Ain

A caxioatives anmenia. knawr

amines&

smine Can Beypaxed taplacernent

dssganatem ammenia alh

Glassigicatiem amine
based mnumlea alR geuns attachad e
the nituagenAtem Amins a slaszipiacd inte 3 na

imasuy- Amines
haeendauy- aminog

deatioouyamin

Meimay4 Amine
dhe Aming in uhich nitsgen a t e m is diacte
atoshedd te emo AlkyRQReLP

gCHa-NH2 methanaming

.CHa-CH2-NHa ethanamine

decemday aminiz

aminas in uwhich nitaagen. atem is disaetly

ttachad te use alkR u p s .

Eq: CH3-NH-CHa nN-methR methamine

ChH3-CHh-NH-CHa N-mehR ethanamine
otiouy amints
amine in ohichnitAsgen. disscthy
attached to aPkyt 4REuNS..
CH
N,N-dimethyl mathanamina
CH-N-CHs CHs
CHs-CHa-CHo-N-CHa N, N-dimethye poopanaming

He qenexal mula Amines i CnHan+aN

semes CaHuN

CHa-CHa-CHa-CHa-NHa BLtanamine
CHa-CH2-CHa-NH-OH3 N-methul 4epanamina
CHa-CHa-NH-CHaCHa N-ethuethanamino
CHa-CH-CHa=NH2 J=mdhk 1epan-eamine.
CHa

CHa-CHa-N=CH3 N,N-dimehR ¢ihanamihs

Nemencahia. omine
Gemmenm nemehelatune._

LhileUIAiting hocemem namos aminos P

uIRtunit henamo albRgaeupRisues

amine Ag

S3ama tn 4nsaxeattached. to ths

nibuegen atem R aming, hen uLAL te use di , ta

a ic mantieming ealyRgap Mame .

Rdipaunt aye eupaaeattachd t9

nitusgen. atem Amine
M a m L -

aRyRRuns inalphaletical SAdo.

&ampob
CHaNHa math arnine
CaHs NHa thu amina
CHa-NH-CHs dimethu arnina
CHa-CHa-NH-CHa
ethy mthk amuna
CHaCH-CHa-NH2 aRn amina
CHa= CH-NHa Aming

NHa
Anilino

CHa-NHa
BervE amune

TUPACnemencPahuae

LssitiemA ulstikuertsName ulstihents in alphabetical.

stdea yela + seet usetcd+ unsakuaatism amineuth paikien
itien at eg2er NN-

amine mustRe aitten. Jsyapkacing-

e fen haname Aydsuseaaben.

Eomps
CHaNH Methanamine
CaHsNHa thanamine
CHa-NH-CHa N-methR methanamina
CH2CH-CH22-NHa OLep-2-en-l-amine
CHs-CHa-CHa-eHa-N= CHa N,N-dimethye utanamino
CHs
NHa CHa-NHa HN-CHs

Benenamine phon mthanamino N-mdlhyk lensmenamina

N-methyaniline
 CHa-CHa-CH-CHa Butan--amina-
NHa

tuotun amine
eoridiatien niegen inaminBi
aminea nitusgen atem. cemdains 3gend
and LLeme a i n
h e s e n d anglinAmins i uhichis
thanterahedsalkend anglo
dmino8 At. cs usisSsa3es Ligands eaaus
esenee leno pain m niiusgen.Atem.

HC CHs
CHa

pauatiem aminza
HAemnite0smpeunds
Ntto empeunds LanLe odueool teamines
teatinguih ARdueingagent LikeHalNilPAlPdl Sn He
Fe+He2

CaHs- NO Ha/Ni1 Pt IPed CaHs-NHa

Sn+HeRL
NO2
NHa
FeFe+HO

e + He i mest polennocd he LenIMIBÍien-

Kecous2 t h e Fe CRaRamad dueing ien.

