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Introduction [16-19], and (3) the operation of turbines within the two-phase
region [20]. With the exception of reference [1], the analytical
L
I HE TWO-PHASE critical flow of one-component mix- models which resulted from these studies were either thermo-
tures has been the subject of many analytical and experimental dynamic equilibrium or frozen (no mass transfer) models. In
investigations because of its importance in (1) safety analyses addition, most of these models require a knowledge of the throat
of pressurized water, boiling water, and liquid-metal-cooled pressure which is generally unknown. Those which can be
nuclear reactors [1—15],2 (2) the flow of refrigerants and cryogens based on stagnation conditions, such as the equilibrium model
proposed by Moody [13], considerably overestimate the flow
rates in nozzles [19, 21]. Therefore, the purpose of this paper
1
Formerly, Lewis Research Center, Cleveland, Ohio. is to develop a model which requires only a knowledge of the
Contributed by the Heat Transfer Division and presented at the stagnation conditions and at the same time accounts for the
Winter Annual Meeting, New York, N. Y., November 29-December
3, 1970, of T H E AMERICAN SOCIETY OF MECHANICAL ENGINEERS.
nonequilibrium nature of the flow.
Manuscript received by the Heat Transfer Division April 28, 1969;
revised manuscript received June 12, 1970. Paper No. 70-WA/HT-5. Numbers in brackets designate References at end of paper.
"Nomenclature-
A = cross-sectional area u = velocity equilibrium (corresponding to local
C — discharge coefficient v = specific volume static pressure)
c = specific heat W = flow rate F = frozen
F = viscous forces x = quality, Wg/{Wg + W,) g == vapor phase
/ = function z — axial length H = homogeneous (equal phase veloci-
G — flow rate per unit area a = void fraction, AQ/Al ties)
H = enthalpy 7 = isentropic exponent I = liquid phase
h = enthalpy r\ = critical pressure ratio, P,/Pn 0 = stagnation
k = velocity ratio, ug/ui T = time V = constant, pressure
N = experimental parameter R = reduced pressure
n = polytropic exponent TP = two-phase
P = pressure Subscripts
t = throat
s = entropy B = backpressure v = constant volume
T — temperature critical condition w = wall
Vapor Continuity
W v (2)
PROPOSED
Momentum
-AdP = d{Wgiig + Wiud + dFw (3)
x
EQUI LIBRIUM \
For the high-veloeit}' flows in a converging nozzle, such as that
shown in Fig. 1, the wall shear forces are negligible compared
lo the momentum and pressure gradient terms. Therefore,
equation (3) can be approximated by AXIAL LENGTH, Z
-dP = Gd[xug + (1 - x)u,] (4) Fig. 1 Comparison oF equilibrium and proposed heat and mass transfer
processes for critical flow in a nozzle
It is assumed that, for fixed stagnation conditions, x, vg, vh ug,
and it, are either constant or composite functions of P and z
(f[P(z)]) for fixed upstream conditions. Hence, equation (4)
shows that dL dL ldP\
(9)
dP dz dz\,
d[xua + (1 - x)ui\
Grl = - dP
(5) where Lt denotes vgt, Vu, x„ or kt. If the above derivatives are
• dz
(The subscript t indicates t h a t all the enclosed quantities are viewed from a Lagrangian system, such that z = U,T and — =
evaluated at the .throat.) At critical flow, the mass flow rate dr
uu equation (9) shows that
exhibits a maximum with respect to the throat pressure.
dL dL ldF_
dGc (10)
= 0
dP ~dr
(6)
dP
Hence, these quantities describe the local rates of interphase heat,
Equation (6) can be applied to equation (5) to give an expression mass, and momentum transfer occurring at the throat.
for the critical flow rate In a converging nozzle, the acceleration and the accompanying
steep pressure gradients essentially occur between the upstream
&? A xk + (1 — x)
[(1 - x)kv, + xvg] (7)
location which has a diameter twice t h a t of the throat and the
dP k throat itself as shown in Fig. 1. Therefore, in normal nozzle
configurations, there is little time for mass transfer to take place,
where k is defined by k = U„/M,. Equation (7) can be expanded and it is reasonable to assume that the amount of mass trans-
to ferred in the expansion is negligible.
