Chemical Kinetics

AtoZ CHEMISTRY CHEMICAL KINETICS
Chemical Kinetics
  Br −   H+    Br −   H+ 
(A)   = 5   (B)   = 6  
1. Introduction, Rate of Reaction t t t 5 t
Q 1. Kinetics depends on 
 Br −
 
 H+    −
 +
(A) Intermediate steps through which (C)   = 5   (D)   Br  = 6   H 
t 6 t t t
reactions happen
dC dn
(B) Initial & Final species of the reaction Q 6. Which is correct relation in between ,
(C) Stability of products dt dt
(D) Stability of reactant P
and where C, n, P, represents concentration,
Q 2. In the reaction; A + 2B → 3C + D which of dt
the following expressions does not describe mole and pressure terms for gaseous phase
changes in the concentration of various species reactant A ( g ) → product
are a function of time. [CBSE PMT 2006]
dC 1 dn 1 dP
d  C −3d  A  3d  D d  C (A) − =− =−
(A) = (B) = dt V dt RT dt
dt dt dt dt dC dn dP
3d  B −2d  C 2d  B d  A  (B) = =−
(C) = (D) = dt dt dt
dt dt dt dt dC RT dn dP
Q 3. For the reaction (C) = =−
dt V dt dt
d A
2A + B → C + D, − = k  A   B (D) All
2
dt 1
Q 7. For the reaction, N 2O5 → 2NO 2 + O2
− d  B 2
The expression for will be
dt d  N 2O5 
Given − = K1  N 2O5  ,
1
K  A   B (B) K  A   B dt
2 2
(A)
2 d  NO2  d  O2 
= K 2  N 2 O5  , = K 3  N 2O 5 
K  A   2B (D) K  2A   B
2 2
(C) dt dt
Q 4. The rate of a reaction is expressed in different The relation between K1,K 2 and K 3 is
ways as follows 2K1 = K 2 = 4K 3
(A)
1 d  C 1 d  D 1 d  A d  B
+ =− =+ =− (B) K1 = K 2 = K3
2 dt 3 dt 4 dt dt
The reaction is (C) 2K1 = 4K 2 = K 3
(A) 4A + B → 2C + 3D (D) None
(B) B + 3D → 4A + 2C Q 8. The instantaneous rate of disappearance of the
(C) A+B→C+D MnO −4 ion in the reaction is 4.56 10−3 Ms −1
(D) B+ D → A + C 2MnO −4 + 10I − + 16H + → 2Mn 2+ + 5I 2 + 8H 2O
Q 5. Which of the following expressions is correct
The rate of appearance of I 2 is
for the rate of reaction given below?
[NCERT EXAMPLAR] (A) 1.14  10−3 Ms −1 (B) 5.7 10−3 Ms −1
5Br − + BrO3− + 6H + → 3Br2 + 3H 2O (C) 4.56 10−4 Ms −1 (D) 1.14  10−2 Ms −1
Q 9. If Ammonia is treated with O2 at elevated
temperatures, the rate of disappearance of
ammonia is found to be 3.5 10−2 mol.L-1.S-1
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during a measured time interval. Calculate the (A) 0.1Msec−1 (B) 0.04Msec−1
rate of appearance of water for the reaction −1 −1
(C) 0.02Msec (D) 0.2Msec
NH3 + O2 → H 2O + N 2O in mol/lit.sec
Q 15. Consider the graph given in figure.
(A) 13.5  10−2 (B) 5.25 10−2 [NCERT EXAMPLAR]
(C) 1.7  10 −2 (D) 1.1 10 −2
V5
Q 10. Rate of formation of SO3 in the following
V4
−1
reaction 2SO2 + O2 → 2SO3 is 100g min .
V3
Hence rate of disappearance of O2 is
(A) 50g/min (B) 40 g/min V2
(C) 200 g/min (D) 20 g/min V1
Q 11. For the reaction
N2 ( g ) + 3H2 ( g ) → 2NH3 ( g ) under certain
conditions of temperature and partial pressure O 20 30 40 50
of the reactant the rate of formation of NH3 is Which of the following is correct option?
V3 − V2
0.001 kg h −1 . Calculate the rate of conversion (A) Avg. rate upto 40 sec is
40
of H 2 under the same conditions?
V − V2
(A) 0.00015 kg/hr (B) 0.001 kg/hr (B) Avg. rate upto 40 sec is 3
40 − 30
(C) 0.00017 kg/hr (D) None of these
Q 12. Unit of rate is V
(C) Avg. rate upto 40 sec is 3
(A) mol lit −1 sec (B) atm sec
−1 40
V − V1
(C) kg / sec (D) All of these (D) Avg. rate upto 40 sec is 3
40 − 20
Q 13. A reaction follows the given concentration
Q 16. Which of the following options does not show
(M)= time graph. The rate for this reaction at 20
instantaneous rate of reaction at 40s?
seconds will be
0.5 V5 − V2 V4 − V2
(A) (B)
0.4
50 − 30 50 − 30
0.3
0.2 V3 − V2 V3 − V1
(C) (D)
0.1
40 − 30 40 − 20
0 20 40 60 80 100 Q 17. The decomposition of N2O5 in CCl4 at 318K has
Time /second
been studied by monitoring the concentration of
(A) 4 10−3 Ms −1 (B) 8 10−2 Ms −1 N2O5 in the solution. Initially the concentration
(C) 2 10−2 Ms −1 (D) 7 10−3 Ms −1 of N2O5 is 2.33 mol.L-1 and after 184 minutes, it
Q 14. For the reaction 2NO2 → 2NO + O2 , the is reduced to 2.08 mol.L-1. The reaction takes
place according to the equation;
constant of ‘NO’ changes with time as follows.
Find the rate of reaction at t= 10 sec 2N2O5 ( g ) → 4NO2 ( g ) + O2 ( g )
[NO] Calculate the average rate of this reaction in
1.2M terms of hours, minutes and seconds. What is
1M the rate of production of NO 2 during this
5 10 15 10 t(sec)
period? [NCERT Solved]

2. Differential Rate Law,

Integrated rate laws for nth order Reaction (A) K  A B (B) K  A
Q 1. Order of a chemical reaction can have
K A K  B
2
(A) –ve values (B) +ve values (C) (D)
(C) Zero values (D) All of these Q 7. For the given reaction, A + B→ Products
Q 2. The value of Rate constant can be The order is 1 w.r.t each of A and B. Value of X
(A) –ve values (B) +ve values and Y in the given data is.
(C) Zero values (D) All of these
Q 3. Calculate the overall order of a reaction which Initial conc. Initial conc. Initial rate
has the rate expression [NCERT Solved] (m/L) (m/L) [moll–1 s–1]
Rate = k  A   B
1/ 2 3/ 2
(A) [A] [B]
0.20 0.05 0.10
Rate = k  A   B
3/ 2 −1
(B) x 0.05 0.40
Q 4. Select the rate law that corresponds to the data 0.40 Y 0.80
shown for the following reaction A + B → C (A) 0.20, 0.80 (B) 0.80, 0.40
Expt. No. [A0] [B0] Initial rate (C) 0.80, 0.20 (D) 0.40, 0.20
1 0.012 0.035 0.10 Q 8. The rate of a reaction A + 2B → 3C , get
2 0.024 0.070 0.80 increased by 72 times when [A] was tripled &
3 0.024 0.035 0.10 that of B is doubled. The order of the reaction
4 0.012 0.070 0.80 with respect to A & B are respectively
(A) rate = k  B (B) rate = k  B (A) 1,2 (B) 2,3
3 4
(C) 3,2 (D) 2,2

