EPA HQ OAR 2018 0415 0025 - Content

AIR PERMIT ROUTING/APPROVAL SLIP-Permits 641
DEQ
A1 No. 1409 Company The Dow Chemicard. ' j "I I Date Received - 6/27/11
Activity No. PER20110024 Facility Cellulose Plant •Permit T 1 e 1' i 4t P-t•t
•CDS No. Perinit No. 2227-V7 ÆxpeditedPèrmitJ. es jno
Approved Date.rec'd Date FW Comments .

1. Technical•Review
Permit Writer.. • 1-Vkl '71) tin i 25- 11
Air Quality /Modeling •
Toxics
PSD/NNSR •
Technical Advisor D a,... 7 1,6 I

Supervisor
Other •
2.• Management ReView ' (if PN req'd) Approved Date rec'd - •Date BY . Comments •
SuPervisor ' 0g re 0
•manager . • 2- i cf
Assistant Secretary,(PN) (--)..4 / VP
3. -Response to Comments (if PN req'd) " Approved Date rec'd ate W Comments
Supervisor' '
'Manager •
• Administrator
• Legal•(BFD)
4. Final Approval Approved Date rec'd Date FW • Comments
Supervisor - - /o/IV/)
t--)'3.&1_4/1"/ •
Manager -}1./ (--- ft.2(i3 fat
Administrator
Assistant Secretary 77 / Oki A
1. Technical Review .
.PN of App needed yes alio Date of•PN of ApP Newspaper '
Fee paid , • Ef yes El no
NSPS apPlieS ..• • yes El no PSD/NNSR•applies 0 yes Dino NESHAP applies ayes Ej no
2. -Post-Technical Review .
Company technical review eyes 0 no 0 n/a E-mail date Off' l Remarks received yes El no glisill
Surveillance technical review . Er yes El no 0 n/a E-mail date , g 4 /it Remarks received • ' • yes gno
3. Public Notice • • '
Public Notice-Required Mes EJno g 10
Library
PN newspaper" 1/City The AdvocatelBaton Rouge PN Date I/1111 EDMS 0/yes 0 no
pN newspaper ./City atoi t.u.rp.ifulto.54--co LA-14$ 'PN Date- 9 i1.1 i 1 Verification aces 0 no
vo,„9-t 5t I -jounard
Company notification letter sent Date mailed '3A)111 -
EpA pN notification e-mail sent Date e-mailed 12-1/11 .
OES PN mailout Date - •
4. • Final Review -
. -
• Date EPA Resp. to Comments-
Pubfic comments received E yes Ri
to. EPA cOmments rec'd 0 yes aria
i mailed
• , PN info entered into
Coinpany comments received 0 yes Ellio Et</es no .Date EPA approved permit
Permit Sec VI
•
•Comments
form_7193_r03
01/28/2011
BOBBY JINDAL PEGGY M. HATCH
GOVERNOR SECRETARY
6tate of Zottigiana
DEPARTMENT OF ENVIRONMENTAL QUALITY
ENVIRONMENTAL SERVICES
Certified Mail No. 7005 1820. 0002 2091 0698

Agency Interest (AI) No. 1409.
Activity No. PER200110024
Mr. Chris Reed
The Dow Chemical Company
P.0 Box 150, Building 3502
Plaquemine, LA 70765-0150
RE: Part 70 Operating Permit Renewal/Modification, Cellulose Plant, The Dow Chemical Company
Plaquemine, IbervilleiWest Baton Rouge Parish, Louisiana.
Dear Mr. Reed:
This is to inform you that the part 70 Operating Permit renewal/modification for the above referenced facility has been
approved under LAC 33:111.501. The submittal was approved on the basis of the application submitted and its approval
in no way relieves the applicant of the obligation . to comply with all applicable requirements.
It will be considered a violation of the permit if all proposed control measures and/or equipment are not installed. and
properly operated and maintained as specified in the application.
Operation of this facility is hereby auejiz u er the terms and conditions of this permit. This authorization shall
expire at midnight on the /1/ of , 016, unless a timely and complete renewal application has been
submitted six months prior to expiration. Terms and conditions of this permit shall remain in effect until such.time as
the permitting authority takes final action on the application for permit renewal. The permit number cited below and
agency interest number cited above should be referenced in future correspondence regarding this facility.
Please be advised that pursuant to provisions of the Environmental Quality Act and the Administrative Procedure
Act, the Department may initiate review of a permit during its term. However, before it takes any action to
modify, suspend or revoke a permit, the Department shall, in accordance with applicable statutes and regulations,
notify the perthittee by mail of the facts or operational conduct that warrant the intended action and provide the
permittee with the opportunity to demonstrate compliance with all lawful requirernents for the retention of the
effective permit.
Done this day of a , 2011.
Permit No.: 2227-V7

Sincerely,
Sam L. Phillips
Assistant Secretary
CSN: TVN
cc: US EPA Region VI
Post Office Box 4313 • Baton Rouge, Louisiana 70821-4313 • Phone 225-.219-3181 • Fax 225-219-3309
www.deq.louisiana.gov
AIR PERMIT BRIEFING SHEET
AIR PERMITS DIVISION
LOUISIANA DEPARTMENT OF ENVIRONMENTAL QUALITY
CELLULOSE PLANT
THE DOW CHEMICAL COMPANY
PLAQUEMINE, IBERVILLE/WEST BATON ROUGE PARISH, LOUISIANA
M NO. 1409; PER20110024
I. BACKGROUND
The Dow Chemical Company, Louisiana Operations, owns and operates the Cellulose
Plant, located near Plaquemine, Louisiana in lberville/West Baton Rouge Parish. The
Cellulose Plant currently operates under Part 70 air permit number 2227-V6 issued on
. November 9, 2009.
II. ORIGIN
A permit application and Emission Inventory Questionnaire were submitted by Dow

