Londhe Chemistry Classes ( LCC)

Time : 00:60:00 TEST ID: 11 CHEMISTRY

Single Correct Answer Type 10. The relative lowering of vapour pressure of a
1. Calculate the molal depression constant of a dilute aqueous solution containing non-
solvent which has freezing point 16.6∘ C and volatile solute is 0.0125. The molality of the
latent heat of fusion 180.75Jg −1 solution is about
a) 2.68 b) 3.86 a) 0.70 b) 0.50
c) 4.68 d) 2.86 c) 0.90 d) 0.80
2. At 24 C the solution of sucrose has O.P.2.5
0 11. Solubility of BaF2 in a solution of Ba(NO3 )2
atm. The strength of solution in gm mol/litre is will be represented by the concentration term
: a) [Ba2+ ] b) [F]
a) 10.25 b) 1.05 c) 1025 d) 0.1025 1
c) [F − ] d) 2[NO− 3]
3. In a solution, the larger proportion of the 2
component is known as ________ 12. The ionisation constant of benzoic acid is
a) Solution b) Solute 6.46 × 10−5 and K sp for silver benzoate is
c) Solvent d) Mixed solution 2.5 × 10−13 . How many times is silver
4. The density of a 3M sodium thiosulphate benzoate more soluble in a buffer of pH 3.19 as
(Na2 S2 O3 ) solution is 1.25 g/mL. Calculate the compared to its solubility in pure water?
per cent by a) 1.5 b) 2.8
a) 12.65% b) 37.92% c) 3.2 d) 2.3
c) 0.87% d) 63.21% 13. NaOH(aq), HCl(aq) and NaCl(aq)
5. Colligative properties are applicable to ________ concentration of each is 10−3 M. Their pH will
solutions be respectively
a) Ideal dilute a) 10,6,2 b) 11,3,7
b) Non-ideal concentrated c) 10,2,6 d) 3,4,7
c) Non-ideal 14. The pK a of HCN is 9.30. The pH of a solution
d) Ideal concentrated prepared by mixing 2.5 moles of KCN and 2.5
6. The sum of mole fractions of A, B and C in an moles of HCN in water and making up the total
aqueous solution containing 0.2 moles of each volume of 500 mL, is
A, B and C is a) 9.30 b) 7.30
a) 0.6 b) 0.2 c) 10.30 d) 8.30
c) 1.0 d) 1.2 15. Then pKa of HCN is 9.30. The pH of a solution
7. In cold countries, ice on frozen roads and prepared by mixing 2.5 moles of KCN and 2.5
footpaths is melted by spraying _________ moles of HCN in water and making up the total
a) NaCl b) CaCl2 volume of 500 mL is
c) Na2 SO4 d) Both (A) and (B) a) 9.30 b) 7.30
8. Which one of the following has the lowest c) 10.30 d) 8.30
vapour pressure at 20 ℃? 16. The pH of neutral water at 25∘ C is 7.0. As the
a) 0.1 M urea solution temperature increases, ionisation of water
b) 0.1 M potassium chloride solution increases, however, the concentration of
c) 0.1 M sodium sulphate solution H + ions and OH− ions are equal. What will be
d) 0.1 M sodium phosphate solution the pH of pure water at 60∘ C ?
9. A mixture has 18 g water and 414 g ethanol. a) Equal to 7.0 b) Greater than 7.0
The mole fraction of water in mixture is c) Less than 7.0 d) Equal to zero
(assume ideal behaviour of the mixture) 17. The pK b for fluoride ion at 25∘ C is 10.83, the
a) 0.1 b) 0.4 c) 0.7 d) 0.9 ionisation constant of hydrofluoric acid at this
temperature is