(C) rate = k  A  B (D) rate = k  A   B
3 2 2
Q 9. For a simple reaction
Q 5. For the reaction [NCERT EXAMPLAR] 2NO ( g ) + O2 ( g ) → 2NO2 ( g )
A ( g ) + 2B( g ) → 2C ( g ) If volume of vessel is suddenly halved then
Following data were obtained experimentally. (A) Rate of reaction will decrease to 1/4th
ExP. [A]0 [B]0 d[C]/dt of its initial value
Mol.L–1 Mol.L–1 mol.L–1s–1 (B) Rate of reaction will decrease to 1/8th
1. 0.30 0.30 0.10 of its initial value
2. 0.30 0.60 0.40 (C) Rate of reaction will increase four times
3. 0.60 0.30 0.20 to its initial value
Choose the correct option for the rate equations (D) Rate of reaction will increase 8 times to
its initial value
for this reaction
Q 10. For the reaction A + B → Products
(A) Rate = k  K   B (B) Rate = k  A  B
2 2
Initial conc. Initial conc. Initial rate
(C) Rate = k  A B (D) Rate = k  A   B [moll–1 s–1]
2 0
(m/L) (m/L)
[A] [B]
Q 6. For the given reaction, A + B→ Products 0.10 0.10 5 10−2
Following data were given [IIT-JEE 2004] 0.20 0.01 7  10 −2
Initial conc. Initial conc. Initial rate
(m/L) (m/L) [ml–1 s–1]
0.10 0.02 8.67 10−2
[A] [B] The rate expression is
K  A   B (B) K  A   B
2 1 1/ 2 3/ 2
0.1 0.1 0.05 (A)
0.2 0.1 0.1
K A  B
1/ 2 1/ 2
0.1 0.2 0.05 (C) (D) None of these

Q 11. In a reaction A + B → products, rate is douled Graph between log(rate) against log[A0] is of
when concentration of B is doubled and rate the type
P
increases by a factor of 8 when concentration of Q
both the reactant A & B are doubled. Rate law log R
(rate)
for the reaction can be written as S
[CBSE PMT 2012/JEE Main 2019]
The rate expression is log [A0 ]
(A) Rate = K  A   B (B) Rate = K  A   B

1 2 2 2 Lines P,Q,R,S are for the order
P Q R S
(C) Rate = K  A B (D) Rate = K  A   B
2
(A) 0 1 2 3
Q 12. When the mechanism of reaction is not known, (B) 3 2 1 0
one often attampts to fit the data with an n th (C) 1 2 3 0
order rate equation of the form (D) 0 3 2 1
dC A Q 15. Time required to decompose half of the
− rA = − = kC nA substance for nth order reaction is inversely
dt
For n  1 , the integration of this equation proportional to
yields (A) a n +1 (B) a n −1 (C) a n −2 (D) a n
(A) C1A+n − C1A+0n = (1 + n ) kt Q 16. The pressure of NH3 vs half life of its
C1A−n − C1A−0n = (1 − n ) kt
decomposition reactions are given
(B)
(C) C1A−n − C1A−0n = ( n −1) kt P (mm) 50 100 200
(D) C1A−n − C1A−0n = kt / ( n −1) t1/2 ( min ) 3.64 1.82 0.91
Q 13. Given that for a reaction of order n the The order w.r.t. NH3 is
integrated form of the rate equation is (A) 0 (B) 1 (C) 2 (D) 3
1  1 1  Q 17. What will be the order of reaction for a
k=  n −1 − n −1  where C0 and C
t ( n − 1)  C C0  chemical change having log t1/ 2 vs log a ?
are the values of the reactant concentration at (Where a = initial concentration of reactant;
the start and after time t. What is the t1/ 2 = half − life )
relationship between t 3/ 4 and t1/ 2 where t 3/ 4
1 log tt/2 45°
is the time required for C to become C0
4
(A) t 3/ 4 = t1/ 2  2n −1 + 1
log a
(B) t 3/ 4 = t1/ 2  2n −1 − 1 (A) Zero order (B) First order
(C) Second order (D) None of these
(C) t 3/ 4 = t1/ 2  2n +1 − 1
Q 18. For the reaction: 2A + B2 + C → A 2B + BC ,
(D) t 3/ 4 = t1/ 2  2n +1 + 1 the rate law expression has been determined
experimentally to be R = k  A   C  with,
2
Q 14. For nth order reaction. [AIIMS 2016]
 dx 
  = Rate = k  A 0
n
k = 3.0 10−4 M −2 min −1 . Determine the initial
 dt  rate (Mmin-1)of the reaction, started with

concentration [A] =0.1 M, Q 3. If ‘a’ is the initial concentration of a substance

B2  = 0.35M & C = 0.25M which reacts according to zero order kinetics
and K is rate constant, the time for the reaction
(A) 7.5 10−7 (B) 3 10−4 to go to completion is
−3
(C) 2.5 10 (D) 6 10−7 a 2 K 2K
Q 19. The rate expression for the reaction (A) (B) (C) (D)
K Ka a a
A ( g ) + B ( g ) → C ( g ) is rate = KC A 2C1/B 2 . Q 4. The decomposition of NH3 on platinum
What changes in the initial concentration of A surface is zero order reaction. What are the rates
and B will cause the rate of reaction increase by of production of N 2 and H 2 if
a factor of eight
(A) CA  2;CB  2 (B) CA  2;CB  4 k = 2.5  10−4 mol−1 L s −1 ? [NCERT]
Q 5.
(C) CA 1;CB  4 (D) CA  4;CB 1 The rate constant of a zero order reaction is 0.2
Q 20. For the irreversible process, A + B → moldm −3 h −1 . If the concentration of the
products, the rate is first –order with respect to reactant after 30 minutes is 0.05 mol dm −3 .
A and second –order with respect to B. If 1.0 Then its initial concentration would be
mol each of A and B introduced into a 1.0 L (A) 6.05 mol/lit (B) 0.15 mol/lit
vessel, and the initial rate was (C) 0.25 mol/lit (D) 4.00 mol/lit
1.0 10−2 mol L−1S−1 , rate when half reactants Q 6. For the zero order reaction A → B + C ;
have been turned into products is concentration of A is 0.1 M. If A = 0.08M
(A) 1.25 10−3 mol L−1s −1 after 10 minutes, then it’s half – life and
completion time (in minute) are respectively
(B) 1.0 10−2 mol L−1s −1 (A) 10 , 20 (B) 2 10−3 , 500
(C) 2.50 10−3 mol L−1s −1 (C) 25 , 50 (D) 250 , 500
(D) 2.0 10−2 mol L−1s −1 Q 7. For a general reaction A → B , plot of
concentration of A vs time is given in figure.
Q 21. For the reaction: 2A + B → A 2B [NCERT] Answer the following questions on the basis of
The rate = k  A  B ; k = 2.0 10 −6 M-2S–1 .
2
this graph. [NCERT EXAMPLAR]
Calculate the initial rate of the reaction when A B
Conc. of A
[A] = 0.1 M & [B] = 0.2 M. Also Calculate the

rate after [A] is reduced to 0.06 M.
Time (t)
(i) What is the order of the reaction ?
(ii) What is the slope of the curve ?
3. Zeroth & First Order Reaction (iii) What are the units of rate constant ?
Q 1. Identify the reaction order from each of the 5
following rate constants [NCERT Solved] Q 8. For the reaction A → product, given that the
2
(i) −5
k = 2.3 10 L mol −1s −1
A
0
−4 −1 rate law is rate = k , find t1/ 2 of the
(ii) k = 3 10 s
Q 2. If for any reaction, the rate constant is equal to reaction.
the rate of the reaction at all concentration. The  A 2  A 0 k
(A) (B)
order is 2k 5/ 2
(A) 0 (B) 2 (C) 1 (D) 3