Chemical Co on June 27, 2011 requesting a Part 70 operating permit
renewal/modification. Additional information dated July 21, 2011 and July 28, 2011 was
also received.
III. DESCRIPTION
The Cellulose Plant produces a range of hydroxypropyl methylcellulose (HPMC) products

by reacting raw cellulose pulp, methyl chloride, propylene oxide, and sodium hydroxide via
a batch reaction. This was previously accomplished with two trains. However, one train has
been permanently shutdown and. there is currently only one operating train for the plant.
Some equipment such as treated blenders and wastewater systems are capable of operating
continuously. The crude product is water washed, dried, sized, treated with additives to meet
customer specifications, and bagged for shipment. The previous annual plant capacity of 39
million pounds of HPMC products per year is being adjusted to 23.5 million pounds of
HPMC products per year.
Raw cellulose pulp is prepared for processing in the pulp preparation area. Raw materials
are fed to the batch reactors where the HPMC is produced. The HPMC is washed and
dried in the product purification and drying section. The size reduction, blending, and
additives section provides uniformity to the product, and treating agents are added to
meet customer specifications. The product is then packaged into bags for shipment.
The Cellulose Plant has the ability to pre-treat the plant wastewater prior to treatment at the
Biological Treatment Plant. Pre-treatment could be utilized when high production rates are
sustained and/or high total oxygen demand (TOD) products are manufactured in order to
affect a lower TOD loading to the Biological Treatment Plant, thus maintaining efficient
biological treatment (TOD refers the amount of oxygen needed by microorganisms to
consume the organics.). ln such situations, distillation column C-120 (JX) is employed to
remove organics from the wastewater. Concentrated organics are disposed of appropriately,
CELLULOSE PLANT
Al NO. 1409; PER20110024
Some process and tank vents from (he Cellulose plant are routed to the Thermal Treatment
Unit at the Methanes Plant for destruction. The Thermal Treatment Unit located at the Vinyl
11 Plant or Thermal Treatment unit located at the Glycol I Plant serves as the backup
treatment device in the event the Thermal Treatment Unit at the Methanes Plant is not
operating.
With this renewal/modification, Dow requested the following:

1. Replace T-1451 which reduces particular matter upstream of Blower B-1451 (F.QT091,
E1Q C7) by using a water spray nozzle with a piece of equipment that is a hot dust
collector, DC-1448. This project will eliminate adding water Mier the drying step and
reduces plant outages due to plugging issues resulting from %%later addition;
2. Add insignificant activity: LA-21-Central Vacuum Blower B-1837 & 1A-22-Hopper
HO-8392 Vent;
3. Add EQT1331 (EIQ Z9) - BDC-5B Blower Loop Vent;
4. Update various emission sources based on the most current emission estimating
methodology;
5. Remove insignificant activity: IA-V1- Purification Emissions; and
6. Remove the following emission points from the permit:
EQT062 7Z - 1DC-1A Dust Collector Vent

EQT064 CY - D-421 Reslurry Tank
EQT074 7W - 1B-1B Blower Exhaust
EQT075 7X - IB-13-1 Blower Exhaust
EQT085 BV - A2E Blender
EQT087 BX - A2H Treated Blender Vent
EQT090 C6 - BDK-I Blower Exhaust
EQT094 80 - 1DC-1C Dust Collector Vent
EQT100 DY - HO-40B Hopper Vent
EQT102 LN - B-422 Blower Exhaust
EQT103 V5 — 1B-2 Blower Exhaust
EQT106 CZ - D-422 Water Recovery Tank
EQT110 E7 - CF-422
EQT11 I V4 - T-76 Tank Vent
EQT119 VH - Train 2 Reactor Vent
2
CELLULOSE PLANT
• THE DOW CHEMICAL COMYANY
AI NO. 1409; PER20110024
Total permitted emissions in tons per year are as follows:
Pollutant Before After Change

PM 8.21 8.65 +0.44
PM10 1.99 2.04 +0.05
C12 0.02 • 0.02 •
*VOC 184.48 71.3 -113.18
*VOC LAC 33:111 Chapter 51 Toxic Air Pollutants (TAPs):

Pollutant Before • After Change
Propylene oxide 0.84 . 0.50 -0.34
Methanol ' 14.14 • 9.47 -4.67
Methyl chloride 13.03 11.53 -1.50
Total VOC TAps 28.01 21.50 -6.51
Other VOCs 156.47 49.80 -106.67
IV. TYPE OF REVIEW
There is no proposed emissions increase of NOx, CO, S02 or PM/PM10 associated with ihe
hot dust collector project above PSD significant levels. Therefore, PSD review is not
required for these pollutants.
Since the emission increase 23.96 tpy VOC does not exceed the current Nonattainment New
Source Review (NNSR) threshold rate of 25 tpy VOC, a NNSR contemporaneous netting
analysis is not required for VOC emissions.
Estimated emission increases due to the project in tons per year are as follows:
PSD Significance Level

Pollutant Project Increase or NNSR Netting Required?
o 25/15 (PM/PMIG) No
S02 40 No
NOx 25 No
CO 100 • No
VOC 23.96 25 -No
CELLULOSE PLANT
THE DOW CIIEMICAL COMPANY
AI NO. 1409; PER20110024
This application was reviewed for compliance with Louisiana Air Quality Regulations
and National Emission Standards for Hazardous Air Pollutants (NESHAP). New Source
. Performance Standards (NSPS), Nonattainment New Source Review (NNSR) and
Prevention of Significant Deterioration (PSD) do not apply.
This facility is a part major source of toxic air pollutants (TAPs) pursuant to LAC
33.111.Chapter 51.
V. CREDIBLE EVIDENCE
Notwithstanding any other provisions of any applicable rule or regulation or requirement

of this permit that state specific methods that May be used to assess compliance with
applicable requirements, pursuant to 40 CFR Part 70 .and EPA's Credible Evidence Rule,
62 Fed. Reg. 8314 (Feb. 24, 1997), any credible evidence or information relevant to
whether a source would have been in compliance with appliCable requirements if the
appropriate performance or compliance test or procedure had been performed shall be
considered for purposes of Title V compliance certifications. Furthermore, for purposes
of establishing whether or not a person has violated or is in violation of any emissions
limitation or standard or permit condition, nothing in this permit shall preclude the use,
including the exclusive use, by any person of any such credible evidence or information.
VI. PUBLIC NOTICE
A notice requesting public comment on the permit was published in the Advocate, Baton
Rouge, on September 1, 2011; in the Plaquemine Post-South On September 1, 2011; and
in the West Side Journal on September I, 2011. A copy of the public notice was mailed
to concerned citizens listed in the Office of Environmental Services Public Notice
Mailing List on August 30, 2011. The draft permit was also submitted to US EPA
Region VI on August 29, 2011. No comments were received.
VII. Effects on Ambient Air
Emissions associated with the proposed facility were reviewed by LDEQ to ensure
compliance with the NAAQS and AAS. LDEQ did not require the applicant to podel
emissions.
Dispersion Model(s) Used: None
4
CELLULOSE PLANT
Al NO. 1409; PER20110024
VIII. General Condition XVII Activities
Work Activity Schedule VOC (TPY)

