DPP (1 TO) Physical Chemistry

PHYSICAL CHEMISTRY
Daily Practice Problems

CLASS : XI TIME : 40 MIN DPP. NO.-1
Q1. The no. of gm molecular of oxygen in 6.02 x 1024 CO molecular are
(A) 2 (B) 0.2 (C*) 5 (D) 0.5
Q2. How many moles of electron weight one kilogram?

1031 6.02 x 1054 108
(A) 6.02 x 1023 (B) (C) (D*)
9.1 9.1 9.1 x 6.02
Q3. 18 gms of water contains

(A) 1 gm atom of hydrogen (B) 2 gm atoms of hydrogen
(C) 3 gm atoms of oxygen (D) 2 gm atoms of oxygen
Q4. Out of 1 gm dioxygen, 1 gm atomic oxygen and 1 gm of ozone, the maximum number of oxygen atoms
are contained in
(A) 1 gm of atomic oxygen (B) 1 gm of ozone
(C) 1 gm of dioxygen (D*) All contains same number of atoms
Q5. Which has the highest mass?

(A) 50 gm of iron (B*) 5 moles of N2 (C) 0.1 gm atom of Ag (D) 1023 atoms of carbon
Q6. 4.4 gm of an unknown gas occupies 2.24 litre of volume at STP. The gas may be
(A*) Carbon dioxide (B) Carbon monoxide (C) Oxygen (D) Sulphure dioxide
Q7. Number of gold atoms in 300 mg of a gold ring of 20 carat gold (atomic mass of gold = 197 gm/mol;
pure gold is 24 carat) are
(A) 4.5 x 1020 (B) 6.8 x 1015 (C*) 7.6 x 1020 (D) 9.5 x 1020
Q8. One litre of milk weighs 1.032 kg. The butter fat it contains to the extent of 4% by volume has a density
of 865 kg m-3. The density of fat free “Skimmed milk” is
(A) 1000 Kg/m3 (B*) 1038 Kg/m3 (C) 1032 Kg/m3 (D) 167 kg/m3
Q9. The mineral quartz and zircon has a density of 2.65 g/cm3 and 4.5 gm/cm3 respectively. A rock composed
of quartz and zircon has a density of 3 gm/cm3 % by volume and % by mass of quartz in the sample are
(A*) 81.1% by vol,71.7% by mass (B) 61.2% by vol, 55.3% by mass
(C) 75% by vol, 60% by mass (D) Data Insufficient
Q10. Comprehension:
Ocean currents are measured in “Sverdrups (sv)” (1 sv = 109m3/sec). The gulf stream off the tip of
florida, for instance, has a flow of 35 sv.
(i) The flow of the gulf stream in milliliters per minute is

(A*) 2.1 x 1018 ml/min (B) 3.5 x 1020 ml/min (C) 3.7 x 1018 ml/min (D) 5.6 x 1020 ml/min
(ii) Mass of water in the gulf stream flows past a given point in 24 hours is (density of water is 1 gm/ml)
(A) 4 x 1021gm (B*) 3 x 1021gm (C) 8 x 1021 gm (D) 7 x 1021 gm
(iii) Time required for one petalitre (1 PL = 1015 ltr) of water to flow past a given point is (approximately)
(A) 36 sec (B) 54 sec (C) 15 sec (D*) 28 sec
PHYSICAL CHEMISTRY
CLASS : XI TIME : 50 MIN DPP. NO.-2
Q1. Volume at NTP of 0.44 gm of CO2 is the same as that of
(A*) 0.02 gm of hydrogen gas (B) 0.085 gm of ammonia gas
(C) 320 mg of sulphur di oxide gas (D) none of these
Q2. 54.4 gm [Fe(H2O)5NO]SO4 contains

(A) 3.2 gm oxygen (B*) 32 gm of oxygen
(C) 6.4 gm of oxygen (D) 64 gm of oxygen
Q3. Weight of oyxgen in Fe2O3 and FeO is in the ratio for the same amount of iron is
(A*) 3 : 2 (B) 1 : 2 (C) 2 : 1 (D) 3 : 1
Q4. The total number of atoms present in 25 mg of Camphor, C10H16O are

(A) 9.89 × 1019 (B) 6.02 × 1020 (C*) 2.67 × 1021 (D) 2.57 × 1020
Q5. The element A (at. wt. = 12) and B(at. wt. = 35.5) combine to form a compound X. If 4 mole of B
combine with 1 mole of A to give 1 mole of X, the weight of 1 mole of X is:
(A) 47.5 gm (B) 74 gm (C*) 154 gm (D) 149 gm
Q6. Two flask of equal volumes are evacuated, then one is filled with gas A and other with gas B at the same
temperature and pressure. The weight of gas B at the same temperature and pressure. The weight of gas
B was found to be 0.8 gm while the weight of gas A is found to be 1.4 gm. The weight of one molecule
of B is
(A) 1.4 times as heavy as A (B) 0.4 times as heavy as A
(C) 0.57 times as heavy as A (D) 0.8 times as heavy as A
Q7. A sample of chalk contained as impurity a form of clay which loses 14.5% of its weight of water on
prolong heating. 5 gm of chalk on heating shows a loss in weight by 1.507 gm. Percentage of chalk in the
sample is
(A) 50% (B) 30.14% (C) 70% (D*) 35.55%
Q8. A pennsylvania bituminus coal is analysed as follows: Exactly 2.5 gm is weighed into a fused silica
crucible weighs 2.415 gm. The crucible next is covered with a vented lid and strongly heated until no
volatile matter remains. The residue coke buttons weighs 1.528 gm. The crucible is then heated without
the cover until all specks of carbon have disappeared, and the final ash weighs 0.245 gm. What are the
percentage of moisture, volatile combustible matter (VCM), fixed carbon (FC) and ash?
[Ans: 3.4%, 35.5 VCM, 51.3% FC, 9.8%ash]
Q9. A plant virus is found to consist of uniform cylindrical particles of 150Å in diameter and 5000 Å long.
The specific volume of the virus is 0.75 cm3/gm. If the virus is considered to be a single particle, find its
molecular weight. [Ans: 7.1 × 107]
Q10. A porous catalyst for chemical reaction has an internal surface area of 800 m2 per cubic centimeter of
bulk material. Fifty percent of the bulk volume consists of the pores (holes), while the other 50% of the
volume is made up of the soild substance. Assume that the pores are all cylindrical tubules of uniform
diameter d and length l, and that the measured internal surface area is the total area of the curved
surfaces of the tubules. What is the diameter of the each pore. [25Å]
PHYSICAL CHEMISTRY
CLASS : XI DPP. NO.- 3
Q.1 4.6 × 1022
atoms of an element weigh 13.8 gm. The atomic mass of the element is :
(A) 120 (B*) 180 (C) 35.5 (D) 108
Q.2 A mixture of gas ''X'' (mol. wt. 16) and gas Y (mol. wt. 28) in the mole ratio a : b has a mean molecular
weight 20. What would be mean molecular weight if the gases are mixed in the ratio b : a under identical
conditions (gases are non reacting).
(A*) 24 (B) 20 (C) 26 (D*) 40
Q.3 A sample of ammonium phosphate, (NH4)3 PO4, contains 3.18 mol of hydrogen atoms.The number of
moles of oxygen atoms in the sample is :
(A) 0.265 (B) 0.795 (C) 1.06 (D) 3.18
Q.4 1 gm-atom of nitrogen represents :

(A) 6.02 × 1023 N2 molecules (B) 22.4 lit. of N2 at N.T.P.
(C) 11.2 lit. of N2at N.T.P. (D) 28 g of nitrogen
Q.5 How many moles of C2H4O2 contains 6.02 × 1023 atoms of hydrogen? [Ans. 0.25]
Q.6 Calculate the % Na in a breakfast cereal which is advertised to contain 110 mg of sodium per
100 g of cereal. [Ans.0.11%]
Q.7 The total number of moles in a closed beaker containing : (approx)

58.5 g of NaCl + 602.2 × 1020 molecules of O2 + 2 g of hydrogen gas + 22.4 litres of SO2 gas at NTP
+ 30 ltr of Cl2 at 0.0821 atm and 27°C.
(Assuming no reaction taking place) (R = 0.0821 L atm K–1 mol–1) [Ans.3.2]
Q.8 1.12L CO2 gas at S.T.P. + 0.44 g CO2 – 6.02×1021 molecules of CO2 = ________ moles of CO2.
[Ans.0.05]
Q.9 How many neutrons are present in 180 mL water at (i) 4°C & (ii) 127°C & 0.821 atm pressure.
[Ans: 80 NA, 0.036 NA]
Q.10 An element (at. mass z) has a isotopic masses (z + 2) and (z – 1). Find the percentage abundance of the
heavier isotope. [Ans.33.3%]
PHYSICAL CHEMISTRY
Q.1 Density of dry air containing only N2 and O2 is 1.146 gm/lit at 740 mm and 300 K. What is % composition
of N2 by weight in the air.
(A) 78% (B) 82% (C) 73.47% (D) 72.42%
Q.2 Weight of nitrogen gas can be obtained from 720 kg of urea

(A) 226 kg (B) 350 kg (C*) 336 kg (D) 420 kg
Q.3 Calculate the percentage of CaO in

(i) CaCO3 (ii) CaC2O4 (iii) Ca3(PO4)2 (iv) Ca(OCl2)·CaCl2·Ca(OH)2·2H2O
Q.4 Determine the percentage composition of each elements of Mg3(PO4)2.