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 a) 2.72 × 10−5 b) 3.52 × 10−3 26. The values of ∆H and ∆S of a certain reaction
c) 6.76 × 10 −4 d) 5.38 × 10−2 are −400 kJ mol−1 and −20 kJ mol−1 K −1
18. A buffer solution is prepared in which the respectively. The temperature below which
conc. NH3 is 0.30 M and the concentration of the reaction is spontaneous is _________
NH4+ is 0.20 M. If the equilibrium constant, Kb a) 100 K b) 20 ℃ c) 20 K d) 120 ℃
for NH3 equals 18×10−5 , what is the pH of this 27. It is a general principle that the less energy a
solution? system contains, it is ________
a) 8.73 b) 9.08 a) Less stable b) More stable
c) 9.44 d) 11.72 c) Unstable d) More unstable
19. A 100 Ml, 0.1 M solution of ammonium acetate 28. Molar heat capacities of vapour and liquid
is diluted by adding 100 mL of water. The pH state of a substance are 38.07 and 63.17 JK-1
of the resulting solution will be respectively. If the latent heat of vapourisation
(pKs of acetic acid is nearly equal to pKb of is 836.8 kJ mol-1 at 300K, its value at 400K is :
NH4OH) a) 417.18 kJ b) 833.79 kJ
a) 4.9 b) 5.9 c) 83.429 kJ d) 1668.5 kJ
c) 7.0 d) 10.0 29. In actual practice, it is impossible to attain the
20. Three sparingly soluble salt that have same low temperature (absolute zero). This
solubility products are given below. lowering of temperature explains which law of
I. A2 X thermodynamics?
II. AX a) First b) Second c) Third d) Zeroth
III. AX3 30. The ratio of heats liberated at 298 K from the
Their solubilities order in a saturated solution combustion of one kg of coke and by burning
will be water gas obtained from 1 kg of coke is
a) ∥> | >∥ I ∥ b) ∥ l ∣>∥> 1 (Assume coke to be 100% carbon). (Given :
c) ∥ il > | >∥ d) ∥> ||| > | enthalpies of combustion of CO2 , CO and H2
21. 1 L. atm is equal to _________ are 393.5 kJ, 285 kJ, 285 kJ respectively all at
a) 12.2 cal b) 20.2 cal c) 24.2 cal d) 28.2 cal 298 K;
22. An ideal gas expands isothermally and a) 0.79: 1 b) 0.69: 1
reversibly from 10m3 to 20m3 at 300K, c) 0.86: 1 d) 0.96: 1
performing 5.187 kJ of work on surrounding, 31. The intermetallic compound LiAg crystallizes
calculate number of moles of gas used. in cubic lattice in which both lithium and silver
a) 1.5 b) 1 have coordination number of eight. The crystal
c) 3 d) 2 class is ________
23. Relation between CP and CV (in calories) is a) Simple cube
a) CP + CV = 2 b) CV – CP = 2 b) Body centered cube
c) CP – CV = 2 C
d) P = 2 c) Face centered cube
CV
d) None of these
24. In a chemical reaction work is done by the
32. In the face centred unit cell, the points are
system when
present at the
a) number of moles of gaseous reactants is
a) Corners and face centre’s of the unit cell
equal to the number of moles of gaseous
b) Corners of the unit cell
products
c) Face centre’s of the unit cell
b) total number of moles increases
d) Corners and centre of the unit cell
c) number of moles of gaseous substances
33. How many Cs+ ions occupy the second nearest
decreases
neighbour locations of a Cs + ion in the
d) number of moles of gaseous products is
structure CsCl ( 8: 8 coordination)?
greater than the number of moles of gaseous
a) 16 b) 8
reactants
25. One calorie is equal to _________ c) 6 d) 24
a) 0.4184 Joule b) 4.184 Joule 34. A compound is formed by elements A and B.