x0 (11)
G? = - Ik [1 + x(k - l)]x -£ + [vg{l + 2x(k - 1)
This is illustrated by the solid line in Fig. 1 as compared to the
dotted line which is representative of the thermodynamic
+ kv,2(x - 1) + fc(l - 2s)'}] ^ + M l + x(k - 2) equilibrium behavior commensurate with the pressure profile.
dP An analogous argument can be applied to the transfer of heat
dvi I v„\ dk between the phases, which is illustrated by the essentially con-
(8) stant liquid temperature shown in Fig. 1.
via = vu (17)
(1 ~ x)c,/cpg + 1
(19)
(1 - x)cu'c 1/7
This exponent reflects a significant heat transfer rate at the
Like the local heat transfer rate, the rate of mass transfer at
throat.
the throat can be appreciable. In reference [1] it was shown
The liquid compressibility is generally a very small part of that
that, if an equilibrium quality is defined as
characterizing the two-phase system: Hence, it is assumed
herein that the liquid phase can be considered incompressible.
xE = (23)
b
dvj. oE
0 (20)
dP the exit plane mass transfer rate for steam-water critical flows in
constant-area ducts can be correlated by
The term — which is indicative of the momentum transfer ds, ds„
dP
rate, is difficult to evaluate and appears to be significant [1, 24]. dx . dxE
= N- (24)
According to the approximation of equation (11), a one-com- dP UP
ponent mixture essentially expands in a two-component manner.
Vogrin [25] determined axial velocity ratio profiles for low- where
quality, air-water critical flows in a converging-diverging nozzle.
Since k was assumed to be/[-P(«)], N = N(xE) (25)
~| 6000
D ^ v
a N^
5000
UJ
<
1-
* 4000
O
_i \ \
U- \ \
-i 3000 N \ —
<t N. \ .
o
t ®® dsn
9 X«» DCN.
g 2000 \ is.
J i i i I i ii I I II 1 1 ,J M i l l ! 1 1 1 1 1 1 1 ll I*'
0.001 0.01 0.001 0.01 0.10
STAGNATION QUALITY, X„ STAGNATION QUALITY, X0
Fig. 3 Comparison between proposed model and experimental data of Fig. 4 Comparison between proposed model and experimental data of
references [26, 27] references [26, 27]
plicable to nozzle flows and that Ar can be represented by N = The equation for the critical flow rate is coupled with the
CixE„ but the constant C\ will have a value other than 20. momentum equation describing the overall pressure history to
obtain a solution in terms of the stagnation conditions. The
The derivative —- can be determined from the expression two-phase momentum equation (4), under the restrictions listed
dP
above, can be written as
T„ds„ dh„ — v„dP (27)
/ « •
If it is assumed that the vapor behaves as a real gas following the - [(1 — x<,)vl0 + x0v„]dP = d (31)
poly tropic process described • in equation (18), it can be shown \2
that
This expression can be integrated between the stagnation and
1 throat locations to give
(28)
dP P, 7.
(1 - z„>,„(P„ - Pt) + —5-4 [P„«„o - Ptvgl]
dk 7 —1
T h e above approximations for x„ , ]et, and simplify
dP
[(1 - x0)vio + .W„,] 2
the critical flow rate expression to <?.* (32)
(1 - x0)N dsls
G> = 5 + K - «"-) S
„J! - « « dP
Substitution of equation (29) for the critical flow rate enables
one to rearrange equation (32) and express it more compactly as
xacm(l/n - 1/7)1" (29) 1 — cuo
!
