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Received: 5 October 2021 Revised: 6 February 2022 Accepted: 11 February 2022

DOI: 10.1002/gj.4430

RESEARCH ARTICLE

Evincing the presence of a trans-Gondwanian mobile belt in


the interior of the Princess Elizabeth Land, East Antarctica:
insights from offshore detrital sediments, rock fragments, and
monazite geochronology

Rashmi Gupta1 | Mayuri Pandey1 | Devsamridhi Arora2 |


Naresh Chandra Pant3 | N. V. Chalapathi Rao1

1
Department of Geology, Institute of Science,
Banaras Hindu University, Varanasi, India East Gondwana was assembled through the stitching of the Indo-Antarctica and
2
Department of Earth Sciences, IIT Bombay, Australo-Antarctica domains which also represents the key Gondwana-forming
Mumbai, Maharashtra, India
3
regions in present-day East Antarctica. However, the Indo-Antarctica and Australo-
Department of Geology, University of Delhi,
Delhi, India Antarctica boundaries remain speculative and contentious, as the thick Antarctic Ice
sheet precludes direct geological characterization of these terranes. In addition, the
Correspondence
Mayuri Pandey, Department of Geology, exact role of the Gamburtsev Subglacial Mountains, present in the interior of Princess
Institute of Science, Banaras Hindu University,
Elizabeth Land (PEL), during the amalgamation of Gondwana, has not been well
Varanasi, India.
Email: mayuri.geo@bhu.ac.in understood. We present new mineralogical data of offshore sediments from Prydz
Bay to infer the geology of the interior of the PEL terrain, East Antarctica. Coast mar-
Funding information
IOE research grant ginal outcrops dominantly expose igneous and granulite facies metamorphic rocks.
Heavy minerals characterization of the rock fragments followed by consideration of
Handling Editor: M. Santosh
the outcrop geology indicate a possible contribution of sediments from the far inte-
rior of PEL terrain. Total U–Pb chemical geochronology of detrital monazites domi-
nantly shows a bimodal age distribution ascribable to Stenian to Tonian (1,100 Ma,
900 Ma) event ages and a younger Pan-African event (500 Ma). Besides these,
Tonian-Cryogenian (700 Ma) ages from texturally constrained monazites of a
low-grade schist rock fragment is reported for the first time from this sector. Consid-
eration of glacial flow directions and the nature of rock fragments indicate their
sourcing from the distal hinterland. The possible provenance is inferred to be from
the Gamburtsev Subglacial Mountains.

KEYWORDS
Antarctica, detrital sediments, monazite, Princess Elizabeth Land

1 | I N T RO DU CT I O N comprehend and refine the correlations between the past-adjacent


landmasses. For example, the Gondwana-forming orogen possibly a
With increasing focus on the stability of polar ice sheets, understand- continuation of the Kuunga orogen is thought to be the main orogenic
ing of the sub-glacial geology of East Antarctica has assumed signifi- domain stitching the Indo-Antarctic and Australo-Antarctic domains
cance as an input to derive the geological boundary conditions for ice that lie beneath the thick East Antarctic Ice Sheet (EAIS) (Boger, 2011;
sheet behaviour (e.g., Gasson & Keisling, 2020; Kennicutt et al., 2014; Boger & Miller, 2004; Collins & Pisarevsky, 2005; Fitzsimons, 2003;
Pandey, Pant, Arora, & Gupta, 2021). This knowledge is also critical to Harley, Fitzsimons, & Zhao, 2013). However, the geological

Geological Journal. 2022;1–27. wileyonlinelibrary.com/journal/gj © 2022 John Wiley & Sons Ltd. 1
2 GUPTA ET AL.

framework of these domains and the exact location and age The tectonic reconstructions of conjugate margins beneath the
of the terrane boundary separating them are debatable (e.g., Fit- icesheets have been carried out either through (i) airborne geophysical
zsimons, 2003; Aitken et al., 2014; Mikhalsky et al., 2015). Though surveys (e.g., Aitken et al., 2014; Ferraccioli, Armadillo, Jordan,
the coastal outcrops provide a direct source of knowledge of the sub- Bozzo, & Corr, 2009) or (ii) extrapolation of continental margin bed-
ice geology, the continuation of coastal geological domains into the rock constrained by sparse outcrops (e.g., Arora et al., 2020;
interior regions of East Antarctica is mostly speculative, due to a lack Flowerdew et al., 2012, 2013; Pierce et al., 2014). However, the
of source material from these distal provenances. above-mentioned two techniques are indirect methods to infer the
East Antarctica dominantly comprises complexly sewed remnants sub-ice geology which needs to be validated through independent evi-
of Archean cratons and not well-demarcated Proterozoic suture belts dence. One direct proof of interior terrain is the occurrence of marine
(e.g., Fitzsimons, 2000a). The Princess Elizabeth Land-Amery Ice Shelf sediments proximal to the coast. With prior knowledge of active glaci-
sector (PEL-AIS: Figure 1) is one of the least explored terranes of East ological processes responsible for glaciogenic marine sediment
Antarctica, preserving, 1,000 Ma, 800 Ma, and 500 Ma orogens deposits and Ocean circulation patterns, heavy mineral suites, and
(e.g., Arora et al., 2020; Fitzsimons, 2000b; Grew et al., 2012). In addi- rock fragments can provide insights into the provenance geology after
tion to this, the detrital zircon ages reported from the Prydz Bay careful consideration of depositional conditions.
region widely range from 1,300 to 500 Ma (e.g., Veevers, 2018; Heavy minerals are an invaluable proxy for determining the prov-
Veevers & Saeed, 2008; Veevers, Saeed, Pearson, Belousova, & Kinny enance of ice-rafted or fluvial-derived material (Diekmann &
et al., 2008). However, these ages are not consistent with the litholo- Kuhn, 1999). The deep ice of EAIS along the coastal section of PEL-
gies which occur in the interior of the PEL sector. The continuation of AIS has been predicted to be retreating significantly in a warming cli-
these orogens inland of PEL-AIS is still enigmatic, requiring collation mate, as depicted by the numerical ice sheet models (e.g., DeConto &
of all the available geological knowledge with the indirect inferences Pollard, 2016). Glaciological processes occurring in PEL-AIS led to the
from the geophysical data. Furthermore, the Gamburtsev Subglacial deposition of packages of terrigenous sediments in Prydz Bay
Mountains (GSM) which is completely buried under thick EAIS, pre- (Allison, 1979). The major sourcing of the sediments is from the
sent in the interior PEL, represents an intriguing geological component coastal belt present on the eastern flank of the PEL terrane compris-
that lacks any direct geological correlation (e.g., Ferraccioli ing of island group and peninsulas.
et al., 2011). The GSM's geology has been linked either to the The other major influx of sediments are carried by three different
Grenvillian-age (ca 1 Ga) or to the Pan-African age (ca 550 Ma) oro- glaciers viz Mellor, Lambert, and Fisher glaciers flow through the
genic events and speculated to have had played a significant role in Lambert Rift and amalgamate at the edge of the southern Prince
the amalgamation of distinct lithospheric plates comprising the entire Charles Mountains to form the main Lambert-Amery ice stream; the
East Antarctic Craton (Aitken et al., 2014; Ferraccioli et al., 2011). most significant sediment transportation system from the interior of

F I G U R E 1 Map of Prydz Bay, East Antarctica and surrounding areas showing the tectonic subdivisions (from Corvino, Boger, Henjes-Kunst,
Wilson, & Fitzsimons et al., 2008) and generalized circulation of ocean currents in Prydz, Bay region (Smith, Zhaoqian, Kerry, & Wright,
et al., 1984). The image manifests the present-day rate of glacier flow patterns in the PEL terrain of east Antarctica (Selley et al., 2021). Black
arrows show directions of ice flow (modified from Hambrey, Ehrmann, & Larsen, 1991). The purple colour striations represent the subglacial
canyon system and its lacustrine stream (Jamieson et al., 2016). The red dots represent the location of three sites drilled during ODP 119.
nPCM = northern Prince Charles Mountains, sPCM = southern Prince Charles Mountains, GSM = Gamburtsev Subglacial Mountains,
PEL = Princess Elizabeth Land
GUPTA ET AL. 3

