  8 . 314 3  8 . 314
Q.12(a) A 50 cc sample of H2O2 liberates 5.08 gm of I2 from acidified KI solution. Find the volume of O2 gas
liberated by complete decomposition of 250 cc of same H2O2 solution at STP.
(1) 2HCl + 2KI + H2O2  I2 + 2KCl + 2H2O
(2) 2H2O2  2H2O + O2

(b) What volume of M/10 and M/30 solutions of H2SO4 should be mixed to prepare 1 L of certain H2SO4
solution whose 50 ml is completely neutralized by 10 ml of 0.5 M NaOH solution.
H2SO4 + 2NaOH  Na2SO4 + 2H2O [3 + 2]
[Ans.(a) 1.12 lit, (b) 250 ml of M/10, 750 ml of M/30]
5.08
[Sol.(a) In (1) nH 2O2  nI 2  nH 2O2  = 0.02
254
 moles of H2O2 in 50 cc = 0.02
250
& moles of H2O2 in 250 cc = 0.02 × = 0.1
50
nH 2O2 0 .1
In (2) = nO2  = nO2
2 2
 nO2 = 0.05
VO2 (at STP) = 22.4 × 0.05 = 1.12 lt.
(b) 10 ml 0.5M NaOH = 5 m moles
2.5 m mole H2SO4
50 ml  2.5 m mole
 Molarity of H2SO4 required = 2.5/50 = 1/20 M
1 1
V1·  V2 ·
10 30 = 1
V1  V2 20

2
2V1 + V = V1 + V 2
3 2
1
V1 = V  3V1 = V2
3 2
2
2V1 + V = V1 + V 2
3 2
1
V1 = V  3V1 = V2
3 2
V1 + V2 = 1000
 4V1 = 1000
V1 = 250 ml
V2 = 750 ml
M M
250 ml of H SO ; 750 ml of H SO ]
10 2 4 30 2 4
Q.13 15 ml of an oxide of nitrogen was taken in a eudiometer tube and mixed with hydrogen till the volume
was 65 ml. On sparking the resulting mixture occupied 20 ml. To the mixture, 10 ml of oxygen was
added and on explosion, again the volume fell to 22.5 ml having N2 and O2 gases. Find the formula of
the oxide of nitrogen that was originally admitted to eudiometer tube. Both explosion led to formation of
H2O(l) only. [5]
[Ans. N2O3]
x y
[Sol. NxOy  N2(g) + O2(g)
2 2
15x 15 y
15
2 2
1
H2 + O  H2O(l)
2 2
 15y  15 y
2  0
 2  2

15x 15 y  15y 
15 – – + 3  = 45
2 2  2 
15x
15y – = 30
2
Last step— const. 7.5
 O2 used = 2.5
H2 used = 5
15 y
 × 2 = 45  y=3
2
Thus, x = 2 ]

Q.14 For the following problem carefully examine the figure and information provided with figure which describes
set up of a experiment under isothermal conditions. [5+3]

The figure shows initial conditions of experiment with frictionless pistons A and B held in shown position
by mechanical stoppers.(Thickness of pistons is negligible).

If the mechanical stopper holding A and B as shown in figure is removed

(a) Pressure developed in each compartment in final state.
(b) What will be the final positions of A and B (with respect to far left end of container)
[Sol:

For Ar P1V1 = P2V2

10
  60 = P × x
3
Px = 200 ..........(1)

For Ne P1V1 = P2V2

 7.5 × 20 = P × (y – x)
P(y – x) = 150 ..........(2)

For He P1V1 = P2V2

 5 × 20 = P (100 – y)
P(100 – y) = 100 ..........(3)
On solving equations (1), (2) and (3)
P = 4.5 atm
400
x= cm
9
700
&y= cm.
9

Q.15 'n' moles of a gas 'X' was trapped in a gas jar over surface of a liquid 'A' as shown in figure. The liquid
'A' rose in inner column (of total length 85 cm above completely filled outer vessel liquid surface) by 20
cm.
When same number of moles of gas 'X' is trapped in same apparatus over liquid 'B', the liquid B rose by
length 22 cm in inner column. [4+2+2]
From the given data at 300 K, calculate
(a) Pressure of gas over liquid 'A'
(b) Pressure of gas over liquid 'B'
(c) Density of liquid 'B'.
(Use: Atmospheric pressure = 760 mmHg, Density of Hg = 13.6 gm/cc)

density V.P. hinner-houter

S.N.
(g/cc) (mmHg) (cm)
Liquid 'A' 6.8 30 20
Liquid 'B' — 40 22
[Sol. Liq. 'A'
P(atmosphere) = Pgas + V.P. + PL.C
6.8  200
760 = Pgas + 30 +
13.6
 Pgas, 1 = 630 mmHg
In Liq. 'B', since no. of moles of gas is same and under isothermal conditions
(Pgas,1 )(l1 ) 65
Pgas, 2 = = 630 × = 650 mmHg
l2 63

( B ·lB )
 760 = 650 + 40 +
 Hg

(70)( Hg )
 B = = 4.33 gm/cc ]
220