7
P(s B « - (l-ij) +
7 - 1 (33)
If N equals unity, the prediction of equation (29) is close to V =
1
that of the homogeneous equilibrium model, and if N equals
zero the solution is approximately the homogeneous frozen
2/3c*(2 + 7 - 1
model. (These two solutions are discussed later in the paper.) where
Therefore, the quantity N describes the partial phase change
occurring at the throat. The experimental results of reference V = PJP« (34)
[11] indicate that the critical flow rates are in relatively good
agreement with the homogeneous equilibrium model for stagna- vm\ / 0 ^ - ^ o W P j . ds^
tion qualities greater than 0.10. For qualities less than this + 1 S dP
V/ \Zo(soE - IE)( )' I
value, the equilibrium model underestimates the data. Hence,
since N describes the deviation from equilibrium mass transfer, e„q/n - 1/7)'
(35)
N is set equal to unity when Xo = 0.10. As was discussed (s„o — sio) _
earlier, the term iV is correlated as a function of throat equilib-
%oVsQ
rium quality, For the operating conditions reported in a0 (36)
reference [11], a stagnation quality of 0.10 corresponds to throat (1 — .To>;o + XoVa0
equilibrium qualities ranging from 0.125 to 0.155 depending on XWgt
the pressure level. For the evaluations given herein, an average (37)
(1 - x0)vio + &>v i
value of 0.14 was chosen, thus
and
A^ = s«/0.14 (30)
For throat equilibrium qualities greater than 0.14, AT is set equal v„t = vAv V (38)
to unity. This numerical evaluation for N is common to all
fluids and geometries considered herein. For given stagnation conditions of Po and x„, the transcen-
"> 5000
S*
D ^ ^ H 0.5
K
4000
0.4 I i I
^ 8 10 12 14 16 20 22
~~~~~~-~- ^^ — STAGNATION QUALITY, x „
1 1 1 1 1 ill i i i i I i Iil I
0.001 0.01 0.10 3 The vapor expands isentropically as a perfect gas, i.e.,
STAGNATION QUALITY, X 0 Pv^i is constant.
4 The kinetic energy is due solely to the vapor expansion.
Fig. 5 Comparison of critical flow predictions and experimental data of
references [26, 27]
5 The critical flow rate is defined by gas-dynamic principles.
The proposed model is compared with the experimental V = (1 — X0)V10 + Xo!W?T (43)
steam-water results of references [26, 27] in Figs. 3 and 4 for a
range of stagnation pressures. The good agreement between respectively, and the critical flow rate is given by
the theory and the data throughout the quality range investi-
gated is apparent. l l / 7
.1 " V ' (44)
GcHF = - "\2:Eoi>„oPo T - 1
One of the standard approaches used in the literature is the
homogeneous equilibrium model. This model is described in
The predictions of the three models are compared to the
reference [11] and is based on the following assumptions:
experimental data in Fig. 5 for a stagnation pressure of 500
1 The average velocities for the phases are equal. psia. The model proposed in this study exhibits the best agree-
2 Thermodynamic equilibrium exists between the phases. ment throughout the quality range of interest.
3 The expansion is isentropic. The critical pressure ratio predictions of the three models dis-
4 Properties correspond to those presented in the steam cussed above are compared to the experimental data in Fig. 6.
tables, reference [28]. The flow rate prediction resulting from Again, it is seen that the formulation developed herein is the
these assumptions is best solution throughout the range. It should be noted here
that there were discrepancies in the critical pressure ratio data
(1 - xE)hh xEh, I'A
oBJ
(39) reported in reference [27]. The two nozzles employed gave two
G.,
(1 - xE)vlE + xEvgE different characteristic curves for the critical pressure ratio as a
function of stagnation quality. As was discussed in reference
The critical flow rate prediction of this model is computed by
[11], this difference could easily be a result of a small difference
choosing successively lower downstream pressures until the
in the relative locations of the throat taps. In Fig. 6 the data
flow rate exhibits a maximum.