the PEL-AIS sector Antarctica (Stagg, 1985) which drains approxi- massive and stratified diamictite and the third sequence lies uncon-
mately 20% of the EAIS (e.g., Allison, 1979; Veevers, 2018). Also, the formably below the flat-lying sequence and to the upper prograding
presence of an 1,140 km-long system of canyons and two large lakes sequence at places. Three sites 740, 742, and 739, were drilled during
connecting south of the Lambert Rift to the West Ice Shelf have been Oceanic Drilling Program 119 located on the Prydz Bay shelf area.
confirmed (Bo et al., 2019; Golynsky, Golynsky, & Cooper, 2007; Site 739A cored a thick sequence of glacial sediments ranging in
Jamieson et al., 2016), which could also be the major contributors of age from late Eocene-early Oligocene to Quaternary (Figure 2a). The
sediments in the Prydz Bay. selected samples for the present study range from 206.9 to 252.39 m
The flow directions suggest that the Mellor and Lambert Glacier below seafloor (mbsf) representing Unit III and from 329.9 mbsf from
supply the bulk of detritals, mainly from the foot of the GSM, while Unit V. Based on the diatoms, Unit III contain stratified diamictite
Fisher carries material from the Interior of southern Prince Charles horizons while Unit IV is dominantly massive diamictite both rep-
Mountains (sPCM) (Figure 1). The other major sourcing is from the north- resenting late Eocene to early Oligocene age (Barron & Larsen, 1989).
ern Prince Charles Mountain (nPCM) through the Charybdis Glacier and Unit V is dated to be of middle Eocene age inferred from the presence
a few small glaciers connect to the western flank of the Amery Ice Shelf of calcareous nannofossils (Barron & Larsen, 1989).
bringing sediment from the interior of PEL proximal to the coast The depths of the selected samples from site 740 range from
(Ferraccioli et al., 2011; Heeszel et al., 2013; Paxman et al., 2016; Van de 6.22 to 223.13 mbsf comprising lithostratigraphic Unit I to Unit III
Flierdt, Hemming, Goldstein, Gehrels, & Cox, 2008) (Figure 1). representing a sequence from Holocene to Permian age (Barron &
The water circulation in Prydz Bay is characterized by a closed Larsen, 1989) (Figure 2b). Based on palaeontological and mag-
cyclonic gyre adjacent to the Amery Ice Shelf (Smith et al., 1984; netostratigraphic signatures, Unit I and Unit II of site 740 are dated to
Wong, 1994). There is an inflow of cold water from the east near the be Pliocene to Holocene in age (Barron & Larsen, 1989). Unit III is cor-
West Ice Shelf and outflow near the Cape Darnley. Because of its related with a Permian age red bed sequence of the Amery Group in
closed circulation, water masses in Prydz Bay play a limited role in cur- the Lambert Graben, (Fedorov, Grikurov, Kurinin, & Masolov, 1982;
rent activity beyond the shelf. Hence, sediments deposited in Prydz Mond, 1972).
Bay archive an excellent record of sub-glacial provenance. One such Sediments recovered from site 742 range in age from Eocene to
suite of marine sediments was drilled during Oceanic Drilling Program Quaternary. The depths of the analysed samples are 65.1 mbsf (Unit
(ODP) 119 at Prydz Bay and heavy mineral fractions from marine sedi- II), 166.3 mbsf (Unit IV), and 244.8 mbsf (Unit V). Based on fossil con-
ments of sites 739, 740, and 742 are investigated in the present study tent Unit II is dated as late Pliocene-Quaternary (Barron et al., 1991).
to infer sub-ice geology of the PEL sector. Site 739 and site 740 are Unit IV is dated early Pliocene–late Miocene while Unit V is dated as
the most seaward and the innermost ones respectively, while site Eocene–Oligocene respectively (Barron et al., 1991; Barron &
742 is located in between sites 739 and site 740 on the shelf Larsen, 1989; Hambrey et al., 1991) (Figure 2c).
(Figure 1). All these sites are within the regime of the Antarctic cir-
cumpolar current (ACC), which suggests negligible chances of mixing
of sediments other than that sourced from inland Antarctica, and pro- 2.2 | Inland geology of the Prydz Bay region
vide an ideal site to examine the sediments for inferring the sub-ice
geology. In this work, we characterize the mineral population as well Prydz Bay extends laterally 700 km along the coastline in the East
as the rock fragments recovered from sites 740, 742, and 739. We Antarctic margin between 66 E and 79 E extending 90 km seaward
backtrack the rock fragments' lithologies and associated monazites (Sun et al., 2013) (Figure 1). It is bounded on the south-west by the
from the Prydz Bay to their plausible provenance in the GSM and Amery Ice Shelf, on the south-east by the Ingrid Christensen Coast
interior of PEL, which will provide the missing linkages in the recon- and in the west by MacRobertson Land. The major glacial drainage
struction of Gondwana. system in the region is the Lambert Glacier–Amery Ice Shelf system.
Geographically, the inland sector of the Prydz Bay region comprises
Proterozoic aged complexly interweaved and deformed East Antarctic
2 | G EO LO GI C A L O V ER V I E W OF T H E A R E A Shield, which can be divided into two main zones that is, the Prince
Charles Mountains-Lambert region (western sector) and the Princess
2.1 | The Prydz Bay and drilling sites Elizabeth Land (eastern sector).
Prince Charles Mountains is the group of several isolated nuna-
The Prydz Bay comprises three major sequences viz. (i) the upper flat- taks and mountain ranges exposed within the Lambert Glacier-Amery
lying sequence, (ii) the steep upper prograding sequence, and (iii) the basin of East Antarctica (Harrowfield, Holdgate, Wilson, &
lower one, more gently inclined, prograding sequence (Hambrey McLoughlin, 2005). Tingey (1991) differentiated the high-grade meta-
et al., 1991). The flat-lying sequence is up to 250 m thick and ranges morphic rocks of the northern Prince Charles Mountains (nPCM) to
from western Prydz Bay to eastern Prydz Bay, consisting of Holocene the lower grade rocks of the southern Prince Charles Mountains
diatom ooze and diatomaceous mud with ice-rafted debris lying above (sPCM). The tectonic subdivisions of the PCM and surrounding
the diamicton and diamictite of late Miocene to Quaternary age regions are shown in Figure 1. The exposed rocks of PCM are divided
(Domack, Jull, & Nakao, 1991). The second sequence is dominated by into four main tectonic domains (the Rayner Terrane, the Fisher
4 GUPTA ET AL.

F I G U R E 2 A Composite litholog of sites 739, 740 and 742 (Barron & Larsen, 1989) along with age constraints based on
biostratigraphy. (a) Litholog of site 739, (Barron & Larsen, 1989) (b) Litholog of site 740, (Barron & Larsen, 1989) (c) Litholog of site
742 (Barron & Larsen, 1989)
GUPTA ET AL. 5

Terrane, the Lambert Terrane, and the Ruker Terrane) primarily based Ice-free outcrops in Princess Elizabeth Land are exposed along
on U–Pb geochronology (e.g., Boger, Wilson, & Fanning, 2001; the 250 km long coastal fringe in form of island groups, peninsulas,
Mikhalsky, Sheraton, Laiba, & Beliatsky, 1996). (Figure 1). The Rayner and bluffs (Figure 1). The easternmost exposure is the Vestfold Hills
Terrane comprises high-grade gneisses that are reported to be com- comprising high-grade metamorphic rocks of Archean age domi-
plexly deformed and metamorphosed at 990–900 Ma (e.g., Boger, nantly derived from igneous protoliths with subordinate meta-
Carson, Wilson, & Fanning, 2000; Carson, Boger, Fanning, & sediments (Collerson, Reid, Millar, & McCulloch, 1983; Oliver, James,
Wilson, 2000; Kinny, Black, & Sheraton, 1997). The Fisher Terrane pri- Collerson, & Ryan, 1982; Sheraton, Black, & McCulloch, 1984;
marily consists of bimodal mafic and felsic intrusive rocks which are Sheraton & Collerson, 1983). The Rauer Group comprises both
metamorphosed under greenschist to amphibolite grade (Mikhalsky Archean as well as Proterozoic rocks and has been interpreted as the
et al., 1996). The Lambert Terrane dominantly consists of felsic transition zone between the Archaean rocks in the Vestfold Hills and
orthogneisses which are characterized by metamorphic zircons the Proterozoic, rocks of Prydz Bay (Sheraton & Collerson, 1983;
exhibiting Early Palaeozoic (ca. 550 Ma and ca. 490 Ma) rims around Harley, 1987a, 1987b). The Brattstrand Bluffs-Larsemann Hills domain
Archaean–Palaeoproterozoic cores (ca. 2,120 Ma and ca. 2,800 Ma; and the surrounding Islands constitute the Neoproterozoic Block of
Boger et al., 2001). These orthogneisses are interleaved with packages PEL which is reported to have preserved Grenvillian and Pan-African
of siliceous, and minor calcareous-meta-sedimentary rocks (Boger & geological history. The Brattstrand Bluffs and the Larsemann Hills
Wilson, 2005). The Ruker Terrane dominantly consists of an Archaean Block mainly comprises of granulite-grade lithology which exhibits
protolith and has a complex geological history (Boger et al., 2001; imprints of a Grenvillian (1,000 Ma), a younger Neoproterozoic
Grew, 1982; Mikhalsky, Sheraton, & Beliatsky, 2001). Meta- (700–800 Ma) as well as a Pan-African orogeny (500 Ma) (e.g., Carson,
sedimentary rocks of ca. 2,500–2,100 Ma of the Ruker Group contain Fanning, & Wilson, 1996; Tong, Wilson, & Liu, 2002; Wang
detrital zircons of 3,200 Ma, 2,800 Ma and 2,500 Ma (Phillips, et al., 2008; Arora et al., 2020 and the references therein). This ter-
Wilson, Campbell, & Allen, 2006). The Sodruzhestvo Group with its rain preserves an older Tonian-Cryogenian imprint partially modified
deposition age of 950 Ma comprises low-grade metamorphic rocks by the Pan-African tectonic activity (Arora et al., 2020; Sadiq
with detrital zircons of 2,800–2,600 Ma, 2,200–2,000 Ma, and et al., 2021). Towards 140 km westwards, the major outcrops just
1,170–950 Ma. adjacent to the Lambert graben belong to the Landing Bluff terrane

F I G U R E 3 Backscattered electron images of heavy minerals present at sites 739, 740 and 742. Red colour dots represent the position of
SEM-EDS point analyses of respective grains. (a) pyroxene, (b) garnet (c) cordierite associated with garnet (d) subhedral grain of monazite
(e) ilmenite (f) aluminosilicate with inclusion of monazite (g) zircon (h) biotite (i) amphibole associated with biotite
6 GUPTA ET AL.

that exposes the undeformed granites of the Pan-African age. A Amphibole and garnet are the most dominant heavy mineral varieties
group of scattered mountains and nunataks known as the Grove at site 739 whereas pyroxenes and amphiboles are dominant in unit I
Mountains is exposed in the interior of PEL. It has a similar metamor- of site 740. Garnet is the most dominant mineral in unit III of site 740.
phic history as the nPCM and other Pan-African dominated domains Site 742 has almost equal proportions of amphibole, garnet, and
of the Prydz Bay sector (e.g., Liu, Wang, & Jezek, 2006; Liu, Zhao, pyroxene. Following is the mineral chemical characterization of identi-
Song, Liu, & Cui, 2009). fied major phases in all the sites.