Dump Tank Daily 4.28
Line and EquipMent'Openings and Unplugging Activities Daily I .30
IX. Insignificant Activities
ID Description • - Citation
IA-1 Distillate Trailer Loading LAC 33:I11.501.B.5.D
IA-II Laboratory Hood Emissions ' LAC 33:111.501.B.5.A.6.
1A-111 Sampling Emissions LAC 33:111.501.B.5.D
IA-IV Analyzer Emissions LAC 33:111.501.B.5.A.9
IA-V • Containment Sump Emissions LAC 33:111.501.B.5.D
1A-VII Treated Chemical Unloading LAC 33:111.501.B.5.D
IA-VII1 B-8141 Product Transfer Blower LAC 33:II1.501.B.5.D
IA-IX 13-8215 Product Transfer Blower LAC 33:111.501.B.5.D
IA-X B-8231 Blower LAC 33:111.501.B.5.D
IA-XI • B-8361 Product Transfer Blower LAC 33:111.501 .B.5.D
IA-X11 B-8511 Central Vacuum Blower LAC 33:111.501.B.5.D
1A-X111 DC-8211 Reactor Bin Vent LAC 33:I11.501.B.5.D
IA-XIV EF-8121 Dump Station Ekhaust Fan • LAC 33:111.501.B.5.D
IA-XV EF-832I Dump Station.Exhaust Fan LAC 33:111.501.B.5D
IA-XVI EF-8391 Dump Station Exhaust Fan LAC 33:111.501.B.5.D
IA-XV11 FL-8341 Blender Bin Vent LAC 33:111.501.B.5.D
1A-XVIII MRU - Mechanical Refrigeration Unit • LAC 33:111.501.B.5.D
IA-XIX WF-8231 Weigh Feeder Vent LAC 33:111.501.B.5.D
1A-XX B-8142 Product Transfer Blower LAC 33:H1.501.13.5.D
1A-XX1 B-1837-Central Vacuum Blower LAC 33:11I.501.B.5.D
IA-XXII Hopper HO-8392 Vent LAC 33:111.501.B.5.D
CELLULOSE PLANT
TIIE DOW CFIEMICAL COMPANY
AI NO. 1409; PER20110024
X. Consolidated Fugitives Program
The permittee shall comply with a streamlined equipment leaks monitoring program.
Compliance with the streamlined program in accordance with this specific condition shall
serve to comply with each of the applicable fugitive emission- monitoring programs being
streamlined, as indicated in the following table. Noncompliance with the streamlined
program in accordance with this specific condition may subject the permittee to
enforcement action for one or more of the applicable fugitive emissions programs.
a_ Permittee shall apply the streamlined program to the combined universe of

components subject to any of the programs being streamlined. Any component
type which does not require periodic monitoring under the overall most stringent
program (40 C1:11 Part 63 Subpart 11 (HON)) shall be monitored as required by the
most stringent requirements of any other program being streamlined and will not
be exempted. The streamlined program will include any exemptions based on size
of component available in any of the programs being streamlined.
b. Permittee shall use leak definition and monitoring frequency base on the overall
most stringent program. Percent leaker performance shall be calculated using the
provisions of the overall most stringent program. Annual monitoring shall be
defined as once every four quarters. Some allowance may be made in the first
year of the streamlined program in order to allow for transition from existing
monitoring schedules.
6
AIR PERMIT 13RIEFING SHEET
CELLULOSE PLANT
AI NO. 1409; PER20110024
c. Permittee shall comply with recording and reporting requirements of the overall
most stringent prograrn. Semiannual report shall be submitted on April 30 and
October 30, to cover the periods October 1 through March 31 and April 1 through
September 30, respectively. The semiannual reports shall include any monitoring •
performed within the reporting period.
Unit or programs Being Streamlined Stream Overall Most

Plant Site Applicability Stringent Program
Cellulose - 40 CFR 63 Subpart UUUU — Cellulose 5% HAPs 40 CFR Part 63
Plant Products MACT (HON Option) Subpart H (HON)
40 CFR Part 63 Subpart H (HON) 5% VOHAPs
LAC 33:111.5109.A (non-HON MACT) 5% HAPs
40 CFR 264 — RCRA Subpart BB (LAC 10% VOC
32:V.1717 Subchapter B)
40 CFR 265 — RCRA Subpart BB (LAC
33:V.4561 Subchapter R)
7
CELLULOSE PLANT
PLAQUEMINE, IBERVILLETWEST BATON ROUGE PARISH, LOUISIANA
AI NO. 1409; PER20110024
XI. Table 1. Applicable Louisiana and Federal Air Quality Requirements

ID No.: Description LAC 3.3111.Chapter
5a 9 11 13 15 2103 2107 2111 2113 2115 2122 2149 2153 51* 56 I 59
CRG0009 Common Requirement Grou_p 9

EQT0070 7N — B-203 Blower Exhaust
EQT0071 70 — B-205 Blower Exhaust
EQT0076 8N — B-20 Blower Exhaust ,
EQT0079 B8 — BDC-30A Blower Exhaust
EQT0080 B9 — BDC-30B Blower Exhaust
EQT0095 CC — BDC-60 Blower Exhaust
EQT0101 DZ — 1-B9 Blower Exhaust
EQT0114 DB — BDC-80 Untreated Packaging Dust
Col lecti on
EQT0121 Z8 — BDC-5A Blower Loop Vent
EQT0591 B5- BDC-1B Blower Exhaust
EQT0880 CY-231 —Cyclone
EQT0881 CY-22 — Cyclone
EQT1331 Z9-BDC-5B Blower Loop Vent
CRG0010 Common Requirement Group 10 . 1

EQT0072 7P — 110-201 Hopper Vent
EQT0073 7Q — H0-202 Hopper Vent
EQT0081 BR — A2A Blender
EQT0082 BS — A2B Blender
E.QT0083 BT — A2C Blender
EQT0084 BU — A2D Blender
EQT0086 BW — H0-30A Hopper Vent
CELLULOSE PLANT
PLAQUEMINE, IBERVILLEAVEST BATON ROUGE PARISH, LOUISIANA
AI NO. 1409; PER20110024
XI. Table 1. Appiicable Louisiana and Federal Air Quality Requirements

ID No.: Description LAC 33:III.Chapter
54 9 1 11 13 15 2103 2107 2111 2113 2115 2122 2149 2153 51* 55 59
EQT0088 BZ —110-30B Hopper Vent 1 .