[Mg = 27.5 %; P = 23.7%; O = 48.8]
Q.5 The dot at the end of this sentence has a mass of about one microgram. Assuming that the black stuff is
carbon, calculate the approximate number of atoms of carbon needed to make such a dot.
[Ans:5 × 1016]
Q.6 The abundance of three isotopes of oxygen are as follows
% of O16 = 90%
% of O17 + % of O18 = 10%
Assume at. mass same as mass no. Find out % of O17 and O18, if the isotopic mass is 16.12.
[Ans.8, 2]
Q.7 Amphitamine (also called dexedrine) is a solid with molecular formula C9H13N. Its density is 0.949 g ml
(i) Total number of atoms in 18.04 gm of amphitanine are
(A) 7 × 1022 (B) 8 × 1022 (C) 7.5 × 1022 (D) 6 × 1022
(ii) Volume of 4.5 mol of dexedrine is
(A) 300 ml (B) 350 ml (C) 450 ml (D) 640 ml
(iii) The weight of amphitemine that contains exactly the same number of H atoms as there are in 171.1
gm of water is
(A) 197.4 gm (B) 167.7 gm (C) 217.4 gm (D) 205.7 gm
PHYSICAL CHEMISTRY
CLASS : XI(J-BATCH) DPP. NO.-5
Q.1 The weight of 350 ml of diatomic gas at 0°C and 2 atm pressure is 1 gm. What is the atomic weight of
the gas ?
(A) 17.7 (B*) 15.99 (C) 27.7 (D) 38
Q.2 A mixture of CuO and Cu2O contain 88% Cu. What is the percentage of CuO present in the mixture?
(A) 91.35% (B*) 9.075% (C) 18.9% (D) 20%
Q.3 The vapour density of gas A is four times that of B. If molecular mass of B is M, then molecular mass of A is
(A) M (B*) 4M (C) M/4 (D) 2M
Q.4 When 10 gm of Na2SO4. xH2O is heated to dryness 5.035 gm water vapour is produced, therefore the
value of x is
(A) 10 (B) 7 (C) 6 (D*) 8
Q.5 How many moles of potassium chlorate to be heated to produce 11.2 litre oxygen at NTP?
3
[KClO3  KCl + O2]
2
1 1 1 2
(A) mol (B*) mol (C) mol (D) mol
2 3 4 3
Q.6 What is fertilizer rating of NH4NO3 (Fertilizer rating = N content by mass). Compare this with urea.
[Ans.35%]
Q.7 A compound contains 8% sulphur by mass. What will be its least molecular weight. [Ans.400]
Q.8 If pure Mohr’s salt crystals contain 15% iron and 30% water. How much Fe and how much water
should be taken to get 20 gm of its crystals. [ Ans.Fe = 3gm ; H2O = 6 gm ]
Q.9 How many kg of sodium and liquid chlorine can be obtained from 585 metric ton of salt ?
[Ans.230, 355 MT]
Q.10 A clay was partially dried and then contained 50% silica and 7% water. The original clay contained 12%
water. What is the % of silica in the original sample? [Ans.47.31%]
Q.11 A sample of impure cuprite Cu2O contains 66.6% copper. What is the % of pure Cu2O by mass in the
sample. [Ans.75%]
Q.12 A certain compound was known to have a formula which could be represented as [PdCxHyNz] (ClO4)2.
Analysis showed that the compound contained 30.15% carbon and 5.06% hydrogen. When converted
to the corresponding thiocyanate, [PdCxHyNz](SCN)2, the analysis was 40.46% carbon and 5.94%
hydrogen. Calculate the values of x, y and z. [At. mass of Pd is 106] [Ans. x = 14, y = 28, z = 4]
Q.13 8 gm sulphur are burnt to form SO2 which is then oxidised by chlorine to sulphate. The solution is now
treated with BaCl2 solution. Find the amount of BaSO4 precipitated in mol. [Ans.0.25 mol]
Q.14 A piece of plumber’s solder weighing 3.0 gm was dissolved in dilute nitric acid, then treated with dilute
H2SO4. This precipitated the lead as PbSO4, which after washing and drying weighed 2.93gm. The
solution was then neutralized to precipitate stannic acid, which was decomposed by heating, yielding
1.27 gm SnO2. What is the analysis of the solder. (Pb = 207.2 amu, Sn = 118.7 amu)
(A*) 66.7% Pb, 33.3% Sn (B) 33.3% Pb, 66.7% Sn
(C) 1 gm Pb, 2 gm Sn (D*) 2 gm Pb, 1 gm Sn
PHYSICAL CHEMISTRY
Q.1 12 mol of H2 and 11.2 mol of Cl2 are mixed and exploded. The composition by mol of mixture is
(A) 24 mol of HCl (B) 0.8 mol Cl2 and 20.8 mol HCl
(C*) 0.8 mol H2 & 22.4 mol HCl (D) 22.4 mol HCl
Q.2 Methyl benzoate is prepared by the reaction between benzoic acid and methanol, according to the equation
C6H5COOH + CH3OH  C6H5COOCH3 + H2O
Benzoic acid Methanol Methyl benzoate
In an experiment 24.4 gm of benzoic acid were reacted with 70.0 mL of CH3OH. The density of
CH3OH is 0.79 g mL–1. The methyl benzoate produced had a mass of 21.6 g. What was the percentage
yield of product ?
(A) 91.7% (B*) 79.4% (C) 71.5% (D) 21.7%
Q.3 One mole of a mixture of CO and CO2 requires exactly 20 gram of NaOH in solution for complete
conversion of all the CO2 into Na2CO3. How many moles more of NaOH would it require for conversion
into Na2CO3 if the mixture (one mole) is completely oxidised to CO2:
(A) 0.2 (B) 0.5 (C) 0.4 (D*) 1.5
Q.4 How many ml of bromine will have the same mass as 12.5 ml of Hg if the densities of bromine and Hg are
3.12 g/ml and 13.6 g/ml respectively :
(A*) 54.5 ml (B) 50.5 ml (C) 25.4 ml (D) 45.5 ml
Q.5 In an experiment 2.847 gm of pure MOCl3 was allowed to undergo a set of reactions as a result of
which all the Cl was converted to AgCl. The weight of AgCl was 7.2 gm. Find at. wt. of M.
[Ans.47.72]
Q.6 According to following reaction :
A + B O3  A3O4 + B2O3
Find the number of moles of A3O4 produced if 1 mole of A is mixed with 1 mole of B O3. [Ans.1/3]
Q.7 In an electric arc tube A, 140 g N2 is taken and in tube B, 20 g H2 is taken . When half the mass of
substance in tube A is transferred to B, reaction took place in B. After the reaction is complete, half of the
mass of substance in B is now transferred to A. Find out the final composition of gases in moles inA and
B.[no reversibility] [Ans.A (2.084 mol N2 ; 3.33 mol NH3) ; B ( 1.25 mol H2 ; 2.5 mol NH3)]
Q.8 A 0.596 gm sample of a gaseous compound containing only B and H occupies 484 cm3 at STP. When
the compound is ignited in excess oxygen, all its hydrogen is recovered as 1.17 g H2O, and all the B is
left over as B2O3. What are the empirical formula and molecular formula, and the molecular weight of B
and H compound. What weight of B2O3 is produced by the combustion.
[Ans.(B2H6), 27.6 gm, 1.5 gm]
Q.9 Window glass is made by mixing soda ash , limestone & silica & then heating to 1500°C to drive off
CO2 from the mixture. The resultant glass contains 12% Na2O, 13% CaO & 75%. Silica by mass. How
much of each reactant would you start to prepare 0.35 kg of glass? [Ans.0.072 g, 0.081 g, 0.26 g]
Q.10 An unidentified bivalent metal M reacts with an unidentified halogen X to form an unknown compound
of halogen gas.When 1.12 g of it is heated, 0.72 g of MX is obtained along with 56 ml of halogen gas at
STP. Identify the metal. [Ans.Cu]
PHYSICAL CHEMISTRY
Q.1 An evacuated glass bulb was weighed, then filled with oxygen and reweighed, the difference in weight
was 0.25 gm. The operation was repeated under identical conditions of (P, V, T) with unknown gas “X”.
The difference was 0.375 gm, find molecular weight. [Ans. Mwt.= 48]
Q.2 600 ml of a mixture of ozone and oxygen at STP weighs one gm. Calculate the volume of ozone at STP
in the mixture. [Ans.200 ml]
Q.3 It is known that when 1 mole of H+ reacts with 1 mole of OH– x kJ of energy is released. Suppose
200 ml of 1 M XOH is mixed with 100 ml 2M H2Y [dibasic acid]. Calculate the total amount of energy
released. Assume that dissociation of the acid & base is complete & requires no energy. What should be
the volume of each solution that should be taken to obtain 100 ml of solution & maximum release of
energy. [Ans. 0.2x kJ; 80 ml, 20 ml]
Q.4 To a sample of an element X (at. wt. 70) element Y (at. wt. 120) is added as impurity. The ratio of atoms
of X to Y in the mixture is 1 : 10–7. How many gms of Y will be required for 100 gm of X for this ratio.
[Ans.1.714×10–5 gm]
Q.5 Xenon is 0.0000087% by volume of the dry atmosphere. Express it in ppb (vol.) [Ans.87 ppb]
Q.6 A ‘w’ gm mixture of AgCl & AgBr undergoes a loss in wt. by 5% if it is exposed to excess chlorination.
Calculate the percentage composition of the mixture. [Ans. % AgBr = 21.12 % AgCl = 78.88% ]
Q.7 A certain compound has the molecular formula X4O6. If 10 gm of X4O6 has 5.72 g X, atomic mass of X is
(A*) 32 amu (B) 37 amu (C) 42 amu (D) 98 amu
Q.8 If ratio of mole fraction of solute to solvent is unity, what would be % by wt. (concentration of solute)
(M solute = molecular mass of solute, M solvent = M molecular mass of solvent)
M solute
(A*) × 100 (B) 50%
(M solute  M solvent)
M solute
(C) 66.67 % (D) × 100
M solvent
Q.9 Molarity of pure ethanol (C2H5OH) with density d g/ml.
21 25
(A) (B) 25 d (C*) 21 d (D)
d d
Q.10 w1 gm of hydrated blue copper sulphate (CuSO4 · 5H2O) crystals are mixed with w2 gm of water. If
density of the crystal (hydrated) is d1 gm / ml, then calculate the molarity & molality of Cu2+, SO 24 ions,
if resultant solution has density d2 gm / ml. Also calculate the volume change.
4w1  d 2 4 w1  w1 ( w1  w 2 ) 
[Ans. ;   w2   ml ]
( w1  w 2 ) ( w 2  0.36w1 )  d1 d2 
Q.11 Calculate the moles of BaSO4 obtained in each case if excess of BaCl2 is reacted with (a) H2SO4
solution produced from collecting all SO3 dissolved in 100 gm of 104.5 % oleum & then reacted with
excess of water. (b) H2SO4 taken from 100 g 104.5% oleum (c) H2SO4 solution obtained when 4.5 gm
1
water is added to 100 gm oleum labelled as 104.5 %. [Ans. (a) , (b) 0.816, (c) 1.066]
4
PHYSICAL CHEMISTRY
Q.1 One mole of N2O4(g) at 300 K is kept in a closed container at 1 atm. It is heated to 900 K when 20%
by mass of N2O4 decomposes to NO2(g). The resultant pressure is
(A) 1.2 atm (B*) 3.6 atm (C) 2.4 atm (D) none of these.
Q.2 2.0267 g of nitrate of a univalent metal was heated with excess of previously ignited silica. A lessin weight
of 1.08 gm took place due to total expulsion of the nitrate part as N2O5% of NO3 in salt is
(A) 20 (B) 30.6 (C*) 61.2 (D) 91.8
Q.3 Benzene diazonium chloride was decomposed in the presence of hypophosphorous acid to evolve N2
gas quantitatively. The gas was found to be 36.9 mL at 1 atmp and 27°C. Find the amount in gms of the
substance decomposed.[Benzene diazonium chloride = C6H5N2Cl] [Ans.210 mg]
Q.4 A sample of 50% CuS reacts with 50% HNO3 according to the reaction,
3CuS + 8HNO3  3Cu(NO3)2 + 3S + 2NO + 4H2O
which yields 320 g of 40% sulphur with 40% yield. How much of the reactants were taken in the reaction.
[Ans. 1910, 3360]
Q.5 For a mixture of only two gases H2 & CO having unknown composition
(a) What could be the maximum & minimum values of V.D. for above mixture
(b) What is the composition by moles of the mixture if V.D. is 4.25
[Ans. (a) Lower value : 1 Higher value :14; (b) Mavg = 8.5  CO = 25%, H2= 75% ]
Q.6 Certain metals have a tendency to form compounds which have a “complex structure” & are known as
complex compound. If M is a metal with such tendencies & is forming compound like [M(NH3)5 Br]Br2.
If it is known that solution of these furnish only those ions which are outside the co-ordination sphere
“[ ]” (the bracketed part) then calculate the wt. of AgBr ppt obtained when w gm solution of the
complex compound containing 40% by wt. of the C.C. is reacted with w gm solution of AgNO3 containing
17% AgNO3 by wt.[At. wt. of M =75] [Ans. 0.188 w gm]
Q.7 On analysis of blood sample of a driver suspected of being drunk over than the permissible value, it was
obtained that 60 gm sample reacted with 30 ml of 8 M K2Cr2O7 (acidic soln.). If the permissible value
for the alcohol content in the blood is 1 % by mass, will the driver be prosecuted for drunken drining.
[Assume K2Cr2O7 reacts only with the alcohol present in blood.]
Reaction : 2K2Cr2O7 + 8H2SO4 + C2H5OH  2Cr2(SO4)3 + 11H2O + 2K2SO4 + 2CO2
Q.8 Mr. Gupta purchase milk from Agarwal dairy which sells milk at a price of R1 Rs/kg. The milk contains
fats and ‘sapreta’ ( fat free milk) only & density of fats is d1 gm/ml & density of ‘sapreta’ (fat free milk)is
d2 gm/ml. The % of fats in the milk is 4%(w/w). Calculate
(a) The pricing in rupees per litre of milk.
(b) If Mr. Agarwal purchase milk at the rate of R2 Rs/ Litre, then establish a relationship between given
parameters so that Mr. Agarwal makes profit by selling the milk at his rate.
 960 40 
[Ans.1000R1 >  d  d  R 2 ]
 2 1
PHYSICAL CHEMISTRY
Q1. If a one litre sample of a gas at 760 torr is compressed to 0.8 litre at constant temperature. Calculate the
final pressure of the Gas. [950 torr]
Q2. At what temperature does a sample of gas occupy 4.0 litre at 1.11 atm, if it initially occupied 2.22 litre
at 1.0 atm and 600C. [393oC]
Q3. To what temperature must a neon gas sample be heated to double its pressure if the initial volume of gas
at 750C is decreased by 15%. [318.6o]
Q4. A meteorological balloon has a radius of 1m. when released from sea level at normal pressure (1 atm)
and 250C and expanded to a radius of 3m. When it has risen to its maximum height altitude where the
temperature was –200C. What is the pressure inside the balloon at that height. [0.03144 atm]
Q5. A refrigeration tank holding 5.0 litre Freon (C2Cl2F4) at 250C and 3 atm. Pressure developed a leak and
repaired, the tank has lost 76 gm of gas. What was the pressure of the gas remaining in the tank.
[0.828 atm]
Q6. If the maximum volume of a cylinder in an automobile engine is 0.63 lt. the volume after the air fuel
mixture is compressed in 0.068 lt, and the fuel mixture is drawn at 1 atm pressure, what is the pressure
in the cylinder at maximum compression? [9.26 atm]
Q7. A large irregularly shaped closed tank is first evacuated and then connected to a 50 litre cylinder containing
compressed nitrogen gas. The gas pressure in the cylinder originally at 21.5 atm, falls to 1.55 atm after
it is connected to the evaculated tank. Calculate volume of the tank. [643.55 lt]
Q8. A gaseous system has a volume of 580 cm3 at a certain pressure. If its pressure is increased by 0.96 atm,
its volume becomes 100 cm3. Determine the pressure of the system. [0.2 atm]
Q9. Liquefied natural gas (LNG) in mainly methane (MW = 16). A 10 m3 tank is constructed to store LNG
at –1640C and 1 atm pressure under which conditions its density is 415 kg/m3. calculate the volume of
a storage tank capable of holding the same mass of LNG as a gas at 200C and 1 atm pressure.
[6231.74 m3]
Q10. In the estimation of molar mass of an organic base by chloroplatinate

salt method, different masses of residue obtained (w2 gm) are plotted
against known amount of its salt (w1 gm), and following curve is plotted.
With the help of given graph, calculate molar mass of organic base.
Given that molar mass of salt of the base is 1408. (Pt = 195)
[89]
PHYSICAL CHEMISTRY
Q1. According to the ideal gas law, the molar volume of a gas equals:
RT RT RT
(A*) (B) (C) 22.4L (D) g
p pV pV
Q2. A fire extinguisher contains 4.4 kg of CO2. The volume of CO2 delivered by this fire extinguisher at
room temperature is:
(A) 24.5 litres (B) 10 x 24.5 litres (C*) 100 x 24.45 litres (D) 1000 x 24.5 litres
Q3. What is the conclusion you would draw from the following graphs?
(A) As the temperature is reduced, the volume as well as the pressure increase.
(B) As the temperature is reduced, the volume becomes zero and the pressure reaches infinity
(C*) As the temperature is reduced, both volume and the pressure decrease.
(D*) A point is reached, where theorectically, the volume as well as the pressure becomes zero.
Q4. At the top of the mountain the thermometer reads 00C and the barometer reads 710 mm Hg. At the
bottom of the mountain the temperature is 300C and pressure is 760 mm Hg. Density of air at the
top with that at the bottom is
(A) 1 : 1 (B*) 1.04 : 1 (C) 1 : 1.04 (D) 1 : 1.5
Q5. A quantity of gas is collected in a graduated tube over the mercury. The volume of the gas at 200C
is 50.0 mL and the level of the mercury in the tube is 100 mm above the outside mercury level. The
barometer reads 750 mm. Volume at STP is
(A*) 39.8 mL (B) 40 mL (C) 42 mL (D) 60 mL
Q6. I, II, III are three isotherm respectively at T1, T2 and T3. Temperature will be in order
(A) T1 = T2 = T3
(B) T1 < T2 < T3
(C*) T1 > T2 > T3
(D) T1 > T2 = T3
Q7. A certain mountain is 14,100 feet above sea-level. The pressure at the top is 17.7 inches of Hg. If
you blow up a balloon at sea level, where the pressure measured to be 29.7 inches and carried it to
the top to the top of the mountain, by what factor would its volume change
(A) 29.7 –17.7 (B*) 29.7/17.7 (C) 17.7/29.7 (D) no change
Q8. 1.509 g sample of an osmium oxide (OsOx) which melts at 400C and boils at 1300C is placed in a
cylinder with a movable piston that enables the cylinder to expand against the atmospheric pressure
of 745 torr. When the sample is heated to 2000C, it is completely vaporized and the volume of the
cylinder expands to 235 mL. Choose the correct alternatives
(A*) the molar mass of the oxide is 254 g/mol (B) the molar mass of the oxide is 238 g/mol
(C*) x = 4 (D) x = 3
Q9. Choose the correct statements
(A*) The density of a gas varies with temperature
(B*) The density of a gas varies with pressure
(C) The volume of a gas always increases with the temperature increases
(D*) The volume of a gas may not increase with the temperature increases
Q10. At a temperature T K , the pressure of 4.0 g argon in a bulb is p. The bulb is put in a bath having
temperature higher by 50K than the first one. 0.8 g of argon gas is to be removed to maintain
original pressure. The temperature T is equal to
(A) 510 K (B*) 200 K (C) 100 K (D) 73 K
PHYSICAL CHEMISTRY
CLASS : XI (J) DPP. NO.- 11
Q1. Equal weights of ethane and hydrogen are mixed in an empty container at 25oC. Total pressure
exerted by hydrogen is:
(A) 162 (B) 1 : 1 (C) 1 : 16 (D*) 15 : 16
Q2. A 0.5 litre flask contains gas ‘A’ and a one litre flask contains gas ‘B’ at the same temperature. The
density of gas ‘A’ is 3.0 gm/l and that of ‘B’ 1.5 gm/l. The molecular mass of gas ‘A’ is one half that
of gas ‘B’. The ratio of pressures PA/PB exerted by the gases is:
(A*) 4 (B) 3 (C) 2 (D) 1
Q3. A 1 : 1 mixture (by weight) of hydrogen and helium is enclosed in a one litre flask at temperature
0oC. Assuming ideal behaviour, the partial pressure of helium is found to be 0.42 atm then
concentration of hydrogen would be
(A*) 0.0375 (B) 0.028 (C) 0.0562 (D) 0.0187
Q4. Daltions’s law of partial pressure is not applicable to:

(A) O2 + O3 (B) CO + CO2 (C*) NH3 + HCl (D) I2 + O2
Q5. To which of the following gaseous mixture’s Dalton’s law not applicable
(A) Ne + He + SO2 (B*) NH3 + HCl + HBr (C*) NO + O2 + CO2 (D) N2 + H2 + O2
Q6. A 1.0 g sample of air consists of approximately 0.76 g of nitrogen and 0.24 g of oxygen. This
sample occupies a 1.0L vessel at 200C. Then
(A) the partial pressure of N2 is 1.45 atm (B) the partial pressure of O2 is 0.36 atm
(C*) the total pressure is 0.83 atm (D) the total pressure is 1.05 atm.
Q7. Weight of 112 mL of oxygen at NTP on liquefaction would be:

(A) 0.32 g (B) 0.64 g (C*) 0.16 g (D) 0.96 g
Q8. A flask contain 36% nitrogen, 39% oxygen and 25% hydrogen. If the total pressure of the mixutre of
gases is 500 mm, the partial pressure of oxygen is
(A) 120 mm (B) 145 mm (C) 195 mm (D) 210 mm
Q9. A gas in an open container is heated from 27oC to 127oC. The fraction of the original amount of gas
escaped from the container will be
(A) 3/4 (B) 1/2 (C) 1/4 (D) 1/8
Q10. A gas in an open container is heated from 27oC to 127o. The fraction of the original amount of gas
remaining in the container will be
(A) 3/4 (B) 1/2 (C) 1/4 (D) 1/8
PHYSICAL CHEMISTRY
Q1. A mixture of three gases A (density = 0.82), B (density = 0.26) and C (density = 0.51) is enclosed
in a vessel at constant temperature when equlibrium is established:
(A) Gas A will be at the top in the vessel (B) Gas B will be at the top in the vessel
(C) Gas C will be between gases A and B in the vessel
(D*) The gases will mix homogeneously throughout the vessel.
Q2. Two gases A and B having same volume diffused through a pin hole in 10 and 5 seconds respectively.
The molecular weight of A is 48. What would be the molecular weight of B?
(A*) 12.0 (B) 15.5 (C) 18.0 (D) 14.5
Q3. Under the similar conditions of P and T the rate of diffusion of hydrogen is about:
(A) Twice that of He (B) Four times that of He
(C) One half that of He (D*) 1.4 times that of He
Q4. Vaporisation of 0.24 gm of a volatile substance gave 45 ml of vapour at NTP. What will be the vapour
density of the substance (density of H2 at NTP = 0.089 gram per litre)
(A) 95.39 (B) 5.993 (C) 95.93 (D) 59.93
Q5. A vessel contains 1.7 g NH3 gas and 5.1 g H2S gas. The value of effective molar mass of this gaseous
mixture at 27oC will be
(A) 34 (B) 27.2 (C) 25.5 (D) 68
Q6. One mole of N2O4(g) at 300 K is kept in a closed container under one atmosphere. It is heated to 600
K when 20% by mass of N2O4(g) decomposes to NO2(g). The resultant pressure is
(A) 1.2 atm (B) 2.4 atm (C) 2.0 atm (D) 1.0 atm
Q7. The rate of diffusion of a gas having molecular weight just double of molecular weight of nitrogen gas, is
56 ml per second. The rate of diffusion of nitrogen will be
(A) 56 ml/sec (B) 28 ml/sec (C) 112 ml/sec (D) 79.19 ml/sec
Q8. 50 ml of hydrogen diffuses out through a small hole from a vessel in 20 minutes. Time needed for 40 ml
of oxygen to diffuse out is
(A) 12 minutes (B) 64minutes (C) 8 minutes (D) 32 minutes
Q9. 16 ml of hydrogen was found to diffuse in 60 seconds. What volume of suphur dioxide would diffuse in
the same time under the same conditions
(A) 2 ml (B) 4 32ml (C) 2 2ml (D) 60 ml
Q10. Two grams of H2 diffuses from a container in 10 minutes. How many gram of oxygen would diffuse
through the same container in the same time under similar conditions
(A) 0.5 gms (B) 4gms (C) 6gms (D) 8gms
Q11. How much 85% pure salt cake (Na2SO4) could be produced from 250 kg of 95% pure salt NaCl
in the reaction, 2NaCl + H2SO4  Na2SO4 + 2HCl (339 kg)
PHYSICAL CHEMISTRY
Q1. A sample of gaseous hydrocarbon occupying 1.12 litre at NTP when completely burnt in air produced
2.2 gm of CO2 and 1·8 gm of H2O. Calculate the weight of compound taken and the volume of O2 at
NTP required for its burning. Find the molecular formula of the hydrocarbon?
[Ans: CH4, 0.8 gm, 2.24 litre]
Q2. 9 volumes of a gaseous mixture consisting of a gaseous organic compound A and just sufficient amount
of oxygen required for complete combustion yielded on burning 4 volumes of CO2, 6 volumes of water
vapour & 2 volumes of N2, all volumes measured at the same temperature and pressure. If the compound
A contained only C, H and N (i) how many volumes of oxygen are required for complete combustion
and (ii) what is the molecular formula of the compound A? [Ans: (i) 7 volumes; (ii) C2H6N2]
Q3. 20 ml of a mixture of C2H2 and CO was exploded with 30 ml of oxygen. The gases after the reaction
had a volume of 34 ml. On treatment with KOH, 8 ml of oxygen remained. Calculate the composition of
the mixture. [Ans: C2H2 = 6 ml, CO = 14 ml]
Q4. 40 ml of a mixture of hydrogen, CH4 and N2 was exploded with 10ml of oxygen. On cooling, the gases
occupied 36.5 ml. After treatment with KOH, the volume reduced by 3 ml and again on treatment with
alkaline pyrogallol, the volume further decreased by 1.5 ml. Determine the compoistion of the mixture.
[Ans:H2 = 12.5%, CH4 =- 7.5%, N2 = 80%]
Q5. 1 litre of a mixture of CO and CO2 is taken. This mixture is passed through a tube containing red hot
charcoal. The volume now becomes 1.6 litres. The volumes are measured under the same condition.
Find the composition of the mixture by volume. [Ans. CO2 = 0.6 lt, CO = 0.4 lt]
Q6. 40 ml of ammonia gas taken in an endiometer tube was subjected to sparks till the volume did not further
change. The volume was found to increase by 40 ml. 40 ml of oxygen gas then mixed and the mixture
was further exploded. The gases remained were 30 ml. Deduce the formula of ammonia. [Ans: NH3]
Q7. When 100 ml of a O2–O3 mixture was passed through turpentine, there was reduction of volume of
20ml. If 100 ml of such a mixture is heated, what will be increase in volume? [Ans: 10 ml]
Q8. 9.5 ml of a hydrocarbon gas was exploded with excess of oxygen. On cooling it was found to have
undergone a contraction of 15 ml, if the vapour density of the hydrocarbon is 14, determine its molecular
formula. (C = 12, H = 1) [Ans: C2H4]
Q9. A mixture of 20 ml of CO, CH4 and N2 was burnt in excess of O2 resulting in reduction of 13 mL of
volume. The residual gas was then treated with KOH solution to show a contraction of 14 mL in volume.
Calculate volume of CO, CH4 and N2 in mixture. All measurements are made at constant pressure and
temperature. [Ans: vol. of CO = 10 ml; Vol. of CH4 = 4 ml; Vol. of N2 = 6 ml]
Q10. 60 ml of a mixture of nitrous oxide & nitric oxide was exploded with excess of hydrogen if 38 ml of N2
was formed calculate the volume of each gas in the mixture. [Ans: NO = 44 ml; N2O = 16 ml]
PHYSICAL CHEMISTRY
Q1. 0.2475 g of organic chemistry on combustion gave 0.495 g of CO2 and 0.2025 g of H2O. Calculate the
% of C and H in the compound. [Ans: C = 55.54%; H = 9.09%]
Q2. 0.93 g of an organic compound on combustion gave 2.64 g of carbon dioxide and 0.63 g H2O. Calculate
the percentage of C and H in the compounds. [Ans: C = 77.42%; H = 7.53%]
Q3. 0.6 g of organic compound gave 100 cm3 of nitrogen collected at 270C and 715 mm pressure in Duma’s
method. Calculate the percentage of nitrogen in the organic compound. (aqueous tension at 270C =- 15
mm) [Ans: 17.46%]
Q4. 0.303 g of organic compound when Kjeldahl’s produced ammonia which was absorbed in 50 ml of
0.05 M H2SO4. The excess acid required 25 ml of 0.1 M NaOH for neutralisation. Find out the
percentage of nitrogen in the organic compound. [Ans: 11.56%]
Q5. 0.5 g of organic compound produced ammonia in Kjeldahl’s method which was absorbed in 50cm3 of
1M H2SO4. The residual acid requried 60cm3 of semi molar KOH solution. What is the percentage of
N in the compound? [Ans: 56%]
Q6. 0.2595 g of organic compound gave 0.5825 g of barium sulphate precipitate in Carius method. Calculate
the percentage of S in the compound. [Ans: 36.78%]
Q7. An organic compound weighing 1.5 g gave 2.5090 g of Mg2P2O7 during estimation of Phosphorus.
Calculate the % of P. [Ans: 46.71%]
Q8. 0.2585 g of organic compound on heating with conc. HNO3 and silver nitrate in Carius tube gave
0.3894 g of silver iodide. What is the percentage of iodine in the compound? [Ans: 81.4%]
Q9. 0.98 g of the chloroplatinate of some diacid base when ignited left 0.39g of platinum as residue. What is
the molecular mass of the base?(at. mass of Pt = 195) [Ans: 80]
Q10. 0.25 g of an organic compound containing carbon, hydrogen and oxygen was analysed by the combustion
method. The increase in the mass of calcium chloride tube and the potash bulbs at the end of the operation
was found to be 0.15 g and 0.1837 g respectively. Calculate the percentage composition of the compound.
[Ans: % of H = 6.66; % of C = 20.04; % of O = 73.30]
PHYSICAL CHEMISTRY
Q1. Kinetic energy of gases presumes collision between molecule to be perfectly elastic beacuse
(A) collisions will not split the molecule (B) the molecules are tiny
(C*) the molecules are rigid (D) the temperature remains constant irrespective of collisions
Q2. According to the kinetic theory of gases, in an ideal gas between two successive collisions a gas molecules
travels
(A*) in a straight path (B) with an accelerated velocity
(C) in a circular path (D) in a wavy path
Q3. If the ratio of molecular weight of two gases is 1:4, what would be the ratio of their root mean square
velocities at the same temperature
(A) 1:2 (B*) 2:1 (C) 1:4 (D) none of these
Q4. The temperature of an ideal gas is increased from 140 K to 560 K. If at 140 K the root-mean
square velocity of the gas molecles is V, at 560 K it becomes
(A) 5V (B*) 2V (C) V/2 (D) V/4
Q5. Translational kinetic energy for 2 moles of a gas at 270C is

(A*) 7.48 x103 J (B) 6.48 x103 J (C) 5.48 x10 3 J (D) 4.48 x103 J
Q6. The average kinetic of a molecule of SO2 at 270C is E. What would be the average kinetic energy of
a molecule of CO2 at the same temperature
E  64 E  44
(A) (B) (C) E (D*) 22  E
44 64
Q7. Two flasks X and Y have capacity 1 litre and 2 litre respectively. Each of them contains 1 mole of a gas.
The temperature of the flask are so adjusted that the average speed of molecules in X
is twice as that in Y. The pressure in flask X would be
(A) 8 times of that in Y (B) twice of that in Y (C) same as that in Y (D*) half of that in Y
Q8. For a monoatomic gas kinetic energy = E. The relation with rms velocity is
1/ 2 1/ 2 1/ 2 1/ 2
 2E   3E   E   E 
(A*) u    (B) u    (C) u    (D) u   
 m   2m   2m   3m 
Q9. If a gas is expanded at constant temperature

(A*) the pressure decreases
(B*) the kinetic energy of the molecules remains the same
(C) the kinetic energy of the molecules decreases
(D) the number of molecules of the gas increases
Q10. The volume of two gases A and B are the same under identical conditions of temperature and pressure.
They would differ in
(A) kinetic energy (B*) rate of effusion
(C) number of molecules (D*) boiling point
PHYSICAL CHEMISTRY
Q1. At what temperature would the most probable speed of CO2 molecules be twice that at 500C.
[10190C]
Q2. At what temperature would N2 molecules have the same average speed as He atoms at 330?
[2310 K]
Q3. Calculate the avg. & total K.E. of 0.5 mole of an ideal gas at 00C. [Kavg = 3404.6 J/mol; Ktotal = 1702.3]
Q4. Oxygen at 1 atmosphere and 00C has a density 1.429 g/litre. Find the rms speed of oxygen molecule.
[461.2 m/s]
Q5. A gas bulb of 1 litre capacity contains 2 x 1021 molecules of Nitrogen exerting a pressure of 7.57 x 103
N/m2. Calculate the rms velocity and temperature of the gas molecules. If the ratio of most probable
speed to the rms speed is 0.82, calculate the most probable speed of these molecules at this temperature.
[C = 494.22 m/s,  = 405.3 m/sec]
Q6. A flask contains 1 mol of N2 molecules at 100K. How many molecules have a velocity in the range of
300 to 300.1 m/sec.? Calculate the ratio of the number of molecules within the 0.1 m/sec. range of
velocity at 300m/sec. to that it 500m/sec.
Q7. According to the figure, calculate the value of speed at which the
two curves cross each other.
Q8. Calculate the no. of molecules in one mole of an ideal gas that have energies greater than four times the
average thermal energy at 250C and 500C.
From 9 to 11
For a gaseous molecular system the probability of finding a molecule with velocity between v and v + dv
is given by
mv 2
dN  m   2 kT
 e vdv
N  kT 
where m = mass of gas molecule ; k = Boltzmann constant
T = temperature of gas ; dN = no. of molecules with velocity between v to v+dv
N = total no. of molecules
Q9. At some temperature the fraction of molecules with kinetic energies between E and E + dE is given by
1  E / kT m  E / kT
(A) e EdE (B) e dE
kT kT
1  E / kT  m   E / kT
(C) e dE (D)  e EdE
kT  kT 
Q10. Fraction of molecules with K.E. greater than E is given by

E   E
1  E / kT 1  E / kT 1  E / kT 1  E / kT
(A)  kT e dE (B)  e EdE (C)  e dE (D)  kT e EdE
0 E
kT E
kT 0
Q11. Ratio of fraction of molecules with K.E. greater than and less than average K.E. is
1 1 e1/ 2 e3 / 2
(A) (B) (C) (D) 3 / 2
e1 / 2  1 e3 / 2  1 1  e1/ 2 e 1
Q12. Assuming ideal gas behaviour, how many atoms of Ar are contained in a typical human breath of 0.5 lt
at 1 bar and 370C. Air consists of 1% Ar atoms. Assuming that the Ar atoms from the last breath of Plato
have been distributed randomly throughout the atmosphere (5 × 1018m3), how long would it take to
breath one of these atoms? A typical adult breath rate is 10min–1.
Q13. Consider a 20 litre sample of moist air at 600C under a total pressure of 1 atm in which the partial
pressure of water vapour is 0.12 atm. Assume the composition of dry air given is 78 mol% N2, 21 mol%
O2 and 1 mol% Ar.
(a) What are the mole percentages of the gases in the sample ?
(b) At 600C, equilibrium vapour pressure is 0.2 atm. What volume must the mixture occupy at 60C if the
relative humidity is to be 100%?
(c) What fraction of the water will be condensed if the total pressure of the mixture is increases isothermally
to 200 atm?
Q14. A water gas mixture has the composition by volume of 50% H2, 45% CO and 5% CO2.
(i) Calculate the volume in litres at STP of the mixture which on treatment with excess steam will contain 5
litres of H2. The stoichiometry for the water gas shift reaction is
CO + H2O  CO2 + H2
(ii) Find the density of the water gas mixture in kg/m3.
(ii) Calculate the moles of the absorbants KOH, Ca(OH)2 and ethanolamine (HO–CH2–CH2–NH2) required
respectively to collect the CO2 gas obtained.
Q15. Suppose you are a manager of a fish drying unit. You are to dry 200 kg of fish containing 40% water on
wet basis. The drier specification is mentioned in the figure:
SVP at 2000C = 40 mm of Hg
SVP at 1000C = 25 mm of Hg
What is the process time of the drier? [12.57 hr]
PHYSICAL CHEMISTRY
Q1. The final speed of the electron accelerated from rest of mass m and charge e through a potential
difference V in vacuum is
(A) eV 2m  (B) 2 eV m (C*) 2 eV m (D) eV m
Q2. When an electron ray deflected by magnetic field (strength B) and brought back to its original position by
an electric field (strength E) then its momentum is
mB mE m E2 mE
(A) (B*) (C) (D)
E B B B2
–
Q3. es is an atom are held by
(A) coloumbic forces (B) nuclear forces (C) gravitation forces (D) Vander-waal’s forces
Q4. As per Rutherford the space between proton and e- is hydrogen atom is
(A) filled with air (B) empty (C) filled with magnetic radiation (D) none
Q5. Rutherford created a theoritical picture of the atom based on