c) 41.84 Joule d) 418.4 Joule This crystallizes in the cubic structure when
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 atoms A are the corners of the cube and atoms 2. 0.30 0.60 0.40
B are at the centre of the body. The simplest
formula of the compound is _________ 3. 0.60 0.30 0.20
a) AB b) AB2 c) A2 B d) A2 B2 a) Rate = k[A]2 [B] b) Rate = k[A][B]2
35. The number of octahedral sites per sphere in c) Rate = k[A][B] d) Rate = k[A]2 [B]0
fcc structure is 42. Which is a correct integrated rate equation ?
a) 1 b) 2 c) 3 d) 4 k
2.303 a
36. The formula for determination of density of a) k = − log b) 2.303 a−x
t a−x = − log
unit cell is ________ t a
a3 × N0 z×M d) All are integrated
a) g cm−3 b) 3 g cm−3 c) −d(a − x) = kdt
z×M a × N0 rate equations
a3 × M M×N 43. The rate constant is given by the equation k =
c) g cm−3 d) 3 0 g cm−3 −Ea
z × N0 a ×z pze RT . Which factor should register a decrease
37. The density of KBr is 2.75 gm cm−3 . Length of for the reaction to proceed more rapidly?
the unit is 654 pm. K = 39, Br = 80. Then what a) T b) z c) Ea d) p
is TRUE about the predicted nature of the 44. The half-life period of decomposition of a
solid? compound is 50 min. If the initial
a) Solid has face centered cubic system with z concentration is made 4 times, the half-life
=4 period reduces to half, i.e. 25 min. What is the
b) Solid has simple cubic system with z = 4 order of reaction?
c) Solid has face centered cubic system with z a) 0 b) ½
=1 c) 3/2 d) 2
d) Solid has body centered cubic system with z 45. A first order reaction is found to have a rate
=2 constant, k = 4.2 × 10−12 s−1 . Find the half-life
38. In CsCl lattice, the coordination number of Cs+ of the reaction.
ion is ________ a) 1.26 × 1013 s b) 1.65 × 1011 s
a) 2 b) 4 c) 8 d) 12 c) 1.65 × 10−11 s d) 1.26 × 10−13 s
39. Pink colour in non-stoichiometric LiCl is due to 46. Which of the following relation is correct for
_________ zero order reaction?
a) Cl− ions in lattice b) Li+ ions in lattice a) t3/2 = 2 t1/2 b) t3/2 = 1.5 t1/2
c) e− in lattice d) Dissociation 1 1
c) t3/2 = 2 t1/2 d) t3/2 = 3 t1/2
40. Graphite is a
47. A first order reaction takes 100 min for
a) Metallic crystal b) Covalent crystal
c) Ionic crystal d) Molecular crystal completion of 60% of reaction. The time
41. Compounds A and B react according to the required for completion of 90% of the reaction
is
following chemical equation,
A(g) + 2B(g) ⟶ 2C(g) a) 150 min b) 200 min
Concentration of either A or B were changed c) 220.9 min d) 245.6 min
keeping the concentrations of one of the 48. The minimum energy needed to convert a
reactants as constant and rates were measured reactant into product is called
as a function of initial concentration. a) Potential energy b) Kinetic energy
c) Threshold energy d) Activation energy
Following results were obtained. Choose the
correct option for the rate equations for this 49. The rate constant of a reaction is 1.2 × 10−5
reaction. Mol−2 liter 2 s−1 . The order of the reaction is
a) Zero b) 1 c) 2 d) 3
Initial Initial Initial 50. Energy of activation of an exothermic reaction
Concen Concen Rate of
Exper is _______
tration of tration Formation
iment a) Zero b) Negative
[A]/ of [B]/ of [C]/
molL−1 molL−1 molL−1 c) Positive d) Can’t be predicted