of nozzle no. 2 was not used because it was found that these re-
Another model which has appeared frequently in the literature sults gave critical pressure ratios which were less than those re-
is the homogeneous frozen model which is based on the following ported for two-component, air-water systems (reference [29]),
assumptions: which is not realistic. Therefore, the data shown were generated
1 The average velocities of the phase are equal. solely by nozzle no. 1.
2 No heat or mass transfer occurs between the phases. By considering Figs. 5 and 6 together, the reader can discern
20 1 1
0.7 0.8 0.9
STAGNATION QUALITY, X 0
Fig. 9 Comparison between proposed model and potassium data of
reference [31]
PROPOSED MODEL
< HOMOGENEOUS EQUILIBRIUM
_0.4 HOMOGENEOUS FROZEN
Table 1 Comparison between the proposed model and data of reference
[33]
0.3
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Flow rate (lbm/sec-ft 2 )
STAGNATION QUALITY, X 0 •Po(psia) Experimental Predicted
•lun
1 21.1
x„
0.788 54 8 53.7
Fig. 8 Comparison of critical pressure ratio predictions and experi-
mental data of reference [30] 2 19.6 0.727 54 7 52.2
3 26.9 0.871 64 1 64.7
4 26.3 0.890 61 4 62.7
5 27.5 0.834 68 1 67.5
6 26.0 0.873 61 3 62.6
the merits of the proposed model. The homogeneous frozen 67.4
7 26.8 0.795 67 4
model yields a good prediction for the critical flow rate but con- 8 23.0 0.680 66 0 62.7
siderably underestimates the critical pressure ratio. On the 9 19.5 0.641 59 1 55.2
other hand, the homogeneous equilibrium model gives a good
estimate of the critical pressure ratio but underestimates the
flow rate. Therefore, neither of these solutions correctly de-
scribes the complete physical phenomenon. The proposed
N ds,E'
formulation gives accurate predictions for both the critical GS == vm) (45)
[(«V dP
pressure ratio and flow rate and, thus, is more characteristic of "a IS
the actual behavior. This is further verified by the recent low- where iV is given by equation (30). Since no vapor is formed
pressure, steam-water data of Deich et al. [30] shown in Figs. until the throat is reached, an additional assumption is necessary
7 and 8. The stagnation pressure is so low that the applicability to estimate the vapor specific volume at the throat. As shown
of the approximation given in equation (13) is weakened con- in equation (45), it is assumed t h a t the vapor which is formed is
siderably. However, these results confirm the above discussion saturated at the local pressure.
regarding various models. The critical pressure ratio relationship for such flows is greatly
Fig. 9 compares the proposed solution to the high-temperature, simplified.
high-quality potassium data [31]. The tabular properties of
Weatherford [32] were used in calculating the predictions. vi«Oc2
r, = 1 - (46)
Table 1 shows the good agreement between the predictions of the 2P 0
proposed model and the recent high-quality, steam-water nozzle
data of Carofano and McManus [33], Figs. 10 and 11 compare Equation (45) can be substituted into equation (46) to give a
the present analysis with the two-phase carbon dioxide nozzle transcendental expression for the critical pressure ratio. A
reported by Hesson and Peck [16] and detailed in reference [17]. solution to this expression gives predictions for both the critical
pressure ratio and flow rate.
In Fig. 12 the predictions for initially saturated and sub-
Saturated and Subcooled Conditions cooled water are compared to the data of references [8, 34, 35,
The proposed solution applies to a saturated-vapor stagnation 36, 37, 38]. The model describes the general behavior of the
condition when x0 — 1. The model can also be applied to cases experimental results. The agreement is better for higher
where the stagnation condition is either saturated or subcooled pressures and subcoolings. The model is also compared to recent
liquid. For such cases x0 = 0 and the critical flow expression subcooled liquid nitrogen data [39] in Fig. 13. The agreement
is simplified to is excellent throughout the reported ranges of pressures and sub-
ATE
T0=I87.2°R>
- 4 A * ^ -
X s<U*s^ ^-"-"^
-
X0=2I6°R „
5000 —— i*- —
P 2000
- , SATURATED -
1 , 1 1 _L_L_J_1 I l l "
100 200 300 600
1
1 1 1
O
X 16
i r A SATURATED
o PSAT = 2I4 psia 9 / • VAPOR
aj \ ft/ / O LIQUID
f° 14 y ° P r,
3=
o 320 psia > P0 > 280 psia
%, f/° / 0 SUBCOOLED LIQUID
E 12 — 0/
A A / / 0 A P S AT= 214 P s i a "
714 psia > P0 > 676 psia
&y /
P
o / O * S A T = 3 M PSif _
«> 10
UJ & / -P S A T = 314 psia Q
1— <3> / /
o / / ^^
^J^^^ -—-^T SATURATED °o/ f
X
£ o / LIQUID
M 6 /<* —
u.
