REVIEW TEST-1

C
H E
M I
STRY

Class : XI (J-Batch)
Time : 100 min Max. Marks : 75
INSTRUCTIONS
General Remarks:
1. The question paper contain 19 questions. All questions are compulsory.
2. Each question should be done only in the space provided for it, otherwise the solution will not be
checked.
3. Use of Calculator, Log table and Mobile is not permitted.
4. Legibility and clarity in answering the question will be appreciated.
5. Put a cross ( × ) on the rough work done by you.

Name ________________________________ Father's Name ____________________________

Class : __________ Batch : B.C. Roll No. ___________

Invigilator's Full Name __________________________________________________

USEFUL DATA

Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.4, Pt = 195,
Se = 79

For Office Use ……………………………. Total Marks Obtained…………………

Q.No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Marks
XI (J-Batch) SOLUTIONS (CHEMISTRY)
35
Q.1 Calculate number of neutrons in 140 g of 17 Cl . [4]
35
[Sol: wt of 17 Cl = 140 gm

35
140
moles of 17 Cl = =4
35
140
No. of atoms = 4NA
35
 No. of neutrons = 4NA × 18 = 72 NA
= 4.34 × 1025 Ans. ]

Q.2 What volume of H2S(g) measured at 1.0 atm and 0°C is produced when 16.60 g of KI reacts with
excess of H2SO4 according to equation 8KI + 5H2SO4  4K2SO4 + 4I2 + H2S + 4H2O.
[4]
[Sol: 8KI + 5H2SO4  4K2SO4 + 4I2 + H2S + 4H2O
nKI
= nH 2 S
8
nKI 16.6 1
 nH 2 S = = =
8 8  166 80
For H2S
1
Volume of H2S = 22.4 × = 0.28 litre = 280 ml Ans. ]
80

Q.3 Copper is obtained from ores containing the following minerals:

Azurite : Cu3(CO3)2(OH)2
Malachite : Cu2 CO3 (OH)2
Chalcocite : CuFeS2
Which mineral has (a) the lowest, (b) the highest copper content on a percentage by mass basis?
[4]
[Sol: Azurite Cu3(CO3)2(OH)2
3  63.5 100 3  63.5 100
% of Cu = molar mass = = 55.3%
344.5
Malachite Cu2CO3(OH)2
2  63.5  100
% of Cu = = 57.47%
221
Chalcocite CuFeS2
63.5  100
% Cu = = 34.6%
183.5
Therefore (a) chalcocite has the lowest % of Cu i.e. 34.6%.
(b) Malachite has the highest % of Cu i.e. = 57.47 % ]

Q.4 What mass of MgCl2 would contain the same total number of ions as 292.5 g of NaCl. [4]
[Sol: Let the mass of MgCl2 required

Moles of MgCl2 =
95
 2
 moles of Cl– =
95

moles of Mg2+ =
95
2  3
 total moles of ions from MgCl2 =  =
95 95 95
3
& total no. of ions from MgCl2 = × NA ....(i)
95
Now
Mass of NaCl = 292.5
292.5
Moles of NaCl = =5
58.5
 total moles of ions from NaCl = 10
& total no. of ions from NaCl = 10NA .....(ii)
 from (1) and (2)
3
N = 10NA
95 A
 = 316.67 gm ]

Q.5 An aqueous solution of ethanol has density 1.025 g/ml and it is 2 M. Determine Molality of this solution.
[4]
[Sol: Let volume of solution = 1000 ml = 1 litre.
 moles of solute = 2
mass of solute = 2 × 46 = 92 gm
mass of solution = 1.025 × 1000 = 1025 gm
 mass of solvent = 933 gm
2
 molality = × 1000 = 2.14 m. Ans. ]
933

Q.6 1.8 gm of copper reacted with excess of O2 and produced x gram of non-stoichiometric compound
Cu1.8O. Find the value of x. [4]
[Sol: Cu  Cu1.8O
POAc for Cu
nCu = 1.8 × nCu1.8 o

1. 8 1.8  x
 =
63.5 1.863.5  16
x = 2.052 gm ]

Q.7 A certain public water supply contains 0.10 ppb (part per billion) of chloroform (CHCl3). How many
molecules of CHCl3 would be obtained in 0.478 ml drop of this water? (assume d = 1 g/ml)
weight of solute
[PPb = weight of solvent ×109] [4]