(A) stars in galaxy (B) model of planets revolving round the sun
(C) behaviour of waves in the oceans (D) clouds in the sky that move & mix with changing shapes
Q6. In Rutherford’s experiment, a few in millions of  -particle suffer 180o concluded that
(A) e-s revolve removed the nucleus (B) space between es- & nucleus is empty
(C) nucleus occupies much smaller volume than that of atom
(D) all the above
Q7. When  -particles are sent thru a thin metal foil most of them go straight thru the foil because:
(A)  -particles are much heavier than es- (B)  -particles are the charged
(C) most of the part of atom is empty space (D)  -particles more with high speed
Q8. To what maximum distance will an  -particle with kinetic energy 0.4 Mev approach in case of a head
on collision with stationary lead nucleus Z = 82.
Q9. With what vel. should an  -particle travel towards the nucleus for a copper atom so as to arrive at a
distance of 10-13m. from the nucleus of copper atom.
Q10. According to Rutherford all the positive charge is present in the nucleus because only one out of
(20,000)  -particles could retrace its path. (T/F)
PHYSICAL CHEMISTRY
Q1. The velocity of photon is:
(A) Independent of its wavelength (B) Depends on its wavelength
(C) Depends on its source (D) Equal to the square of its amplitude
Q2. Which is not characterishics of planek’s quantum theory of radistion:

(A) Radiation is associated with energy
(B) Energy is not absorbed or emitted in whole no. or multiples of quantum
(C) The magnitude of energy associated with a quantum is proportional to the frequency.
(D) Radiation energy is neither emitted nor absorbed continuously but in small packets called quantam.
Q3. Which is not the property of the photons:

(A) Momentum (B) Energy (C) Velocity (D) Rest mass
Q4. The rest mass of a photon of wavelength λ is:

he h h
(A) Zero (B) (C) (D)
λ Cλ λ
Q5. Calculate the mass of a photon having wavelength 1 nm. is 
Q6. Which of the following statements is true:

(A) Energy associated with one photon is directly proportional to the frequancy of radiation
(B) Total energy of radiation is inversely related to the λ of radication
(C) Graph between wavelength & energy of one photon is non linear
(D) Curve between energy of one photon & wave no. of radiation is linear
Q7. Planck’s constant has the same dimensions as:

(A) Work (B) Wavelength (C) Power (D) Angular momentum
Q8. If wavelength of photon is 2.2 x 10-11 m, than momantum of photon is:

(A) 3 x 10-23 kg. m/sec. (B) 3.33 x1022 kg. m/sec.
-44
(C) 1.452 x 10 kg. m/sec (D) 6.89 x 1043 kg. m/sec.
Q9. Calculate the frequancy of a yellow light having wavelength 600 nm. :
hc
Q10. The relation E = relates particle & wave nature of radiation. (T/F)
λ
Q11. A per electromagnetic theory the energy of a wave depends only on its amlitude and not on its frequency
or wavelength. (T/F)
Q12. The dynamic mass/equivalent mass of a photon of wavelength  is:

(A) Zero (B) he/  (C) h/c  (D) h/ 
Q13. Calculate the no. of photons emitted in 10hrs. by a 60W sodium lamp  = 5893Å.
PHYSICAL CHEMISTRY
Q1. All the photons of light have same energy.(T/F)
Q2. How many photons of light having a wavelength 4000Å are necessary to provide 1.0 J of energy?
Q3. Calculate the mass of one photon having its radiation wavelength equal to 1Å.
Q4. If the energy difference between the ground state of an atom and its excited state is 4.4 x 10-19 J. What
is the wavelength of the photon required to produce this transition?
Q5. What is the equivalent of energy in joules associated with a photon of 1.00 cm-1?
Q6. The wavelength of blue light is 480 nm. Calculate the frequency and wave no. of this light.
Q7. Suppose 10-17 J of light energy is needed by the inferior of human eye to see an object. How many
photons of Green light (  =550 nm) are needed to generate this minimum amount of energy?
Q8. Find the number of quanta of radiations of frequency 4.67 x 1013 s–1 that must be absorbed in order
to melt 5g of ice. The enrgy required to melt 1g of ice of 333 J.
*Q9. In a measurement of Quautum eficiency of photosynthesis in Green plants, it was found that 8 quanta of
red light at 6850 Å were needed to evolve one molecule of O2. The avg. energy storage in the photosyn-
thetic process is 112 kcal/mole O2 evolved. What is the energy conversion efficiency in this experiment.
Q10*. The photochemical dissociation of oxygen results in the production of two oxygen atoms, one in the
ground state and one in the excited state O2 
h O + O* . The maximum wavelength , needed
for this is 174 nm. If the excited energy O  O· is 3.15 x 10–19 J how much energy in kJ/mol is
needed for the dissociation of one of oxygen into normal (i.e. ground state) atoms?
Q11*. Infrared lamps are used in restaurants and cafeteria to keep the food worm. The Infra-Red Radia-
tion is stronly absorbed by water raising its temparature and that of food in which it is corporated.
How many photons per second of Infra-Red Radiation are produced by an infra-red lamp that
consumes energy at the rate of 100 watt and is 12% efficient in converting this energy to Infra-red
radiation? Assume that the radiation has a wavelength of 1500 nm.
*Q12. 1.0 gm of Mg atoms in the vapour phase absorb 50.0 kJ of kinetic energy. Find the composition of the
final mixture, if the first and second ionisation energies of Mg are 740 and 1450 kJ/mol respectively.
PHYSICAL CHEMISTRY
CLASS : XI (J) TIME : 100 MIN DPP. NO.- 20
Q1. Bohr model can explain:
(A) The sectrum of hydrogen atom (B) spectrum of an atom or ion containing one e- only.
(C) The spectrum of hydrogen molecule. (D) The spectrum of He+ ion.
Q2. Which concerning Bohr model is not true:

(A) It predicts the probability of electron near nucleus is more.
(B) Angular momentum of electron in H-atom = nh/2 
(C) Introduces the idea of stationary states (D) Explains the line spectrum of hydrogen.
Q3. According to Bohr’s postulates which Quantity can take up only discrete values:
(A) K.E. (B) Angular momentum (C) Momentum (D) P.E.
Q4. Bohr’s model violates the rules of classical physics become it assumes that:
(A) All es- have same charge. (B) The nucleus have same charge
-
(C) es can revolve round the nucleus.
(D) A charged particle can accelerate without anithing radiant energy.
Q5. Calculate the Ratio of time period of electron in first & second orbit of H-atom.
Q6. Angular momentum of the e- of H-atom is proportional to

(A) r2 (B) 1/r (C) r (D) 1/ r
Q7. The angular speed of the e- in the nth orbith of Bohar hydrogen atom is
(A) Directly proportional (B) Inversely proportional to n
(C) Inversely proportional to n 2 (D) Inversely proportional to n3
Q8. If a H-atom is excited by giving 8.4 eV of energy, then the no. of possible transitions is equal to
(A) None (B) Two (C) Three (D) Four
Q9. The largest wavelength capable of ionising H-atom is:

(A) 91.2 nm (B) 65.7 nm (C) 54.8 nm (D) 84.1 nm
Q10. Three photons originating from excited atomic hydrogen atoms are found to have energies of 0.66 eV,
1.89 eV 2.55 eV respectively. These photons must have originated from
(A) Two atoms (B) one atom (C) either two or three atoms (D) Three atoms
PHYSICAL CHEMISTRY
Q1. e-
A stationary hydrogen atom in its ground state collidos with an accelerated through an energy of 12.09 N
and the e- stops after the collision. The change in the angular momentum of the e- is h/  . [T/F]
Q2. A continuous band of U.V. radiation with wavelengths raning from 960Å to 1400Å is incident on a sample
of hydrogen atoms in their ground state contained in a tube with windows transparent to U.V. radiation.
The no of wavelengths that will lose their intensity on passing through a sample is
(A) 1 (B) 2 (C) 3 (D) 4
Q3. In hydrogen spectrum most energetic transitions of e s are found in which series?
Q4. Which statement regarding H-spectrum is false-
(a) The lines can be defined by quantum nos.
(b) The lines of longest wavelength in the Balmer series corresponds to the transition between n = 3 and
n = 2 levels.
(c) The spectral lines are closer together at longer wavelengths. (D) None of these
Q5. The frequency v of a certain line of Lyman series of the atomic spectrum of hydrogen satisfies the following
conditions-
(1) It is the sum of the frequencies of another Lyman line and a Balmer line.
(2) It is the sum of the frequencies of a certain Lyman line, a Balmer line and a pashchen line.
(3) It is the sum of the frequencies of a Lyman and Pashchen live but no Brackett line
(A) 3  1 (B) 3  2 (C) 2  1 (D) 4  1
Q6. The dynamic masses of photons corresponding to the first lines of the Lyman and the Balmer series of the
atomic spectrum of hydrogen are in the ratio of-
(A) 5 : 27 (B) 1 : 24 (C) 27 : 5 (D) 4 : 1
Q7. E1, E2, E3 & E4 are respectively the energies of the first line of Lyman, Balmer, Pashchen and Brackett
series, the decreasing order of energy is-
(A) E1, E2, E3, E4 (B) E4, E3, E2, E1 (C) E1, E3, E2, E4 (D) E2, E1, E4, E3
Q8. Electrons are accelerated from rest by an energy of 12.75 ev, are leombarded on a mono atomic hydrogen
gas. Possible emission of spectral lines are-
(A) first three Lyman lines, first two Balmer lines, and first Pashchen line
(B) first three Lyman lines only (C) first two Balmer lines only (D) none of the above
Q9. The frequency of one of the lines in Paschen series of a hydrogen atom is 2.34 x 10 14 Hz. The
quantum number n2 , which produces this transitions is
(A) three (B) four (C) six (D) five
Q10. Which one is wrong regarding hydrogen sectra?
(A) The continuous wavelengths exist in the emitted radiation in the H-spectrum
(B) The Balmer series lies in visible region
(C) A hydrogen sample may emit radiation more than those in the visible range
(D) In each series, the separation between the consecutive wavelengths increases as we move from
lower wavelength to higher wavelength.
Q.11 The bulb on the right has volume V contains N molecules of an ideal gas at
temperature T (K). On left is a cylindrical vessel of cross sectional area A,
containing a liquid of density d in contact with atmp P0. What is the condition that
h must obey in order for the piston not to move (k is Boltzmann constant)
NkT 3 NkT
(A) d g h – P0 = (B) P0 + d g h =
V 2 V
NkT
(C) P0 + d g h = (D) None of these
V
PHYSICAL CHEMISTRY
Q1. State whether the following statement are True or False.
The radius of the 3rd orbit of the hydrogen atom is 0.529 x 10-8 x 3 cm.
Q2. The ionisation energy of hydrogen atom is 13.6 eV. What will be the ionisation energy of He+ and Li2+
ions?
Q3. Calculate energy of electron which is moving in the orbit that has its radius sixteen times the radius of first
Bohr orbit.
Q4. Calculate the no. of revolutions per second made by electron in second shell of hydrogen atom.
Q5. Let v1 be the frequency of the series limit of the Lyman series, v2 be the frequency of the first line of
the Lyman series, and v3 be the frequency of the series limit of the Balmer series
(A) v1 – v2 = v3 (B) v2 – v1 = v3 (C) v3 – ½(v1 + v2) (D) v1 + v2 = v3
Q6. An excited hydrogen atom emits a photon of wavelength  in returning to the ground state. If R is
the Rydberg’s constant, then the quantum number n of the excited state is
R
(A) R (B) R  1 (C) (D) R (R  1)
R  1
Q7. The figure indicates the energy level diagram of an atom and the
origin of six spectral lines in emission (e.g. line no. 5 arises from the
transition from level B to A). Which of the following spectral lines
will also occur in the absorption spectrum?
(A) 4, 5, 6 (B) 1, 2, 3, 4, 5, 6 (C) 1, 4, 6 (D) 1, 2, 3
Q8. In hydrogen atom H - line arises due to transition n = 3  n = 2. In the spectrum of singly ionised
helium there is a line having the same wavelength as the H line. This is due to the transition
(A) n = 3  n = 2 (B) n = 2  n = 1 (C) n = 5  n = 3 (D) n = 6  n = 4
Q9. Whenever a hydrogen atom emits a photon in the Balmer series
(A) it may emit another photon in the Balmer series (B) it must emit another photon in the Lyman series
(C) the second photon, if emitted will have a wavelength of about 122 nm
(D) it may emit a second photon, but the wavelength of this photon cannot be predicted
Q10. A hydrogen atom in an excited state emits a photon which has the longest wavelength of the Paschen
series. Further emissions from the atom cannot include the
(A) longest wavelength of the Lyman series (B) second longest wavelength of the Lyman series
(C) longest wavelength of the Balmer series (D) second longest wavelength of the Balmer series
Q11. In an oil drop experiment, the uniform velocity of an oil droplet was observed to be 1 mm/sec. The
density of the oil is 0.85 gm/cm3, and the coefficient of viscosity of air () is 1.83 × 10–5 N–s/m.
Calculate the mass and the radius of the oil droplets.
PHYSICAL CHEMISTRY
Q1. Water is evaporated from 135 ml of 0.224 M MgSO4 solution until the volume of solution becomes 105
ml. What is the molarity of MgSO4 in the resulting solution.
Q2. What volume of water is to be added to 1600 ml of a 0.205 M solution, so that the resulting solution will
be 0.200 N?
Q3. What will be the final concentration of the ions in a solution made by mixing 0.015 moles of Sr(NO3)2
R
and 0.003 moles of NaF in enough water to make 0.2 L of solution. Assuming that SrF2 is completely
insoluble.
YEA
Q4. Calculate the molarity, molality and mole fraction of ethyl alcohol in a solution of total volume 95 ml
prepared by adding 50 ml C2H5OH (d = 0.789 gm/ml) to 50 ml water (d = 1.0 gm/ml). Calculate
molarity of water in alcohol.
Q5. A solution contains 57.5 ml ethyl alcohol and 600 ml benzene. How many gram alcohol are in 1000 gm
benzene? What is the molality of the solution?
Given: d C2 H 5OH = 0.8 gm/ml and d C 6 H6 = 0.9 gm/ml
NEW
Q6. When 10 ml of ethanol of density 0.7893 gm/ml is mixed with 20ml of water of density 0.9971 gm/ml,
the final solution has a density of 0.9591 gm/ml. Calculate the percentage change in total volume on
mixing. Also calculate molarity of final solution.
Q7. The molarity of Cl– in an squeous solution which was 2% NaCl, 4% CaCl2 and 6% NH4Cl (w/V) will
be
(A) 0.342 (B) 0.721 (C) 1.12 (D) 2.18
PY
Q8. 5 litres of 0.6 M H2SO4 (sp. gravity = 1.02) is mixed with 2 litre of 98% (w/V) of H2SO4 (sp. gravity
= 1.84). If the specific gravity of the resulting solution is 1.4. What is the molarity of the resulting,
assuming no loss in mass due to mixing.
HAP
Q9. The acid solution has a specific gravity of 1.8, when it contains 62% by wt. of acid. The solution is
diluted to such an extent that its specific gravity is lowered to 1.2. What is the % by weight of this acid
in the resulting solution?
Q10. The mole fraction of an aqueous solution of Na2CO3 is 0.1 and the density of the solution is 1.07 gm/ml.
The correct options is(are):
(A) Molality = 6.17 m (B) Molarity > molality
(C) %(w/W) = 39.6% (D) %(w/V) > %(w/W)
Q11. 100 ml of aqueous solution of HCl is heated. The original concentration of solution is 40 gm per 100 ml.
On heating the volume of solution decreases by 10 ml and at the same time 20% of HCl also comes out.
Calculate the % wt/vol of the final solution.
Q12. In a solution the concentration of CaCl2 is 5 M and that of MgCl2 is 5m. The specific gravity of solution
is 1.05. Calculate the concentration of Cl– in the solution in terms of molarity.
PHYSICAL CHEMISTRY
Q1. The shape of tobacco virus is cylindrical having length and diameter 3000Å and 170 Å respectively. The
density of virus particle is 0.08 gm/cm3. What is the molecular weight of tobacco virus if the virus is
considered to be single particle.
Q2. 5 moles of CuSO4 and 8 moles of KI react together according to the reaction
CuSO4 + KI  Cu2I2 + I2 + K2SO4
The iodine liberated is passed through the solution of Na2S2O3 having 6 moles of solute. Find the weight of
NaI obtained.
Q3. A mixture of FeO and Fe2O3 when heated in air to a constant weight, gains 5% in weight. Find the
composition of initial mixture.
Q4. NH3 gas is present in a balloon of volume 5.6 litre at NTP. Find the number of electrons inside the balloon.
Q5. 5 moles of KIO3, 6 moles of KI and 8 moles of HCl react together such that following chemical reaction
takes place
KIO3 + KI + HCl ICl + KCl + H2O
Find (a) What is the limiting reagent. (b) moles of each species left or produced.
Q6. A sample of a mixture of CaCl2 and NaCl weighing 4.22 gm was treated and precipitate all calcium as
calcium carbonate, which was then heated and qualitatively converted to 0.959 gm of CaO. Calculate % of
CaCl2 in the original mixture.
Q7. A natural gas sample contains 84% by volume CH4 , 10% C2H6, 3% C3H8 and 3% N2. If a series of
catalytic reaction could be used for conversion of all C–atoms of the gas into butadiene (C4H6) with 80%
efficiency. Then how much butadiene could be prepared from 100 lts of natural gas at 10 atm pressure and
400 K temperature?
Q8. S8  O2
  SO2 Cl
 2 SO2Cl2 
H2O
 H2SO4 + HCl
3.2 gm
Calculate the number of moles of BaSO4 formed and number of moles of NaOH required to react completely
with HCl formed.
Q9. In a particular experiment, 272 gm of P4 reacted with excess of oxygen to form P4O10 in 89.5 % yield. In
the second step of reaction, 97.8% yield of H3PO4 was obtained. What mass of H3PO4 was obtained.
Q10. A 5 gm solid mixture consisting of lead nitrate and Sodium nitrate was heated below 6000C until the weight
of residue is constant. If loss in weight is 28% (by wt.) find the amount of lead nitrate and sodium nitrate in
the mixture.
Q11. A thremally insulated container initially holds No molecules of an ideal monoatomic gas at an absolute
temperature T0. Molecules escape from the container through a small hole in the wall and it can be shown
that in such a process at a temperature T, the average K.E. of the escaping molecules is 2kT. How many
molecules remain in the container when the temperature has fallen to T0/2?
Q12. 1 gm of tetrabasic organic acid on reacting with silver produces 3.89 gm of silver salt. If no. of C-atoms =
no. of H-atoms = ½ (no. of O-atoms) in the organic acid. Determine molecular formulae of the acid. Also
if 10 litre of H4X 50% (v/V) solution is mixed with 20 litres of 70% (v/V) NaOH solution & the density of
H4X and NaOH solutions are  gm/lit. and 2gm/lit respectively then determine whether the resulting
solution will be acidic, basic or neutral.
PHYSICAL CHEMISTRY
Q1. What is the oxidation number of sulfur in each of the following cases?
(i) S2– (ii) H2SO4 (iii) S2O32– (iv) CS2 (v) S8 (vi) Na2S4O6 (vii) S2Cl2
Q2. What is the oxidation state of hydrogen in each of the following?
(i) HCl (ii) H+ (iii) NaH (iv) H2 (v) LiAlH4
Q3. Find the oxidation number of P in:
(i) PH3, (ii) P4, (iii) H3PO2 , (iv) PBr3, (v) P4 O 10
Q4. Find the oxidation number of Chlorine in
(i) ICl, (ii) CCl4, (iii) Cl2, (iv) HCl, (v) OCl– , (vi) KClO2 ,
(vii) ClO2 , (viii) NaClO2 , (ix) NaClO3 , (x) KClO4
Q5. Find the oxidation number of Carbon in
(i) CH4 , (ii) C2H6, (iii) C3H8, (iv) C2H4, (v) C2H2, (vi) graphite,
(vii) glucose, (viii) CO, (ix) H 2C 2O 4, (x) Na 2 CO 3
Q6. Find the oxidation number of manganese in
(i) MnO, (ii) Mn(OH)2, (iii) Mn3O4, (iv) Mn(OH)3, (v) K2MnO3,
(vi) K2MnO4 (vii) KMnO 4
Q7. Calculate the oxidation number of the underlined element in each of the following:
(a) SO 2
3
(b) H2CO (c) Na 2 Cr 2 O 7 (d) O 3
Q8. State the oxidation number of the underlined element in each of the following :
(a) P 2 O 4
7
(b) C 3O 2 (c) MnO 4 (d) MnO 2
4
(e) VO2 (f) UO 2
2
(g) ClO 3
Q9. Find oxidation number of Nitrogen in
(i) AIN, (ii) Ca3N2, (iii)N2H4, (iv) NH2OH, (v) NaN3, (vi)N2O, (vii) NO, (viii) N2O3
(ix) N2O4, (x) N2O5
Q10. Given that in these compounds the oxidation state of hydrogen is +1, of oxygen –2, and of fluorine
–1, determine the oxidation states of the other elements.
(a) PH3 (b) H2S (c) CrF3 (d) H2SO4 (e) H2SO3 (f) Al2O3
Q11. What is the oxidation number of the element associated with oxygen in each
(i) CrO42– (ii) PO43– (iii) CO32– (iv) HPO32–
(v) NO3– (vi) SO32– (vii) NO2– (viii) SO42–
(ix) OH– (x) ClO3– (xi) ClO4– (xii) ClO–
Q12. Find oxidation number of underlined elements in each of the following:
(i) Rb4Na[HV10O28] (ii) Ba2XeO6 (iii) Ba(ClO3)2
(iv) Na2S2 (v) V(BrO2)2 (vi) CrO5
(vii) H2SO5 (viii) H2S2O8 (ix) [Co(NH3)6]Cl3
(x) Na2[Fe(CN)5NO] (xi) K[Co(C2O4)2(NH3)2] (xii) [Co(NH3)5H2O]Cl3
(xiii) CH2O (xiv) (CH3)2SO (xv) [Pt(C2H4)Cl3]–
(xvi) S4O62– (xvii) RuO4 (xviii) K2TaF7 (xix) ZnO (xx) K2PtCl6 (xxi) Sb2S3
(xxii) Na2MoO3 (xxiii) H2C2O4 (xxiv) ICl3 (xxv) H2SO5
(xxvi) H2S2O8 (xxvii) NH4NO3 (xxviii) OsO4 (xxix) K4Fe(CN)6
(xxx) HCN (xxxi) HNC (xxxii) NH2OH (xxxiii) KO2
(xxxiv) (N2H5)2SO4 (xxxv) KI3 (xxxvi) N3H (xxxvii) Fe(CO)5
(xxxviii) [Co(NH3)5Cl]Cl2 (xxxix) FeSO4.(NH4)2SO4.6H2O (xxxx) NOCl
(xxxxi) NOClO4 (xxxxii) Na2[Fe(CN)5NOS] (xxxxiii) [Fe(NO)(H2O)5]SO4
(xxxxiv) Na2S2O6 (xxxxv) (CH3)2CO (xxxxvi) Ba(H2PO2)2
(xxxxvii) C2H12O6 (xxxxviii) CaCl(OCl)
PHYSICAL CHEMISTRY
Q.1. Which one(s) of the following involve redox reactions?
(i) Burning of gasoline (ii) evaporation of water (iii) human respiration
(iv) preparation of metals from their ores
(v) production by lightning of nitrogen oxides from nitrogen and oxygen in atmosphere
(vi) production by lightning of ozone (O3) from O2 (vii) reaction of H2SO4 with NaOH.
Q.2 Name the four most important oxidation states exhibited by sulfur.
Q.3 What is the change in oxidation number of the underlined atom in following conversions :
(i) NaHCO3 + HCl  NaCl + H2O + CO2
(ii) 2NaOH + Br2  NaBr + NaBrO + H2O
(iii) KI  KIO3
(iv) H2SO5 + 2KI  K2SO4 + H2O + I2
(v) 2HNO3  H2O + N2O5
(vi) CaOCl2 + H2O  Ca(OH)2 + Cl2
(vii) Mn O 4 + 3OH–  MnO2 + H2O
(viii) As2S3 + OH–  As S34
Q.4 Identify oxidant and reductant in the following redox reactions

(i) 2MnO2 + 4KOH + O2  2K2MnO4 + 2H2O
(ii) 2K2MnO4 + Cl2  2KCl + 2KMnO4
(iii) 2MnO42– + 2H2O current – –
  2MnO4 + 2OH + H2
(iv) P4 + 5O2  P4O10
(v) Hg2+ + NO2– + H2O  Hg + NO3– + 2H+
Q.5 Identify disproportionation reactions in the following :

(i) 3MnO42– + 4H+  MnO2 + 2MnO4– + 2H2O
(ii) 2KClO3  2KCl + 3O2
(iii) 2C6H5CHO + OH–  C6H5COO– + C6H5CH2OH
(iv) 
P4 + 3NaOH + 3H2O  3NaH2PO2 + PH3
(v) 
NH4NO3  N2O + 2H2O
Q.6 Balance the following equations by POAC

(i) BaCl2 + Al2(SO4)3  AlCl3 + BaSO4
(ii) KCN + H2SO4  K2SO4 + HCN
(iii) BCl3 + P4 + H2  BP + HCl
(iv) (NH4)2 Cr2O7   N2 + Cr2O3 + H2O
(v) KMnO4 + HCl  MnCl2 + H2O + Cl2 + KCl
(vi) Ca (OCl)2 + KI + HCl  I2 + CaCl2 + H2O + KCl
(vii) H3AsO4 + KI + HCl  H3AsO3 + KCl + I2 + H2O
(viii) NaClO3 + KI + HCl  NaCl + I2 + KCl + H2O
Q.7 Balance the following equations.
(i) Cr(OH)3 + IO3–  I– + CrO42–
(ii) Cr2O72– + Fe2+  Cr+3 + Fe3+ + H2O
(iii) I2 + HNO3  HIO3 + NO2 + H2O
(iv) MnO4– + C2O42– + H+  Mn2+ + CO2 + H2O
(v) Br2 + H2O2  BrO3– + H2O
(vi) Zn + HNO3 NH4+ + Zn+2 + H2O
(vii) Fe + N2H4  Fe(OH)2 + 2NH3
(viii) KMnO4 + NH3  KNO3 + MnO2 + KOH
(ix) HNO3 + As2S5 H2SO4 + H3AsO4 + NO2
(x) FeCl2 + H2O2 + HCl  FeCl3 + H2O
(xi) H2S + NO3–  NO2 + S8 (acidic)
(xii) MnO4– + SO2  SO42– + Mn2+ (acidic)
(xiii) Bi(OH)3 + Sn(OH)3–  Sn(OH)62– + Bi (basic)
(xiv) MnO4– + I–  MnO2 + IO3– (basic)
(xv) H2O2 + MnO4–  O2 + MnO2(basic)
(xvi) Al + NO3–  Al(OH)4– + NH3 (basic)
(xvii) Zn + NO3–  Zn2+ + N2 (acidic)
(xviii) CdS + I2 + HCl  CdCl2 + HI + S
Q.8 Balance the following redox reactions in basic medium by O.N. Method.
(i) Mn2+ + H2O2  MnO2 + H2O
(ii) MnO4– + NO2–  MnO2 + NO3–
(iii) Mn2+ + ClO3–  MnO2 + ClO2
(iv) MnO4– + NO2– + H2O2  MnO2 + NO3–
Q.9 Balance the following equations :

(i) N2O4 + Br O3  N O3 + Br– ; (in acidic medium)
(ii) As O33 + Mn O 4  As O34 + MnO2 ; (in alkaline medium)

(iii) N2H4 + Cu(OH)2  N2 + Cu ; (in neutral medium)
Q.10 Which of the following are examples of disproportionation reactions and balance them:
(i) Ag(NH3)2+ + H+  Ag+ + 2NH4+
(ii) Cl2 + OH–  ClO– + Cl– + H2O
(iii) Cu2O + H+  Cu + Cu2+ + H2O
(iv) HCuCl2  Cu + Cu2+ + Cl– + H+
(v) MnO4–  MnO42– + O2
(vi) Pb(NO3)2  PbO + NO2 + O2
(vii) Cl2  ClO3– + Cl–
(viii) H2O2  H2O + O2
PHYSICAL CHEMISTRY
Q1. Find the equivalent weight of compound in the following non-redox interaction.
(a) Of base
(i) Al(OH)3 + HCl  Al(OH)Cl2 + H2O
(ii) Al(OH)3 + H2SO4  Al(OH)(HSO4)2 + H2O
(iii) MgAl(OH)5 + HCl  MgCl + AlCl3 + H2O
(iv) Ba(OH)2 + HCl  Ba(OH)Cl + H2O
(v) Ba(OH)2 + HCl  BaCl2 + H2O
(vi) R–NH2 + HCl  R–NH3  Cl–
CH 2  NH 2 CH 2  NH 3  Cl 
(vii) | + HCl  |
CH 2  NH 2 CH 2  NH 2
CH 2  NH 2 CH 2  NH 3 Cl 
(vii) | + HCl  |
CH 2  NH 2 CH 2  NH 3 Cl 
(ix) + HCl 
(b) Of acid
(i) H3SbO4 KOH
 KH2SbO4 + H2O
(ii) H3SbO4 + KOH  K2HSbO4 + H2O
(iii) H2SO4 + KOH  KHSO4 + H2O
(iv) H2SO4 + KOH  K2SO4 + H2O
(v) H3PO4 + NaOH  Na3PO4 + H2O
(vi) + NaOH  + H2O
(vii) NaOH
 + H2O
(viii) KOH