3 | M E TH O DO LO GY A N D A N A L Y TI C A L 4.1 | Garnet
TECHNIQUES
Garnet is the most dominant mineral among the heavy mineral
Twenty representative samples were selected from various depths population. The representative analyses of garnet are given in
of sites 739, 740, and 742. About 10 g of representative samples Table S1. The composition of garnet is plotted on a ternary dia-
were used for heavy media separation of the non-clay (grain size gram formulated by Mange and Morton (2007) (Figure 4). Garnets
>62 μm) fraction using bromoform. Few rock fragments were recov- from three sites overlap all the fields. Most of the garnet samples
ered from the depths of 281.8 mbsf (RF4) of Unit IV, 347.28 mbsf from all three sites plot in field A. Type A garnet represents
(RF2), and 415.19 mbsf (RF1) (Unit V). These rock fragments are the almandine composition with significant Mg and low Ca content
ice-rafted debris transported to Prydz Bay from the interior of Prin- which are likely to have been derived either from the high-grade
cess Elizabeth Land. The separated heavy mineral fractions and rock granulite-facies metasedimentary sequence (Morton, Hallsworth, &
fragments were mounted on glass slides, polished, and analysed Chalton, 2004; Sabeen, Ramanujam, & Morton, 2002) and/or
using Carl Zeiss EVO18 model Scanning electron microscope (SEM) from charnockites and intermediate felsic igneous rocks
and CAMECA SXFive Electron Probe Micro Analyser (EPMA) facility (Fitton, 1972; Green & Ringwood, 1968; Hamer & Moyes, 1982).
at Department of Geology, Institute of Science, Banaras Hindu Uni- This indicates the dominance of granulite-grade sequences in the
versity, Varanasi, India. Polished thin sections were coated with a provenance. Type B garnets are represented by low Mg and
20 nm thin layer of carbon for electron probe microanalyses using variable Ca. Two subgroups of type B are distinguished based on
LEICA-EM ACE200 carbon coater. A voltage of 15 kV and current the XCa %, Bi which has XCa < 10% and Bii which has XCa > 10%.
10 nA with a LaB6 source in the electron gun was used for the gen- Garnets of field Bii are likely to have been derived from
eration of electron beam for silicate analyses (Pandey, Rao, Pandit, amphibolite-facies metasedimentary rocks whereas the population
Sahoo, & Dhote, 2018). Andradite was used as an internal standard of field Bi represents intermediate to felsic igneous source or
to verify positions of TAP, LPET, LLIF crystals w.r.t corresponding low-grade metasedimentary rocks (if Mn >25%) (Mange &
wavelength dispersive spectrometers for silicate analyses (Pandey Morton, 2007).
et al., 2018). Quantification of Rare Earth Element (REE) in monazite
was acquired at a voltage of 15 kV and 40 nA current as well as at
15 kV and 200 nA for the calibration with higher current being used
mainly for the trace element analyses for chemical dating. Synthetic
glass standards of all REE (La to Lu) were used for calibration and
quantification. Routine calibration, acquisition, quantification, and
data processing were carried out using SxSAB version 6.1 and SX-
Results of CAMECA. REE analyses were carried out on LiF crystal
attached with Table S2. Pb, Th, and U are analysed with LPET crystal
and PET crystals. Background values for Th, U, Pb, and K are calcu-
lated from a non-linear regression of high precision wavelength dis-
persive scans (Pandey, et al., 2019). Background values for the rest
of the elements are based on linear interpolation of intensities
between paired off-peak wavelength positions (Pandey et al., 2019).

4 | RESULTS

Minerals like garnet, amphibole, pyroxene, ilmenite, magnetite, pyrite,


zircon, rutile, apatite, biotite, monazite, staurolite, epidote, olivine, and
K-feldspar as an associated phase (Figure 3) were identified as part of F I G U R E 4 Fe + Mn-Mg-Ca ternary plot (Mange & Morton, 2007)
the heavy fraction of the marine sediments besides rock fragments. of garnet showing the presence of type A, B and C classes of garnet
GUPTA ET AL. 7

Type C garnets are Mg enriched with two subdivisions based on the supply from a metabasic sequence (Figure 4) (Mange &
Mg percentage where Ci is XMg < 40% and Cii is XMg > 40%. Field Ci Morton, 2007). Source of type Cii garnets are ultramafic rocks such as
shows the dominance of garnet from the sites 739 and 740 indicating pyroxenites and peridotites or even high-pressure eclogitic rocks

F I G U R E 5 Composition plot of
amphiboles from the sediments of sites
739, 740 and 742 on the classification diagram
devised by Leake et al. (1997). (a) (Na
+ K)A < 0.50, shows the dominance of
magnesio-hornblende and tschermakite.
(b) (Na + K)A ≥ 0.5, shows the dominance of
magnesiohastingsite and ferropargasite.
(c) Composition of calcic amphiboles on Alvi
versus Aliv discrimination graph of
Leake (1965)
8 GUPTA ET AL.

which could be plausibly present in proximity as few garnets show the presence of Ca garnet suggests a metasomatic input from
composition of pyrope type. very low-grade metabasic rocks, or ultrahigh temperature
A few grains of grossular are detected from sites metamorphosed calc-silicate granulite (Mange & Morton,
739 and 740 and shown in the Type D field in Figure 4. The 2007).

F I G U R E 6 (a) Classification diagram of pyroxene after Morimoto (1988) showing plots of detrital pyroxene of site 740 and 742. (b) Plot of
Al2O3 v. FeO + MgO for distinguishing between igneous and metamorphic orthopyroxenes (field after Bhattacharya, 1971). (c) Ti versus Na + Ca
(in a.p.f.u)., (d) Ti versus Al (in a.p.f.u), and (e) Ti + Cr versus Ca (in a.p.f.u) are Discrimination diagrams of Leterrier, Maury, Thonon, Girard, and
Marchal (1982) for clinopyroxenes
GUPTA ET AL. 9

4.2 | Amphibole 4.3 | Pyroxene

The classification scheme derived by Leake et al. (1997) is used to Pyroxene was present in sediments of sites 740 and 742. The pyrox-
understand the chemical behaviour of amphiboles from different ene classification formulated by Morimoto (1988) is used to classify
sites. The representative analyses of amphiboles are given the pyroxene based on the chemical composition (Figure 6a). The rep-
in Table S2. Calcic amphiboles are present as a major phase in resentative analyses of clinopyroxene and orthopyroxene are given in
heavy mineral assemblage and their classification is shown in Tables S3 and S4, respectively. Both enstatite and ferrosilite are
Figure 5. Magnesiohornblende, ferrohornblende, tschermakite, and equally dominant varieties with the composition varying from
ferrotschermakite are present predominantly in all three sites En95Fs5Wo0 to En15Fs82Wo3. Diopside and augite are the major cli-
(Figure 5a). These amphiboles are characterized by low Na + K nopyroxene varieties identified. Diopside (Ca-rich clinopyroxene) is
content in site A. The other plot where Na + K > 0.50 at site A of present as a major phase. Diopside is generally found in ultramafic
mineral formula are classified as edenite, pargasite, ferropargasite, igneous rocks like kimberlite or lamproite. Diopside is also reported
hastingsite, and magnesiohastingsite (Figure 5b). The Al vi and Aliv from a variety of metamorphic rocks, such as in contact metamor-
values of calcic amphiboles are used to chemically distinguish igne- phosed skarns developed from high silica dolomites. Figure 6b shows
ous and metamorphic affinity amphiboles (Figure 5c). The grey that majority of orthopyroxene present are of metamorphic origin and
portion indicates the field of plutonic igneous source and the white few orthopyroxenes are of igneous affinity based on the FeO + MgO
portion outlined by the dotted line indicates the field of metamor- and Al2O3 contents (Bhattacharya, 1971).
phic calcic amphiboles. Interestingly most of the calcic amphiboles Pyroxene geochemistry shows that clinopyroxenes derived from
indicate igneous origin which covers almost all the fields of the an intermediate to acidic source rocks have Aliv content ranging from
plutonic igneous sources. 0.03 to 0.05 a.p.f.u. (atoms per formula unit on six O basis), while the

F I G U R E 7 (a) Hand specimen of rock


fragment (RF1) collected from Site 739.
(b) Photomicrograph of RF1 (white dotted
lines are showing the schistosity direction)
shows the presence of garnet
porphyroblast associated with magnetite,
fine-grained quartz, chlorite, and
muscovite defining the schistosity. (c) and
(d) Photomicrographs showing three types
of chlorites (chl-1, chl-2, and chl-3).
(e) Backscattered electron image of rock
fragment showing the presence of three
compositionally different chlorites,
muscovite, quartz, and location of multiple
monazite grains. (f) Garnet (spessartine)
shows internal schistosity and is
associated with magnetite and muscovite
10

TABLE 1 Representative analyses of garnet chlorite schist (RF1) from site 739
Wt%
Oxide grt grt grt chl_1 chl_1 chl_1 chl_1 chl_1 chl_1 chl_1 chl_1 chl_1 chl_2 chl_2 chl_2 chl_2 chl_2 chl_2 chl_2 chl_2 chl_2 chl_2 chl_2 chl_3 chl_3 chl_3 muscovite muscovite muscovite Muscovite

SiO2 36.52 36.41 36.54 25.57 29.45 25.42 24.79 25.15 24.97 28.02 29.69 30.53 26.50 26.36 26.33 26.15 28.76 28.38 27.83 26.41 25.72 25.05 25.53 33.20 31.93 34.743 45.20 46.33 45.22 46.16

TiO2 0.03 0.08 0.04 0.06 0.67 0.09 0.00 0.00 0.00 0.88 0.92 0.84 0.12 0.16 0.06 0.10 0.47 0.37 0.19 0.11 0.13 0.17 0.15 0.36 0.82 0.218 0.04 0.14 0.09 0.08

Al2O3 19.76 19.71 20.14 23.15 19.66 22.96 22.49 22.57 23.29 19.44 20.06 19.64 20.15 20.38 20.71 19.34 19.72 20.16 20.45 19.51 19.67 20.09 19.84 21.48 19.44 29.028 32.36 33.25 33.20 34.61

Cr2O3 0.03 0.03 0.02 0.09 0.00 0.06 0.00 0.00 0.04 0.04 0.06 0.00 0.00 0.09 0.00 0.11 0.00 0.00 0.08 0.08 0.14 0.04 0.11 0.00 0.00 0.055 0.00 0.00 0.00 0.00

FeO 27.48 27.16 26.78 16.78 19.51 18.79 17.58 17.42 18.43 20.82 21.01 21.48 29.44 30.29 27.32 31.42 23.37 22.20 28.34 28.28 32.51 29.84 31.22 17.05 19.02 8.970 1.75 2.46 1.98 1.83