[Sol: Mass of solution = 0.478 × 1 = 0.478 gm

  mass of CHCl3 = 0.478 × 0.1 × 10–9
= 0.478 × 10–11 gm
4.78 10 11
moles of CHCl3 = = 4 × 10–13
119.5
 no. of molecules of CHCl3 = 4 × 10–13 × NA
= 2.41 × 1011 ]
v
Q.8 Convert 20%   HCl(aq) solution into % by mass, if density of solution is x g/ml. [4]
V
[Sol: When HCl(g) is dissolved in water, it gives HCl (aq). If (V/V) % = 20%, it means 20 ml of HCl(g) is
dissolved in water to give 100 ml of solution.
When the temperature & pressure of a gas is not given it is taken as STP. Hence, the no. of moles of
20
HCl(g) = moles
22400
20 36.5
wt. of HCl(g) = g
22400
Density of Solution = x g ml–1
mass of 100 ml solution = 100 x g
20  36.5  100 3.259 102
(w/w)% = %= %]
22400  100 x x

Q.9 A compound of formula XCl3 reacts with aqueous AgNO3 to yield a precipitate of solid AgCl according
to the following equation
XCl3(aq) + 3AgNO3(aq)  X(NO3)3 (aq) + 3AgCl(s)
When a solution containing 1 g of XCl3 was allowed to react with an excess of aqueous AgNO3, 2.65
g of solid AgCl was formed. What is the identity of the atom X? [5]
[Sol: XCl3(aq) + 3AgNO3(aq)  x(NO3)3(aq) + 3AgCl(s)
nxCl3 n AgCl

1 3
1 2.65

A  35.53 3 143.5
A + (35.5) (3) = 162.5
A = 56 Ans ]

Q.10 A compound X contains 63.3 percent Manganese (Mn) and 36.7 percent oxygen (O) by mass. When
X is heated O2 is evolved and a new compound Y containing 72.0 % Mn & 28% oxygen is formed.
(a) Determine the empirical formula of X and Y.
(b) Write a balanced equation for the conversion of X to Y. [4]
[Sol: (a) for X
% by mass moles Emipirical Formula
Mn 63.3 Mn 1.15 Mn1.15 O2.3
O 36.7 O 2.3 = MnO2
Empirical Formula of X = MnO2
For Y
 % by mass moles Emipirical Formula
Mn 72 Mn 1.314 Mn1.31 O1.75
O 28 O 1.75 = MnO1.33
= Mn3O4
Empirical Formula of Y = Mn3O4
(b) 3MnO2  Mn3O4 + O2 ]

Q.11 26.2 g of MgCl2.2H2O is mixed with 92.8 g of H2O. Calculate

(i) Molarity of Cl– ion
(ii) Molality of Cl– ion density of resultant solution is 2.38 g/ml. [5]
[Sol: Mass of MgCl2 ·2H2O
26.2
 moles of MgCl2·2H2O = = 0.2
95  36
 moles of H2O from compound = 0.2 × 2 = 0.4
 mass of H2O in solution = 92.8 + (0.4 × 18) = 100 gm
(i) mass of solution = 26.2 + 92.8 = 119 gm
119
volume of solution = = 50 ml
2.38
moles of Cl– = 0.2 × 2 = 0.4
0.4  1000
 molarity of Cl– = = 8M
50
0.4  1000
(ii) Molality of Cl– = = 4m Ans. ]
100

Q.12 Consider the following unbalanced reaction:

MnI2 + F2  MnF3 + IF5
(i) Balance the reaction
(ii) What is the minimum mass of F2 that must be used to react with 30.9 g of MnI2 is overall
yield of MnF3 is no more than 80%. [6]
[Sol: (i) aMnI2 + bF2  cMnF3 + dIF5
 a = c; 2a = d; 2b = 3c + 5d
Put a = 1, d = 2, c = 1
13
b = 3 + 10 =
2
13
so MnI2 + F  MnF3 + 2IF5
2 2
 2MnI2 + 13F2  2MnF3 + 4IF5
30.9
(ii) nMnI 2 = = 0.1 mole
30.9
nMnF3 = 0.1 mole (considering 100% yield)
nMnF3 = 0.08 mole (considering 80% yield)
Hence, the no.of mole of F2 required for 0.08 mole of MnF3 = 0.52 mole
Hence, the wt. of F2 required = 0.52 × 38 g = 19.76 g
Q.13 On combustion analysis, a 0.450 g sample of Caproic acid (contained only C,H & O) gives
0.418 g of H2O and 1.023 g of CO2. What is the empirical formula of Caproic acid? If the molecular
mass of Caproic acid is 116 amu, what is the molecular formula? [5]
[Sol: C  CO2 H  H2O
POAc for C POAc for H
nC = nCO2 nH = 2 × nH 2 O
1.023 2 0.418
nC = nH =
44 18
= 0.023 = 0.046
C = 0.279 g H = 0.0464 g
 0 = 0.45 – (0.279 + 0.0464) = 0.1245
 n0 = 0.00778
empirical formula = C0.023H0.046O0.00778 = C3H6O
Molecular mass 116
n = Emipirical formula mass = = 2
58
 molecular formula = (C3H6O) } 2 = C6H12O2 ]