1. 0.30 0.30 0.10

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 Londhe Chemistry Classes ( LCC)
Date : TEST ID: 11
Time : 00:60:00 CHEMISTRY
Marks :
1.SOLID STATE,1.THE SOLID STATE,2.SOLUTIONS,2.SOLUTIONS AND COLLIGATIVE PROPERTIES,3.CHEMICAL
THERMODYNAMICS AND ENERGETICS,3.IONIC EQUILIBRIA ,4.CHEMICAL THERMODYNAMICS ,5.CHEMICAL
KINETICS,6.CHEMICAL KINETICS

: ANSWER KEY :
1) b 2) d 3) c 4) b 29) c 30) b 31) b 32) a
5) a 6) c 7) d 8) d 33) c 34) a 35) a 36) b
9) a 10) a 11) c 12) c 37) a 38) c 39) c 40) b
13) b 14) a 15) a 16) c 41) b 42) b 43) c 44) c
17) c 18) c 19) c 20) a 45) b 46) b 47) d 48) c
21) c 22) c 23) c 24) d 49) d 50) c
25) b 26) c 27) b 28) b

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 Londhe Chemistry Classes ( LCC)
Date : TEST ID: 11
Time : 00:60:00 CHEMISTRY
Marks :
1.SOLID STATE,1.THE SOLID STATE,2.SOLUTIONS,2.SOLUTIONS AND COLLIGATIVE PROPERTIES,3.CHEMICAL
THERMODYNAMICS AND ENERGETICS,3.IONIC EQUILIBRIA ,4.CHEMICAL THERMODYNAMICS ,5.CHEMICAL
KINETICS,6.CHEMICAL KINETICS

: HINTS AND SOLUTIONS :

Single Correct Answer Type p° − ps p° − ps wM
= x ⇒ =
1 (b) p° 2
p° mW
R ⋅ Tf2 8.314 × (289.6)2
kf = = = 3.86 wM w 0.0125
1000 × Lf 1000 × 180.75 0.0125 = ⇒ = = 0.00069
mW mW 18
4 (b) w
Molecular weight of Na2 S2 O3 = 158 g mol−1 Hence, molality = × 1000 = 0.00069 × 1000
mW
From, molarity = = 0.69
% by weight of solute × density of solution ×10
M = 0.70
% by weight of Na2 S2 O3 ×1.25×10
3= 11 (c)
158
Ba(NO3 )2 gives NO− 3 and Ba
2+ ions, hence Ba2+
3 × 158
∴ % by weight of Na2 S2 O3 = ion increases. To keep K sp constant, [F −]
1.25 × 10 1
= 37.92% decreases. Thus, it is represented as 2 [F − ].
12 (c)
6 (c) C6 H5 COOAg(s) ⇌ C6 H5 COO− + Ag + ; K 1 = K sp
The sum of mole fractions of all components of a 1
solution is always one. C6 H5 COO− + H + ⇌ C6 H5 COOH; K 2 =
Ka
8 (d) C6 H5 COOAg(s) + H+ ⇌ C6 H5 COOH + Ag + ; K 3
K sp
Solut- Conce- Ionic Total =
ion ntration particles particle Ka
s [C6 H5 COOH][Ag + ] S ⋅ S S2 K sp
K3 = = = =
0.1 M 𝑥 1 𝑥 [H+ ] [H + ] [H + ] Ka
urea where, S is the solubility of C6 H5 COOAg.
0.1 M 𝑥 2 2𝑥 In a buffer of pH = 3.19
KCl
log[H + ] = −3.19 = 4̅. 81
0.1 M 𝑥 3 3𝑥
[H+ ] = antilog 4̅ . 81 = 6.46 × 10−4
Na2 SO4
S2 Ksp Ksp ×[H+ ]
0.1 M 𝑥 4 4𝑥
[H+ ]
= or S2 =
Ka Ka
Na3 PO4
As the number of particles increases, colligative 2.5×10−13 ×6.46×10−4
S=√ 6.46×10−5
properties increases
∴ Vapour pressure decreases S = √2.5 × 10−13 × 10
9 (a) S = 1.6 × 10−6 M (in buffer)
18 gm of water = 1 mole of water In aqueous solution, solubility of C6 H5 COOAg :
414 gm of ethanol = 9 moles of ethanol K sp = [C6 H5 COO− ][Ag + ] = S ⋅ S = S2
Mole fraction of Water = 1+9 =0.1
1 S = √K sp = √2.5 × 10−13 = 5 × 10−7 M

10 (a)