canpNEduco Hee n Agsetyaiss ushich
Lan Le sed
Ruothen in
 2 äsuemnitils
Nitoile Reductiem in 2ence2 LA H4 , NaBH44
HaINi Pt Auee m Amine

smines which entaina pUBpuith

Oocta Betemaed duing adien

CHa-C=N. UAe H4, NaBH4 CHa-CHa-NH2

HalPt I Pod INi

CaHs-CEN LARH CoHs-CHa-NHa

layanskengna). (phan methonamina)

inam. amidea

dmidos m Aductien. in sLBRNce LAe Ha NaBH4E

HlNiLPt|Ad MeilA ReAm Aminesz

CHa-CNHa LARH4 CHa-CHo-NHo

-NHa CHa-NHa2
LARH4
O

eoleial phthalimide nthei

hhalimidle n AQOctiem uth alcehelic hoCH
Renmpetnssium. 3alta phthalimidauhich.. Rastien
usih alkR Aalido1si nN-atiAsulstduted. phthalimidu
uhich en duekysisu0 em Amine

N alc. AQH , O CHc

LOH+CH3-NHa Hsd
N-CHa
eOH
O
 aparatien ye amines Joy ihis mathed i
net Secause 0uR halidos
nessilt

5) Hmann &emamide degradatien

mides m seactien 1oith.Bemine in eNCa

Sedum. Aydseocicke. usi2 Kmamines

gn his aaetien. he- amine samLduLhae

caseen atem es Ahan tho paaenkamicle.

CHa-Ë-NHa Baa 2NaoH CHa NHa+ Naa COa

2Hh0 2 NaBa.
NHa NHa
+Baa+ 2NaOH NaaC0a+2Ha0
+2 NaB
dmmemslyeis
mmenia m u0ctiemUith alRAalidesueO
m uimasyamin:3uhichUsD 2actusikh_ Alky?
halides And.a m s miootua 2 3 and4ammer

sats

CHaC HNHa 313 CHa-NA CHSC CHa-ÁCHa

CH3
CHs-NCH3 CQ Hs0CHaN-CH
CHa CH3

mathedL a epaaatisn.

aminss Leeause h eduet CEmtains midune

n
aming& uhich 8eanate y xacticmaldistoloE
uhich Laninexa0sg the 9st qoueductiem-
 Lhysical epeitizs amines
Hethanamina is a ga ethanamine i a lquuid,

LAigher alighaticamin hawing ishy ame22

bsiling psint.
dmines 0 Aaing lgh eiking psin uhen
LCempaxedto hyduecasbems adehydos,Reens and thers
themsalus
Lecaus heyran mhlsegenBendling ameng

dmins 08 hasing- Leus Bsiling eginta uhen

camaad o alcehoesandcaslbeeuic acidls Leeause ha

elactrenagatisihy niegen i s han ugena

sminas ANe Aausngsiling psints han

Cempaned toammenia_Because- hen hydsusgenafsmi.
dinactiy attachedL tethenidegenatem a Pess inha
amines 0 setentRhydssgen sending ialse £u

he oeiling inds aminesdecsease1h incxoa8e

n8:na alkR gasupsdisoctlyatachadte ndxegen atem
atem

hestdar
ho oeting rd imasuy 30cendasy
ectiauy amines And ammenia UsOR Le A Rolleus

Reubilih
dmine& 094 ulke n JUSates Lecause Can

Adoegen. endingAsih ASaton..

itasefubilty Amine8deexea3t8ut inexe0s2 in_

num&ea alkR geuna diackeayatached to ha ndogan a
 Rde , 243
3aminesAnd
ammemiua JuiRRLe
3 < NHs

in SRgonicc 2ewents
sminas Aignay
acdene Sengee CCR4 DMS te.

Ghemiml penenties omines

Ra seasons hemical2 RQadtivrity- a n i n 2 z
leosuenagatisihy Rnisusgen atem
0sence. eno naismnitsgenctem

NAasicnatune
m i n e s Asts fousis ecause 12A032NcQG2ena
pais am nitusgen atem.