 A 0 Q 15. 99% of a first order reaction was completed in

(C) (D) None of these 32 minutes when 99.9% of the reaction will
5k
complete
Q 9. H 2 + Cl2 ⎯⎯⎯→
sunlight
2 HCl (A) 50 min (B) 46 min
In the above reaction, the order of reaction is (C) 48 min (D) 49 min
(A) 3 (B) 2 (C) 0 (D) 1 Q 16. The reaction A → B follows first order kinetics.
Q 10. The concentration of R in the reaction R → P The time taken for 0.8 mole of A to produce 0.6
was measured as a function of time and the mole of B is 1 hr. what is the time taken for
following data is obtained. [JEE Adv. 2010] conversion of 0.9 mole of A to 0.675 mole of
[R] 1.0 0.75 0.40 0.10 B? [CBSE PMT 2003]
T(min.) 0.0 0.05 0.12 0.18 (A) 0.25 hr (B) 2 hr
(C) 1 hr (D) 0.5 hr
(A) 0 (B) 1 (C) 2 (D) 3 Q 17. For a given reaction of first order, it takes 20
Q 11. Let decomposition of Cl2O7 ( g ) into minutes for the concentration to drop from 1.0
M to 0.6 M. The time required for the
ClO2 ( g ) &O2 ( g ) be a zero order reaction. If concentration to drop from 0.6 M to 0.36 M will
−d  Cl2O7  be
at a particular time = 50 mm of (A) more than 20 minutes
dt
(B) less than 20 minutes
Hg/sec. for the decomposition reaction having
(C) equal to 20 minutes
initial pressure of Cl2O7 = 600mm of Hg. (D) infinity
(A) Calculate rate of production of O2 at t Q 18. The initial concentration of N 2O5 in the
= 2sec following first order reaction
1
(B) Calculate t1/ 2 for reaction of Cl2O 7
N 2O5 ( g ) → 2NO 2 ( g ) + O 2 ( g ) was
(C) Calculate rate of reaction 2
2Cl2O7 → 4ClO2 + 3O2 at this time 1.24 10−2 mol L−1 at 318 K. The concentration
(D) What is the total pressure after 10 sec of N 2 O5 after 60 minutes was
initially ClO2 and O2 were absent ? 0.20 10−2 molL−1 . Calculate the rate constant
Q 12. The rate constant for a first order reaction is 60 of the reaction at 318 K. [NCERT Solved]
S-1. How much time will it take to reduce the
Q 19. Rate constant of a reaction is 0.0693min −1 .
initial concentration of the reactant to its 1/16th Starting with 10 mol, rate of the reaction after
value ? [NCERT] 10 min is:
Q 13. Thermal decomposition of a compound is of
(A) 0.693M min −1
first order. If 50% sample of the compound is
decomposed in 120 minute, how long will it (B) 0.0693  2M min −1
take for 90% of the compound to decompose? (C) 0.0693  5M min −1
(A) 6.6 hours (B) 200 min
(C) 540 min (D) 6 hours (D) 0.0693  25M min −1
Q 14. A first order reaction is 50% completed in Q 20. Rate constant k = 2.303min −1 for a particular
1.26  1014 s . How much time would it take for reaction. The initial concentration of the raction
100% completion? [NCERT EXAMPLAR] is 1 mol/litre then, rate of reaction after 1
(A) 1.26  1015 s (B) 2.52  1014 s minute is
−1
(C) 2.52 1028 s (D) Infinite (A) 2.303M min (B) 0.2303M min −1

−1 change in concentration of reactants and

(C) 0.1 M min (D) None of these
products with time? [NCERT EXAMPLAR]
Q 21. Two first order reaction have half – lives in the
ratio 8 :1 . Calculate the ratio of the intervals [B]
Concentration
Concentration
[B]
t1 : t 2 . The t1 and t 2 are the time period for
th th [A] [A]
1 st 3
  completion of 1 reaction and   (A) Time (B) Time
4 4
nd [B]
2 reaction completion respectively
Concentration
Concentration
[A]
(A) 1: 0.301 (B) 0.125: 0.602
(C) 1 : 0.602 (D) None of these [A] [B]
Q 22. t1/4 can be taken as the time taken for the conc. (C) Time (D) Time
of a reactant to drop to ¾ of its initial value. If
rate constant for a 1st order reaction is K, then
t1/4 is written as [JEE Main 2005/AIIMS 2011]
(A) 0.75/K (B) 0.69/K
(C) 0.29/K (D) 0.10/K
Q 23. Which of the following curves represents a Ist 4. First Order & Second Order Reaction
order reaction Q 1. In first order reaction, log K vs t is a straight
line with slope …..
t1/2 t1/2 −K
(A) –K (B)
2.303
(A) a (B) a K −K
(C) − (D)
R 2.303R
t1/2 t1/2
Q 2. In the 1st order reaction
Rate: K1PA & Rate = K 2 .CA
(C) a2 (D) a3
Q 24. A graph between t1/ 2 and conc. For n th order (A) K1  K 2 (B) K1  K 2
reaction is a straight line. Reaction of this nature (C) K1 = K 2 (D) None of these
is completed 50% in 10 minutes when conc. Is 2 Q 3. In the 2 nd
order reaction
mol L−1 . This is decomposed 50% in t minutes Rate = K1PA2 , Rate = K 2C A2
at 4 mol L−1 n and t are respectively
K P = K 2RT (B) K1 = K 2 ( RT )
2
(A)
K 2 = K1.RT (D) K 2 = K1 ( RT )
2
(C)
t
Q 4. Find the time duration in which concentration of
a substance producing by first order kinetics
Fig. conc. increases to 10 times of its value, if rate
(A) 0, 20 min (B) 1, 10 min constant is 2.303min −1
(C) 1, 20 min (D) 0, 5 min (A) 1 min (B) 10 min
(C) 2.303 min (D) 0.693 min
Q 25. Consider the reaction. A → B . The
Q 5. Double life of first order production is
concentration of both the reactants and the
(A) (0.693)K (B) 0.693/K
products varies exponentially with time. Which
(C) 2.303/K (D) 2.303.K
of the following figures correctly describes the
Q 6. Avg life of a first order reaction is

1 1 5  10−2 M −1hr −1 then the time duration in

(A) (B)
K t1/ 2 which [B] increases from 1.0 M to 5.0 M is
( 0.693).t1/ 2 ( 0.693) .k
(A) 16 min (B) 8 min
(C) (D)
(C) 32 min (D) None of these
dA Q 13. For the reaction A → products
Q 7. In the reaction, A → Products, − = K1 A
dt time 0 5sec 10sec 12sec
If we start with 10 M of A, then after one
natural life time, concentration of A is
 A 1.0 0.6M 0.2M 0.04
decreased to [AIIMS 2016] The order of reaction is
(A) 5M (B) 2.5 M (A) 0 (B) 1
(C) 2 (D) None of these
10 10
(C) M (D) M Q 14. For the reaction A → Products
e e2
t(min.) 0 10 20 40
Q 8. For the 2nd order reaction
[A] 0.020 0.0176 0.0156 0.0122
1 1
Kt = − The order of reaction is
 A   A 0 (A) 0 (B) 1
The ratio of t 3/ 4 & t1/ 2 is equal to
Q 15. For the reaction A → Products
(A) 0.2 (B) 2 t(min.) 0 10 20 40
(C) 3 (D) 5 [A] 0.20 0.15 0.12 0.0866
Q 9. For the decomposition of NOCl(g) The order of reaction is
2NOCl ( g ) → NO ( g ) + Cl2 ( g ) ; (A) 0 (B) 1
K = 0.81M −1S−1 If  NOCl0 = 4 10−3 M then
time required for  NOCl to be….

