MATERIAL SAFETY DATA SHEET

SULFURYL FLUORIDE
EMERGENCY TELEPHONE (+86 571)86875455

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SECTION I – PRODUCT INFORMATION

MANUFACTURER’S NAME – Maui (Hangzhou) Electronic Chemicals Co., Ltd.

MANUFACTURE’S ADDRESS
No.161 Road 5, Hangzhou Economic-Technological Development Area
Zip：310018，P. R. CHINA
INFORMATION TELEPHONE – (+86 571)86788523
CAS REGISTRY NO. 2699-79-8 DATE PREPARED 05/2018
FORMULA F2O2S SUPERSEDES None
INDONESIA REGISTRATION NAME :
INDOFUM 99 GA(REGISTERED BY PT.INDO GLOBAL TRADE )
CHEMICAL FAMILY – Inorganic acid halide
PREPARED BY – Research Services Department
Maui (Hangzhou) Electronic Chemicals Co., Ltd.
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SECTION II
HAZARDOUS COMPONENTS (Specify Chemical Identity: Common Names)

COMPONENT OSHA PEL ACGIH TLV Other Limits %

Recommended (Optional)

Sulfuryl 5ppm 5ppm 10ppm STEL ≥99.8

fluoride
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SECTION III – PHYSICAL/CHEMICAL CHARACTERISTICS

Boiling Point – 55.38℃
Specific Gravity (water=1) 1.36

Maui (Hangzhou) Electronic Chemicals Co., Ltd.

MSDS- Sulfuryl fluoride
 Vapor Pressure (mm Hg) 9150 at 10℃
Melting Point – 135.82℃
Vapor Density (AIR=1) 3.72

Evaporation Rate
(Butyl Acetate=1) Not Available
Solubility in Water 0.075g/100g
Appearance, Odor and Color Compressed gas
Colorless odorless
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SECTION IV – FIRE AND EXPLOSION HAZARD DATA

Flash Point (Method Used) Not Applicable
Flammable Limits Nonflammable
LEL Nonflammable
UEL Nonflammable

Extinguishing Media – Nonflammable. Use extinguishing media suitable for

suitable for immediate surroundings.

Special Fire Fighting Procedures

Wear self-contained breathing apparatus.

Unusual Fire and Explosion Hazards

Cylinders under pressure may rupture and explode under fire conditions, releasing
toxic gas. Cool cylinders in fire situations with water spray.
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SECTION V – REACTIVITY DATA

Stability Stable [√] Unstable
Conditions to Avoid: None
Incompatibility (Materials to Avoid)
Strong bases
Hazardous Decomposition or Byproducts
Sulfur dioxide, hydrogen fluoride

Hazardous Polymerization

Maui (Hangzhou) Electronic Chemicals Co., Ltd.

MSDS- Sulfuryl fluoride
 May Occur Will Not Occur [√]
Conditions to Avoid: None

SECTION VI – HEALTH HAZARD DATA

Route(s) of Entry:
Inhalation? Yes Skin? No Ingestion? Yes
Health Hazards (Acute and Chronic):
Single exposures at high concentrations may cause death. Repeated
exposure to high concentrations may cause lung and kidney damage.
Exposure may cause severe irritation to the upper respiratory tract and
lungs, central nervous system effects and fluorosis of teeth and bones.
RTECS offers the following toxicological data: The inhalation LC50 in
rats is 3020 ppm/1H; The inhalation LC50 in mice is 1200 ppm/1H;
The oral LC50 in rays is 100 mg/kg.
Carcinogenicity:
NTP? No IARC Monographs? No OSHA Regulated? No
Signs and Symptoms of Exposure:
Inhalation of vapors may be fatal. Sulfuryl fluoride has no odor or
warning properties. Early symptoms of overexposure may include
respiratory irritation, abdominal pain, pulmonary edema and nausea.
Medical Conditions Generally Aggravated by Exposure:
Existing dermatitis and respiratory problems may be aggravated by exposure.
Emergency and First Aid Procedures:
In all cases of overexposure, get medical attention. Take person to a doctor
or emergency treatment facility.
Eyes: Immediately flush with large amounts of water for at least 15 minutes;
get medical attention.
Skin: Immediately flush with large amounts of water for at least 15 minutes
while removing contaminated clothing, shoes, jewelry and other items on
skin. If frostbite or irritation occurs, get medical attention.
Inhalation: Remove person to fresh air. Give symptomatic and supportive care.
Keep warm.
If not unconscious, rinse mouth out with water. Get medical attention immediately.
Ingestion: Get medical attention immediately.
General: Clean and launder contaminated clothing before reuse.

Maui (Hangzhou) Electronic Chemicals Co., Ltd.

MSDS- Sulfuryl fluoride
SECTION VII – PRECAUTIONS FOR SAFE HANDLING AND USE
Steps to be Taken in Case Material is Released or Spilled
Evacuate immediate area of spill or leak. Use a NIOSH/MSHA approved
self-contained breathing apparatus (SCBA) or combination air-supplied/
SCBA respirator for entry into affected area to correct problem. Move
leaking or damaged cylinders or containers outdoors or to an isolated
location, observing strict safety precautions. Work upwind if possible.
Allow spill area by person without appropriate respiratory protection
until concentration of sulfuryl fluoride is determined to be less than 5ppm.
Waste Disposal Method
Dispose of waste at an approved chemical waste disposal facility as allowed
by current Local, State, and Federal laws and regulations.
Precautions to be Taken in Handing and Storing
Store in a cool, dry, well ventilated area. Store cylinders upright, secured
to a rack or wall to prevent tipping. Cylingders should not be subjected to
roug handling or mechanical shock such as dropping, bumping, dragging,
or sliding.Do not use rope slings, hooks, tongs, or similar devices to unload
cylinders.Transport cylinders using hand truck, fork truck or other device to
which the cylingder can be firmly secured. Do not remove valve protection
bonnet and safety cap until immediately before use. Replace safety cap and
valve protection bonnet when cylinder is not in use. When cylinder is empty,
close valve, screw safety cap on to valve outlet, and replace protection bonnet before
returning to shipper.
Other Precautions
DOT: Proper Shipping Name: Sulfuryl fluoride
Hazard Class\ Division Number: 2.3
Identification Number: UN2191
Label: Poison Gas
Poison-Inhalation Hazard
Zone D

SECTION VIII – CONTROL MEASURES

Respiratory Protection
If the concentration of sulfuryl fluoride exceeds exposure guidelines of
5ppm, a NIOSH/MSHA approved self-contained breathing apparatus should be
worn.
Ventilation

Maui (Hangzhou) Electronic Chemicals Co., Ltd.

MSDS- Sulfuryl fluoride
 Local Exhaust –Essential when indoors. Lethal doses may exist in places
with poor ventilation.
Mechanical – Use for general area control.
Special – None Other – None
Protective Gloves – Do not use
Eye Protection – Wear full face shield when handling liquid.

Other Protective Equipment

Monitoring device for sulfuryl fluoride, available from Foxboro and DowElanco.
Work Hygienic Practices
Wear all necessary protective equipment. Make sure piping is empty before doing
maintenance work. All persons working with sulfuryl fluoride should be trained
in the hazards, use of required respirator equipment and emergency procedures.

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Information on this form is furnished solely for the purpose of compliance with OSHA’S
Hazard Communication Standard, 29CFR 1910.1200 and the Canadian Environmental
Protection Act, Canada Gazette Part II, Vol. 122, No. 2 and shall not be used for anyother
purpose.

Maui (Hangzhou) Electronic Chemicals Co., Ltd.

MSDS- Sulfuryl fluoride