(ix) KOH

Q2. Find the equivalent weight of underlined compound in following redox interaction
(a) S + NaOH  Na2S + Na2S2O3 + H2O
(b) N2H4  N2 + NH3
(c) KMnO4  K2MnO4 + MnO2 + O2
(d) CH4 + O2  CO2 + H2O
(e) Cl2  ClO4– + Cl–
Q3. Balance the following equations by n-factor method:
(i) As2S5 + HNO3 (conc.)  H3AsO4 + H2SO4 + H2O + NO2
(ii) Cu + HNO3 (conc.)  Cu(NO3)2 + H2O + NO2
(iii) Zn + HNO3 (dil.)  Zn(NO3)2 + H2O + NH4NO3
(iv) Na2C2O4 + KMnO4 + H2SO4 K2SO4 + H2O + Mn2+ + SO42– + CO2
(v) MnO + PbO2 + HNO3  HMnO4 + Pb(NO3)2 + H2O
(vi) Na2HAsO3 + KBrO3 + HCl  NaCl + KBr + H3AsO4
(vii) Na2TeO3 + NaI + HCl  NaCl + Te + H2O + I2
(viii) U(SO4)2 + KMnO4 + H2O H2SO4 + K2SO4 + MnSO4 + UO2SO4
(ix) Bi2O3 + NaOH + NaOCl  NaBiO3 + NaCl + H2O
(x) K3[Fe(CN)6] + Cr2O3 + KOH K4[Fe(CN)6] + K2CrO4 + H2O
(xi) MnSO4 + (NH4)2S2O8 + H2O MnO2 + H2SO4 + (NH4)2SO4
(xii) KClO3 + H2SO4 KHSO4 + O2 + ClO2 + H2O
Q4. The compound YBa2Cu3O7 which shows super conductivity has copper in oxidation state _______.
Assume that the rare earth element is in +3 oxidation state.
Q5. Which is the anhydride of HNO3 out of N2O, NO, N2O5?
Q6. For redox reaction MnO4– + C2O42– + H+  Mn2+ + CO2 + H2O the correct coefficient of balanced
reaction are:
(A) 2, 5, 16 (B) 16, 5, 2 (C) 5, 16, 2 (D) 2, 16, 5
Q7. One mole of N2H4 loses 10 mol of electrons to form a new compound Y. Assuming that all the nitrogen
appears in the new compound. What is the oxidation state of nitrogen in Y.
(A) –1 (B) –3 (C) +3 (D) +5
Q8. The number of moles of KMnO4 that will be needed to react one mole of sulphite ion in acidic solution
is :
(A) 2/5 (B) 3/5 (C) 4/5 (D) 1
Q9. KMnO4 oxidises Xn+ ion into XO3–, itself changing to Mn2+ in acid solution. 2.68 × 10–3 mol of Xn+
requires 1.61 × 10–3 mol of MnO4–. What is the value of n?
Q10. A given amount of Fe2+ is oxidised by x mol of MnO4– in acidic medium. Calculate mol of Cr2O72–
required to oxidise same amount in Fe2+ in acedic medium.
Q11. C2O42– can be oxidised to CO2 by MnO4– in acidic as well as in basic madium. What is ratio of mol of
MnO4– used per mol of C2O42– ?
Q12. How many mol of KI are oxidised by no of mol of KlO3 formed when 1 mol of I2 is boiled with excess
of KOH?
KOH + I2  KI + KIO3 + H2O