1.50 10−3 M
(A) 185.2sec (B) 92.6 sec
(C) 46.3 sec (D) None of these 5. Pseudo Order Reaction, Pressure Change
Method, Volume Change Method
Q 10. For the reaction 2NO2 → N2O4
Q 1. The rate law of the reaction A + 2B → product
−d  NO2  d  P
= ( 8 10−4 )  NO
2
= K  A   B . If A is taken in
2
dt is given by
dt
If initial concentration of NO is 0.15M then half
large excess, the order of the reaction will be
life of the reaction is
(A)Zero (B)1 (C)2 (D)3
(A) 8.34  103 sec (B) 1.67  10 4 sec Q 2. The value of rate constant of a pseudo first
(C) 8.34  10 4 sec (D) 1.67 103 sec order reaction [NCERT EXAMPLAR]
Q 11. For the reaction 2A → products : (A) depends on the concentration of
K = 2 10−1 M −1 min −1 reactants present in small amount
The time duration in which [A] decreases from (B) depends on the concentration of
5.0 M to 0.5 M reactants present in excess
(A) 9 min (B) 4.5 min (C) is independent of the conc. of reactants
(C) 5 min (D) 18 min (D) depends only on temperature
Q 12. If production of ‘B’ follows 2nd order kinetics Q 3. For the reaction A + B → Products
Rate = K  A   B
1 1
w.r.t B with rate constant of production of B is

If  A0 = 0.5M &  B0 = 0.0001M then new Q 9. In a pseudo first order hydrolysis of ester in
water, the following results were obtained:
rate constant of the pseudo order reaction is
t/s 0 30 60 90
(A) 10 −4 K (B) 0.5K [Ester] 0.55 0.31 0.17 0.085
(C) 5K (D) 10 4.K (i) Calculate the average rate of reaction
Q 4. In above reaction, time required for between the time interval 30 to 60 seconds
 B = 10−5 M is (ii) Calculate the pseudo first order rate
constant for hydrolysis of ester. [NCERT]
2.303 23.03 Q 10. The decomposition of azo methane, at certain
(A) (B)
K K temperature according to the equation
(C)
4.606
(D) None of these ( CH3 )2 N2 → C2H6 N2 is a first order
K reaction. After 40 minutes from the start, the
Q 5. For the reaction 2C + D → Pr oducts total pressure developed is found to be 350 mm
Rate = K  C  D  where K = 0.5M −2 min −1
2 1
Hg in place of initial pressure 200 mm Hg of
azo methane. The value of rate constant k is
If C0 = 0.01M & D = 5.0M then find the
(A) 2.88 10−4 s −1 (B) 1.25  10 −4 S−1
time duration in which C = 0.001M (C) 5.77 10−4 s −1 (D) None of these
(A) 180 min (B) 360 min Q 11. The following data were obtained during the
(C) 900 min (D) 1800 min first order thermal decomposition of N2O5 ( g )
Q 6. In above questions if
at constant volume [NCERT Solved]
C = 2.0M & D = 0.05M then the time 2N2O5 ( g ) → 2N2O4 ( g ) + O2 ( g )
duration in which  D = 0.02M is S. NO. Time/s P Total (atm)
(A) 1.8424 min (B) 0.9212 min 1. 0 0.5
(C) 3.6848 min (D) None of these 2. 100 0.512
Q 7. Example of pseudo 1st order reaction is Calculate the rate constant
(A) Basic hydrolysis of ester Q 12. The decomposition of a gaseous substance A to
(B) Basic hydrolysis of ester yield gaseous product,
(C) In version of cane sugar A ( g ) → 2B( g ) + C ( g ) follows first order
(D) Decomposition of H 2O 2 kinetics. If the total pressure at the start of an
Q 8. Hydrolysis of methyl acetate in aqueous experiment & 9 minutes after the start are 100
solution has been studied by titrating the mm and 150 mm, what is the rate constant ?
liberated acetic acid against sodium hydroxide. (A) 0.06804 min −1 (B) 0.032 min −1
The concentration of the ester at different times (C) 0.04536 min −1 (D) 0.3780 min −1
is given below. Q 13. For a first order homogeneous gaseous reaction,
t/min 0 30 60 90 A → 2B + C then initial pressure was P while
[C] 0.8500 0.8004 0.7538 0.7096
Show that it follows a pseudo first order total pressure after time ‘t’ was P1 . The write
reaction, as the concentration of water remains expression for the rate constant k in terms of
nearly constant(55.55M), during the course of Pi , Pi and t is
the reaction. What is the value of k’ in this
2.303  2Pi 
equation? [NCERT Solved] (A) k= log  
Rate = k 'CH3COOCH3  H2O t  3Pi − Pt 

2.303  2Pi  evolved. The first order rate constant

k=
(B)
t
log  
 3Pt − Pi 
( in min ) for the disappearance of N O
−1
2 5 is
2.303 2.303 100
2.303  Pi  (A) (B) log
(C) k= log   500 500 90
t  Pi − Pt  2.303 90 100
(D) None of these (C) log (D)
500 100 10  500
Q 14. Consider a first order gas phase decomposition
Q 17. The half – life of first order decomposition of
reaction given below [NCERT EXAMPLAR]
NH 4 NO2 is 2.10 hr at 288 K temperature
A ( g ) → B( g ) + C ( g )
The initial pressure of the system before NH4 NO2 ( aq ) → N2 ( g ) + 2H2O ( ) , if 6.4g
decomposition of A was p i . After lapse of time of NH 4 NO2 is allowed to decompose, The
‘t’ total pressure of the system increased by x time required for NH 4 NO2 to decompose 90%
units and became 'p t ' . The rate constant k for
and the volume of dry N 2 produced at this
the reaction is given as
point measured at NTP are respectively
2.303 p
(A) k= log i (A) 6.978 hr, 2.016 L (B) 0.319 hr, 2.12 L
t pi − x (C) 0.319 hr, 2.016 L (D) None of these
2.303 pi
(B) k= log
t 2pi − p t
2.303 pi
(C) k= log
t 2pi + p t
2.303 p 6. Parallel 1st order Reaction
(D) k= log i Q 1. A substance undergoes first order
t pi + x
decomposition. The decomposition follows two
Q 15. The following data represent for the K1 B
decomposition of NH 4 NO2 in aqueous A
solution K2
parallel first order reaction as C
T(min.) 10 15 20 25  k1 = 1.26 10 sec and k 2 = 3.6 10−5 sec −1