MnO 9.01 9.03 9.54 0.29 0.19 0.25 0.05 0.25 0.10 0.47 0.45 0.28 0.38 0.61 0.50 0.27 0.21 0.37 0.75 0.30 0.45 0.69 0.64 0.08 0.22 0.075 0.00 0.00 0.00 0.00

MgO 3.18 2.84 2.97 19.27 14.95 19.07 18.52 18.88 19.17 14.12 13.94 12.18 9.91 9.05 10.50 8.79 12.11 11.41 9.92 10.94 9.00 9.12 9.09 10.26 13.18 7.175 0.70 0.84 0.72 0.47

CaO 1.88 2.65 2.23 0.01 0.00 0.01 0.00 0.00 0.02 0.07 0.05 0.15 0.00 0.02 0.00 0.00 0.09 0.00 0.08 0.05 0.06 0.02 0.11 0.00 0.00 0.056 0.00 0.00 0.00 0.00

Na2O 0.02 0.06 0.04 0.00 0.10 0.01 0.00 0.01 0.04 0.52 0.00 0.12 0.05 0.03 0.06 0.06 0.09 0.05 0.05 0.03 0.00 0.00 0.00 0.15 0.15 0.635 1.94 1.77 1.94 2.50

K2O 0.00 0.01 0.03 0.03 2.25 0.02 0.00 0.00 0.05 1.88 2.00 1.77 0.29 0.14 0.26 0.34 1.18 1.41 0.58 0.33 0.00 0.00 0.00 3.38 4.51 4.937 8.42 8.80 8.88 7.81

Total 98.04 97.99 98.35 85.30 87.10 86.86 83.43 84.28 86.49 86.85 88.96 87.27 86.85 87.54 85.74 86.52 86.34 84.39 88.67 86.40 87.97 85.34 87.29 86.28 89.85 86.143 90.42 93.59 92.02 93.46

Si 3.003 2.996 2.990 5.291 6.124 5.233 5.290 5.310 5.17 5.92 6.10 6.34 5.775 5.741 5.747 5.794 6.109 6.133 5.911 5.77 5.65 5.61 5.64 6.806 6.480 6.79 6.338 6.299 6.256 6.240

Ti 0.002 0.005 0.002 0.009 0.105 0.015 0.011 0.019 0.01 0.14 0.14 0.13 0.020 0.026 0.010 0.016 0.076 0.061 0.031 0.02 0.02 0.03 0.02 0.056 0.125 0.03 0.005 0.015 0.009 0.008

Al 1.928 1.924 1.955 5.648 4.818 5.569 5.656 5.615 5.68 4.84 4.85 4.81 5.175 5.230 5.328 5.053 4.938 5.135 5.120 5.03 5.09 5.31 5.17 5.190 4.650 6.69 5.349 5.329 5.413 5.513

Cr 0.000 0.000 0.000 0.015 0.000 0.009 0.000 0.000 0.01 0.01 0.01 0.00 0.000 0.016 0.000 0.000 0.000 0.000 0.014 0.01 0.02 0.01 0.02 0.000 0.000 0.01 0.000 0.000 0.000 0.000

Fe 1.902 1.881 1.845 2.905 3.394 3.234 3.137 3.076 3.19 3.68 3.61 3.73 5.366 5.516 4.987 5.824 4.153 4.013 5.033 5.17 5.97 5.59 5.77 2.924 3.229 1.47 0.205 0.279 0.229 0.207

Mn 0.632 0.634 0.665 0.050 0.034 0.043 0.009 0.044 0.02 0.09 0.08 0.05 0.070 0.112 0.092 0.050 0.037 0.068 0.135 0.06 0.08 0.13 0.12 0.013 0.038 0.01 0.000 0.000 0.000 0.000

Mg 0.393 0.351 0.365 5.946 4.634 5.853 5.893 5.941 5.91 4.45 4.27 3.77 3.220 2.937 3.416 2.902 3.834 3.677 3.140 3.57 2.95 3.05 2.99 3.134 3.987 2.09 0.147 0.171 0.148 0.094

Ca 0.166 0.235 0.197 0.002 0.000 0.003 0.000 0.000 0.00 0.02 0.01 0.03 0.000 0.006 0.000 0.000 0.021 0.000 0.018 0.01 0.01 0.01 0.03 0.000 0.000 0.01 0.000 0.000 0.000 0.000

Na 0.004 0.009 0.006 0.000 0.042 0.003 0.001 0.005 0.02 0.21 0.00 0.05 0.021 0.014 0.025 0.027 0.037 0.022 0.022 0.01 0.00 0.00 0.00 0.060 0.059 0.24 0.526 0.466 0.520 0.656

K 0.000 0.001 0.003 0.008 0.596 0.006 0.000 0.000 0.01 0.51 0.52 0.47 0.079 0.040 0.072 0.095 0.319 0.388 0.158 0.09 0.00 0.00 0.00 0.883 1.168 1.23 1.507 1.527 1.566 1.347

Total 8.031 8.035 8.028 19.874 19.747 19.968 19.976 19.971 20.01 19.87 19.59 19.38 19.727 19.637 19.677 19.761 19.524 19.497 19.582 19.74 19.80 19.73 19.76 19.067 19.737 18.57 14.077 14.085 14.142 14.065

Py 12.7 11.3 11.9

Alm 61.5 60.7 60.1

Gro 5.4 7.6 6.4

Sp 20.4 20.4 21.7

XMg 0.67 0.58 0.64 0.65 0.66 0.65 0.55 0.54 0.50 0.38 0.35 0.41 0.33 0.48 0.48 0.38 0.41 0.33 0.35 0.34 0.52 0.55 0.59

Note: Chlorite Cation calculations on the basis of 28 Oxygen. Phengite Cation calculations on the basis of 22 Oxygen. Garnet Cation calculations on the basis of 12 Oxygen.
GUPTA ET AL.
GUPTA ET AL. 11

F I G U R E 8 BSE images of chlorite schist rock fragment (RF2). Photomicrographs showing the presence of banding and schistosity of fine-
grained chlorite, phengite and quartz (a) and (b) confirm metamorphic origin. (c) Chlorite also shows association with zircon (20 μm). (d) phengite
is associated with iron oxide and sodic plagioclase. (e) and (f) are BSE images of well-developed phengite and chlorite that define the schistosity in
the rock fragments

clinopyroxenes of mafic volcanic origin have Alivcontent higher than forsterite with MgO 53% which suggests its sourcing either from
0.05 (Rodriguez-Gonzalez et al., 2012). Therefore, clinopyroxene with ultramafics like peridotite/pyroxenite or a very ultra-high temperature
Aliv higher than 0.05 is considered for geochemical discriminant dia- granulite facies. The presence of olivine also suggests that sediments
grams. The results show that most of the samples indicate the tholei- are immature and have experienced negligible reworking and
itic basalt as a prime source rock (Figure 6c–e). Few grains show recycling.
affinity towards calc-alkaline basalt as well. Ti + Cr versus Ca discrimi-
nation graph shows the orogenic basaltic source for clinopyroxenes
indicating genesis of basic volcanic source in the provenance area. 4.6 | Rock fragments (RF)

Besides the heavy minerals, we have analysed the detrital fragments


4.4 | Ilmenite which comprise two or more associated mineral phases and preserve
the textural properties of its source rock. Rock fragments present as
Ilmenite dominates the heavy mineral population of sites 739,740, the Ice Rafted Debris (IRDs) in sediments shed insights on the sub-ice
and 742. According to Basu and Molinaroli (1991), ilmenite grains with geology of East Antarctic terrain. Four different rock fragments were
TiO2 contents between 50 and 60 wt% are more prevalent in meta- recovered from ODP site 739 and site 742.
morphic rocks, but they also occur in igneous rocks with TiO2 ranging Detailed microscopy and EPMA analyses confirm the presence
between 40 and 50 wt%. Schneiderman also (Schneiderman, 1995) of low-grade metamorphic rock fragments as IRDs from the investi-
noted that ilmenite from metamorphic sources is richer in TiO2 than gated marine sediments. These include garnet-chlorite schist, chlo-
in the igneous rocks. SEM–EDX analysis show both the types of rite schist, and a fine-grained quartz biotite schist containing iron
ilmenites (with TiO2 content 50 to 60 wt% and TiO2 content 40 to oxides (recovered from site 739). One granitic rock fragment is also
50 wt%) are present in these sites suggesting the igneous and meta- recovered from site 742. Based on the physical and petrological
morphic types of lithology in the provenance. examination along with the EPMA analysis, all four lithic fragments
are different in colour, texture, and mineralogical composition. RF1
is medium to fine-grained, dark green, and preserves schistosity.
4.5 | Olivine Bands of mica and chlorite are present in RF2. RF4 is very fine-
grained and dark. Also, RF1 (Depth-415.19 mbsf) and RF2 (Depth-
Rare and sporadic olivine are reported from site 740. The representa- 347.28 mbsf) were recovered from Unit V of site 739, and RF4 from
tive data is given in Table S4. The composition of olivine is mainly Unit IV (Depth-281.8 mbsf) of site 739. RF3 was recovered from
12

