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CLASS - XII –A
ROLL NUMBER -
UNDER GUIDANCE OF
1
Variation of
Conductance
with
Temperature in
Electrolytes
2
Index
1. Certificate.................................................................3
2. Acknowledgements.....................................................4
3. Aim..........................................................................5
4. Apparatus..................................................................6
5. Important Terms........................................................7
6. Conductivity...............................................................8
7. Factors Affecting Electrical Conductivity.........................9
8. Procedure.................................................................10
9. Physical Constants.....................................................11
10. Observation Set
1 12
11. Graph of Observation Set
1 13
12. Observation Set
2 14
13. Graph of Observation Set
2 15
14.14.
Result.....................................................................16
15.15.
Conclusion...............................................................17
16.16.
Precautions..............................................................18
17.17.
Bibliography.............................................................19
3
Certificate
Mr N SATHISH KUMAR
Department of Chemistry
4
Acknowledgements
"There are times when silence speaks so much more loudly than
words of praise to only as good as belittle a person, whose words
do not express, but only put a veneer over true feelings, which
are of gratitude at this point of time."
5
Aim
6
Apparatus
7
Important Terms
Conductance: The property of ease of flow of electric
current through a body is called conductance.
Faraday's Laws:
🌕 First Law: The mass of a substance produced or
consumed in electrolysis is directly proportional to the
quantity of charge passing through it.
m Q
or, m = Z × I × t
where, Z is electrochemical equivalent; I is current; t is
time in seconds; Q is charge.
8
Conductivity
R=1/C
Κ=1/R*L/A
9
Factors Affecting Electrical
Conductivity
10
Procedure
11
Physical Constants
Voltage
Nature of electrodes
Size of electrodes
Separation between the electrodes
Concentration of the electrolytes
Nature of the electrolytes
Resistance in the circuit
12
Observation Set 1
For ZnSO4 electrolyte with Zn electrodes
I V R=V/I C=1/R
1 23 □C 100 mA 1.0 V 10 Ω 0.100 Ω-1
2 26 □C 100 mA 0.95 V 9.5 Ω 0.105 Ω-1
3 29 □C 110 mA 0.89 V 8.09 Ω 0.120 Ω-1
4 32 □C 110 mA 0.84 V 7.63 Ω 0.130 Ω-1
5 35 □C 120 mA 0.80 V 6.66 Ω 0.150 Ω-1
6 38 □C 125 mA 0.75 V 6.00 Ω 0.160 Ω-1
7 41 □C 130 mA 0.71 V 7.6 Ω 0.180 Ω-1
8 44 □C 130 mA 0.65 V 5.00 Ω 0.200 Ω-1
13
Graph of Observation Set 1
0.2
0.2
Conductance (in Mho)
0.18
0.16
0.15
0.15
0.13
0.12
0.11
0.1
0.1
0.05
0
20 25 30 35 40 45 50
Temperature (in degree Celsius)
14
Observation Set 2
For CuSO4 electrolyte
I V R=V/I C = 1/R
1 25 □C 75 mA 1.4 V 18.67 Ω 0.053 Ω-1
2 28 □C 75 mA 1.35 V 18.00 Ω 0.055 Ω-1
3 31 □C 75 mA 1.3 V 17.33 Ω 0.057 Ω-1
4 34 □C 75 mA 1.25 V 16.67 Ω 0.060 Ω-1
5 36 □C 80 mA 1.2 V 15.00 Ω 0.066 Ω-1
6 38 □C 80 mA 1.15 V 14.38 Ω 0.069 Ω-1
7 42 □C 80 mA 1.10 V 13.75 Ω 0.072 Ω-1
8 44 □C 85 mA 1.10 V 12.94 Ω 0.075 Ω-1
9 47 □C 85 mA 1.05 V 12.35 Ω 0.080 Ω-1
10 49 □C 90 mA 1.10 V 11.11 Ω 0.090 Ω-1
11 53 °C 90 mA 1.90 V 10.00 Ω 0.100 Ω-1
15
Graph of Observation Set 2
0. 1
0.1
0. 09
0. 08
0.08 0.08
0.07
Conductance (in Mho)
0. 07
0. 07
0. 06
0.06 0.06
0.06
0. 05
0.04
0.02
0
20 25 30 35 40 45 50 55
Temperature (in degree Celsius)
16
Result
17
Conclusion
18
Precautions
19
Bibliography
20