−4 −1
VN 2 (ml) 6.25 9.0 11.40 13.65 33.05 . Calculate the % distribution of B & C.
Calculate velocity constant (A) 23.2, 76.8 (B) 77.7, 22.3
(C) 66.5, 33.5 (D) 80.20
(A) 2 10−2 min −1 (B) 3  10 −2 min −1
Q 2. A substance undergoes first order
(C) 4 10−3 min −1 (D) 2 10−3 min −1 decomposition. The decomposition follows two
Q 16. The decomposition of N 2O5 in chloroform was parallel first order reactions as
K1 B
followed by measuring the volume of O2 gas
A
evolved 2N2O5 → 2N2O4 + O2 ( g ) . The K2
C
maximum volume of O2 gas obtained was The percentage distributions of B and C are
76.83% B and 23.17% C If k1 = 1.26 10 −4 s −1
100cm3 . In 500 minutes, 90cm3 of O2 were
then find the value of k 2
The percentage distributions of B and C are
(A) 3.8  10 −6 s −1 (B) 3.9  10 −5 s −1 Q 7. A certain organic compound A decompose by

(C) 3.8  10 −3 s −1 (D) 3.8  10 −4 s −1 two parallel first order mechanisms
k1 B
Q 3. For the following parallel chain reaction
B A
k2
A C
If k1 : k 2 = 1: 9 and k1 = 1.3 10−5 is −1 .
C the
overall half life of A is 12 hrs of
rate of formation of C is 60% of a rate of Calculate the concentration ratio of C to A if an
decomposition of A than what will be half life experiment is started with only A and allowed
of A while it is converting into B to run for one hour
(A) 40 hours (B) 60 hours (A) 0.537 (B) 0.355
(C) 50 hours (D) 30 hours (C) 0.0525 (D) 1.52
Q 4. For the following parallel chain reaction Q 8. For the reaction
–4 –1 R – OH + X¯
k1 = 2× 10 s B k1
2nd Order
A R – X + OH¯
–4 –1
k2
k2 = 2× 10 s C
if the sum of the st
1 Order R – OH + X¯
concentration of B and C at any time is 2M The rate is given by
then, what will be  Bt and Ct respectively ? Rate = k1  RX  OH −  + k 2  RX 
11 13 3 5 Calculate % of RX which reacts by 2 nd order
(A) M& M (B) M& M
12 12 4 4 mechanism, when OH −  is 0.1 M
4 6 8 18
(C) M & M (D) M& M k1  100 k 2 100
5 5 13 13 (A) (B)
Q 5. For a hypothetical elementary reaction k1 + k 2 k1 + k 2
k1 2B 10k1 100k1
(C) (D)
A k1 + k 2 k1 + 10k 2
k2 k1 1 Q 9. For the first order parallel reaction of A starting
2C where = Initially only 2
k2 2 with 1 M initial concentration of A
3k B
moles of A are present. The total number of
A 2k
moles of A, B & C at the end of 50% reaction 2C
k
are
3C
(A) 2 (B) 3 Which of the following is/are true
Bt : Ct : Dt is independent of time
(C) 5 (D) None
Q 6. For the reaction (A)
k1 2B
(B) Ct  Bt = Dt
A
k2 3C
k1 1
=
(C) C = 0.67M
k2 2 (D) If k = 0.5min −1 then [B] = 1M after
The total no. of moles of A, B & C at the end of 1.386 min
50% reaction when started with 10 mole of A is Q 10. For the consecutive unimolecular type first
(A) 30 mole (B)
55
mole order reaction, A ⎯⎯ k1
→ R ⎯⎯ k2
→ S , the
3 concentration of component A, CA at any time
(C) 20mole (D) None of these is given by

(k1 + k 2 ) t − (k1 + k 2 ) t
(A) CA = CA0 e (B) CA = CA0 e (C) 1,2,0 (D) 1,2, not defined
− k1t Q 4. For the reaction H2 ( g ) + Br2 ( g ) → 2HBr ( g )
(C) CA = CA0 e (D) CA = CA0 e
k1t
the experiment data suggested that

Q 11. For the reaction A → B → C , t1/2 for A and B
r = k  H 2  Br2 
1/ 2
the molecularity and order
are 4 & 2 minutes respectively. How much time
would be required for B to reach maximum of the reaction are respectively
concentration. (A) 2, 3/2 (B) 3/2, 3/2
(A) 2 min (B) 4 min (C) Not defined, 3/2 (D) 1, ½
(C) 6 min (D) 8 min Q 5. For a reaction A + B → Products, the rate law
 B is –Rate = k  A  B
3/ 2
. Can the reaction be an
Q 12. In above question, at any time ‘t’ ( t  0 )
A elementary reaction ? Explain.
is equal to [NCERT EXAMPLAR]
(A) 1 (B) 1:2 Q 6. Assertion (A): Order and molecularity are same
(C) 2:1 (D) None of these [NCERT EXAMPLAR]
Reason (R):Order is determined experimentally
& molecularity is the sum of the stoichiometric
coefficient of rate determining elementary step
(A) Both assertion & reason are correct &
the reason is correct explanation of
assertion
7. Reaction Mechanism (B) Both assertion and reason are correct,
Q 1. The rate law for the single –step reaction, but reason does not explain assertion
2A + B → 2C , is given by (C) Assertion is correct, but reason is
(A) Rate = K  A. B incorrect
(D) Both assertion and reason are incorrect
Rate = K  A  . B
2
(B) (E) Assertion is incorrect, but reason is
(C) Rate = K  2A. B correct
K1
Q 7. In the reversible reaction 2NO2 N 2 O4 ,
Rate = K  A  . B
2 0 K2
(D)
Q 2. For the elementary step, the rate of disappearance of NO 2 is equal to
( CH3 )3 .CBr ( aq ) → ( CH3 )3 C+ ( aq ) + Br − (A)

2K1
 NO 2 
2
the molecularity is K2
2K1  NO 2  − 2K 2  N 2O 4 
2
(A) Zero (B) 1 (B)
(C) 2 (D) Can’t determine
2K1  NO 2  − K 2  N 2O 4 
2
Q 3. The following two step mechanism has been (C)
proposed for the gas – phase decomposition of (D) ( 2K1 − K2 ) NO2 
nitrous oxide ( N 2O )
B + 3C,2C ⎯⎯ →3D ,
k1 k2
Q 8. For 2A
Step I: N2O ( g ) → N2 ( g ) + O ( g )
k −1
assuming all reactions to be single step

Step II: N2O ( g ) + O ( g ) → N2 ( g ) + O2 ( g ) (Elementary) reactions. Find the expression for
What is the molecularity of each of the d C
elementary reactions and over all molecularity ? dt
(A) 1,2,3 (B) 1,2,2

Q 9. For the reaction sequence Q 13. The chemical reaction, 2O3 → 3O2 proceeds
A+B C+G
K1
K−1 as follows
C + D ⎯⎯ K2
→ E ; E + F ⎯⎯ K3
→ 2C O3 O 2 + O ….. (fast)
d C O + O3 → 2O2 … (slow)
The term is expressed as
dt The rate law expression should be
(A) K1  A B − K1 CG (A) r = K  O3 
2
(B) r = K  O3   O 2 
2 −1
−K2 C D + 2K3  E F (C) r = K O3 O2  (D) Unpredictable