TABLE 2 Representative analyses of Chlorite schist (RF2) from site 739


Wt% 6/1 7/1 8/1 9/1 10/1 13/1 15/1 16/1 12/1 14/1 52/1 53/1 54/1 55/1 56/1 57/1 58/1 59/1 63/1 64/1 65/1 66/1 67/1
Oxide plag plag plag plag plag plag phengite phengite chl chl chl chl chl chl chl chl chl chl chl chl chl chl chl
SiO2 63.70 64.04 67.59 62.34 63.85 68.13 46.43 46.61 27.76 30.46 29.56 27.65 29.99 29.22 29.82 33.26 28.82 30.51 28.43 29.76 29.51 36.10 30.82
TiO2 0.00 0.00 0.12 0.01 0.00 0.00 0.64 0.76 0.48 1.36 0.10 0.16 0.11 0.47 0.51 1.44 0.00 0.19 0.23 0.16 0.52 1.68 0.25
Al2O3 22.31 21.59 19.87 22.33 22.02 19.84 28.49 28.45 19.49 19.21 20.07 19.29 21.06 19.22 20.32 20.39 22.32 20.10 21.55 22.64 21.28 20.82 22.14
Cr2O3 0.00 0.00 0.00 0.02 0.00 0.05 0.13 0.28 0.13 0.19 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.06 0.03 0.07 0.15 0.17
FeO 0.11 0.66 0.01 0.00 0.00 0.30 5.31 5.61 22.70 22.56 22.51 20.61 21.27 20.75 19.92 18.10 21.13 19.64 18.23 17.33 18.25 15.51 18.97
MnO 0.00 0.00 0.07 0.07 0.00 0.08 0.07 0.03 0.33 0.48 0.17 0.17 0.16 0.27 0.16 0.01 0.12 0.16 0.36 0.25 0.23 0.21 0.21
MgO 0.00 0.00 0.02 0.00 0.00 0.00 1.61 1.82 12.05 14.41 12.31 13.03 12.82 13.85 13.43 10.21 13.36 13.36 13.15 11.69 12.94 8.57 12.06
CaO 2.99 2.68 0.35 3.89 3.53 0.24 0.00 0.00 0.05 0.04 0.00 3.72 0.01 0.01 0.00 0.01 0.00 0.00 0.10 0.12 0.11 0.06 0.16
Na2O 9.22 9.87 9.57 9.14 8.81 10.86 0.14 0.24 0.04 0.01 0.02 0.06 0.02 0.03 0.02 0.02 0.03 0.01 0.05 0.08 0.07 0.05 0.06
K2O 0.12 0.10 0.14 0.13 0.16 0.08 10.43 10.25 0.50 0.73 0.79 0.67 0.69 0.86 0.88 2.58 0.07 0.98 0.22 0.67 0.76 4.64 1.09
Total 98.49 98.94 97.76 98.02 98.48 99.63 93.42 94.05 83.87 89.88 85.52 85.36 86.13 84.67 85.07 86.02 85.84 84.94 82.60 82.88 83.84 87.93 86.12
Si 11.379 11.429 12.012 11.254 11.411 11.951 6.464 6.442 6.049 6.161 6.250 5.922 6.237 6.206 6.249 6.817 6.001 6.390 6.084 6.285 6.217 7.183 6.331
Ti 0.000 0.000 0.000 0.000 0.000 0.000 0.067 0.079 0.079 0.207 0.015 0.026 0.018 0.075 0.081 0.222 0.000 0.030 0.037 0.025 0.082 0.251 0.038
Al 4.696 4.541 4.162 4.751 4.638 4.102 4.675 4.634 5.006 4.579 5.002 4.869 5.161 4.811 5.018 4.926 5.477 4.960 5.435 5.634 5.282 4.883 5.361
Cr 0.000 0.000 0.000 0.000 0.000 0.000 0.014 0.030 0.022 0.030 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 0.006 0.011 0.024 0.028
Fe 0.016 0.098 0.002 0.000 0.000 0.044 0.619 0.648 4.137 3.817 3.981 3.691 3.699 3.686 3.491 3.103 3.678 3.439 3.263 3.060 3.214 2.580 3.258
Mn 0.000 0.000 0.000 0.000 0.000 0.000 0.008 0.003 0.062 0.082 0.030 0.030 0.027 0.049 0.028 0.002 0.021 0.028 0.066 0.044 0.042 0.035 0.036
Mg 0.000 0.000 0.000 0.000 0.000 0.000 0.333 0.374 3.915 4.347 3.880 4.160 3.976 4.386 4.195 3.121 4.146 4.172 4.197 3.682 4.064 2.542 3.693
Ca 0.572 0.513 0.067 0.753 0.676 0.045 0.000 0.000 0.011 0.008 0.000 0.854 0.003 0.002 0.000 0.001 0.000 0.000 0.023 0.027 0.026 0.014 0.035
Na 3.194 3.417 3.296 3.201 3.054 3.693 0.037 0.064 0.017 0.003 0.009 0.023 0.008 0.011 0.009 0.009 0.010 0.003 0.021 0.032 0.027 0.020 0.024
K 0.026 0.022 0.031 0.030 0.037 0.019 1.853 1.807 0.138 0.187 0.214 0.183 0.183 0.232 0.235 0.674 0.020 0.261 0.061 0.182 0.205 1.178 0.286
Total 19.884 20.020 19.571 19.988 19.817 19.854 14.070 14.083 19.435 19.422 19.381 19.757 19.311 19.458 19.305 18.875 19.353 19.283 19.198 18.977 19.170 18.711 19.091
An 15.1 13.0 2.0 18.9 18.0 1.2
Ab 84.2 86.5 97.1 80.3 81.1 98.3
Or 0.7 0.6 0.9 0.8 1.0 0.5

Note: Chlorite Cation calculations on the basis of 28 Oxygen. Phengite and muscovite Cation calculations on the basis of 22 Oxygen. Feldspar Cation calculations on the basis of 32 Oxygen.
GUPTA ET AL.
GUPTA ET AL. 13

F I G U R E 9 (a) Granitic rock fragment


recovered from sediments of Site 742.
(b) photomicrograph shows the feldspar
and (c) the BSE image shows the presence
of K-feldspar, plagioclase feldspar and
apatite

Unit V of site 742. RF3 (Granitic rock) is very light coloured and does event is also supported by the presence of the third type of chlorite-like
not show any planar fabric. Following is the detailed fragment-wise composition (chl-3) with XMg ≈ 0.5 and unusual 3–5% K2O content,
description: inferred to be a product of retrogressive metamorphism of the detrital
biotite. The minerals present in this rock fragment are spessartine + chl-
1 + chl-2 + muscovite + titanomagnetite + chl-3 + monazite. The rock
4.6.1 | Garnet chlorite schist (RF1) fragment composition describes greenschist facies metapelitic assem-
blage. Garnet is texturally constrained with chlorite. The internal schis-
A euhedral porphyroblast of garnet along with well-defined schistosity tosity is mainly defined by chlorite and quartz. Also, the internal and
defines the first rock fragment to be of metamorphic origin (Figure 7a,b). external schistosity is in continuation hence the garnet is either syn tec-
The representative analyses of rock fragment phases are given in tonic or post tectonic. Garnet does not show any evidence of retrograde
Table 1. The schistosity is defined mainly by chlorite and muscovite alteration.
(Figure 7c–e). The internal schistosity inside the garnet porphyroblast is
defined by quartz and iron oxides inclusions (Figure 7b,f). The garnet
composition is Alm62–60Py13–12Sp22–20Gr5–6 and corresponds to an 4.6.2 | Chlorite schist (RF2)
almandine-rich variant with significant spessartine content inferred to
represent low-grade metamorphic facies of pelitic protolith. The chemical The second rock fragment is fine-grained chlorite schist. Schistosity
composition of chlorite varies significantly from XMg = 0.33 to 0.67 is defined by the fine bands of phengite and chlorite (Figure 8a,b).
suggesting at least three different types of chlorites (Figure 7b). The high The major assemblage is defined by chlorite+phengite+quartz
XMgchlorite (chl-1) is present as the primary phase which exhibits the +plagioclase+iron oxide+zircon (Figure 8c–f) indicating a pelitic
development of Fe-rich chlorite (chl-2) at the rim suggesting low- protolith of the rock. The representative analyses are given in
temperature conditions (Figure 7e). The high XMg(chl-1) present at the Table 2. Compositionally, chlorite varies from XMg0.49 to XMg0.55
core is a relict of the detrital chlorite that has metamorphosed to high which signifies a single event of chlorite formation. The composi-
XFe chlorite (chl-2) during low-grade metamorphism. This metamorphic tion and texture of the rock indicate the presence of a low-grade
14

TABLE 3 Representative analyses of Granite (RF3) from site 742


126/ 127/ 132/ 128/ 129/ 130/
68/1 69/1 70/1 71/1 72/1 73/1 74/1 83/1 84/1 85/1 89/1 1 1 75/1 76/1 77/1 78/1 79/1 80/1 81/1 82/1 86/1 87/1 88/1 90/1 91/1 1 1 1 1 131/1
Wt% K K K K K K K K K K K
Oxide feld feld feld feld feld feld feld feld feld feld feld K feld K feld plag plag plag plag plag plag plag plag plag plag plag plag plag plag qtz qtz qtz qtz

SiO2 63.16 63.17 63.19 62.87 62.95 62.84 63.04 63.59 63.72 63.40 62.58 63.33 63.36 65.66 67.17 67.74 68.15 67.43 66.33 66.86 67.75 66.59 65.63 66.01 67.32 67.16 67.63 97.45 98.37 98.26 98.28

Al2O3 17.62 17.97 17.91 17.64 17.75 17.76 18.06 17.71 17.81 17.94 17.94 17.69 17.92 18.76 19.34 19.58 19.48 19.40 19.08 18.82 19.55 19.19 19.32 18.96 19.52 19.14 19.08 0.00 0.00 0.00 0.00

FeO 0.05 0.05 0.12 0.07 0.15 0.00 0.00 0.00 0.03 0.03 0.00 0.00 0.00 0.00 0.15 0.00 0.00 0.00 0.00 0.06 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

CaO 0.00 0.00 0.05 0.00 0.00 0.00 0.04 0.00 0.00 0.00 0.05 0.03 0.01 1.01 0.56 0.50 0.45 0.53 0.56 0.36 0.39 0.43 0.51 0.44 0.43 0.41 0.43 0.00 0.00 0.05 0.00

Na2O 0.45 0.38 0.30 0.33 0.27 0.30 0.30 0.42 0.23 0.27 0.94 0.41 0.27 10.79 11.47 11.53 11.59 8.96 11.52 11.25 11.27 11.47 10.47 11.28 11.35 10.76 11.51 0.00 0.00 0.00 0.00

K2O 16.70 16.76 16.83 16.71 16.84 16.56 17.41 16.15 16.68 16.84 16.11 16.40 16.87 0.04 0.02 0.00 0.00 0.00 0.00 0.03 0.11 0.00 0.01 0.00 0.01 0.00 0.02 0.00 0.08 0.00 0.00