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 S(C6 H5 COOAg) in buffer 1.6 × 10−6 Conc. of NH4+ (salt) = 0.20M
=
S(C6 H5 COOAg) in aqueous solution 5.0 × 10−7 K b = 1.8 × 10−5
= 3.2 [ salt ]
∵ pOH = pK b + log
C6 H5 COOAg is 3.2 times more soluble in buffer [ base ]
than in pure water. 0.20
⇒ 4.74 + log = 4.74 + (0.301 − 0.477)
13 (b) 0.30
= 4.74 − 0.176 = 4.56
NaOH = [OH− ] = 10−3
⇒ pH = 14 − 4.56 = 9.44
[H + ][OH− ] = 10−14
19 (c)
[H + ] = 10−11
Ammonium acetate is a salt of weak acid and
pH = − log[H + ] = − log[10−11 ] = 11
weak base. When solutions are of weak and weak
HCl(aq) = [H + ] = 10−3
base, pH of solution is calculated from the
pH = − log[10−3 ] = 3
following relationship.
NaCl(aq) = Neutral; [H + ] = [OH− ] = 10−7
1 1
i.e . pH = 7 pH = 7 + ( pK a − pK b )
2 2
14 (a) ∵ pK a ≈ pK b (given)
[KCN] 2.5
pH = pK a + log = 9.3 + log = 9.30 ∴ pH of solution = 7
[HCN] 2.5
20 (a)
15 (a) 1
Ksp 3
[salt] S1 = [ ] for A2 Xi
∵ pH = pK a + log 4
[acid] 1
K
sp 4
As [salt] = [acid] S∥l = √K sp for AX; S∥II = [ 27 ] for AX3
∴ pH = pK a = 9.30 ∴ S∥ > S1 > S∥II
16 (c) 21 (c)
With rise in temperature pH decreases, thus, for 1 L. atm = 101.3 J
water pH becomes less than 7 at 60∘ C. 1 cal = 4.18 J
17 (c) 1
F + H2 O ⇌ HF + OH− ∴1J= = 0.239 cal
4.18
[HF][OH− ] 1 L. atm = 0.239 × 101.3 = 24.2 cal
Kb = [F−]
…….(i)
22 (c)
Kw = [H3 O+ ][OH− ]= 10−14 …..(ii)
W = −∫ pext dV
Given, pK b = 10.83
Since, the process is reversible, pext = p, which
Dissociation of HF in water is represented by the
gives
equation,
HF + H2 O ⇌ H3 O+ + F −
[H3 O+][F−] W = − ∫ p ⋅ dV
K= [HF]
….(iii)
K b ⋅ K = [H3 O+ ][OH− ] = K w Substituting the ideal gas equation for p leads to,
Kw
or =K nRT
Kb W = −∫ ⋅ dV
V
Taking log on both sides, we get
Since the process is isothermal,
log K = log K w − log K b V2
W = −nRT ln ( )
V1
= −pK w + log K b
−5.187 × 1000 J
= −14 + 10.83 = −3.17
= −n
20 m3
or K = 6.76 × 10−4 × 8.314 JK −1 mol−1 ln ( )
10 m3
18 (c)
Given, conc. of NH3 (base) = 0.30M

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 5.187 × 1000 5.187 × 1000 H2 = (570 × 83.33)kJ
⇒ n= = mol
8.314 × ln 2 8.314 × 0.6931
∴ Required ratio = H1 : H2 = 393.5: 570
= 3 mol = 0.69: 1