KI + KIO3 H I2 + H2O
PHYSICAL CHEMISTRY
Q1. Determine the amount of solute in each of the following solutions.
(a) 1 litre N-NaOH (b) 250 mL N/2 Na2CO3
Q2. A soluble carbonate has an equivalent weight of 69. Calculate the amount of soluble carbonate in
250 mL (N/5) solution.
Q3. Calculate the normality of a solution in known amount of solute in 1 litre. (a) 200gm NaOH
(b) 2.45 gm H2SO4
Q4. 100 gm of hydrochloric acid of specific gravity 1.17 contain 33.4 gm hydrogen chloride. Calculate
the normality of the solution.
Q5. Determine the molarity of pure water.
Q6. A solution contains 410.3 gm of H2SO4 per litre at 20oC. If its density be 1.243gm ml-1, what will
be its molarity and molality?
Q7. What is the molality, molarity and normality of a 13% solution by weight of H2SO4? Its density is 1.09
gm/ ml.
Q8. What is the strength in grams per litre of a solution of H2SO4, 12 ml of which neutralise 15 ml of N/10
solutiom hydroxide solution?
Q9. Calculate the normality of resulting solution made by adding two drop (0.1ml ) of 0.1N - H2SO4 in 1.0
litre of distilled water.
Q10. What amount of 95% pure Na2CO3 is required to prepare 250 mL N/10 solution?
Q11. How much of 1.0 M HCl should be mixed with what volume of 0.25 M HCl in order to prepare 1.0 litre
of 0.5 M HCl.
Q12. What is mass of sodium bromate and molarity of solution necessary to prepare 85.5 ml of 0.672 N
solution when the reaction is BrO3– + 6H+ + 6C–  Br– + 3H2O.
What would be the mass and molarity if the reaction is: 2BrO3– + 12H+ + 10e–  Br2 + 6H2O
PHYSICAL CHEMISTRY
Q1. Find equivalent weight of reactants for the following:
(i) KMnO4  Mn2+ (ii) KMnO4  MnO2
(iii) K2Cr2O7  Cr3+ (iv) S2O82–  SO2
(v) Ag+  Ag (vi) H2SO4  SO2
Q2. The equivalent mass of MnSO4 is half of its molar mass when it is converted to:
(A) Mn2O3 (B) MnO2 (C) MnO4– (D) MnO42–
Q3. A solution of KMnO4 is reduced to MnO2. The normality of solution is 0.6. The molarity is:
(A) 1.8 M (B) 0.6 M (C) 0.1M (D) 0.2 M
Q4. Equivalent weight of KMnO4 in acidic medium is 31.6. What are corresponding value in basic medium?
Q5. MnO4– can oxidise NO2– to NO3– in basic medium. How many mol of NO2– are oxidised by 1 mol of
MnO4–.
Q6. 0.2g of oxygen and 3.17 g of a halogen combine separately with the same amount of a metal. What is the
equivalent weight of the halogen?
Q7. When 31.6 gm of pure copper oxide are completely reduced by dry hydrogen, 7.2 gm of water are
produced. Calculate eqquivalent wt. of Copper.
Q8. The equivalent weight of a metal is 30. What volume of chlorine would be liberated at 270C and 750 mm
pressure by 0.6 gm. of the metal.
Q9. One gm of a metallic Carbonate was strongly heated it gave 154 ml of CO2 measured at NTP and left a
residue of Metallic oxide. Calculate equivalent weight of metal.
Q10. The eq. wt. of a metal is 36. What wt. of the metal would give 9.322 gm of its chloride?
Q11. 2 gm of a metal when dissolved in nitric acid converted to its nitrate. The nitrate was then precipitated to
2.66 gm of Metal chloride. Calculate equivalent weight of metal.
Q12. On heating 5 × 10–3 equivalents oc CaCl2 · xH2O, 0.18 gm of water is obtained. Calculate x.
Q13. 1.80 g of a metal oxide required 833 ml of hydrogen at NTP to be reduced to its metal. Find the
equivalent weights of the oxide and the metal.
Q14. What mass of Na2S2O3·5H2O is needed to make 500cm3 of 0.200 N solution for the reaction
2S2O32– + I2  S4O62– + 2I–
Q15. The molecular formula of an oxide of an element X is XmOn what is the equivalent wt. of the metal?
(Given at. wt. of X = a)
PHYSICAL CHEMISTRY
Q1. What is the equivalent weight of HNO3 in the following reaction?
HNO3 + H2S  H2O + NO + S
Q2. What is the equivalent weight of ClO3– in the following reaction?
ClO3– + Fe2+ + H+  Cl– + Fe3+ + H2O
Q3. Equivalent weight of NH3 in the given reaction is; 3CuO + 2NH3 = 3Cu + N2 + 3H2O
(A) 17 (B) 17/4 (C) 17/5 (D) 17/3
Q4. In the given set of reactions what is the ratio of equivalent weights of HNO3
(a) 5 Cu + 2HNO3 = 5CuO + N2 + H2O (b) NaOH + HNO3 = NaNO3 + H2O
Q5. The ratio of the equivalent weights of C2H5OH in the following reaction is
(a) C2H5OH  CH3CHO + 2H+ + 2e (b) C2H5OH + Na  C2H5ONa + ½ H2
(A) 1 : 4 (B) 1 : 1 (C) 1 : 2 (D) 1 : 3
Q6. The equiv. wt. of hypo in the reaction Na2S2O3 + Cl2 + H2O  Na2SO4 + H2SO4 + HCl is
(A) Mol. wt./2 (B) Mol. wt./4 (C) Mol. wt./1 (D) Mol. wt./8
Q7. What weight of HNO3 is needed to convert 62 gm of P4 in H3PO4 in the reaction?
P4 + HNO3  H2PO4 + NO2 + H2O
(A) 62 gm (B) 630 gm (C) 315 gm (D) 126 gm
Q8. Determine the value of ‘n’ in the following conversions
(a) I–  I2 (b) I2  I (c) K2CrO4  K2CrO7
(d) SO2  H2SO4 (e) SO2  H2S (f) SO2  S2O32–
Q9. Calculate the equivalent weights of the following:
(i) KMnO4 in acidic medium (ii) KMnO4 in alkaline medium
(iii) FeSO4.(NH4)2SO4.6H2O (Converting to Fe3+) (iv) K2Cr2O7 in acidic medium
(v) H2C2O4 (converting to CO2) (vi) Na2S2O3.5H2O (reacting with I2)
Q10. In the reaction VO + Fe2O3  FeO + V2O5, the eq. wt. of V2O5 is equal to its
(A) Mol. wt. (B) Mol. wt./8 (C) Mol. wt./6 (D) None of these
Q11. The equivalent weight of an element is 9. If it forms volatile chloride of vapour density 66.75. What is the
approximate at. wt. of the element?
(A) 9 (B) 18 (C) 27 (D) 54
Q12. What weight of H2C2O4· 2H2O (mol. wt. = 126) should be dissolved to prepare 250 ml of centinormal
to be used as a reducing agent?
(A) 0.63 gm (B) 0.1575 gm (C) 0.126 gm (D) 0.875 gm
Q13. What mass of phosphoric acid, H3PO4, is required to make 550 ml of 0.400 N solution?
(a) Assuming complete neutralisation of the acid (b) Assuming reduction to HPO32–
H3PO4 + 3OH–  3H2O + PO43– ; H3PO4 + 2e––  HPO3 + H2O
Q14. 5 Lit. of KMnO4 solution contain 0.01 equiv. of KMnO4. 50 ml of the given solution contain, how many
moles of KMnO4? KMnO4  MnO2
(A) -6
10 /4 (B) -4
10 /3 (C)` 3 × 10–5 (D) 10–5
Q15. [Na+] in a solution prepared by mixing 30.00 mL of 0.12 M NaCl with 70 mL of 0.15 M Na2SO4 is:
(A) 0.135 M (B) 0.141 M (C) 0.210 M (D) 0.246 M
PHYSICAL CHEMISTRY
Q1. In a reaction, Cr2O72– is reduced to Cr3+. What is concentration of 0.1 M K2Cr2O7 in equivalent per
litre? Cr2O72– + 14H+ + 6e–  2Cr3+ + 7H2O
Q2. Maximum no. of mol of PbSO4 that can be precipitated by mixing 20.00 mL of 0.1 M Pb(NO3)2 and
30.00 mL of 0.1 M Na2SO4 will be:
(A) 0.002 (B) 0.003 (C) 0.005 (D) 0.001
Q3. 0.7g of a sample of Na2CO3.xH2O were dissolved in water and the volume was made to 100ml, 20 ml
of this solution required 19.8 ml of N/10 HCl for complete neutralisation. The value of x is
(A) 7 (B) 3 (C) 2 (D) 5
Q4. What will be present in the solution when 50 ml of 0.1(M) HCl is mixed with 50 ml of 0.1 (M) NaOH
(A) 4.5 ml mol of H+ (B) 0.05 (m) mol of OH–
(C) 0.05 M NaCl (D) 6(M) H+
Q5. 2 litres of ammonia at 130C and 0.9 atmospheric is neutralized by 134 ml of H2SO4 solution. Find the
normality of the acid.
Q6. In a compound AxBy
(A) mole of A = mole of B = mole of AxBy (B) eq. of A = eq. of B = eq. of AxBy
(C) y × mole of A = y × mole of B = (x + y) × mole of AxBy
(D) y × mole of A y × mole of B
Q7. What volume of 0.3 M H2SO4 is required to exactly neutralize 200 ml of 0.5 M NaOH.
Q8. Calculate the molarity of original H3PO4 solution of 20mL of H3PO4 solution is required to completely
neutralize 40 mL of 0.5 M Ba(OH)2 solution.
Q9. For a titration of 100cm3 of 0.1 M Sn2+, 50 cm3 of 0.40 M Ce4+ solution was requried. The oxidation
state of cerium in the reduction product is
(A) +1 (B) +2 (C) +3 (D) 0
Q10. A volume of 12.53 ml of 0.051 M SeO2 reacts exactly with 25.5ml of 0.1M CrSO4 which is oxidised to
Cr3+. To what oxidation state was the selenium converted by the reaction?
Q11. What mass of Na2SO3 must have been present in a sample that required 26.50 ml of 0.0510 M KMnO4
for its oxidation to Na2SO4 in acidic solution?
Q12. 0.2240 gm of pure iron were dissolved in pure H2SO4 and required for oxidation, 21.6 mL of acidic
KMnO4 solution. Calculate normality of KMnO4.
Q13. 2 litres of KCl & KOH is completely neutralised with 120 mL of 0.12 HCl. Calculate wt. of KOH in
mixture.
Q14. 1.2 gm mixture of Na2CO3 & K2CO3 was dissolved in water to form 100 mL of a solution, 20 cm3 of
this solution required 40 ml of 0.1 N HCl for neutralisation. Calculate the weight of Na2CO3 and K2CO3
in the mixture.
Q15.
(a) The ion An+ is oxidised to AO3– by MnO4– changing to Mn2+ in acid solution. Given that 2.68 × 10–3 mol
of An+ requires1.61× 10–3 mol of MnO4–, what is the value of n?
(b) What is the weight of one gram equivalent ACln for the above reaction if the atomic mass of A is 97.0?
PHYSICAL CHEMISTRY
Q1. 3 mol of mixture of FeSO4 and Fe2(SO4)3 required 100 mL of 2 M KMnO4 solution is acidic medium.
Hence mol fraction of FeSO4 in the mixture is
(A) 1/3 (B) 2/3 (C) 2/5 (D) 3/5
Q2. What mass of N2H4 can be oxidised to N2 by 24 gm of K2CrO4 which is reduced to [Cr(OH)4]–.
Q3. What volume of 0.1 M KMnO4 are needed to oxidise a mixture containing 100 mg each of FeC2O4 and
FeSO4 in acidic medium.
Q4. A solution of Na2CO3.xH2O was made up, containing 15.5g/lt. 20cc of this solution required 25cc of
0.2N HCl acid solution for neutralisation. Find the value of x.
Q5. A KMnO4 solution can be standardized by titration against As2O3(s). A 0.1156 gm sample of As2O3
requires 27.08 ml of the KMnO4 (aq) for its titration. What is the molarity of the KMnO4(aq) [As = 75]
5As2O3 + 4MnO4– + 9H2O + 12H+  10H3AsO4 + 4Mn2+
Q6. 15 ml of 12N H2SO4, 30ml of 10N HCl, 10ml of 2N HNO3 and 100ml of 3N NaOH solutions are
mixed and the volume made upto 1000ml. Is the solution acidic or alkaline?Explain the acidity of alkalinity
in terms of normality.
Q7. Calculate mol of (a) MnO4– and (b) Cr2O72– to oxidise 1 mol of FeC2O4 (ferrous oxalate) in acidic
medium.
Q8. Two acids H2SO4 and H3PO4 are neutralised separately by the same amount of an alkali when sulphate
and dihydrogen phosphates are formed respectively. Find the ratio of moles of H2SO4 and H3PO4.
Q9. Find the volume in 0.1 N HCl required to react completely with 1 gm mixture of sodium bicarbonate and
sodium carbonate containing equimolecular amount of the two components.
Q10. 3.5 gm of a sodalime sample are dissolved in water to prepare 300 ml of solution. The normality of
solution is found to be 0.3105 N. What are the percentages of NaOH and CaO in sodalime sample.
Q11. 0.5 gm of fuming sulphuric acid (oleum) is diluted with water. This solution is completely neutralised by
26.7 ml of 0.4 N NaOH. Find the percentages of NaOH and CaO in sodalime sample.
Q12. In basic solution CrO42– ion oxidises S2O32– ion to form Cr(OH)4– and SO42– ions respectively. How
many ml of 0.154 M Na2CrO4 solution are required just to react with 40 ml of 0.246 M Na2S2O3
solution.
PHYSICAL CHEMISTRY
Q1. A 1.0g sample of H2O5 solution containing x% H2O2 by mass requries x cm3 of a KMnO4 solution for
complete oxidation under acidic conditions. Calculate the normality of KMnO4 solution.
Q2. 0.2828 g of iron wire was dissolved inexcess dilute H2SO4 and the solution was made upto 100 mL. 20
ml of this soltuion required 30 mL of N/30 K2Cr2O7 solution exact oxidation. Calculate percent purity of
Fe in wire.
Q3. Metallic tin in the presence of HCl is oxidised by K2Cr2O7 to stannic chloride, SnCl4. What volume of
deci-normal dichromate solution would be reduced by 1 g of tin.
Q4. Potassium acid oxalate K2Cr2O4.3H2C2O4.4H2O can be oxidised by MnO4– in acid medium. Calculate
the volume of 0.1 M KMnO4 reacting acid solution with one gram of the acid oxalate.
Q5. 2 gms of FeC2O4 are made to react in acid solution with 0.25 M KMnO4 solution. What volume of
KMnO4 solution would be required. The resulting solution is treated with excess of NH4Cl and NH4OH
solution. The precipitated Fe(OH)3 is filtered off, washed and ignited. What is the mass of the product
obtained.
Q6. A 0.7160 g of a hydrated metallic sulphate of formula Mx(SO4)y·18H2O precipitated 0.7002 g of BaSO4.
When mixed with K2SO4 and crystallised, the metallic sulphate yielded an alum isomorphous with potash
alum. Find the atomic weight of the metal.
Q7. K2Cr2O7 oxidizes HCl to Cl2, which oxidizes K2MnO4 to KMnO4. Calculate the weight of KMnO4
formed from one gram of potassium dischromate by reacting it with excess HCl and using the generated
chlorine for oxidizing K2MnO4. (Mn = 55; Cr = 52)
Q8. A solution is made by mixing 200 ml of 0.1 M FeSO4, 200 gm of 0.2 M KMnO4 and 600 ml of 1 M
HClO4. A reaction occurs in which Fe2+ is converted to Fe3+ and MnO4– to Mn2+ in acid solution.
Calculate the concentration of each ion.
Q9. The reaction Zn + CuSO4 Cu + ZnSO4 goes on completion to the right. In one experiment 10 gm of
metallic zinc was added to 200 ml of copper sulphate solution. After all the copper was precipitated it
was found that not all the zinc had dissolved. After filteration the total solid at the end of the reaction was
9.81 gm. Calculate the weight of copper deposited and molarity of CuSO4 in the original solution.
Q10. A solution contains Na2CO3 and NaHCO3 10 ml of this solution required 2.5 ml of 0.1 M H2SO4 for
neutralisation using phenolphthalein as an indicator. Methyl organe is added when a further 2.5 ml of 0.2
M H2SO4 was required. Calculate the amount of Na2Co3 and NaHCO3 in one litre of solution.
Q11. Both Cr2O72–(aq) and MnO4–(aq) can be used to titrate Fe2+ (aq). Suppose you have available 0.100 M
solution of each. For a given sample Fe2+ (aq).
(a) With which solution Cr2O72–(aq) or MnO4–(aq), would the greater volume of titrant (titrating solution) be
required? Expalin.
(b) If a given titration required 24.50 ml of 0.100 M Cr2O72– (aq), how many ml of 0.100 M MnO4–(aq)
would have been required if it had been used instead?
Q12. 5 ml of 8N HNO3, 4.8 ml of 5N HCl, 1.4 gm of NaOH and a certain volume of 17 M H2SO4 are mixed
together and made upto 2 lts. 50 ml of this solution exactly neutralised 32.9 ml of barium hydroxide
solution containing 2.21 gm of Ba(OH)2·8H2O in 100 ml solution. Calculate (a) the volume H2SO4 used.
(b) the amount in grams of sulphate ion in the solution.
PHYSICAL CHEMISTRY
Q.1 For complete reaction 20 mL of 0.1 mol/litre aqueous Na2S2O3 required 40 mL of a solution of bromine
containing 32 g of bromine per litre. Which of the following equations is in agreement with the data given:
(A) S2O32– + 5Br2 + 5H2O  S2O82– + 10Br– + 10H+
(B) S2O32– + 4Br2 + 5H2O  2SO42– + 8Br– + 10H+
(C) S2O3– + Br2 + 4H2O  SO32– + SO42– + 2Br– + 4H+
(D) S2O32– + 2Br2 + 3H2O  2SO32– + 4Br– + 6H+
Q.2 On balancing the equation and using integral coefficients for the reaction :
Cu3P + Cr2O72–  Cu2+ + H3PO4 + Cr3+ ;
which of the following numbers will be the coefficient of dichromate ion:
(A) 22 (B) 10 (C) 11 (D) 14
Q.3 0.36 gm of Iron Pyrites is heated strongly in air. The SO2 thus produced is passed through acidified
decimolar K2Cr2O7 solution. The volume of acidified K2Cr2O7 solution used in redox titration
(A) 10 ml (B) 20 ml (C) 30 ml (D) 40 ml
Q.4 N2 + 3H2  2NH3
Molecular weight of NH3 and N2 are M1 and M2, their equivalent weight are E1 and E2. Then (E1 – E2) is
 2M1  M 2 
(A)   (B) (M1 – M2) (C) (3M1 – M2) (D) (M1 – 2M2)
 6 
Q.5 20 ml solution containing 0.1 M Na2CO3, 0.15 M NaOH and 0.20 M NaHCO3 was titrated with
25 ml of a solution of HCl using phenolphthalein indicator. Hence strength of HCl solution was
(A) 0.1 M (B) 0.15 M (C) 0.05 M (D) 0.20 M
Q.6 1.25 gm of a sample of bleaching powder is dissolved in 100 ml of water and 25 ml of which are treated
with KI solution. The iodine so liberated required 12.5 ml of N/25 hypo solution in titration. Find the %
of chlorine available from the sample of bleaching powder.
Q.7 50 ml of a solution, containing 1 gm each of Na2CO3, NaHCO3 and NaOH, was titrated with N–HCl.
What will be the volume of HCl used in each case when (a) only phenolphthalein is sued as an indicator.
(b) Only methyl orange is used as an indicator form the very begining (c) methyl orange is added after the
first end point with phenolphthlein.
Q.8 4.08 gm of mixture of BaO and an unknown carbonate MCO3 was heated strongly. The residue weighed
3.64 gm. This was dissolved in 100 ml of 1 N HCl. The excess of acid required 16 ml of 2.5 N NaOH
for complete neutralisation. Identify the metal M.
Q.9 A 100 mL solution consists of H2C2O4 and H2SO4 in 1 : 1 molar ratio. 25 mL of this solution requires 30
mL of KOH which was prepared by adding 5.6 gm KOH in 500 mL of solution. Find out the volume of
CO2 liberated at STP if 50 mL of this solution is boiled.
Q.10 0.2 gm of a solution of mixture of NaOH and Na2CO3 and inert impurity was first titrated with HPh and
N/10 HCl, 17.5 mL of HCl was required at the end point. After two MeOH was added and 2.5 mL of
same HCl was again required for next end point. Find out % of NaOH and Na2CO3 in the mixture.
Q.11 A sample of FeCl3 and FeC2O4 was dissolved in an acidic solution. 30 ml of 0.133 N K2Cr2O7 was
required for complete oxidation. After oxidation, the mixture was reduced by Zn and H2SO4. On again
titrating the mixture with same K2Cr2O7 solution, 50 ml of it were required. Find the ratio of moles of
FeCl3 and FeC2O4 in the sample.
Q.12 When ammonium vanadate (NH4)VO4 is heated with oxalic acid solution, a compound (Z) is formed. A
sample of (Z) was treated with KMnO4 solution in hot acidic solution. The resulting liquid was reduced
with SO2, the excess SO2 boiled off and the liquid again titrated with KMnO4. The ratio of volumes of
KMnO4 used in the two titrations was 5:1. What conclusions can you made regarding the nature of
compound (Z). Given that KMnO4 oxidises all oxidation states of vanadium to vanadium(+5). SO2
reduces vanadium(+5) to vanadium(+4).
PHYSICAL CHEMISTRY
Q1. 100 kg hard water contains 5g MgSO4. Find hardness.
Q2. IL hard water contains 1 mg CaCl2 and 1 mg MgCl2
Q3. Calculate the amount of lime Ca(OH)2 required to remove the hardness in 60L of pond water
containing 1.62 mg of calcium bicarbonate per 100 mL of water .
Q4. 10L of hard water required 0.56 g of lime CaO for removing hardness. Hence temp hardness in
ppm is_________.
Q5. A sample of hard water contains 20 mg of Ca++ ions per litre. How much of Na2CO3 in moles
would be required to softer 1 L of sample.
Q6. 50 L of temp hard water required 22.2g Ca(OH)2. Calculate strength of temp hard water and
hardness.
Q7. A sample of hard water contains 20 mg of Ca2+ ions per L. How many m.eq. of Na2CO3 would be
required to soften I L of the sample.
Q8. A sample of hard water has 20 mg per L Ca2+ ions and 48 mg per l Mg2+ ions, calculate the total
hardness in equivalent per L.
Q9. Calculate the wt of CaO required to remove the hardness of 106L water containing 1.62g calcium
bicarbonate per L
Q10. Calculate the hardness of water sample which contains 0.001 mol MgSO4 per L of water.
Q11. 100 mL of hard water required 25.1 mL of 0.02 N H2SO4 for neutralization. Calculate hardness.
Q12. 50 mL of hard water required 10 ml, N/50 HCl for naturalization. Calculate temp. hardness.
Q13. 200 mL of a hard water sample was boiled with 100 mL of N/50 soda reagent. After boiling the
volume was again made to 200 mL and the solution filtered. 25 mL of filtrate required 8.2 mL of
N/50 HCl for neutralisation. Calculate hardness .
Q14. A mixture of 100 mL hard-water & 100 mL N/50 Na2CO3 was boiled and filtered. The filtrate
required 60 mL of N/50 HCl for titration. Calculate hardness
Q15. A sample of hard water has hardness 77.5 ppm of Ca2+. This sample is passed through an ion
exchange column and the Ca2+ ions are replaced by H+. Calculate molarity of H+ ions.
PHYSICAL CHEMISTRY
Select only one correct alternative. [25 x 3 = 75]
Q.1 What is the molarity of H2SO4 solution that has a density 1.2 g/ml at 25°C and contain 75.5 % by mass
of H2O
(A) 1.5 M (B) 3.0 M (C) 9.24 M (D) None
Q.2 A chemist set up a synthesis of phosphorus trichloride by mixing 12.0 g P with 35.5 g Cl2 and obtained
42.4 g PCl3. The percentage yield of this compound is
(A) 90 % (B) 92.51 % (C) 33.33 % (D) 45 %
Q.3 Which of the following statement(s) is/are correct:

Statement 1 : C–F is most polar bond in C–F, Cl–Cl, N–F, O–F bonds
Statement 2 : If a gaseous mixture of H2 and CO2 gas contains 88 mass % of CO2, then vapour
density of the mixture is 12.5
Statement 3 : If 48.0 gm of a gas occupies the same volume as 42.0 gm. N2 (g) under similar
T& P condition then molecular weight of the gas is 28 gm
(A) Statement 1 (B) Statement 2 (C) Statement 1,3 (D) All
Q.4 In a reaction FeS2 is oxidised by O2 to Fe2O3 & SO2. If the equivalents of O2 consumed are 'y' then the
equivalents of FeS2 consumed & moles of Fe2O3 & SO2 produced are respectively
y y y 2y y 2y
(A) y, y, y (B) y, , (C) y, , (D) y, ,
22 11 22 11 11 11
Q.5 Which is not correctly matched with its structure?

(A) SF6 ; octahedral (B) ClF3 ; T-shape
(C) I3 ; trigonal planar (D) XeF2 ; Linear shape
Q.6 Which one of these graphs for an ideal gas having a fixed amount the arrow indication is incorrectly
marked.
(A) (B)
(C) (D)
Q.7 According to Bohr’s atomic theory, which of the following is/are correct:
Z2
(I) Kinetic energy of electron 
n2
(II) The product of velocity of electron and principle quantum number ‘n’  Z2
Z2
(III) Frequency of revolution of electron in a Bohr orbit  3
n
Z2
(IV) Coulombic force of attraction on the electron 
n4
(A) I, III (B) I, IV (C) II (D) I
Q.8 If 0 is the threshold wavelength for photoelectric emission,  wavelength of light falling on the surface of
metal, and m, mass of electron, then de Broglie wavelength of emitted electron is
1 1 1 1
 h 02  h ( 0   )  2  h ( 0 )  2  h (   0 )  2
(A)   (B)   (C)   (D)  
 2mc   2mc  0   2mc( 0  )   2mc  0 
Q.9 It is known that atom contain protons, neutrons and electrons. If the mass of neutron is assumed to half
of its original value where as that of proton is assumed to be twice of its original value then the atomic
14
mass of 6 C will be
(A) same (B) 25% more (C) 14.28 % more (D) 28.5% less
Q.10 Which is correct statement?