Total 98.00 98.34 98.40 97.62 97.95 97.45 98.85 97.88 98.47 98.48 97.61 97.85 98.43 96.26 98.41 99.35 99.67 96.33 97.49 97.38 99.07 97.69 95.94 96.69 98.63 97.47 98.66 97.45 98.29 98.31 98.28

Si 11.98 11.95 11.95 11.98 11.96 11.98 11.91 12.03 12.01 11.97 11.92 12.01 11.97 11.94 11.93 11.93 12.10 12.10 11.91 12.00 11.95 11.93 11.93 11.94 11.93 12.00 11.98

Al 3.94 4.00 3.99 3.96 3.98 3.99 4.02 3.95 3.96 3.99 4.03 3.95 3.99 4.02 4.05 4.06 4.10 4.10 4.04 3.98 4.06 4.05 4.14 4.04 4.08 4.03 3.98

Fe(ii) 0.01 0.01 0.02 0.01 0.02 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.01 0.00 0.00 0.00 0.00 0.00 0.00 0.00

Ca 0.00 0.00 0.01 0.00 0.00 0.00 0.01 0.00 0.00 0.00 0.01 0.01 0.00 0.20 0.11 0.09 0.10 0.10 0.11 0.07 0.07 0.08 0.10 0.09 0.08 0.08 0.08

Na 0.17 0.14 0.11 0.12 0.10 0.11 0.11 0.15 0.08 0.10 0.35 0.15 0.10 3.80 3.95 3.93 3.12 3.12 4.01 3.91 3.85 3.98 3.69 3.96 3.90 3.73 3.95

K 4.04 4.04 4.06 4.06 4.08 4.03 4.19 3.90 4.01 4.05 3.91 3.97 4.06 0.01 0.00 0.00 0.00 0.00 0.01 0.01 0.02 0.00 0.00 0.00 0.00 0.00 0.00

Total 20.14 20.14 20.14 20.13 20.14 20.10 20.24 20.03 20.06 20.11 20.21 20.08 20.12 19.97 20.04 20.01 19.42 19.42 20.08 19.97 19.97 20.05 19.86 20.02 19.99 19.84 20.00

An 0.00 0.01 0.25 0.00 0.00 0.00 0.17 0.00 0.00 0.01 0.26 0.15 0.06 4.92 2.61 2.33 2.11 3.20 2.63 1.72 1.86 2.03 2.61 2.11 2.06 2.08 2.02

Ab 3.95 3.30 2.60 2.93 2.35 2.66 2.54 3.81 2.07 2.36 8.10 3.62 2.37 94.87 97.28 97.79 98.08 97.21 97.22 98.13 97.52 98.11 97.32 97.91 97.90 98.03 97.87

Or 96.25 96.68 97.16 97.09 97.73 97.40 97.30 96.28 97.94 97.62 91.64 96.23 97.57 0.21 0.11 0.00 0.00 0.00 0.15 0.15 0.62 0.00 0.07 0.00 0.04 0.00 0.10
GUPTA ET AL.
GUPTA ET AL. 15

F I G U R E 1 0 (a) Rock fragment of magnetite quartz schist, recovered from sediments of site 739. (b) and (c) are the BSE images showing the
presence of iron oxides, quartz, apatite, biotite, and Na-plagioclase

metamorphic terrane in the source area. Plagioclase present is of phases while chlorite and apatite are identified as accessory phases.
albitic composition (An1–20Ab80–98) confirming very low-grade Quartz, plagioclase, and biotite flakes define the schistosity
metamorphism. (Figure 10b,c). The representative analyses of magnetite-rich quartz
schist are given in Table 4. The rock is extensively enriched in iron
oxide which might correspond to the iron oxide ore associations pre-
4.6.3 | Granitic rock (RF3) sent in the provenance. The assemblage is represented by magnetite
+ plagioclase + biotite (phlogopitic) + apatite + chlorite + quartz.
The third rock fragment comprises K-feldspar, plagioclase, and quartz as The phlogopitic biotite is interpreted through the SEM-EDS analyses
major phases (Figure 9a,b) conforming to granite mineralogy. The repre- (Figure 10c) while chlorite is Mg-rich with XMg  0.72. This rock frag-
sentative analyses of granite are given in Table 3. Inequigranular texture ment may have been derived from a felsic volcanic rock.
with porphyries of feldspars in quartz/feldspar groundmass support an
igneous origin (Figure 9b,c). Apatite is present as accessory phases. K-
feldspar composition varies from Ab4An0Or96 to Ab2An0Or98. The tex- 4.7 | Monazite geochronology
tural features and modal proportion of phases exhibit an intermediate
pressure series mobile belt intruded by sub-solvus granite or a leucosome Twenty-five representative grains of detrital monazites from site
abundantly exposed in PEL outcrops. 740 were analysed and chemically dated, from two representative
depths viz 159 and 178 mbsf. A total of ninety-one points were
analysed in twenty-five grains, using an electron microprobe. The rep-
4.6.4 | Quartz magnetite schist (RF4) resentative analyses are given in Table S5. Detrital monazites (MZ 1,
2, 3, 6, and 10) from depth 178 mbsf are subhedral to anhedral in
The fourth rock fragment (Figure 10a) represents a very fine-grained shape and ranges from 300 to 50 μm in size suggesting abrasion/
rock composed of plagioclase, quartz, biotite, and iron oxide as major rounding through physical wear and tear and distal sourcing while
16

TABLE 4 Representative analyses of magnetite schist (RF4) from site 739

99/1 103/1 108/1 115/1 125/1 110/1 125/1 71/1 74/1 67/1 72/1 117/1 104/1 105/1 106/1
Wt% Oxide plag plag plag plag plag K-feld K-feld chl chl phengite phengite qtz magnetite magnetite magnetite
SiO2 67.93 67.50 67.37 67.72 67.54 67.67 67.54 25.78 27.97 50.91 48.56 98.52 0.00 0.59 0.00
TiO2 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.10 0.04 0.36 0.06 0.00 0.00 0.00 0.00
Al2O3 19.09 19.43 19.77 19.11 19.31 18.87 19.31 23.23 25.55 24.21 28.18 0.00 0.00 0.36 0.00
Cr2O3 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.03 0.06 0.03 0.00 0.00 0.00 0.00 0.00
BaO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
FeO 0.27 0.31 0.46 0.42 0.35 0.40 0.35 14.79 13.68 2.17 5.13 0.59 83.96 84.38 85.52
MnO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.53 0.57 0.04 0.13 0.00 0.00 0.00 0.00
MgO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 21.85 18.85 0.81 6.50 0.00 0.00 0.00 0.00
CaO 0.30 0.27 0.67 0.32 0.21 0.06 0.21 0.00 0.06 0.02 0.08 0.00 0.08 0.05 0.07
Na2O 11.22 10.68 11.21 11.17 11.04 11.29 11.04 0.08 0.71 1.18 3.93 0.00 0.00 0.00 0.00
K2O 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.06 0.34 5.04 0.51 0.00 0.00 0.18 0.03
Total 98.77 99.52 99.49 98.74 98.45 98.29 98.45 86.78 88.11 84.86 93.26 99.11 84.04 85.58 85.62
Si 12.009 11.986 11.869 11.991 11.979 12.263 12.229 5.219 5.507 7.338 6.461
Ti 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.015 0.006 0.039 0.006
Al 3.978 4.066 4.105 3.987 4.036 2.572 2.629 5.542 5.927 4.113 4.419
Cr 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 0.009 0.003 0.000
Ba 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Fe 0.040 0.047 0.068 0.062 0.052 0.086 0.074 2.504 2.253 0.261 0.571
Mn 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.091 0.095 0.005 0.014
Mg 0.000 0.000 0.000 0.000 0.000 0.000 0.000 6.594 5.532 0.174 1.290
Ca 0.056 0.050 0.126 0.061 0.041 0.010 0.032 0.001 0.012 0.004 0.012
Na 3.847 3.677 3.830 3.835 3.795 2.193 2.141 0.032 0.272 0.330 1.015
K 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.016 0.085 0.927 0.087
Total 19.931 19.825 19.998 19.937 19.903 17.123 17.106 20.016 19.698 13.193 13.874
An 1.4 1.4 3.2 1.6 1.1 100.1 100.2
Ab 98.8 98.9 97.1 98.6 99.0 0.0 0.0
Or 0.0 0.0 0.0 0.0 0.0 0.1 0.1
XMg 0.72 0.71
GUPTA ET AL.
GUPTA ET AL. 17

F I G U R E 1 1 (a) Back-scattered electron microscopic images of detrital monazites recovered from site 740 at the depth of 178.91 mbsf.
(b) BSE images of detrital monazites were recovered from site 740 at the depth of 159.47 mbsf. (c) BSE images of monazites present in garnet
chlorite schist (RF1), recovered from site 739 at the depth of 415.19 mbsf

MZ-4,5,7,8, and 9 are elongated and well-formed with an intact grain from 0.025 to 0.046 a.p.f.u while Ca value range from 0.027 to 0.036
boundary indicating limited or no chemical reaction or dissolution a.p.f.u. The narrow range of compositions signifies low to no chemical
(Figure 11a). Monazites (MZ-11-MZ19, Figure 11b) belonging to zoning in these monazites.
159 mbsf are euhedral in shape but show physical abrasion texture Variation diagram of monazite involving the solid solution of
and appear to have experienced physical weathering. These are Ce- monazite-cheralite-huttonite (Bowie & Horne, 1953; Linthout, 2007;
rich with its value ranging from 0.360 to 0.467 a.p.f.u (formula calcu- Pabst & Hutton, 1951) depicts a lack of any significant chemical
lated based on 4O). Th varies from 0.042 to 0.116 a.p.f.u while Ca changes suggesting negligible or no chemical alteration of the REEs
value range from 0.025 to 0.097 a.p.f.u. Monazites found in the rock during transportation and deposition of these phases (Figure 12a).
fragment of garnet chlorite schist are shown in Figure 11c. All the However, the detrital monazites show a large compositional variation.
monazite grains are anhedral, close to 50 μm in size and matrix mona- Th + U content of detrital monazites ranges from very high to low.
zites are associated with chlorite and quartz. These monazites are Ce- Almost all detrital grains have Th + U content higher than RF mona-
rich with the value ranging from 0.371 to 0.415 a.p.f.u. Th value varies zites. However, the REE content of both RF and detrital monazites
18 GUPTA ET AL.