Hho asic natuse amines Lan

he eadtiemA amines usith Heo

NHa Hee NH anmonLum chloride

CHaNHa+ He2 CHaNHa+ 0 mefhuk ammonilmt
CoHsNH + Heo CuHNH3 anilinium chlesial

Soasic notio Amins inceasO Lethincxoas Ain

ne CHa aeupbdinctlp attachad ta thonitegen. ahem

min MEAL Lasic in natuee uhon cmpas.a

Ammenio. Leeause +I act

Acsnding JE +I Rtect dho oaic natuaesde

NHa , 2,3aminu is
 CHa
CHa-NHa CHa-NH-CHa S CHa-N-eH3-

Loasic natwue Amino albe dapenda

salsatiem BReet 80l1satiem ARRect daranda en
Le Numlea.
nydoungen. Semda hat Aernpelund toan
tm
sdecending e 2001satienm oct ho asic nau
amines incxases usith Jinenease2 in eatenb ydusgan
ending
he sasio natuwe ndaa NHa,,,3amins
As eISUS Ace e3aloatien ect
CHs
NHs CHa-NHa CHa-`H-CH3 CHa-N-CHa
2

dheSRdeagsasic natuso 2,33aminisand.

ammania akaa ensideaing hageoa in he2030 -

NHa CHa)a N CHa NHa (CHal2 NH

3

he 3 methyR amino Ros8Laaic han 2 and

mth sminsLeeaug8stexio hindance
mathi Bna

öhesadex natuso and s cthe

Amine Jusila

NHa (CaHs) NHa (CaHs)sN < (CaHs) NH

3

3 3 ethye amine 1 asis han ethyR Amina

Lecause h e Llodten aingcapacity sthyeQRBLp_
deminatta h Btosio hindnanc act hye up-
Basio natue aniline VS alkyt amines
miline Aasio uthen empaned te
alki
amines ecaus he lene nais alaotenb mndnegen
atem in Aniline usi0Q nartieipate. ining a@nane duad
e -I Kect engne aung
NHa NH2

MaCempeundausith Ses8phb salues

kasie in natuAe and

ekasie natuze niline nexeaso8 uith nesons2

sloctuensele asing gasup> and deereases usith_ ineanase

eloctenUsithduausing LSups-
NH2 NHa NH2

CH3
O [O
NO2
dAnilina ERG dniline shniline t EllG

) sdeatatiem
ARRRamine- alk Aalideg,Lsie
mhighan Amines

CHa-NH CH3C2) CHa-NH-cHa

NHa
2CHaC CH-N-OH
 Reachem JUith nitusus Acid

diphatie am m eactien. Jsith NaNOa and

HC at 213-218 6 tempewatuna aliphati
diarenium.Anicde salts uhioh au high4 unstalRa

and ARasts Lsilh u9ata Aapeu BRnt he

atmasnhere te oReohoi

CHa NHa NaN02 4+He CHa N H=OH, CHaOH Na + Hz

213-218

smiline. Ratiem.1oith NaNOa And He

l223-2186empexatuneAsieo REAm Bennenediangmium
choenicde hichismae stalkohanalyR diotgniurn 2alt
Aeeause the 3Manco Btalilinatien inBengena. aing
NH2
NaNO2+ HOL
213-278 %
TO
Benene diasgnum chlnide ed inkanadiato
many naaatisna

A Renctien U9ith Hin&leaq A000pt

Benen 2u0pheny shleaido is kneuen a3 in&2

hisig J1ged te distinquish ekueon , 2 and 3'

amine
BumnsuyF amines mA0ctismusih Rinsleag agent
Rem Nmethye Sengene. sulphemamido uhich Lan.