26 (c) 33 (c)
∆H = −400 kJ mol−1 In the structure of CsCl, the 2 nd nearest
∆S = −20 kJ mol−1 K −1 neighbour locations of Cs+ is 6 in number.
Since, both ∆H and ∆S are negative, the reaction
will be spontaneous at lower temperatures 34 (a)
1
The temperature at which change over between Atoms A at the corners of cube; 8 × 8 = 1
spontaneous and non-spontaneous behavior Atoms B at the centre of cube = 1
∆H
occurs is calculated as : T = A : B at the centre of cube = 1
∆S
A:B=1:1
36 (b)
Density of unit cell
∴ T = 20 K z(no. of atoms in unit cell) × M(molecular weight)
= 3 ′ s number)
g cm−
Thus, the given reaction is spontaneous below 20 a (volume of unit cell) × N 0 (Avogadro
K 37 (a)
28 (b) d × N0 × a3
z=
Liquid → Vapour M
CP(vapour) = 38.07 JK-1 mol-1 ∆H1 836.8 kJ 2.75 × 6.022 × 1023 × (6.54 × 10−8 )3
=
CP(liquid) = 63.17 JK-1 mol-1 T1 = 300 K 119
2.75 × 6.022 × 27.97 463.197
T2 = 400 K = = = 3.89 ≅ 4
119 119
∆CP = CP(vapour) - CP(liquid) 41 (b)
= 38.07 – 68.17 = -30.1 J = -30.1 × 10-3 kJ
Exp. [A] [B] Rate of Effect of Eff
∆H2 = ∆H1 + ∆CP (T2 – T1)
Formation [A]
= 836.8 + (-30.1 × 10-3) (400 - 300) Initial Initial [A
of [C]
= 836.8 – 30.1 × 10-3 × 10-2 on [C]
Initial
= 836.8 – 30.1 = 833.79 kJ (mol 𝐋−𝟏 ) (mol𝐋−𝟏 )
(mol 𝐋−𝟏 )
30 (b)
1000
Number of moles in 1 kg coke = = 83.33 mol 1. 0.30 0.30 0.10 No No
12
For the combustion of 1 kg of coke effect eff

C + O2 ⟶ CO2 ; ΔH = 393.5 kJ 2. 0.30 0.60 0.40 No On

effect do
⇒ heat liberated from 1 mole of coke = 393.5 kJ [B]
be
∴ heat liberated from 83.33 mole of coke
4t
H1 = (393.5 × 83.33)kJ tha
tha
Also, for the burning of water gas [C]

C + H2 O ⟶ ⏟
CO + H2 3. 0.60 0.30 0.20 On
Water gas doubling e
the
CO + H2 + O2 ⟶ CO2 + H2 O,
[A],[C]
ΔH = 285 + 285 = 570 kJ becomes
2[C]
∴ Ratio of heat liberated from burning of water
gas obtained from 1 mole of coke

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 The above table suggests that the rate law 0.693 0.693
t1/2 = =
expression would be k 4.2 × 10−12 s−1

Rate = k [A] [B]2 = 1.65 × 1011 s

42 (b) 46 (b)
X X t½
For first order reaction, t½ = 2 ; =
4 2

2.303 a 2.303 a−x ∴ t¼ = t½ + t½ = 1.5 t½

k= log =− log 47 (d)
t a−x t a 2.303 C
For the order reaction, k = log C0
t
43 (c) t
Case I :
For the reaction to proceed more rapidly, k should
C0 = 100 M, Ct = 100 – 60 = 40, t = 100 min
increase which can be brought about by decreases
2.303 100
in Ea k = × log
100 40
44 (c) 2.303 × 0.3979
We know that, t1/2 ∝ C1−n (where, n is the order k = ……...…I
100
of reaction)
Case II :
(t1/2 )
1 C1 1−n C0 = 100 M, Ct = 100 – 90 = 10 M
=( )
(t1/2 ) C2 2.303 100
2 t = log
k 10
2.303
50 C 1−n 1 1−n = k …….. Substituting K from I
=( ) or 2 = ( )
25 4C 4 2.303 × 100
= = 245.6 min
2.303 × 0.3979
2 = (2)2n−2 or 2n − 2 = 1 49 (d)
dx
n = 3/2 = k
dt[C]
1
3
Hence, the order of reaction = 2. Order of reaction = Cn − 1 = C1 − n
50 (c)
45 (b) Energy of activation is always positive
For first order reaction,

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