As the s-character of a hybrid orbital decreases
(I) The bond angle decreases (II) The bond strength increases
(III) The bond length increases (IV) Size of orbital increases
(A) (I), (III) and (IV) (B) (II), (III) and (IV)
(C) (I) and (II) (D) All are correct
Q.11 Which of the following compounds have the same no. of lone pairs with their central atom
[I] XeF5 [II] BrF3 [III] XeF2 [IV] H3S+
(A) III and IV (B) I and III (C) I and II (D) II and IV
Q.12 The hybridization of atomic orbitals of N in NH 4 , NO 2 & NO 3 are respectively

(A) sp, sp2, sp3 (B) sp3, sp, sp2 (C) sp2, sp, sp3 (D) sp3, sp2, sp
Q.13 Aqueous solutions of two compounds M1–O–H and M2–O–H are prepared in two different beakers.
If, the electronegativity of M1 = 3.4, M2 = 1.2, O = 3.5 and H = 2.1, then the nature of the two solutions
will be respectively:
(A) acidic, basic (B) acidic, acidic (C) basic, acidic (D) basic, basic
Q.14 The ground state electronic configurations of the elements, U, V, W, X and Y (these symbols do not
have any chemical significance) are as follows
U 1s22s22p3
V 1s22s2 2p63s1
W 1s22s22p63s23p2
X 1s22s22p63s23p63d54s2
Y 1s22s22p63s2 3p63d104s24p6
Determine which sequence of elements satisfy the following statements
(i) element-has highly reactive nature
(ii) element-is d-block element most likely to form coloured ionic compounds
(iii) element-has largest atomic radius
(iv) element-forms only acidic oxide
(A) V W Y U (B) V X Y W (C) V W Y X (D) V X W U
N N
Q.15 Volume of water to be added to 200 ml of HCl solution so that its new strength becomes is
10 20
(A) 100 ml (B) 200 ml (C) 300 ml (D) 400 ml
Q.16 The correct name of 1-methoxy-1-ethyl-2-methyl propane is
(A) 3-methoxy-2-methyl pentane (B) 1-methoxy-1-iso-propyl methane
(C) 3-methoxy-4-methylpentane (D) None of these
Q.17 IUPAC name of CH 3  CH 2  N  CHO is

|
H
(A) N-ethyl aminoethanol (B) N-formyl aminoethane
(C) N-ethyl methanamide (D) ethanaminal
Q.18 Give the correct order of initials T (true) or F (false) for following statements.
(I) Molality is temperature independent.
(II) Mean free path () is directly proportional to Pressure if Temperature is constant.
(III) The value of Vander Waals constant a is very high for H2 gas.
(IV) The ratio of time periods (T1/ T3) in first and third orbits of hydrogen atom is 1 : 27
(A) FTTT (B) TFFT (C) TTFF (D) TTFT
Q.19 Give the correct order of initials T (true) or F (false) for following statements.
(I) N 2 has bond order of 2.5.
(II) The hybridisation of S atom in SO2 is sp2.
(III) Polarization power of a cation increases when size of cation increases.
(IV) Be shows diagonal relationship with Si.
(A) FTFF (B) TFFF (C) TTFF (D) FTTT
Q.20 These questions consist of two statements each, printed as assertion and reason, while answering these
questions you are required to choose any one of the following responses.
(A) If assertion is true but the reason is false.
(B) If assertion is false but the reason is true.
(C) If both assertion and reason are true and the reason is a correct explanation of assertion.
(D) If both assertion and reason are true but reason is not a correct explanation of assertion.
Assertion : F atom has less electron affinity than Cl atom.
Reason : Additional electrons are repelled more strongly by 3p-electrons in Cl atom than by
2p-electrons in F atom.
Q.21 For a general ideal gaseous reaction

aA(g) + bB(g) cC(g) + dD(g)
equilibrium constant Kc, Kp and Kx are represented by the following relations
[C]c [D]d p Cc ·p Dd x Cc ·x Dd
Kc = ; Kp = a b and Kx = a
[A]a [B]b p A ·p B x A ·x Bb
where [A] represents molar concentration of A
pA represents partial pressure of A and P represents total pressure
xA represents mole fraction of A
ng = (c + d) – ( a + b)
On the basis of above work-up. Select write option
n g n g  ng n g
(A) Kp = K c (RT ) ; Kx = K p (RT) (B) Kc = K p (RT) ; Kp = K x P
n g n g  n g n g
(C) Kc = K x P ; Kp  KxP (D) Kc = K p (RT) ; Kx = K p (RT)
Q. 22 to Q. 25 (4 Questions)
Preparation of hydrocarbons can be done by various methods. Three important methods for this are as
follows:
(I) R1X + R2X Na / dry  R1R1 + R1R2 + R2R2 + NaX
ether

(II) R1COOK + R2COOK electricit
 y  R1R1 + R1R2 + R2R2
(III) RCOOH + NaOH + CaO  RH
All the three reactions follow different type of mechanism. Based on the above data answer the following
questions.
Q22. CH4 can be prepared by which method.

(A) I only (B) II only (C) III only (D) all the three
Q23. Free radical is formed as intermediate in

(A) I & III (B) I & II (C) II & III (D) all three
Q24. Method I & II are best for preparation of following compounds:

(A) CH3 – CH2–CH2–CH3 (B) Ph–CH2–CH3
(C) CH 3  CH  CH 2  CH 3 (D) CH3–CH2–CH2–CH2–CH3
|
CH 3
Cl 2 Na
Q25. CH3–CH2–CH2–CH3  
h ether
controlled
Major product of the above reaction is :
(A) CH3–(CH2)6CH3 (B) CH 3  CH 2  CH  CH  CH 2  CH 3

| |
CH 3 CH 3
(C) CH 3  CH  CH 2  CH 2  CH  CH 3 (D) none of these

| |
CH 3 CH 3
PHYSICAL CHEMISTRY
QUESTIONS FROM MAJOR REVIEW TEST PAPER HELD LAST YEAR FOR ACME
Take exactly 2 hrs to solve it.
Q.1 (a) Boiling point of o-Nitrophenol is less than meta and para nitrophenol. Why?
(b) A large closed tank is first fully evacuated and then connected to 10 litre cylinder containing O2(g) at
a pressure of 8.21 atm. The prerssure of cylinder is reduced to 1.642 atm after it is connected to the
tank. Calculate the volume of the tank. [2+2]
Q.2 (a) Arrange the isoelectronic species O2–, F–, Na+ and Mg2+ in order of their
(i) increasing ionic radius (ii) increasing ionization energy
(b) Arrange the following ions in order of their increasing ionic radii Li+, Mg2+, K+, Al3+. [2+2]
Q.3 (a) Predict the magnetic moment for S2–, Co3+.
(b) On the basis of Heisenberg uncertainty principle, show that an electron cannot exist in the nucleus
[2+2]
Q.4 (a) A sample of 0.50 gm of an organic compound was treated according to Kjeldahl’s method. The
ammonia evolved was absorbed in 50 ml of 0.5 M H2SO4. The residual acid required 60 ml of 0.5 M
solution of NaOH for neutralisation. Find the percentage composition of nitrogen in the compound.
(b) The critical wavelength for producing the photoelectric effect in tungsten is 2600Å. What wavelength
would be necessary to produce photoelectrons from tungston having twice the kinetic energy of those
produced at 2200Å ? [2+2]
Q.5 The electron in the first excited state of H-atom absorbs a proton and is further excited. The de-Broglie
wavelength of the electron in this excited state is 1340 pm. Calculate the wavelength of photon absorbed
by the atom and also longest wavelength radiation emitted when this electron de-excited to ground state.
[4]
Q.6 (a) How much 85% pure salt cake (Na2SO4) could be produced from 250 kg of 95% pure salt NaCl
in the reaction.
2NaCl + H2SO4  Na2SO4 + 2HCl
(b) A mixture of FeO and Fe2O3 is reacted with acidified KMnO4 solution having a concentration of
0.25 M, 100 ml of which was used. The solution was then titrated with Zn dust which converted Fe3+ of
the solution to Fe2+. The Fe2+ required 1000 ml of 0.10M K2Cr2O7 solution.
Find the % of FeO and Fe2O3 in the mixture. [2+3]
Q.7 (a) 120 ml of O2 takes 8 minutes to pass through the hole. What volume of SO2 will pass through the
hole in 12 minutes? [2]
(b) Arrange the following set of compounds in order of their decreasing relative reactivity with an
electrophile. E.
(i) Chlorobenzene ; 2, 4 dinitro chlorobenzene; p–nitrochlorobenzene
(ii) Toluene; p–CH3–C6H4–CH3; p–CH3–C6H4NO2; p–NO2–C6H4–NO2 [1.5 x 2]
Q.8 (a)How many grams of water must be added to 100 g aqeous solution of HCl containing 25% by weight
of HCl in order to form resulting solution contain 20 % by weight of HCl.
(b) A lawn fertilizer as rated as 6.0% nitrogen, measuring 6 g of N in 100 g of fertilizer. The nitrogen is
present in the form of urea [(NH2)2CO]. How many grams of urea are present in 100 g of the fertilizer
to supply the rated amount of nitrogen?
(c) Qualitative analysis of an unknown acid found only carbon, hydrogen and oxygen. Quantitative
analysis gave the following data. A 10.46 mg sample, when burned in oxygen, gave 22.17 mg CO2 and
3.40 mg H2O. It's molecular weight was determined to be 166. When a 0.1680 g sample of the acid
was titrated with 0.125 M NaOH, the end point was reached after 16.18 ml of the base had been
added.
(i) What is the empirical formula?
(ii) What is molecular formula?
(iii) Is the acid mono-, di-, or triprotic? [1+1+3]
Q.9 (a) An unsaturated hydrocarbon having molecular formula C4H8.

(i) Write the geometrical isomer of this compound.
(ii) Write ring chain isomer of this compound.
(iii) Write positional isomer of this compound.
(iv) Write chain isomer of this compound.

e
(b) If Cl+(g)  Cl(g) H = –1255 kJ/mol
–
& I.E. of Cl is 348 KCal / mol then
(i) calculate E.N. of Cl on Pauling scale
(ii) What can be predicted about order of electronegativity of Cl, Cl+ & Cl–. [2+3]
Q.10 (a) Write the IUPAC name of the following compound.
Cl O
| ||
(i) CH  CH  C  O  CH  CH (ii)
2 2 3
|
OCH 3
(b) Balance the redox reaction:

KClO3 + H2SO4  KHSO4 + HClO4 + ClO2 [2+3]
Q.11 Carry out the following conversions [1.5 × 4]

(1) 1–Chlorobutane to n–octane (2) Ethanol to Fluoroethane
(3) CH3CCH to CH 3  C  CH 3 (4) CH3COOH to CH3–CH3
||
O
Q.12 (a) Calculate the weight of water present in one litre of air at 25°C and 40% relative humidity. The
vapour pressure of water at 25°C is 23.7 torr.
(b) The subshell that arises after f sub-shell is called g sub-shell.
(i) How many g orbitals are present in the g sub-shell
(ii) In what principal electronic shell would the g sub-shell first occur and what is the total number
of orbitals in the shell.
(c) A mixture of NH3(g) & N2H4(g) is placed in a sealed container at 300K. The total pressure is 0.5
atm. The container is heated to 1200 K at which both substances decompose completely according to
the equations:
2NH3(g)  N2(g) + 3H2(g); N2H4(g)  N2(g) + 2H2(g)
After decomposition is complete, the total pressure at 1200K is found to be 4.5 atm. Find teh mole
percent of N2H4(g) in the original mixture. [2+2+2]
PC VC 3
Q.13 (a)Calculate the volume occupied by 14.0 g N2 at 200 K and 8.21 atm pressure if = and
RTC 8
Pr Vr
=2.2.
Tr
(b) What are the bond orders in each of
(i) CN (ii) CN–
which should have greater bond energy.
(c) Arrange the following in order of their reactivity towards HBr:
1–Phenyl–1–propanol, 1–Phenyl–2–propanol, 3–Phenyl–1–propanol [2+2.5+1.5]
Q.14 (a)Predict the type of hybridisation, bond angle and shape of the following molecules based on VSEPR
theory.
(i) ClO 3 (ii) ICl4
(b) Draw all geometric isomers of the PBr2Cl3 molecules state whether each isomer has a dipole moment
or not. [3+3]
Q.15 (a)The H–P–H bond angles in PH3 are smaller than the H–N–H angles in NH3. Explain
(b) Draw the total isomers of the compound containing benzene ring & molecular formula is C7H8O.
(c) Ether and water have same hybridization at oxygen. What angle would you
expect for them ? [2+2+2]

DPP (1 TO) Physical Chemistry

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PHYSICAL CHEMISTRY

Daily Practice Problems

Q2. How many moles of electron weight one kilogram?

Q3. 18 gms of water contains

Q5. Which has the highest mass?

(i) The flow of the gulf stream in milliliters per minute is

Q2. 54.4 gm [Fe(H2O)5NO]SO4 contains

Q4. The total number of atoms present in 25 mg of Camphor, C10H16O are

Q.4 1 gm-atom of nitrogen represents :

Q.7 The total number of moles in a closed beaker containing : (approx)

Q.2 Weight of nitrogen gas can be obtained from 720 kg of urea

Q.3 Calculate the percentage of CaO in

Q.4 Determine the percentage composition of each elements of Mg3(PO4)2.

Q10. In the estimation of molar mass of an organic base by chloroplatinate

Q4. Daltions’s law of partial pressure is not applicable to:

Q7. Weight of 112 mL of oxygen at NTP on liquefaction would be:

Q5. Translational kinetic energy for 2 moles of a gas at 270C is

Q9. If a gas is expanded at constant temperature

Q10. Fraction of molecules with K.E. greater than E is given by

Q5. Rutherford created a theoritical picture of the atom based on

Q2. Which is not characterishics of planek’s quantum theory of radistion:

Q3. Which is not the property of the photons:

Q4. The rest mass of a photon of wavelength λ is:

Q5. Calculate the mass of a photon having wavelength 1 nm. is 

Q6. Which of the following statements is true:

Q7. Planck’s constant has the same dimensions as:

Q8. If wavelength of photon is 2.2 x 10-11 m, than momantum of photon is:

Q12. The dynamic mass/equivalent mass of a photon of wavelength  is:

Q2. Which concerning Bohr model is not true:

Q6. Angular momentum of the e- of H-atom is proportional to

Q9. The largest wavelength capable of ionising H-atom is:

Q.4 Identify oxidant and reductant in the following redox reactions

Q.5 Identify disproportionation reactions in the following :

Q.6 Balance the following equations by POAC

Q.9 Balance the following equations :

(ii) As O33 + Mn O 4  As O34 + MnO2 ; (in alkaline medium)

(ix) + HCl 

(vi) + NaOH  + H2O

Q5. Determine the molarity of pure water.

Q2. IL hard water contains 1 mg CaCl2 and 1 mg MgCl2

Select only one correct alternative. [25 x 3 = 75]

Q.3 Which of the following statement(s) is/are correct:

Q.5 Which is not correctly matched with its structure?

Q.10 Which is correct statement?

Q.12 The hybridization of atomic orbitals of N in NH 4 , NO 2 & NO 3 are respectively

Q.17 IUPAC name of CH 3  CH 2  N  CHO is

Q.21 For a general ideal gaseous reaction

Q22. CH4 can be prepared by which method.

Q23. Free radical is formed as intermediate in

Q24. Method I & II are best for preparation of following compounds:

Major product of the above reaction is :

(A) CH3–(CH2)6CH3 (B) CH 3  CH 2  CH  CH  CH 2  CH 3

(C) CH 3  CH  CH 2  CH 2  CH  CH 3 (D) none of these

Q.9 (a) An unsaturated hydrocarbon having molecular formula C4H8.

Q.10 (a) Write the IUPAC name of the following compound.

(b) Balance the redox reaction:

Q.11 Carry out the following conversions [1.5 × 4]

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