S2aot sith a Laze Lecouse senes Acidic

hydugen. atem
a aAodic hyduogun
Na

-N-CHs S-NCH
 4decemday aming em Octiem uoith kinaktag
usiee mN,N-dimebnyt . Benmene3ulphemamide uhiehtan
Lannet
React uith base Lecause alence AriditAudseen
CHa
CHs N-CH3
C -N-Ha Bae No_e0ctim

Jatiayaminos s0aotJuith inslkng A00gent

LSecause hesois nexopacralRe hydsegen atemm attaohed
nibusgen. atem Aminos

Ha-i-CHa- Ne 2actien-

imasu amings emAeactiemuith chlCAReam in

0seneeA Ale hoHUuIOQ_ iseoyanides

CHaNH2 CHCD3 +3,alc. bOH CHaNC+ 3Hao + a hc2

NH2
NC
CHCa +3 ale. 6DH t3Ha0t3 He_

deuatie.
Rimosu anino RROdtien Usith_ aehalides
en anhydridosuR m N-alke alkanamidlos hoy on
Usith ase eeause 0senco A.oidie-
pegenatem

CH3-cg -N-CHa acidie kuunn

CHa--N-CH3 +HeL_

`ecemdasuy minessmALActiem uith aoue halide

anhydsidas sD AmN,N-dialR alkanamides hy Conhet
cannst
onotuith ase keaauge alsenes Asidic hydsogen
 CHa
CHa-o-t-oHs t H-N- CHa--NCHa CHs-oH

detiass amines nst Aylhalids

anhydicdes ecause alen.ce 0placealtohdusgen
atem dixectly akached tsniksqenatem
CHa
CHa--ee CHa-N-Ha N o _AROdtien

HSlectephilic uLstitutien. actiens

daiedalCaats Aeactiemz
dmiline usi00stundazge3uiodalxagt dylatism.
and Aalatiem ecause iedasCragt' 0agentsdnyduous
AeClaisa tou arid and aniline is a usis Lase
Bcth uith sthea. And ReRm&

NH2 HN-:ARCl
sdnhdl AL.Cl3
O
ulpaenatien
dnilino m Leactiem.sith cmc. HasD4
anilinium uhich en hacting-at 450=410 K
hydasGen._ 3ulphate
Hernpaaatune Lsi0g ndaags dlehydoatien. m
which m eauangemont ui eampaminebemane.sulphenic Acid
NH2 NH3 HS04 NH3 NH
+Conc HS04 -Ha0
O 450-410 K TO
$0sH

Nete
Amine qNEUpin anilineis ing AstiaingQeup.
NHa is anathe-pasa dixodtinggAp
(NH2)
dho ing- actisating Capacity A ani
han- ho aing astusatingcapacity -oH gsup inphanma
Aituatim
miline Aeactiem. usih CMc HNO3 in
19103eNeCa
tassy pidatien duct
Cmc HaSO4 etm

the nitsatien. niline meta nitue oniling

Duxing
allse s Ketmed as ma h eduets Lecause

matienA anilinium. ien Um aniline Roy ccating a

Asten Lem cenc: Haso4 and Anilinium ien A mata-_

disaoting Lu
C41
(7)
NHa NHa NHa NH2
tCemc: HN03 Cemc: Ha804 NO2.
O ND
NO

de et he mens zulstiutbol anilina ue'IR 4stect_

high igh aactingcanaoiy8NHa4Eun
ao halide Actic Anhycoiole Rem ocrtanilide uhich.
Pmaeatinguith cenc HNDa in LRSRNCR cenc. Ha804
andeims pnixoacctanilisdoJhichsn hyseysi
mp-nitseariline

H NH-C-CHa NH-C-CHs NH2

Ceme: HND3 t CH3(mH1

O Cenc HaS04 Hao

onatorulde
NO2 NOa

he high AOOdtingcanarihy NHa euNis asteetucl-

Ayotigm de 9 ho KO3Emanee staliltatism Lekueen -NH
and -& gasura.

