BAB IV

HASIL DAN PEMBAHASAN

A. Hasil Pengamatan

1. Tabel Pengamatan

Tabel IV.1 Hasil Pengamatan Larutan Standar

x y
No. Larutan x.y x2 y2
(mg/L) (Adsorbansi)

1 Standar 1 0,5 0,0466 0,0233 0,25 0,00217156

2 Standar 2 1 0,0728 0,0728 1 0,00529984

3 Standar 3 2 0,1483 0,2966 4 0,02199289

4 Standar 4 4 0,3342 1,3368 16 0,11168964

5 Standar 5 8 0,6865 5,4920 64 0,47128225

n=5 Σ = 15,5 Σ =1,2884 Σ =7,2215 Σ = 85,25 Σ =0,61243618

Tabel IV.2 Hasil Pengamatan Larutan Contoh

No. Larutan x (mg/L) y (Adsorbansi) Panjang
Gelombang (nm)

1 Sampel 1 30 0,1325 0,0442

2 Sampel 2 45 0,0779 0,0959

3 Sampel 3 60 0,0833 4,0240

4 Sampel 4 75 0,1238 4,9520

5 Sampel 5 90 0,0739 8,7440

 Tabel IV.3 Hasil Perhitungan Efektivitas Adsorpsi Larutan Sampel
Konsentrasi Kapasitas Efektivitas
No. Larutan Adsorbansi
Sisa Adsorpsi Adsorpsi

1 Sampel 30 ppm 0,1325 1,657163837 0,005668567 94,47 %

2 Sampel 45 ppm 0,0779 1,027839229 0,000879443 97,71 %

3 Sampel 60 ppm 0,0833 1,090080124 0,011781983 98,18 %

4 Sampel 75 ppm 0,1238 1,556886839 0,014688622 97,92 %

5 Sampel 90 ppm 0,0739 0,981734862 0,017803653 98,90 %

Tabel IV.4 Persamaan Freundlich

No. Larutan Ce Qe x (log Ce) y (log Qe)

1 Sampel 30 ppm 1,657163837 0,0056685672 0,2193654476 -2,246526698

2 Sampel 45 ppm 1,027839229 0,0008794432 0,0119251894 -3,055792197

3 Sampel 60 ppm 1,090080124 0,0117819839 0,0374584213 -1,928781572

4 Sampel 75 ppm 1,556886839 0,0146886226 0,1922570476 -1,833018926

5 Sampel 90 ppm 0,981734862 0,0178036530 -0,008005786 -1,749490878

Tabel IV.5 Persamaan Langmuir

No. Larutan Ce Qe x (1/Ce) y (1/Qe)

1 Sampel 30 ppm 1,657163837 0,0056685672 0,6034406361 176,4114219

2 Sampel 45 ppm 1,027839229 0,0008794432 0.9729148020 1137,083099

3 Sampel 60 ppm 1,090080124 0,0117819839 0.9173637588 84,87534938

4 Sampel 75 ppm 1,556886839 0,0146886226 0.6423074400 68,07990287

5 Sampel 90 ppm 0,981734862 0,0178036530 1,0186049601 56,16824816

 2. Grafik
a. Larutan Standar

Larutan Standar
0.8
0.8000
0.7
0.7000
f(x) =f(x)
0.0864548387096774 x − 0.00924999999999998
= 0.0864548387096774 x − 0.00924999999999998
0.6
0.6000 R² = 0.998496213958368
R² = 0.998496213958368
Y (Absorbansi)

0.5
Adsorbansi (Y)

0.5000
0.4
0.4000 Absorbansi
Adsorbansi
0.3 LinearLinear
(Adsorbansi)
0.3000 (Ab-
sorbansi)
0.2
0.2000
0.1000
0.1
0.0000
0
0 0
1 12 2 3 3 44 55 6 6 7 78 9
8 9
Konsentrasi
Konsentrasi (mg/L) X (ppm)

Grafik IV.1 Larutan Standar

b. Larutan Contoh

Larutan
Konsentrasi ContohContoh
Larutan
0.14
10.0000
0.129.0000
8.0000 f(x) = 0.0499799756097561 x − 1.67587743902439
f(x) = 0.000732285714285714
0.17.0000 x + 0.0452857142857143
Y (Absorbansi)

R² = 0.959203989732364
R² = 0.253501624285846
Adsorbansi (Y)

0.086.0000 Absorbansi
5.0000 Adsorbansi
Linear
0.064.0000 (Ab-
Linear (Adsorbansi)
sorbansi)
0.043.0000
2.0000
0.021.0000

0
0.0000
0 100 20 5030 100 15060 200
40 50 70 250 90 100
80
Konsentrasi (mg/L) X (ppm)
Konsentrasi

Grafik IV.2 Larutan Contoh

c. Grafik Isoterm Adsorpsi Freundlich

Isoterm Adsorpsi
Persamaan Freundlich
Freundlich
0.25 0.0000
-1.0000 0.0000 1.0000 2.0000 3.0000
0.2 -0.5000

0.15 -1.0000
Persamaan Freundlich
Log Ce
Log Ce
log Qe

0.1 -1.5000 Linear (Persamaan

Linear (Log Ce)
Freundlich)
-2.0000
f(x) = 9.14285714285715E-05 x + 0.0674285714285714
0.05 R² = 0.00087491455912525
f(x) = 0.207928803173391 x − 2.46900705578348
-2.5000 R² = 0.748566526578363
0
0 10 20
-3.0000 30 40 50 60 70 80 90 100
-0.05
logKonsentrasi
Ce X (ppm)

Grafik IV.3 Isoterm Adsorpsi Freundlich

d. Grafik Isoterm Adsorpsi Langmuir

Isoterm Adsorpsi
Persamaan Langmuir
Langmuir
0
450.0000
0 10 20 30 40 50 60 70 80 90 100
400.0000
-0.5
350.0000 f(x) = 166.519500856621 x + 120.739080767104
R² = 0.870853610830886
-1
300.0000
f(x) = − 0.0141904761904762 x − 1.08714285714286
250.0000
R² = 0.210808480576108 Persamaan Langmuir
-1.5
Log Qe
1/Qe

200.0000 Linear (Persamaan

Log Qe
Langmuir)
150.0000
-2 Linear (Log Qe)
100.0000
-2.5
50.0000
-3 0.0000
0.00000.50001.00001.50002.0000
-3.5
1/Ce
Konsentrasi X (ppm)

Grafik IV.4 Isoterm Adsorpsi Langmuir