F I G U R E 1 2 (a) 2REEPO4–CaTh(PO4)2–2ThSiO4 diagram of monazite (Linthout, 2007) showing position of monazites from the studies
samples. (b) (Th + U) versus Si, (c) (Th + U) versus Si + Ca and (d) (Th + U) versus Ca are the plots of monazite composition illustrating chemical
exchanges

are similar (Figure 12b–d). Si + Ca versus Th + U plot (Figure 12c) 500 Ma age in both types of monazites. RF monazites are relatively
indicate the dominance of the cheralite exchange [(Th, U)$Ca] and Ce-enriched and Th-poor as compared to detrital monazites. The
possible metamorphic origin (Spear & Pyle, 2002). None of the mona- other cluster show a dominance of 910 Ma with 30% of its population
zites falls in the field of the huttonite indicating the absence of any suggesting a presence of 1,100 Ma age.
granitic monazite (Broska, Petrík, & Williams, 2000) (Figure 12c,d). On Nine grains of monazite present in RF1 (garnet chlorite schist)
account of these considerations, the monazite ages are considered were analysed and chemically dated. Two age populations are
suitable for geochronological backtracking of the provenance. The observed from the seventeen-point analysis of nine grains. 30% frac-
probability density plot for point age data of monazite grains of each tion yielded 454 ± 24 Ma (near Pan-African age) and the 70% fraction
sample is computed using an unmixing of data method following the yielded 686.1 ± 17 Ma age representing a Tonian-Cryogenian event
isoplot program (Ludwig, 2003) and the representative analyses are (Figure 13c). 700 Ma ages also correspond to the event reported
given in Table 5. Declustering of the age data is carried out based on from the coastal outcrop of PEL (e.g., Arora et al., 2020; Sadiq
the probability graphs and two major groups are represented sepa- et al., 2021), though from different types of rocks. For further evalua-
rately as shown in Figure 13a,b. The plots indicate the dominance of tion, age versus Ce, Th, and Y weight percentages of both types of
TABLE 5 Chemical analysis of monazites present in garnet chlorite schist (RF 1) (4 O basis)

4/1 5/1 7/1 8/1 9/1 10/1 11/1 12/1 13/1 15/1 16/1 18/1 19/1 20/1 21/1
GUPTA ET AL.

SiO2 0.00 0.00 1.14 0.00 0.00 0.00 0.00 1.18 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Al2O3 0.00 0.00 0.27 0.00 0.00 0.24 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
FeO 0.45 0.44 0.47 0.32 0.58 0.29 0.37 0.53 0.35 0.44 0.37 0.44 0.32 0.40 0.31
P2O5 30.61 30.69 34.41 31.36 30.79 31.66 30.75 31.47 30.74 30.35 31.68 30.69 31.55 32.27 33.10
CaO 0.82 0.89 0.87 0.92 0.98 0.86 0.80 0.92 0.94 0.73 0.68 0.76 1.01 0.86 0.88
Y2O3 1.94 1.98 1.39 1.88 0.82 1.76 2.05 2.06 1.86 1.67 1.74 1.87 1.85 1.67 1.98
La2O3 13.10 13.42 12.86 13.37 14.72 13.87 13.48 12.59 13.39 15.07 13.98 13.40 13.68 14.48 13.28
Ce2O3 27.56 27.72 26.15 28.48 28.05 28.04 27.56 27.04 27.17 28.52 28.39 27.51 27.68 28.14 26.84
Nd2O3 13.05 13.41 12.46 13.57 11.85 13.21 13.26 13.18 13.13 12.49 13.60 13.19 12.96 12.62 12.44
Sm2O3 3.04 3.11 2.96 2.94 2.47 3.17 2.91 2.98 3.36 2.81 2.94 3.12 3.10 2.90 2.76
Gd2O3 2.75 2.57 2.54 2.39 1.66 2.58 2.78 2.57 2.68 2.37 2.67 2.65 2.77 2.73 2.62
PbO 0.45 0.52 0.44 0.47 0.43 0.50 0.45 0.51 0.52 0.44 0.48 0.44 0.46 0.49 0.52
ThO2 3.77 3.89 3.50 3.30 2.94 3.15 3.61 3.64 4.24 2.97 2.87 3.67 5.30 3.95 4.45
UO2 1.28 1.20 1.24 1.23 1.23 1.17 1.35 1.26 1.28 1.28 1.23 1.11 1.30 1.25 1.28
Total 100.02 101.05 101.69 101.45 97.34 101.42 100.53 100.89 100.72 100.14 101.78 99.89 102.94 102.71 101.51
Age (Ma) 450 614 603 501 470 775 651 767 654 834 681 576 624 290 702
Age err 51 81 51 39 45 61 54 62 46 62 61 82 50 77 47
Si 0.000 0.000 0.041 0.000 0.000 0.000 0.000 0.044 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Al 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
P 1.029 1.023 1.048 1.035 1.043 1.039 1.028 1.007 1.023 1.022 1.038 1.029 1.026 1.041 1.059
Ca 0.035 0.038 0.034 0.038 0.042 0.036 0.034 0.037 0.040 0.031 0.028 0.032 0.042 0.035 0.036
Y 0.041 0.042 0.027 0.039 0.017 0.036 0.043 0.041 0.039 0.035 0.036 0.039 0.038 0.034 0.040
La 0.192 0.195 0.171 0.192 0.217 0.198 0.196 0.176 0.194 0.221 0.200 0.196 0.194 0.204 0.185
Ce 0.400 0.400 0.344 0.406 0.411 0.398 0.398 0.374 0.391 0.415 0.402 0.399 0.389 0.393 0.371
Pr 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Nd 0.185 0.189 0.160 0.189 0.169 0.183 0.187 0.178 0.184 0.177 0.188 0.187 0.178 0.172 0.168
Sm 0.042 0.042 0.037 0.039 0.034 0.042 0.040 0.039 0.045 0.039 0.039 0.043 0.041 0.038 0.036
Gd 0.036 0.034 0.030 0.031 0.022 0.033 0.036 0.032 0.035 0.031 0.034 0.035 0.035 0.034 0.033
Pb 0.005 0.005 0.004 0.005 0.005 0.005 0.005 0.005 0.006 0.005 0.005 0.005 0.005 0.005 0.005
Th 0.034 0.035 0.029 0.029 0.027 0.028 0.032 0.031 0.038 0.027 0.025 0.033 0.046 0.034 0.038
U 0.011 0.010 0.010 0.011 0.011 0.010 0.012 0.011 0.011 0.011 0.011 0.010 0.011 0.011 0.011
Total 1.988 1.991 1.933 1.991 1.979 1.987 1.990 1.977 1.989 1.993 1.984 1.986 1.988 1.980 1.966
19
20 GUPTA ET AL.

monazites have been plotted (Figure 14a–c). The concentration of


Th, Y, and Ce in detrital monazites is highly variable. It indicates the
sourcing from multiple metamorphic terrains. Whereas monazites
associated with rock fragments are not showing any major variation in
concentration of Th, Y, and Ce. Significant variation in 500 Ma age
points suggests the protracted nature of the Pan-African orogenic
activity.

5 | DI SCU SSION

The texture and chemical composition of heavy mineral assemblages


recovered from sites 739, 740, and 742 exhibits dominance of both
magmatic as well as metamorphic affinities. The classification of gar-
net based on Mange and Morton (2007) indicate the presence of
high-grade amphibolite to granulite facies metasedimentary sequence
(Morton et al., 2004; Sabeen et al., 2002) as well as charnockites and
intermediate felsic igneous rocks (Fitton, 1972; Green &
Ringwood, 1968; Hamer & Moyes, 1982) in the provenance. Sourcing
from skarn and low-grade metabasic rocks is also suggested by the
grossular content of garnets. Different types of amphiboles are classi-
fied in the discrimination diagram of Leake et al. (1965) (based on Alvi
and Aliv values of calcic amphiboles) shows the presence of
plutonic igneous sourcing. Classification of pyroxene based on
Morimoto (1988) displays the presence of enstatite, ferrosilite, augite,
and diopside. Classification based on Leterrier et al. (1982) enables us
to differentiate between metamorphic and igneous orthopyroxene.
Further, clinopyroxene cation-based classification suggests the pres-
ence of tholeiitic to calc-alkaline basalt as a prime source rock for cli-
nopyroxene of igneous affinity.
The presence of igneous origin olivine, pyroxenes (orthopyroxene/
clinopyroxene), and amphiboles imply the existence of mafic/ultramafic
magmatic rocks and/or charnockites in the interior of the PEL/ Lambert
rift area. The dominance of orthopyroxene in sites 740 and 742 and its
absence in site 739, suggests proximal ultramafic/charnockite sources.
Also, the gyral movement of water bodies within the Prydz Bay sug-
gests that the deposition of the sediments was likely from the immedi-
ate coastal terrain and/ or from the near-coast inland region of the PEL
through the network of sub-glacial canyons and waterways. The domi-
nance of igneous origin pyroxenes in unit I of site 740 are derived from
the tholeiitic and calc-alkaline basalts which suggest a direct sediment
supply from the dyke swarms of Vestfold hills (e.g., Collerson &
Sheraton, 1986; Kuehner, 1986, 1989; Seitz, 1991). The absence of
igneous pyroxenes and dominance of garnet and amphiboles in the
other lithostratigraphic units of site 740 and other sites evinces shifting
of depocenter for the supply from the Vestfold terrain during Pliocene
to Holocene. The sourcing of olivine could be from a much proximal
F I G U R E 1 3 (a) Grains MZ-1 to MZ-19 (Figure 11a–b) were source. The presence of ultra-high temperature mafic granulite is
declustered in two different groups and separate probability density reported from the Manning Nunatak of southwestern Prydz Bay (Liu,
plots (Ludwig, 2003) were made for two groups of ages. (a) gives two
Jahn, Zhao, Liu, & Ren, 2014).
age populations that are 521.7 ± 3.8 Ma and 632 ± 10 Ma. (b) gives
two age populations that are 910 ± 11 Ma and 1,100.6 ± 20 Ma. The coastal belt of PEL comprises a Neoproterozoic-aged granu-
(c) The probability density plot (Ludwig, 2003) of monazites from lite-grade terrain dominated by paragneisses and orthogneisses
garnet chlorite schist (Rf_MZ-1 to Rf_MZ-9) gives two distinct ages, (e.g., Arora et al., 2020; Stüwe, Braun, & Peer, 1989; Tong et al., 2017)
454 ± 24 Ma and 686.1 ± 17 Ma
GUPTA ET AL. 21