EQT0120 VT —BV-20D Bin Vent for HO-20D 1
CRG0011 Common Requirement Group 11 1 I
EQT0089 C5 —TR-200 Treated Blender Vent 1 3 1
EQT0091 C7 —B1451 Blower Exhaust 1 3 1 1
EQT0096 CG TR-300 Treated Blender Vent 1 3 1
EQT0098 DC — Consolidated 13lower Exhaust 1 3 1
,
CRG0012 Common Requirement Group 12 1
EQT0061 6A — Treating Chemical System 3 1
EQT0586 Fl — D-221 Reslurry Tank 3 1
EQT0588 E3 — CF-226 3 1
CRG0013 Comrnon Requirement Group 13 I 1
EQT0092 C8 — B-232 Blower Exhaust 1 • 3 1
EQT0104 V6 — B-200 Blower Exhaust 1 . 3 1 •
EQT1304 001-DC-1140 Dust Collector Vent 1 • 3 1

EQT 1305 002-DC-1142 Dust Collector Vent 1 -3 1
CRG0014 Common Requirement Group 14 1
EQT0066 VF — R-201 Reactor Vent 3 1
EQT0093 C9 — Reactor Blower Exhaust . 3 1
,EQT0109E6 —CF-221/CF-222/D223 3 3 1
EQT0118 VG —R-202 Reactor Vent 3 1
1 3
,FUG0006 D4 — Fugitive Emissions
9
CELLULOSE PLANT
AI NO. 1409; PER20110024

ID No.: Description LAC 33:111.Chapter
-- 5A 9 11 13 15 2103 2107 2111 2113 2115 2122 2149 2153 51 56 59

RLP0102 Process Vents
EQT0107 D5 — T-21 I Tank Vent 3
EQT0108 DA — D-8554 Tank Vent 3
EQT0113 V9 — T-50 Tank Vent 3
EQT0115 VA — T-17A Tank Vent 3
EQT0116 VB — T-I 7B Tank Vent 3
EQT0587 E2 — D-222 Water Recovery Tank 3 1
EQT0589 E4 — Cooling Tower CT-7000 I
EQT0718 75 — Vinyl II Plant F-410 TTU Operates under Perrnit No 2285-V3 dated January 25, 2007
EQT0719 76 — Vinyl II Plant F-420 TTU Operates under Perrnit No 2285-V3 dated January 25, 2007
EQT0858 C3 (E-I 10A) — Exchanger Vent
EQT0859 C3 (E-I 10B) — Exchanger Vent
EQT0860 AT-200 — Spray Tank 3
EQT0863 SP-200 — Spray Tank 3
EQT0864 SP-300 --Spray Tank 3
EQT0866 HA — CMP R-750 THROX TTU Operates under Permit No. 2037-V 1, dated July 18, 2011
EQT0877 C-120 — Steam Stripper
EQT0878 C-12 I — Steam Stripper I
EQT0879 Group 1 Wastewater Streams
RLP0098 T-120 — Tank Vent
10
CELLULOSE PLANT
AI NO. 1409; PER20110024
XL Table I. Applicable Louisiana and Federal Air Quality Requirements

ID No.: • LAC 33:11LChaoter
• Description
5A 9 11 13 15 2103 2107 2111 2113 2115 2122 2149 2153 51* 56 59
UNF0002 Cellulose Plant 1 1 l 1 , 1 2 I 1 I
KEY TO MATRIX
1 -The regulations have applicable requirements that apply to this particular emission source.
The emission source may have an exernption from control stated in the regulation. The emission source may not have to be controlled but may have
monitoring, recordkeeping, or reporting requirements.
2 -The regulations have applicable requirements that apply to this particular emission source but the source is currently exempt from these requirements
due to meeting a specific criterion, such as it has not been constructed, modified or reconstructed since the regulations have been in place. If the
specific criteria changes the source will have to cornply at a future date.
3 -The regulations apply to this general type of ernission source (i.e. vents, fumaces, towers, arid fugitives) but do not apply to this particular emission
source.
Blank — The regulations clearly do not apply to this type of emission source.
* The regulations indicated above are State Only regulations.
A All LAC 33:11E Chapter 5 citations are federally enforceable including LAC 33:111.501.C.6 citations, except when the requirement found in the "Specific
Requirements" report specifically states that the regulation is State Only.
11
CELLULOSE PLANT
AI NO. 1409; PER20110024
XI. Table I. Applicable Louisiana and Federal Air Quality Requirements

43 CFR 60 40 CFR 61 40 CFR 63 40 CFR 40 CFR 82
ID No: Description
A K KaKbAMFF A F HOLINU6463E F G
CRG0009 Common Requirement Group 9

EQT0071 70 — B-205 Blower Exhaust
EQT0079 B8 — BDC-30A Blower Exhaust
EQT0080 B9 — BDC-30B Blower Exhaust
EQT01395 CC — BDC-60 Blower Exhaust
EQT0101 DZ — 1-B9 Blower Exhaust
DE3 — BDC-80 Untreated Packaging Dust
EQF0114
Collection
EQT0121 Z8 — BDC-5A Blower Loop Vent
EQT0591 B5- BDC-1B Blower Exhaust .
EQT0880 CY-231 — Cyclone
EQT 881 CY-22 — Cyclone
EQT1331 Z9-BDC-5B Blower Loop Vent

EQT0072 7P —1-10-20 I Hopper Vent
EQT0073 7Q — HO-202 Hopper Vent
EQT0081 BR — A2A Blender
EQT0082 BS — A2B Blender
EQT0083 BT — A2C Blender
EQT0084 BU — A2D Blender
12
CELLULOSE PLANT
AI NO. 1409; PER20110024
XI. Table 1. Applicable Louisiana and Federal Air Quality Re uirements

ID No.: Description
' A K Ka Kb A M FF A F II Q LUX 64 68 E F G
EQT0086 BW — HO-30A Hopper Vent
EQT0088 BZ — HO-30B Hopper Vent
EQT0120 VT — BV-20D Bin Vent for HO-20D -
EQT0089 C5 — TR-200 Treated Blender Vent •
EQT0091 C7 — B1451 Blower Exhaust
EQT0096 CG — TR-300 Treated Blender Vent
EQT0098 DC —Consolidated Blower Exhaust
EQT0061 6A — Treating Chemical System
EQT0586 El — D-221 Reslurry Tank 3
EQT0588 E3 —CF-226 3
EQT0092 C8 — B-232 Blower Exhaust
EQT0104 V6 — B-200 Blower Exhaust •
EQTI304 001-DC-1140 Dust Collector Vent

EQT1305 002-DC-1142 Dust Collector Vent .
EQT0066 VF — R-201 Reactor Vent '
EQT0093 C9 — Reactor Blower Exhaust
EQT0109 E6 — CF-221/CF-222/D223 3
13
CELLULOSE PLANT
AI NO. 1409; PER20110024
XI. Table 1. Applicable Louisiana and Federal Air Quality Re uirements