Q.14(a) The vapour density of a mixture of gas A (Mol. mass = 40) and gas B (Mol. mass = 80) is 25. Calculate
mole % of gas B in the mixture. Molar mass = 2 × vapour density.
(b) How many ml of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 & NaHCO3
containing equimolar amounts of two? [6]
[Sol: (a) Mavg = yAMA + yBMB
 25 × 2 = yA(40) + yB(80)
 4yA + 8yB = 5 ...........(1)
& yA + yB = 1 ...........(2)
on Solving
3
yA =
4
1
yB =
4
1
 mole % of B = × 100 = 25%
4
(b) Let mass of Na2CO3 = xg
x
 moles of Na2CO3 =
106
& molesof NaHCO3 = (1 – x) g
1 x
 moles of NaHCO3 =
84
here nNa2CO3 = nNaHCO3

x 1 x
=
106 84
 84 x = 106 – 106 x
x = 0.558 gm
 nNa2CO3 = 5.023 × 10–3, nNaHCO3 = 5.263 × 10–3
 (1) NaHCO3 + HCl  NaCl + CO2 + H2O
(2) Na2CO3 + 2HCl  2NaCl + CO2 + H2O
moles of HCl used in (1) = nNaHCO3 = 5.263 × 10 –3
moles of HCl used in (2) = 2 × nNa2CO3 = 2 × 5.263 × 10–3 = 10.526 × 10–3
 total moles of HCl used = (10.526 + 5.263) 10–3 = 0.015789
M V
 = 0.015789
1000
0.1 V
= 0.015789
1000
 V = 157.9 ml
 158ml ]

Q.15(a) An enzyme isolated from human red blood cells was found to contain 0.316% Selenium. What is the
minimum molecular weight of enzyme?
(b) 54 g of aluminium is to be treated with a 10% excess of required H2SO4. The chemical equation
(unbalanced) for the reaction is Al + H2SO4  Al2(SO4)3 + H2.
What volume of concentrated sulphuric acid of density 1.80 g/cm3 and containing 90% H2SO4 by
weight must be taken? [6]
[Sol: (a) ESex (Formula)
x  ASe  100
% of Se = = 0.316
M
for min. molecular weight x = 1
1 79
 0.316 =  100
M
M = 25000 Ans.
54
(b) Moles of Al given ==2
27
2Al + 3H2SO4  Al2(SO4)3 + 3H2
2
Moles of H2SO4 required = ×3 = 3
2
10
 moles of H2SO4 taken = 3 + 3 = 3.3
100
 mass of H2SO4 taken = 3.3 × 98 = 323.4 g
323.4
so mass of solution =  100 = 359.33 gm
90
let volume of H2SO4 solution = V ml
 V = 1.8 = 359.33
V = 200 cm3. Ans. ]

Q.16 A mineral consists of an equimolar mixture of the carbonates of two bivalent metals. One metal is present
to the extent of 13.2% by weight. 2.58 g of the mineral on heating lost 1.232 g of CO2. Calculate the %
by weight of the other metal. [6]
[Sol: In the mixture
MCO3 + NCO3
% of M + % of N + % of CO32– = 100 .......(1)
here % of M = 13.2 %
Now mixture  CO2
(CO32–)
moles of CO32– = moles of CO2
1.232
= = 0.028
44
 mass of CO32– = 0.028 × 60 = 1.68 gm
1.68
% of CO32– in the mixture = × 100 = 65.1%
2.58
from (1)
% of N = 100 – 65.1 – 13.2 = 21.7%
 % of other metal = 21.7% ]