8 / ^ ^
3 4 — °/
o ^»*»*« ^SATURATED VAPOR
a:
w -i
*-T°**! 1 1 1
400 600 800 1000 1200
STAGNATION PRESSURE, P0 psio
F
SATURATED _Jpj_»F DATA OF REF
3000^
• 302 (37)
edged orifices do not choke; however, thej' do asymptotically
O (35)
2000 — A (36) 8 284 (37) • approach a maximum flow rate. For flows operating well into
• (37) s 284 (8) the compressible range (PB/Po < 0.3 where PB is the downstream
1000 __ r 316 (38) receiver pressure), a compressible discharge coefficient for fixed
, stagnation conditions can be defined as
1 \ 1
50 100 150 200 250 350
actual flow rate
STAGNATION PRESSURE, P. psio C =
critical flow rate in ideal nozzle
Fig. 12 Comparison befween proposed model and saturated and sub-
COO led water data of references [8, 3 4 - 3 8 ] This definition can be incorporated into equation (32) to give a
y 2000 — ~ ^ " ~ ^ 3 — ^ — _ ^
%. 10 1 1 1 1 1 1 Ml 1 1 I inn 1 i 1 1 1 Mi
A —- ;-P0 = 882 psia -
1000 .1 1 1 1 - o •
-<F>o=o5E psia _
0.10 0.20 0.30 0.40 0.5C
_ P0=294 psia-^^5"^-- / A~Vv\ —
STAGNATION QUALITY, X0
Fig. 16 Comparison between proposed model and two-phase orifice
data of reference [17] 1^=88.2 psia- : : ^--. 9
— ^^\ » 8
^^\^
formulation for two-phase compressible flows through orifices. - *\ _
Equation (33) is then written as
- ~\® _
1 - «o 7
7-1
— x >
«o (1 - i?) + 7 - 1
(47) 1 1 1 II 1 II! I 1 1 Mill 1 1 1 1 11 III
1 7 10 ' 10' 10' 10"
2C2/3a,2 7 - 1 STAGNATION QUALITY, X„
As before, this transcendental expression for the critical pressure Fig. 18 Comparison between proposed model and short-tube, steam-
water data of reference [49]
ratio can be solved to give a prediction for the maximum flow
rate.
The single-phase experiments of Perry show the compressible Strobridge [48]. In Fig. 18, the model is also compared to
discharge coefficient for sharp-edged orifices is 0.84. This value the short-tube, steam-water results of Friedrich [49], The
is also representative of single-phase critical flows through short model is in good agreement for all the mixtures considered.
tubes [45]. I t is assumed that this discharge coefficient is also
applicable to one-component, two-phase flows through similar
geometries. (As stated above, this only applies to systems
which are two-phase mixtures in the upstream stagnation Summary and Conclusions
chamber.)
A model is developed for the two-phase critical discharge of
The predictions for compressible two-phase flow of carbon
one-component mixtures through convergent nozzles. The
dioxide through a sharp-edged orifice are compared to the data
salient features of the model are:
of Hesson [17] in Figs. 15 and 16. The saturation properties of
carbon dioxide were assembled from references [46, 47]. Fig. 17 1 The proposed solution is based on and requires a knowledge
compares the model to the two-phase nitrogen data of Bonnet of only the geometry and the upstream stagnation conditions.
[19] and Campbell and Overcamp [18]. To effect a common 2 The stagnation conditions covered by the model include
basis for comparison, the model and the data from both refer- subcooled liquid, saturated liquid, two-phase mixtures, and
ences were all evaluated from the saturation properties of saturated vapor.