(B) K1  A B − K −1 CG  − Q 14. The mechanism of the reaction,
2H2 + 2NO → N 2 + 2H 2O
K2 C D − K3  EF
Follows the steps
(C) −K2 C D + K3  E FG 2NO N2O2
−K2 C D + K3  E F N2O2 + H2 → N2O + H2O (slow)
(D) None of these
N2O + H2 → N2 + H2O (fast)
Q 10. For the reaction 2NO2 + F2 → 2NO2F ,
The overall order of the reaction is
following mechanism has been provided: (A) 2 (B) 3 (C) 4 (D) 1
NO 2 + F2 ⎯⎯⎯
Slow
→ NO 2 F + F Q 15. For a two step reaction
NO2 + F ⎯⎯→ NO 2F
fast
A
K1
R + B; R + C ⎯⎯
K3
→ Pr oducts
K2
Thus rate expression of the above reaction can (where, R is s reactive intermediate, whose
be written as concentration is maintained at some low steady
(A) r = k  NO 2   F2  (B) r = k  NO2  F2 
2
state through out the reaction). Find the rate law
(C) r = k  NO2  (D) r = k  F2 
expression.
−
Q 11. Following mechanism has been proposed for a H + + HNO2 + C6 H5 NH 2 ⎯⎯→
Br
C6 H5 N 2+ + 2H 2O
reaction.
The mechanism is given as
2A + B → D + E
H + + HNO2 H 2 NO2+ (fast eq.)
K1
A + B → C + D ……. (slow) K2
A + C → E …… (fast) Interimediate
+ −
The rate law expression for the reaction is H 2 NO + Br ⎯⎯→ NOBr+ H 2O (slow)
2
K3
(A) r = K  A   B (B) r = K  A B

2
NOBr + C6 H 5 NH 2 → C6 H 5 N 2+ + H 2O + Br − fast
(C) r = K  A  (D) r = K  AC
2
Find the rate law of the overall reaction.
Q 17. The steady –state concentration of the
Q 12. Mechanism of a hypothetical reaction
activated molecule [A*] in the following
X 2 + Y2 → 2 XY is given below [NEET 2017]
sequence of steps
X + X ( fast )
⎯⎯→
X2 K1
A+A A + A*
X + Y2 → XY + Y ( slow)
X + Y → XY(fast) A* + A
K2
⎯⎯→
2A
The overall order of reaction will be is given by
(A) 1 (B) 2 (C) 0 (D) 1.5 (A) k2[A] /k1 (B) k1 [A] / k2

(C) k1 k2 [A] (D) k1k2 / [A] 8. Collision Model For Chemical Kinetics
st
Q 18. A two step endothermic reaction with 1 step as Q 1. The rate of reaction becomes 2 times for every
RdS can be represented as 10°C rise in temperature. How the rate of
e reaction will increase when temperature is
increased from 30°C to 80°C [JEE Main 2011]
e (A) 16 times (B) 32 times
(C) 64 times (D) 128 times
(A) R.C (B) R.C Q 2. For a certain reaction the variation of the rate
constant with temperature is given by the
e
equation in ( t  0C)
The value of the temperature coefficient of the
reaction rate is, therefore
(C) R.C (D) None of these (A) 0.1 (B) 1.0
Q 19. The following mechanism has been proposed (C) 10 (D) 2
for the exothermic catalyzed complex reaction Q 3. Consider figure and mark the correct option
A+B
fast
IAB ⎯⎯k1
→ AB + I ⎯⎯k2
→P + A [NCERT EXAMPLAR]
Activated complex
If k1 is much smaller than k 2 . The most E1
suitable qualitative plot of potential energy Products
Energy
E2
(P.E.) versus reaction coordinate for the above
Reactants
reaction
Reaction coordinate
(A) Activation energy of forward reaction is
E1 + E 2 and product is less stable than reactant
P.E.
AB+I A+P
P.E
(B) Activation energy of forward reaction is

A+B IAB A+P A+ B
AB+I
IAB
E1 + E 2 and product is more stable than
(A) reaction coordinate (B) reaction coordinate
reactant
(C) Activation energy of both forward and
backward reaction is E1 + E 2 and reactant is
P.E.
P.E.
A+B A+B more stable than product

AB+I A+P IAB
IAB
AB+I A+P (D) Activation energy of backward reaction
(C) reaction coordinate (D) reaction coordinate is E1 and product is more stable than reactant
Q 4. What percentage fraction of the molecule will
cross over the energy barrier at 1000 K
temperature for 18.424 KJ/mol activation
(
energy R = 8J mol −1K −1 )
(A) 10 % (B) 20%
(C) 90% (D) 80 %
Q 5. In a chemical reaction 1/4th of the molecules
are in activated state at T = 127ºC . The
activation energy of the reaction is (in 2 = 0.7)
(A) 280 R (B) 560 R
(C) 56 R (D) 28 R
Q 6. The activation energy for the reaction (A) It considers reacting molecules or atoms
2HI ( g ) → H2 + I2 ( g ) is 209.5 kJ mol −1
at to be hard spheres and ignores their structural
features
581K. Calculate the fraction of molecules of
(B) Number of effective collisions
reactants having energy equal to or greater than
determines the rate of reaction
activation energy? [NCERT]
(C) Collision of atoms or molecules
Q 7. Rate of reaction increases by lower factor than
possessing sufficient threshold energy results
increment in effective collision due to
into the product formation
(A) activation energy
(D) Molecules should collide with sufficient
(B) orientation factor
threshold energy and proper orientation for the
(C) Arhenius Constant
collision to be effective
(D) None of these
Q 11. Arhenius constant is
Q 8. Assertion (A): All collision of reactant
(A) independent of temperature
molecules lead to product formation
(B) dependent on temperature
Reason (R): Only those collisions in which
(C) Independent of orientation factor
molecules have correct orientation and
(D) Independent of collision frequency
sufficient kinetic energy lead to compound
Q 12. The correct graph of K vs T is
formation. [NCERT EXAMPLAR]
(A) Both assertion and reason are correct and K K
the reason is correct explanation of assertion
(B) Both assertion and reason are correct, but (A) T (B) T
reason does not explain assertion
(C) Assertion is correct, but reason is incorrect K K
(D) Both assertion and reason are incorrect
(E) Assertion is incorrect, but reason is correct (C) T (D) T
Q 9. Assertion (A): Rate constant determined from Q 13. What is the slope of the straight line for the
Arrhenius equation are fairly accurate for graph drawn between In k and 1/T, where k is
simple as well as complex molecules the rate constant of a reacting at temperature T ?
Reason (R): Reactant molecules undergo −E a −E a
chemical change irrespective of their orientation (A) (B)
during collision. [NCERT EXAMPLAR] 2.303R R
(A) Both assertion and reason are correct Ea R
(C) (D)
and the reason is correct explanation of R Ea
assertion Q 14. First order rate constant k is related to temp. as
(B) Both assertion and reason are correct,
but reason does not explain assertion
( )
log k = 15.0 − 106 / T which of the following
(C) Assertion is correct, but reason is pair of value is correct ?
incorrect (A) A = 1015 and E = 1.9 104 KJ
(D) Both assertion and reason are incorrect (B) A = 10 −15 and E = 40KJ
(E) Assertion is incorrect, but reason is
(C) A = 1015 and E = 40KJ
correct
Q 10. Which of the following statements is incorrect (D) A = 10 −15 and E = 1.9 104 KJ
about the collision theory of chemical reaction? Q 15. For a first order rate constant k is related to
[NCERT EXAMPLAR] temp. as log k = 6.0 − ( 2000 / T ) . Which of the
following values are correct ? [IIT-JEE 2009]
(A) A = 106 and Ea = 9.2KJ