FIGURE 14 A plot of (a) Th, (b) Y and (c) Ce variation versus Age of monazite grains obtained from rock fragments and detrital monazite

which explains the dominant presence of almandine and metamorphic Although ages of 1,100 to 500 Ma are observed in the detri-
amphiboles in the detritals. tal monazites, no Grenvillian age is estimated in texturally con-
Garnet chlorite schist, chlorite schist, and low-grade iron oxide strained monazites in the rock fragment (RF1) which makes the
schist were three different rock fragments recovered from site 739 while geochronological refinement of the terrain more complex. Pan-Afri-
granitic rock fragment was recovered from site 742. First, three rock can granulite metamorphism with relics of at least two older events
fragment compositions reveal the presence of greenschist facies low- have been widely reported from the Prydz Bay (1,000 Ma: Zhao
grade metamorphic terrain in the interior of the PEL-Lambert domain et al., 1992; Hensen & Zhou, 1995 and 800 Ma: Arora
which has further experienced retrogression. It is unlikely that the low- et al., 2020; Mikhalsky et al., 2020; Sadiq et al., 2021) (Figure 15b).
grade metamorphic rocks are derived from the coastal granulite terrain. New emerging data from various mobile belts signify the presence
The other probable source could be the low-grade terrains of the sPCM, of 800 Ma events (e.g., Arora et al., 2020). Another supporting
however, the drainage pattern of the Amery Ice shelf area and age data evidence comes from 800 Ma event recently reported from other
of sPCM does not support this possibility. The metasediments exposed terrains worldwide (e.g., Eastern Ghats Mobile Belt in India: Bose,
in the Amery Oasis region or the interior Gamburtsev Mountains are Das, Torimoto, Arima, & Dunkley, 2016; North-western shield of
most likely the source for the low-grade greenschist facies metamorphic India: Arora, et al 2017; Africa: Sommer, Kröner, & Lowry, 2017;
rock fragments (Figure 15a). Fortunately, one of the low-grade meta- China: Ge, Zhu, & Wilde, 2016; Wilkes Land, East Antarctica:
pelitic lithologies comprises in situ monazites, which provide Pan-African Pandey et al., 2017). Novel data of 700–800 Ma event getting
and near Tonian-Cryogenian boundary ages. reported from various terranes of East Antarctic Shield as well as
22 GUPTA ET AL.

F I G U R E 1 5 Map of Prydz Bay and hinterland, made using Quantarctica (Matsuoka et al., 2021) is used as the base map. The elevation data
used is the BEDMAP-2 Elevation model (1,000 m) from Fretwell et al. (2013). Blue pathways show the subglacial water flux (Le Brocq
et al., 2013). Maroon colour markings show rock outcrops. (a) This base map is superimposed by the East Antarctic rift system (Ferraccioli
et al., 2011), ice divide, catchment area and flow directions (Hambrey et al., 1991), Indo–Australo–Antarctic Suture (IAAS) (Bo et al., 2019) and
circulation of ocean currents in Prydz, Bay region (modified from Smith et al., 1984). Red circles show the location of sites drilled during ODP Leg
119. (b) The map shows an enlarged view of various outcrops in Prydz Bay hinterland and their ages from Fitzsimons (2003) and Mikhalsky
et al., (2018)

its contiguous terranes further signifies the presence of at least Interestingly, the 700 Ma ages have been reported from the detri-
one event in between the 1,000–500 Ma period, which needs bet- tal zircons speculated to be from the GSM (Veevers, 2018; Veevers
ter resolution through future studies. et al., 2008). A notable concentration of 830–750 Ma magmatic
GUPTA ET AL. 23

events took place in the Arabian-Nubian Shield (ANS) (Fritz University for awarding them Seed Grant and Faculty Incentive grants
et al., 2013) while 780–603 Ma U–Pb detrital zircon ages in the bed- respectively under the IOE scheme. N. V. Chalapathi Rao thanks DST-
rock of eastern Dronning Maud Land in the Schirmacher Hills, the SERB, New Delhi for awarding a major project to establish the EPMA
Sør-Rondane Mountains, the Yamato-Belgica and Thala Hills (Elburg facility at BHU. Constructive comments by Prof. Kaushik Das and an
et al., 2016; Jacobs et al., 2015; Mikhalsky et al., 2017; Ravikant, anonymous reviewer and editorial suggestions by Prof. M. Santosh
Laux, & Pimentel, 2007; Shiraishi et al., 2008). Orogenic signatures of are thankfully acknowledged.
700 Ma are widely reported from East African Antarctic Orogeny (EA-
AO) considered representing the amalgamation of Africo-Antarctic CONFLICTS OF INTEREST
terrain (Elburg et al., 2016; Fritz et al., 2013; Jacobs et al., 2015; The authors declare that they have no known competing financial
Mikhalsky et al., 2017; Ravikant et al., 2007; Shiraishi et al., 2008). interests or personal relationships that could have appeared to influ-
The EA-AO was the result of multiple collisions between the East ence the work reported in this paper.
Gondwana and West Gondwana by forming the Trans-Gondwanian
Supermountains (TGSM) of age 700  500 Ma (Squire, Campbell, PE ER RE VIEW
Allen, & Wilson, 2006; Veevers, 2018). Musgrave Complex/ The peer review history for this article is available at https://publons.
Petermann orogen of Australian counterpart also comprises reported com/publon/10.1002/gj.4430.
ages of 715–545 Ma (Quentin de Gromard et al., 2017) and 622 Ma
(Aitken & Betts, 2009; Kirkland et al., 2013; Martin, Collins, & DATA AVAILABILITY STAT EMEN T
Kirkland, 2017; Wade, Kelsey, Hand, & Barovich, 2008). The presence The data that supports the findings of this study are available in the
of low-grade lithologies (garnet chlorite schist; quartz biotite schist; supplementary material of this article.
chlorite schist) itself provides evidence of the presence of a mobile
belt of 700 Ma age. We speculate the extension of a putative OR CID
Africo-Australo(?)-Antarctic mobile belt associated with the GSM in Mayuri Pandey https://orcid.org/0000-0001-8125-8051
the interior of the present-day East Antarctic Shield and GSM is either Devsamridhi Arora https://orcid.org/0000-0003-1790-6960
a detached Block or continuation of TGSM. We believe, this mobile Naresh Chandra Pant https://orcid.org/0000-0002-3204-0563
belt was reactivated and reset during the Pan-African event N. V. Chalapathi Rao https://orcid.org/0000-0003-0476-5302
(Figure 15a). We infer, from the existing knowledge, that this mobile
belt was the provenance for the 700 Ma detrital zircons reported RE FE RE NCE S
widely from Antarctica, Africa, and Australia. Aitken, A. R., & Betts, P. G. (2009). Multi-scale integrated structural and
aeromagnetic analysis to guide tectonic models: an example from the
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6 | C O N CL U S I O N S Aitken, A. R. A., Young, D. A., Ferraccioli, F., Betts, P. G., Greenbaum, J. S.,
Richter, T. G., … Siegert, M. J. (2014). The subglacial geology of Wilkes
1. Site 739 drilled during ODP 119 became the major proximal land, East Antarctica. Geophysical Research Letters, 41(7), 2390–2400.
Allison, I. (1979). The mass budget of the Lambert Glacier drainage basin,
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the Prydz Bay, henceforth, the major sediment sourcing is from (2017). Inferring a Neoproterozoic orogeny preceding the Rodinia
the coastal outcrops. break-up in the Sirohi Group, NW India. Geological Society, London,
Special Publications, 457(1), 319–338.
2. The dominance of Pan-African ages in detrital monazites indicates
Arora, D., Pant, N. C., Pandey, M., Chattopadhyay, A., Greenbaum, J.,
the presence of a  500 Ma orogen in PEL.
Siegert, M., … Bhandari, A. (2020). Insights into geological evolution of
3. The flow pattern in the Lambert-Amery region suggests significant Princess Elizabeth Land, East Antarctica-clues for continental suturing
supply from the inland Gamburtsev Subglacial Mountains depos- and breakup since Rodinian time. Gondwana Research, 84, 260–283.
ited at site 739. Barron, J., & Larsen, B. (1989). Proceedings of the Ocean Drilling Program,
Volume A - Initial Reports, Leg 119 (Vol. 942). In Barron, J., Larsen, B.,
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et al., Proc. ODP, Init. Repts., 119, College Station, TX: Ocean Drilling
in low-grade rock fragments from site 739 speculates the presence Program.
of a Tonian-Cryogenian orogen in the interior of PEL. Barron, J. A., Baldauf, J. G., Barrera, E., Caulet, J. P., Huber, B. T.,
Keating, B. H., … Wei, W. (1991). Biochronologic and magneto-
5. An Africo-Australo-Antarctic mobile belt associated with GSM is
chronologic synthesis of Leg 119 sediments from the Kerguelen
speculated in interior PEL, which was active during 700 Ma and Plateau and Prydz Bay, Antarctica. In J. Barron & B. Larsen (Eds.), Pro-
was partially reset during the extensive Pan-African event. ceedings of ODP Science Results (Vol. 119, pp. 813–847). TAMU Publi-
cations: College Station, TX.
ACKNOWLEDGEMEN TS Basu, A., & Molinaroli, E. (1991). Reliability and application of detrital
opaque Fe-Ti oxide minerals in provenance determination. Geological
IODP (International Ocean Discovery Program) core Repository is
Society, London, Special Publications, 57(1), 55–65.
acknowledged to provide sediment samples of ODP 119. Mayuri Pan- Bhattacharya, C. (1971). An evaluation of the chemical distinctions
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