ID No.: Description
A K Ka Kb A M FF A F HQ UUL1U 64 68 E F G
EQT0118 VG — R-202 Reactor Vent
T
FUG0006 D4 — Fugitive Emissions 1
RLP0102 Process Vents I
EQT0107 D5 — T-2 l 1 Tank Vent 3
EQT0108 DA — D-8554 Tank Vent 3
EQT0113 V9 — T-50 Tank Vent 3
EQTO I 15 VA — T-17A Tank Vent 3
EQT0116 VB — T-17B Tank Vent 3
EQT0587 E2 — D-222 Water Recovery Tank 3
EQT0589 E4 — Cooling Tower CT-7000 3
EQT0718 75 — Vinyl II Plant F-410 TTU Operates under Permit No. 2285- V3 dated January 25, 2007
EQT0719 76 — Vinyl II Plant F-420 TTU - Operates under Permit No. 2285- V3 dated January 25, 2007
EQT0858 C3 (E-110A) — Exchanger Vent
EQT0859 C3 (E-110B) — Exchanger Vent
EQT0866 I-IA — CMP R-750 TFIROX TTU Operates under Pertnit No, 2037-V1, dated July 8, 2011
EQT0877 C-1 20 — S team Stripper 1 1 1 1 1
14
CELLULOSE PLANT
AI NO. 1409; PER20110024

- • 40 CFR 60 40 CFR 61 40 CFR 63 40 CFR 40 CFR 82
ID No,: Description
A K Ka Kb A 11 FF A F HQ UM 64 68 E F G
EQT0878 C-121 — Steam Stripper
•
EQT0879 Group 1 Wastewater Streams ' 1
RLP0101 T-208 — Tank Vent .
UW0002 Cellulose Plant I 1 • -1 1 1 1 1
KEY TO MATRIX
1 -The regulations have applicable requirements that apply to this particular ernission source.
The emission source may have an exemption from control stated in the regulation. The emission source may not have to be controlled but may have
monitoring, recordkeeping, or reporting requirements.
2 -The regulations have applicable requirements that apply to this particular ernission source but the source is currently exempt from these requirements
due to meeting a specific criterion, such as it has not been constructed, modified or reconstructed since the regulations have been in place. If the
specific criteria changes the source will have to comply at a future date.
3 -The regulations apply to this general type of emission source (i.e. vents, furnaces, tOwers, and fugitives) but do not apply to this particular emission
source.
Blank — The regulations clearly do not apply to this type of emission source. .
0
-
15
CELLULOSE PLANT
AI NO. 1409; PER20110024
XII. Table 2. Explanation for Exemption Status or Non-Applicability of a Source

ID No.: Requirement
EQT0061, EQT0066, LAC 33:111.2115 DOES NOT APPLY — The streams subject to LAC 33:111.2149-
EQT0089, EQT0091 Wastc Gas Disposal Limiting VOC Emissions from Batch Processing.
EQT0092, EQT0093,
EQT0096,EQT0098,
EQT0I 04, EQT0118,
EQT1304 and EQTI305
EQT0109 and EQT0588 LAC 33:111.2103 DOES NOT APPLY — Contents have a true vapor pressure less than 1.5
Storage of Volatile Organic Compounds psia at storage conditions or capacity of the tank is less than 250 gallons
, LAC 33:HI.2115 DOES NOT APPLY — The streams subject to LAC 33:111.2149-
Waste Gas Disposal Limiting VOC Ernissions from Batch Processing,
40 CFR 60 Subpart Kb for VOL Storage DOES NOT APPLY — Capacity is less than 75 cubic meters.
Vessels
EQT0107, EQT0108, LAC 33:111.2103 DOES NOT APPLY — Contents have a true vapor pressure less than 1.5
EQT0586, EQT0587 and Storage of Volatile Organic Compounds psia at storage conditions or capacity of the tank is less than 250 gallons
EQT0860 through EQT0865 40 CFR 60 Subpart Kb for VOL Storage DOES NOT APPLY — Capacity is less than 75 cubic meters.
Vessels
EQT0113, EQT01 I Sand LAC 33:111.2103 DOES NOT APPLY — Content has a true vapor pressure less than 1.5
EQT0i 16 Storage of Volatile Organic Compounds psia at storage conditions.
40 CFR 60 Subpart K for Petroleum Liquids DOES NOT APPLY — Tanks do not storc petroleum liquids and were
Storage Vessels constructed prior to June 11, 1973 or tanks do not store petroleurri
hquids and has a capacity less than 40,000_gallons.
EQT0589 40 CFR 63 Subpart Q - NESHAP for DOES NOT APPLY — Cooling tower does not use chromium-based
Industrial Process Cooling Towers water treatment chemicals on or after September 8, 1994. §63.400(a)
FUG0006 LAC 33:111.2122 - Fugitive Emission Control DOES NOT APPLY —Not a SOCMI facility
for Ozone Nonattainment Areas
UNF0002 LAC 33:111.2153 - Limiting VOC Emissions EXEMPT — Overall control of VOC emissions frorn wastewater is less
Cellulose Plant from Industrial Wastewater than 90% of the 1990 baseline emissions inventory. §2153.G.4
I6
General Information
Al ID: 1409 The Dow Chemical Co - Louisiana Operations
Activity Number: PER20110024
Permit Number: 2227-V7
Air - Title V Regular Permit Renewal
Also Known As: ID Name User Group Start Date
2204700008 AFS (EPA Air Facility System) AFS (EPA Air.Facility System) 01-01-2000
RAL-020 Recognized Asbestos Landfill Asbeslos 12-15-2006

