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In 1897, Joseph Thomson demonstrated the existence of tiny particles much smaller in mass than
hydrogen, the lightest atom. Thomson had discovered the first subatomic particle, the electron
In the late 19th century, physicist J.J. Thomson began experimenting with cathode ray tubes. Cathode ray
tubes are sealed glass tubes from which most of the air has been evacuated. A high voltage is applied
across two electrodes at one end of the tube, which causes a beam of particles to flow from the cathode
(the negatively charged electrode) to the anode (the positively charged electrode). The tubes are called
cathode ray tubes because the particle beam or "cathode ray" originates at the cathode. The ray can be
detected by painting a material known as phosphors onto the far end of the tube beyond the anode. The
phosphors spark, or emit light, when impacted by the cathode ray.
To test the properties of the particles, Thomson placed two oppositely charged electric plates around the
cathode ray. The cathode ray was deflected away from the negatively charged electric plate and towards
the positively charged plate. This indicated that the cathode ray was composed of negatively-charged
particles.
The mass of each particle was much, much smaller than that of any known atom. Thomson repeated his
experiments using different metals as electrode materials, and found that the properties of the cathode
ray remained constant no matter what cathode material they originated from. From this evidence,
Thomson made the following conclusions:
The particles must exist as part of the atom, since the mass of each particle is only 1/20 the mass of a
hydrogen atom.
In 1911, Ernest Rutherford carried out an experiment where he bombarded very thin sheets of gold foil
around 100 atoms thick, with fast moving alpha particles. Alpha particles, a type of natural radioactive
particle, are positively charged particles with a mass about four times that of a hydrogen atom.
Because the vast majority of the alpha particles had passed through the gold, he reasoned that most of
the atom was empty space. In contrast, the particles that were highly deflected must have experienced a
tremendously powerful force within the atom. He concluded that all of the positive charge and the
majority of the mass of the atom must be concentrated in a very small space in the atom's interior,
which he called the nucleus.
The nucleus is the tiny, dense, central core of the atom and is composed of protons. It contains
almost 99% of the mass of an atom.
The Protons were deflected slower than the electrons, therefore were heavier than electrons.
Rutherford's atomic model became known as the nuclear model. In the nuclear atom, the protons and
neutrons, which comprise nearly all of the mass of the atom, are located in the nucleus at the center of
the atom. The electrons are distributed around the nucleus and occupy most of the volume of the atom.
Discovery of neutron
In May 1932, James Chadwick announced that the core also contained a new uncharged particle,
which he called the neutron.
Around 1930, several researchers, including German physicist Walter Bothe and his student Becker had
begun bombarding beryllium with alpha particles from a polonium source (Polonium is a very rare
natural element found in uranium ores) and studying the radiation emitted by the beryllium as a result.
Frédéric and Irène Joliot-Curie had studied the then-unidentified radiation from beryllium as it hit a
paraffin wax target. They found that this radiation knocked loose protons from hydrogen atoms in
that target, and those protons recoiled with very high velocity.
Joliot-Curie believed the radiation hitting the paraffin target must be high-energy gamma photons,
but Chadwick thought otherwise. Photons, having no mass, would not knock loose particles as heavy
as protons from the target, he reasoned. In 1932, he tried similar experiments himself, and became
convinced that the radiation ejected by the beryllium was in fact a neutral particle about the mass of
a proton. He also tried other targets in addition to the paraffin wax, including helium, nitrogen, and
lithium, which helped him determine that the mass of the new particle was just slightly more than
the mass of the proton.
Chadwick also noted that because the neutrons had no charge, they penetrated much further
into a target than protons would.
They also passed straight through the charged plates of a cathode ray tube.
The first emission spectrum of a hydrogen atom is the Balmer series, which was discovered by
scientist Johann Balmer in 1885. He showed that the frequencies of the lines observed in the
visible region of the spectrum of hydrogen fit a simple equation that can be expressed as
follows:
V = constant (1/22−1/n2)