(B) A = 6 and E a = 16.6KJ (A) k1 = 2k 2e

Ea 2 / RT
(B) k1 = k 2e
Ea1 / RT
(C) A = 106 and E a = 16.6KJ (C) k 2 = k1e Ea 2 / RT (D) k1 = Ak 2e

Ea1 / RT
(D) A = 106 and Ea = 38.3KJ Q 22. The rate constant K1 & K2 for two different
Q 16. Activation energy of a chemical reaction can be reactions are 1016.e −2000/T & 1015.e −1000/T
Determined by [NCERT E./CBSE PMT 1998] respectively. The temperature at which K1 = K2
(A) evaluating rate constant at standard is [CBSE AIPMT 2008]
temperature 2000
(B) evaluating velocities of reaction at two (A) 1000 K (B) K
2.303
different temperature
1000
(C) evaluating rate constant at two different (C) 2000 K (D) K
temperature 2.303
(D) changing concentration of reactants Q 23. The rate constants of a reaction at 500 K and
Q 17. How much faster would a reaction proceed at 700 K are 0.02s −1 and 0.07s −1 respectively.
25°C that at 0°C if the activation energy is 65 Calculate the values of E a and A.
kJ? [NCERT Solved]
(A) 2 times (B) 5 times Q 24. The first order rate constant for the
(C) 11 times (D) 16 times decomposition of ethyl iodide by the reaction
Q 18. A first order reaction is 50% completed in 20
C2H5I ( g ) → C2H4 ( g ) + HI ( g ) at 600 K is
minutes at 27°C if 3.8 10−16% of the reactant
molecules exists in the activated state, the E a 1.60 10−5 s −1 . Its energy of activation is 209
kJ/mol. Calculate the rate constant of the
(activation energy) of the reaction is
reaction at 700K. [NCERT Solved]
(A) 12 kJ/mole (B) 831.4 kJ/mole
Q 25. The rate constant for the decomposition of
(C) 100 kJ/mole (D) 88.57 kJ/mole
Q 19. The activation energy of certain reaction is 87 hydrocarbons in 2.418  10 −5 s −1 at 546 K. If
KJ mol–1. What is the ratio of the rate constants the energy of activation is 179.9 kJ/mol. What
for this reaction when the temperature is will be the value of pre-exponential factor.
decreased from 37°C to 15°C ? [NCERT]
(A) 5/1 (B) 8.3/1 Q 26. The decomposition of hydrocarbon follows the
(C) 13/1 (D) 24/1 equation k = ( 4.5  1011 s −1 ) e −28000K / T
Q 20. From the following data; the activation energy
Calculate E a . [NCERT]
for the reaction (cal/mol) H2 + I2 → 2HI
Q 27. The decomposition of A into product has value
T, ( in, K ) 1/ T, ( in, K −1 ) log10 K of k as 4.5 103 s −1 at 10°C and energy of
769 1.3  10−3 2.9 activation 60 kJ mol −1 . At what temperature
667 1.5  10−3 1.1 would k be 1.5  104 s −1 ? [NCERT]
(A) 4 10 4
(B) 2 10 4 Q 28. The time required for 10% completion of a first
order reaction at 298K is equal to that required
(C) 8  10 4
(D) 3  10 4
for its 25% completion at 308 K. If the value of
Q 21. A reactant (A) forms two products
A is 4 1010 s −1 . Find K at 318K & E a
A ⎯⎯ k1
→ B , Activation energy E a1
[NCERT]
A ⎯⎯
k2
→ C , Activation energy E a 2
If E a 2 = 2E a1 , then k1 and k 2 are related as

9. Arhenius Equation, Catalyst effect (iii) At 300K, value of equilibrium constant

Q 1. A reaction takes place in various steps. The rate of reaction I = e
constant for first, second, third and fifth step are (iv) At 300 K, value of equilibrium constant
k1 , k 2 , k 3 and k 5 respectively. The overall rate of reaction II = e
(A) ii & iii are true
constant is given by
1/ 2
(B) I & iv are true
K K  (C) only ii is true
K= 2 1
K3  K5  (D) None of these
If activation energy are 40,60,50 and 10 KJ/mol
A + B → C + D; H = +20kJ / mole , the
respectively, the overall energy of activation
( KJ / mol ) activation energy of the forward reaction is 85
kJ/mole. Calculate the activation energy of the
(A) 10 (B) 20 reverse reaction
(C) 25 (D) None of these (A) 105 kJ/mol (B) 85 kJ/mol
Q 2. The rate constant, the activation energy, and the (C) 65 kJ/mol (D) 45 kJ/mol
Arrhenius parameter of a reaction at 25°C are Q 6. Water and oxygen atoms react in upper
−4 −1 −1
3.0 10 s , 104.4KJ mol , and atmospheric level bimolecularly to form two
OH radicals having heat of reaction 72 kJ at 400
6.0 1014 s −1 respectively. The value of rate
K and energy of activation being 77 kJ.
constant as T →  is [IIT-JEE 1996S]
18 −1 Calculate the Eaf ( kJ ) for bimolecular
(A) 2.0 10 s (B) 6.0 1014 s −1
(C) Infinity (D) 3.6 1030 s −1 combination of two OH radicals to form H 2O
1 dK and O-atom.
Q 3. The term is equal to (A) 10 (B) 72
K dT
(C) 77 (D) 5
ea −e a
(A) (B) Q 7. In presence of catalyst,[NCERT EXAMPLAR]
RT RT (A) Activation energy decreases
ea −e a (B) Enthalpy change decreases
(C) 2
(D)
RT RT 2 (C) Equation constant decreases
Q 4. For the two reactions I & II [‘A’ & 'Ea ' are (D) More amount of product is formed from
a given amount of reactant
constant] Ai = 2Aii & the energy diagram of Q 8. Which of the following statement is not correct
the two reaction are represented as below for the catalyst? [NCERT EXAMPLAR]
Reaction I Reaction II
Units cal/mol (A) It catalyses the forward and backward
Units cal/mol
reactions to the same extent
200 Potential 800
(B) It alters G of the reaction
Potential Energy Reactant
600
Energy Product
600 (C) It is a substance that does not change
Reactant
Product the equilibrium constant of a reaction
Reaction
Reaction
coordination coordination (D) It provides an alternate mechanism by
reducing activation energy between reactions
Given: G = H − S = ln Keq
0 0 0
and products
(i) The ratio of rate constant of forward Q 9. Assertion (A): The enthalpy of reaction
reaction for both reaction is independent of remains constant in the presence of a catalyst
temperature Reason (R): A catalyst participating in the
(ii) 1st reaction is endothermic & 2nd is reaction forms different activated complex and
exothermic. lowers down the activation energy but the
difference in energy of reactant and product (C) 540 k cal (D) None of these
remains the same. [NCERT EXAMPLAR] Q 13. At 380 °C, the half life period for the first order
(A) Both assertion and reason are correct decomposition of H 2O 2 is 360 min. The energy
and the reason is correct explanation of
of activation of the reaction is 200 kJ
assertion
(B) Both assertion and reason are correct, K = 9.13 10−4 sec −1 , E a = 76.65kJ . Calculate
but reason does not explain assertion the time required for 75% decomposition at 450
(C) Assertion is correct, but reason is °C.
incorrect Q 14. The time required for 10% completion of a first
(D) Both assertion and reason are incorrect order reaction at 298 K is equal to that required
(E) Assertion is incorrect, but reason is for its 25 % completion at 308 K. If the pre –
correct exponential factor for the reaction is
Q 10. on adding a catalyst at 300 K, the activation 3.56 109 s −1 , calculate its rate constant at 318
energy increases by 5.75 KJ/mol. The ratio of K and also the energy of activation
K1 Q 15. In the Arrehenius equation for a certain
rate constant ( ) will be [AIIMS 2018]
K2 reaction, the values of A and E a (energy of
−1
(A) 20 times (B) 10 times activation) are 4 1013 sec −1 and 98.6kJ mol
(C) 1000 times (D) 100 times
respectively. If the reaction is of first order, at
Q 11. A hydrogenation reaction is carried out at 500
what temperature will its half life period be 10
K. If the same reaction is carried out in presence
minute ?
of a catalyst at the same rate, the temperature
Q 16. A first order reaction A → B requires
required is 400 K. Calculate Activation energy
of the reaction if catalyst decreases activation activation energy of 70 kJ. When a 20%
solution of A was kept at 25 °C for 20 minutes,
energy by 20 kJ mol −1 [IIT-JEE 2003]
50% decomposition took place. What will be
(A) 80 KJ (B) 100 KJ
the percent decomposition in the same time in a
(C) 120 KJ (D) None of these
30% solution maintained at 40°C ? Assume that
Q 12. Rate constant becomes 2 times if catalyst is add
activation energy remains constant in this range
to a reaction at 400 K. The activation energy of 745
the reaction in absence of catalyst, if in presence of temperature ? Given e 900  ln 2 = 1.6 = ln5
of catalyst activation energy is 20 kcal
(A) 580 kcal (B) 20.56 k cal