HN-C-CH3 HN=C-CHa
Beminatisn
rikine HLAstien Uith aemine in 1OencoA

Rm 2,4,6-tilLeme aniline

NH2 NHa
B
Ha0
OJ
JMeNe-_Rteminawd Leduot

haanilins Lsith AcyR halidla Juhich om actoanieido

urthichAmReating uilhkAminein 03eneo -Hao_

LNR em p-Saemsacetanilida hich hydsekyais

m -Raemaanilin

N-H
CHa--ce
H- NH-C-CHs NHa
Ha0
TO Hs0* O
BL

DianamiAAn JomAUMAN
egoneaal mula diosgmiumcempounds
R.NX
i n hat,R alky Sup X s É, c , B,Í
HBE4 NO2
Whilg itingtho names diangniumA8mpeunds
Ue Sita tho nomo ALRDAALn
Hgaeup Reltsued ayhaLRcdiasgmaum.-
noma X-u

&rample
CHaNac2 Melhydianenium hInida
CaHs N B Et diasgonium ermido
CHsN HSO4 bengeno dianenium.hydagen 2uphate
CaHsNBF bennene diangmium korapustekeata.
 ise dianenium salt o oanam
Man
Eganic Aempeunds

Kkcpakatien diannum sall (Dianptsatien)

Bimasy aik aminog m ineating uGith NaNoa and
NalO2 And
HOc 213-218 K tempenate Rotn alnRdiaspniun
halidssuhichae unstalte 80 usth usith Jatu
Japsua and fenmsalcohols

CHsNHa NaNO2+HCL CHaNa. Ha0 CH3OHtNa t He2

213-218 4

AAAmatic diangnium satka can e anaadlAy adting

ariline 1ih sediumnitite and HCaato-5CJ

m engenadiaggnium.shlsatodo Juthich due

te 0sSmanco

NHa
NaNO2 +He2 NENC
O 0-SC

Phusicos netioe
Nareniuum Rempundla A hiteLUstalina sekids
seui in Usatia. eeause RG hein iene natune and
highyBSuIRein ganie 361senta

hemicol ontiss&
Reastiens inoling optocement diargnilutm gRup
Reptnoemet by , B, CN
0benusen dangmiLurn chlerides AOdiem Msith
AupLEU& chOsMidos , ureus emidz
upsus Ajanides
ui am
hisADXeNugne,bemebenuene euans&anmne
spertiuel
 CuaCRa +Na + Cuacl.

Cuala +Na+ CuB

CN
CuaClo

GÄtsaslenzene and aemskenano Lan

foeaing- Lennene diongmium shIaide h A2pactise
Aadsgen Asidsin o32neo inay dioided. Csppe mutal
Na CL CuL/ HeL
Na + CuLO_

Gul HB Na+ CubaA

Replncerment isdlide ian

enspne dianamium chlsaido en KOactiem uith T

usig iedsienyeno

I Na+ AeL

Replaoenent Ruide ien

Bensgn diasenium chlenide m 0aotiem Lsith
ydgen braguSRD-Berat. etm Rensen. diasnemium tutoo-
Leenate hion neating Joig m LLSRDAenane

NaC HBF4 Na BF
t Na + B E a
Replocam.ent y-OH
diaemium chonida m actienusith.
Benriene J9aoa
aleue283 temporatua JusiALRm phens.

NC 233 %
OH
Nat HCL
Hoo

Repearement H
Aemnene diasemium ohleidePY 00etienusith3aduans
ngents ko HaPOa alechels si en ensgana

NXCL H-O-H
HaPOS HaPOa + Na t HC

Nac
CHa0OH H-C-H+ Na t Hco

Ropkacemart NO
Benngen2 diaggniumchicaide em xactien uih HBF4
usODetm enngenediaenium_ketbuageusaefeat uhich m heating
in NOenee NaNO2Usi0g Am nituekeneng
NO HBF4 NBF NO2
NaNDa +BE3 + Na NaE
-HCL

Reactiemg inetbingtentin. diarss gaaup(Diarp c8upting Raad

Benspna.diangmium chieaido m eaotiem Uoith phnsk
in 03en00 Acidic EAbasic medium usiO
p-Aydsuemydiangterspna

t+ O) Ka o (oNO)>
 Bengene diasenium chlsnide sm HoOctien. uth-arilin2
in acidic Basic madium ULQ REAmp-amins diane Lenspna.

NH HO

Uses
Bennieng diamemium- LhIsaide is Used as An
inkextmaciab e o aatien iedekenren. Ruaekenngne
and epnekensang uhichsannst etopaaas By dcect
ulstitetiem Aeactien.