Answer Key
(13). A (14). B (15). C
1. Introduction, Rate of Reaction
(1). A (2). D (3). B 5. Pseudo Order Reaction, Pressure Change
(4). B (5). C (6). A Method, Volume Change Method
(7). A (8). D (9). B (1). B (2). B (3). B
(10). D (11). C (12). B (4). A (5). A (6). D
(13). D (14). C (15). C (7). B −5
(8). 3.64 10 M −1 min −1
−2
(16). B (17). 4.07  10 mol.l −1h −1 , (9). 4.67 10−5 MS −1 , 1.98 10−2 S −1
6.79 10−4 mol.l −1 min −1 , (10). C (11). B (12). B
1.13 10−5 mol.l −1s −1 (13). A (14). 4.98  10 −4 S −1
Rate of production of NO2 = 2.72 10−3 mol.l −1 min −1 (15). A (16). A (17). A
2. Differential Rate Law, 6. Parallel 1st order Reaction

Integrated rate laws for nth order Reaction (1). B (2). B (3). D
(1). D (2). B (3). A: 2, B: 1/2 (4). D (5). B (6). C
(4). A (5). B (6). B (7). A (8). D (9). D
(7). C (8). B (9). D (10). B (11). B (12). A
(10). C (11).D (12). C
(13). A (14). B (15). B 7. Reaction Mechanism
(16). C (17). A (18). A (1). B (2). B (3). D
(19). B (20). A (4). C (5). No (6).D
−9
(21). 8 10 MS −1 ; 3.89 10−9 MS −1 (7). B
(8). 3K1  A  − 3K −1  B C − 2K 2  C
2 3 2
3. Zeroth & First Order Reaction (9). A (10). B (11). B

(1). 2, 1 (2). A (3). A (12). D (13). B (14). B
−4 −4
(4). 1.25  10 , 3.75 10 (5). B
(6). C (7). 0, -K, molL-1S-1 (15). Rate = K1  A 
(8). C (9). C (10). A K  B
1+ 2
(11). A). 75 mm of Hg B). 6 sec K 3  C
C). 25 mm of Hg D). 1850 mm of Hg
(16). Rate = k1.k 2  H +   HNO 2   Br − 
0.693 k3
(12). sec (13). A (14). D
15 (17). B (18). C (19). A
(15). C (16). C (17). C
(18). 1.733 10−4 M min −1 (19). C 8. Collision Model For Chemical Kinetics,
(20). B (21). C (22). C Arhenius Equation
(23). B (24). B (25). B
(1). B (2). D (3). A
(4). A (5). B (6).1.47 10−19
4. First Order & Second Order Reaction
(7). B (8). E (9). C
(1). B (2). C (3). C
(10). C (11). B (12). B
(4). A (5). B (6). A
(13). B (14). A (15). D
(7). C (8). C (9). C
(16).C (17). C (18). B
(10). A (11). B (12). A
(19). C (20). A (21). B
(22). D (23). Ea = 18230.8 J, A = 1.61

(24). K2 = 6.36  10 −3 S −1
(25). A = 3.912 1012 S −1
(26). 232.79 KJ/mol (27). 240C
−3
(28). K = 9.93 10 , Ea = 76.75 KJ/mol
9. Arhenius Equation, Catalyst effect

(1). C (2). B (3). C
(4). C (5). C (6). D
(7). A (8). B (9). A
(10). B (11). B (12). B
(13). 20.4 min
(14). K = 9.13 10−4 sec −1 , E a = 76.65kJ
(15). T = 311.4 K
(16). % decomposition = 80 %


Chemical Kinetics

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Chemical Kinetics

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AtoZ CHEMISTRY CHEMICAL KINETICS

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 2

2. Differential Rate Law,

(C) 3,2 (D) 2,2

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 3

(A) Rate = K  A   B (B) Rate = K  A   B

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 4

concentration [A] =0.1 M, Q 3. If ‘a’ is the initial concentration of a substance

[A] = 0.1 M & [B] = 0.2 M. Also Calculate the

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 5

 A 0 Q 15. 99% of a first order reaction was completed in

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 6

−1 change in concentration of reactants and

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 7

1 1 5  10−2 M −1hr −1 then the time duration in

time required for  NOCl to be….

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 8

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 9

2.303  2Pi  evolved. The first order rate constant

T(min.) 10 15 20 25  k1 = 1.26 10 sec and k 2 = 3.6 10−5 sec −1

(A) 3.8  10 −6 s −1 (B) 3.9  10 −5 s −1 Q 7. A certain organic compound A decompose by

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 11

the experiment data suggested that

( CH3 )3 .CBr ( aq ) → ( CH3 )3 C+ ( aq ) + Br − (A)

assuming all reactions to be single step

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 12

−K2 C D + 2K3  E F (C) r = K O3 O2  (D) Unpredictable

(A) r = K  A   B (B) r = K  A B

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 13

(B) Activation energy of forward reaction is

A+B A+B more stable than product

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 15

(B) A = 6 and E a = 16.6KJ (A) k1 = 2k 2e

(C) A = 106 and E a = 16.6KJ (C) k 2 = k1e Ea 2 / RT (D) k1 = Ak 2e

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9. Arhenius Equation, Catalyst effect (iii) At 300K, value of equilibrium constant

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 18

2. Differential Rate Law, 6. Parallel 1st order Reaction

3. Zeroth & First Order Reaction (9). A (10). B (11). B

(22). D (23). Ea = 18230.8 J, A = 1.61

9. Arhenius Equation, Catalyst effect

RISHI SIR [B.TECH. IIT KANPUR] www.atozchemistry.com 20

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