1280-00008 CDS Number CDS Nurnber 05-27-1993
846731 1 EPA EIS Facility Site ID EPA EIS Facility Site ID 01-01-2008
38-1285128 Federal Tax ID Federal Tax ID 11-21-1999
LA0008187080 Dow Chemical Co LA Operations Hazardous Waste Notification 01-29-1986
PMT/CA GPRA Baselines Hazardous Waste Permitting 10-01-1997
F0550 UM Station # I/M Station 07-07-2011
00290 Dow Chemical Inactive & Abandoned Sites 09-01-1986
LA0008187080 Dow Chernical USA Inactive & Abandoned Sites 06-09-1981
LA0003301 • LPDES Permit # LPDES Permit # 11-23-1987
LAM/51,1128 LPDES Permit # LPDES Permit # 10-24-2001
LAR1013702 LPDES Permit # LPDES Permit # 10-29-2001
GP1596 LWDPS # LWDPS Permit # 1 1-21 -1999
WP1561 LWDPS # LWDPS Permit # 06-25-2003
WP1654 LWDPS # LWDPS Permit # 06:25-2003
Priority 1 Emergency Site Priority 1 Emergency Site 07-18-2006
LA-2002-L02 Radioactive Material License Radiation License Number 03-12-2001
2002 X-Ray Registration Number Radiation X-ray Registration Number 11-21-1999
GPDT-047-0107 Site ID # • Solid Waste Facility No. 04-30-2001
P-0069 Standard Permit Solid Waste Permitting 01 -1 3-1 986
1280A0002 Stage II Vaper Recovery Stage II Vapor Recovery 08-19-2002
11649 Dow Chemical USA TEMPO Merge 05-22-2001
126305 Dow Chemical Co - Vinyl II Cooling Tower TEMPO Merge 12-19-2005
19794 Dow Chemical USA - LA Division New Tank Farm TEMPO Merge 07-01-2001
38771 Dow Chemical Co - LA Operations TEMPO Merge 05-22-2001
41283 Dow Chemical Co TEMPO Merge 05-22-2001
44749 Dow Lighthouse Rd TEMPO Merge 08-25-2002
44945 Dow Chemical USA TEMPO Merge 05-22-2001
52295 Dow Chemical USA - COal Gasification TEMPO Merge 05-22-2001

70765THDWCHIGHW TRI # Toxic Release Inventory 07-08-2004
24011629 UST Facility ID # UST FID # 10-11-2002
Page 1 of 4 'MORO 148

General Information
Main Phone: 2253538888
Physical Location: 21255 Hwy 1
(Portion of)
Plaquemine, LA 70765
Mailing Address: PO Box 150

Plaquemine, LA 707650150
Location of Front Gate: 30 313611 latitude. -91_240381 longitude. Coordinate Method: Lat,\Long. • DMS. Coordinate Datum NAD83
Related People: Name . Mailing Address Phone (Type) Relationship
Scott Bemis PO Box 150 Plaquemine, LA 707650150 2253538888 (WP) Responsible Official for
Catherine Bilello PO Box 150 Piaquemine, LA 707650150 2253538888 (WP) Responsible Official for
Lucius Boudreaux 21255 Hwy 1 Bldg 3502 Plaquemine. LA 70764 2253536094 (WP) Remediation Contact for
Mike Chnstal PO Box 150 Plaquemine. LA 707650150 2253538888 (WP) Responsible Official for
Sharon Cole PO Box 150 Plaquemine, LA 707650150 2253538888 (WP) Responsible Official for
Steve Cook PO Box 150 Plaquemine, LA 707650150 2253538888 (WP) Responsible Official for
Joseph Hanna PO Box 150 Plaquemine, LA 707650150 2253538888 (WP) Responsible Official for
Dan Jason PO Box 150 Plaquemine, LA 707650150 2253538888 (WP) Responsible Official for
Gretchen LeBlanc PO Box 150 Plaquemine, LA 707650150 2253531642 (WP) Accident Prevention Billing Party for
Gretchen LeBlanc PO Box 150 Plaquemine, LA 707650150 2253531642 (WP) Stage li Vapor Recovery Billing Parry for
Gretchen LeBlanc PO Box 150 Plaquemine. LA 707650150 2253531642 (W P) Water Billing Party for
Gretchen LeBlanc PO Box 150 Plaquemine. LA 707650150 2253531642 (WP) Soho Waste Billing Party for
Gretchen LeBlanc PO Box 150 Plaquemine, LA 707650150 2253531642 (WP) Responsible Official for
Steve Ledoux PO Box 150 Plaquemine, LA 707650150 2253538888 (WP) Responsible Official for
C Craig Leopard PO Box 495 Plaquemine. LA 70765 2253535871 (WP) Responsible Official for
Donald Lyle PO Box 150 Plaquemine. LA 707650150 2253538888 (WP) Responsible Official for
William Myers PO Box 150 Plaquemine. LA 707650150 2253538888 (WP) Responsible Official for
Lisa Perry PO Box 150 Bldg 3502 Plaquemine, LA 707650150 2253534316 (W P) Hazardous Waste Permit Contact For
Lisa Perry PO Box 150 Bldg 3502 Plaquemine. LA 707650150 2253534316 (WP) Underground Storage Tank Contact for
Brad Rabelais 21255 Hwy 1 Bldg 3502 Plaquemine, LA 70764 2253226146 (DP) Radiation Contact For
Brad Rabelais 21255 Hwy 1 Bldg 3502 Plaquemine, LA 70764 BRABALAIS-(gDOW Radiation Contact For
Brad Rabelais 21255 Hwy 1 Bldg 3502 Plaquemine, LA 70764 2253538001 (WF) Radiation Contact For
Brad Rabelais 21255 Hwy 1 Bldg 3502 Plaquemine, LA 70764 2253536.146 (WP) Radiation Contact For
Brae Rabelais 21255 Hwy 1 Bldg 3502 Plaquemine. LA 70764 2253226146 (DP) Radiation Safety Officer for
Brad Rabelais 21255 Hwy 1 Bldg 3502 Plaquemine. LA 70764 BRABALAIS@DOW Radiation Safety Officer for
Brad Rabelais 21255 Hwy I Bldg 3502 Plaquemine, LA 70764 2253536146 (wp) Radiation Safety Officer for
Brad Rabelais 21255 Hwy 1 Bldg 3502 Plaquemine, LA 70764 2253538001 (WF) Radiation Safety Officer for
Ray Ratcliff 21255 LA 1 South Plaquemine. LA 70765 2253538519 (VVP) l/M Contact tor
Chris Reed PO Box 150 Plaquemine, LA 707650150 2253538888 (WP) Responsible Official for
John Rinaudo Po Box 150 Bldg 3502 Plaquemine, LA 707640150 2253535883 (WP) Emission inventory Facility Contact for
Page 2 of 4 TPOROIAB
General Information
Related People: Name Mailing Address Phone (Type) Relationship
John Rinaudo PO Box 150 Bldg 3502 Plaquemine: IA 707640150 jjrinaudo@dow.com Emission Inventory Facility Contact for
Amy Schilling PO Box 150 Plaquemine, LA 707650150 2253538888 (WP) Responsible Official for
Paul Soileau ' PO Box 150 Plaquemine, LA 707650150 2253538888 (WP) Responsible Official for
Susan Williams PO Box 150 Plaquemine, LA 707650150 2253538888 (WP) Responsible Official for
Related Organizations: Name Address Phone (Type) Relationship
JE Merit Constructors Inc 4949 Essen Ln Baton Rouge, LA 70898 2257685548 (WP) Provides environmental services for
National Maintenance Corp 2865 Mason St Baton Rouge, LA 70865 Provides environmental services for
Petrin Corp 1405 Commerical Dr Port Alien, LA 70767 2253430471 (WP) Provides environmental services for
Petrin Corp 1405 Commerical Dr Port Allen, LA 70767 2253430475 (WF) Provides environmental services for
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 irinaudo@dow.com Air Billing Party for
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 2253531883 (WP) Air Billing Party for
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquernine, LA 707650150 jjrinauclo@dow.com Radiation License Billing Party for
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 2253531883 (WP) Radiation License Billing Party for
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 2253531883 (WP) Emission Inventory Billing Party
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 2253531883 (WP) Radiation Registration Billing Party for
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 grinaudo@dow.com Radiation Registration Billing Party for
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 2253531883 (WP) Radiation Registration Billing Party far
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 jjrinaudo@dow.corn Air Billing Party for
The Dow Chernical Co PO Box 150 Bldg 3502 E Plaquernine, LA 707650150 2253531883 (WP) Air Billing Party for
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 jirinaudo@dow.com Owns
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 2253531883 (WP) Owns
The Dow Chemical Co PO Box 150 BIdg 3502 E Plaquemine, LA 707650150 jjrinaudo@dow.com Radiation License Billing Party for
.
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 2253531883 (WP) Radiation License Billing Party for
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquernine, LA 707650150 ljrinaudo@clow.com Operates
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 2253531883 (WP) Operates
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 jjrinaudo@dow.com Emission Inventory Billing Party
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 2253531883 (WP) UST Billing Party for
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine. LA 707650150 brinaudo@dow.com UST Billing Party for
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 2253531883 (WP) Owns
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 jirinaudo@dow.com Owns
The Dow Chemical Co PO Box 150 Bldg 3502 E Plaquemine, LA 707650150 jkinaudo@dow.com Radiation Registration Billing Party for
Page 3 of 4 TPORC11411
General information
Perrnit Number: 2227-V7
Note: This report entitled "General Information" contains a summary of facility-level information contained in LDEO's TEMPO database for this facility and is not considered a part of the permit.
Please review the Information contained in this document for accuracy and completeness. if any changes are required or if you have questions regarding this document, you may contact Ms.
Tornrnie Milam, Permit Support Services Division, at (225) 219-3259 or email your changes to facupdate@la.gov.
Page 4 of 4 TP040148
INVENTORIES
Permit Nurnber: 2227-V7
Subject Item Inventory:

ID Description Tank Volume ' Max. Operating Rate 1 Normal Operating Rate Contents Operating Time
.
______i_
Cellulose Plant
-EQT 0061 6A - Treating Chernical System 3139 lb/hr 3139 lb/hr 8760 hrlyr
I
EQT 0066 VF - R-201 Reactor Vent 468 ft^3/hr 79 ft"3/hr 8760 hr/yr
1
EOT 0070 7N -13-203 Blower Exhaust 2600 lb/hr 2226 lb/Fir 13760 hr/yr
EQT 0071 70 - B-205 Blower Exhaust 2600 lb/hr i 2226 lb/hr 8760 hr/yr
EQT 0072 7P - H0-201 Hopper Vent 5200 lb/hr 2226 lb/hr 8760 hrlyr
EQT 0073 70 - HO-202 Hopper Vent 5200 lb/hr ----1 2226 lb/hr 8760 hrtyr
EQT 0076 8N - B-20 Blower Exhaust • • 6000 lb/hr 2820 lb/hr 8760 hilyr
EQT 0079 B8 -130C-30A Blower Exhaust 6000 lb/hr 2226 lb/hr 8760 hr/yr
.__._
EQT 0080 89 - BDC-30B Blower Exhaust 6000 ibThr 2226 lb/hr 8760 hrtyr
EQT 0081 BR - A2A Blender 10000 lb/hr F 1484 lb/hr 8760 hrtyr
8760 hr/yr
EQT 0082 BS - A2B Blender 10000 lb/hr T 1484 lb/hr
8760 rir/yr
EQT 0083 BT - A2C Blender . 10000 lb/hr 1484 lb/hr
EOT 0084 BU - A2D Blender 10000 lb/hr l 1484 lb/hr 8760 hr/yr
EQT 0086 BW - BW HO-30A Hopper Vent 6000 lb/hr 2226 ib/hr 8760 hrtyr
EQT 0088 BZ - HO-30B Hopper Vent 6000 lb/hr 2226 !NW • 8760 hrlyr
EOT 0089 C5 - TR-200 Treated Blender Vent 30000 lb/hr —1 1256 lb/hr 8760 hr/yr
EQT 0091 C7 - B-1451 Blower Exhaust 6000 lb/hr I 3200 lb/hr 8760 hr/yr
EQT 0092 C8 - B-232 Blower Exhaust 6000 lb/hr 2968 lb/hr 8760 hr/yr
EQT 0093 C9 Reactor Blower Exhaust 4680 SCFM 1800 SCFM 8760 hrlyr
EOT 0095 CC '- BDC-60 Blower Exhaust 10000 lb/hr 2536 lb/hr 6760 hrlyr
EQT 0096 CG - TR-300 Treated Blender Vent 30000 lb/hr 1256 lb/hr 8760 hr/yr
EQT 0098 DC - Consolidated Blower Exhaust 8760 hr/yr
EDT 0101 DZ - 1-89 Blower Exhaust 500 lb/hr .57 lb/hr 8760 hr/yr
EOT 0104 V6 - B-200 Blower Exhaust 18000 lb/hr 2413 lb/hr .8760 hr/yr
EQT 0107 D5 .! T-211 Tank Vent 73 gallons • —I 8760 hrtyr
EQT 0108 DA - 0-8554 Tank Vent 1581 gallons 8760 hr/yr
EQT 0109 E6 - CF-221/CF-222/0223 1512 gallons . 8760 hr/yr
EOT 0113 V9 - T-50 Tank Vent •4136 gallons 8760 hr./yr
EOT 0114 DB - BDC-80 Untreated Packaging Dust Collection • 500 lb/hr 25 lb/hr 8760 hrlyr
EQT 0115 VA - T-17A Tank Vent 9107 gallons 1- 8760 hr/yr
EQT 0116 VB - T-17I3 Tank Vent 9106 gallons i 8760 hr/yr
EQT 0118 VG - R-202 Reactor Vent . 468 ft"3/hr - 79 tt"3/hr 8760 hrlyr .
EOT 0120 VT - BV-20D Bin Vent tor HO-200 5000 lb/hr 1712 lb/hr 8760 hr/yr
EQT 0121 28 - BDC-5A Blower Loop Vent 6000 lb/hr 3000 lb/hr 8760 hrlyr
EQT 0586 El - 0-221 Reslurry Tank 752 gallons 8760 hr/yr
EQT 0587 E2 - D-222 Water Recovery Tank 6200 gallons 8760 hr/yr
EQT 0588 E3 - CF-226 23 gallons i 8760 hr/yr
EQT 0589 E4 - Cooling Tower CT-7000 4890 gallons/min 8760 hr/yr
EQT 0591 815 - BDC-1B Blower Exhaust 6000 lb/hr 1712 lb/hr 8760 hr/yr
Page 1 01 6 TPORD149
INVENTORIES
Al ID: 1409 - The Dow Chemical Co - Louisiana Operations
Alr - Title V Regular Permit Renewal
Subject Item Inventory:

Description I Tank Volume : Max. Operating Rate I Normal Operating Rate Contents I Operating Time
ID
' !
!Cellulose Plant
• 8760 hrtyr
j75 - Boiler F-410 40 2 MM BTU/hr 40 2 MM BTUfhr
40 2 MM BTU/hr 8760 hrlyr
EQT 0719 :76 - Boiler r-420 40 2 MM BTU/hr
OTT3858 IC3(E110-A) - Exchanger Vent - C3(E110-A) 8760 hrtyr
r EQT 0859 1C4(E110-B) • Exchanger Vent - C4(E110-13)

EOT 9860 'AT-200 • Spray Tank - AT-200
•
8760 hrtyr
8760 hrtyr
8760 hrtyr
, EQT 0861 AT-300 - Spray Tank - AT-300
• 8760 hrtyr
IEOT 0862 IAT-400 - Sp:ay Tank • AT-400
I EDT 0863 ISP-200 - Spray Tank • SP-200 8760 hrtyr
Spriy Tank - SP-300 8760 hrtyr
E0T 0865 :Spray Tank - SP-400 8760 hrlyr
30 MM BTU/hr 30 MM BTUfhr Also in EDC I and Cellulose l 8760 hr/yr
rEdIT 0866 1HA - CMP R-750 THROX
Plant Perrrots
I EOT 0877 lc.120. Stearn Stripper 8760 hr tyr
EOT 0878 C-121 - Steam Stnpper -1- 8760 hrlyr —
13760 hr/yr
Itbf 0-879- 7 (3roup 1 Wastewater Streams
8760 hr/yr
:EOT 0880 CY-231 - Cyclone
EQT 0881 CY-22 - Cyclone 8760 hrtyr
9000 lb/hr 2226 lb/hr 8760 hr/yr
, EOT 1304 1001 - DC-1140 Dust Collector Vent
IEQT 1305 1002 - DC-1142 Dust Collector Vent 9000 lb/hr • 2226 ibfhr 8760 hr/yr
6000 lb/hr 3000b/h lr 8760 hrtyr
EQT 1331 Z9 - BDC•513 Blower Loop Vent
FUG 9006 D4 -.Fugitive Emissions 876Ct hdyr
, RLP 0098 ,7-120 • Tank Vent 8760 rirtyr
RLF-5 0099 17-121 • Tank Vent 8760 hrfyr
RIP CW36 'IT-75 - vent 8760 hrtyr
I
RLP-El1O1 - Tani Vent 8760 hr/yr
IRLP 0 102 :VENTS - Process Vents 8760 hrlyr
.. . .
Stack information:
ID DescriptIon Velocity Flow Rate Diameter DIscharge Area Height Temperature
(Ittsec) (cubic ft/min-actual) (feet) (square feel) (leet) (oF)
Cellulose Plant
5000 67 52 77
EQT 0061 6A - Treating Chemical System
EQT 0066 VF • R-201 Reactor Vent 23.9 8.6 .01 60 160
1.17 9 77
j151T3677)-7,7:tr:05 fic7ver Exhaust
85.5 6000 1.17 9 77
EQT 0071 70 • B-205 Blower Exhaust
5 40 77
TETDI9072-70 - H-0-201 Hopper Vent
5 40 77
TEdi-697-3--7.(5= .17t6-202 Hopper Vent
Page 2 01 6 7 PORD t4S

INVENTORIES
Air - Title V Regular Perrnit Renewal
Stack information:
ID Description Velocity Flow Rate Diameter Discharge Area Height Temperature
(ft/sec) (cubic ft/min-actual) (feet) (square feet) (feet) (on
•
Cellulose Plant
EOT 0076 8N - B-20 Blower Exhaust 214 5000 .39 14 • 77
EQT 0079 B8 - BDC-30A Blower Exhaust 238 5000 .35 17 77
EQT 3080 B9 - BDC-30B Blower Exhaust 238 5000 .35 17 77

EQT 0081 BR - A2A Blender .17 44
EQT 0082 BS - A2B Blender .17 44
EQT 0083 BT - A2C Blender .17 44
EDT 0084 BU - A2D Blender .17 44
EOT 0086 BW - BW HO-30A Hopper Vent .17 65 77
EOT 0088 BZ -1-10-30B Hopper Vent ..17 65 77

EOT 0089 C5 - TR-200 Treated Blender Vent .5 64
EOT 0091 C7 - B-1451 Blower Exhaust 36.7 1300 .59 60 147
EQT 0092 C8 - 8-232 Blower Exhaust 32.38 4565 .79 72 129
EOT 0093 C9 - Reactor Blower Exhaust 30 159 .09 .5 81
EOT 0095 CC - BDC-60 Blower Exhaust 93.6 5000 .89 63 77
EQT 0096 CG - TR-300 Treated Blender Vent .5 64 170

EOT 0098 DC - Consolidated Blower Exhaust 93 6000 1.07 15 77
EDT 0101 DZ - 1-B9 Blower Exhaust 362 5000 .23 11 77
EOT 0104 V6 - B-200 Blower Exhaust 61.9 3491 .94 20 77
EQT 0107 D5 - T-211 Tank Vent .25 77
EOT 0108 DA - D-8554 Tank Vent

EQT 0109 E6 - CF-2211CF-222/D223
EDT 0113 V9 - T-50 Tank Vent .09 1 77
EQT 0114 DB - BDC-80 Untreated Packaging Dust Collection .5 2.3
EOT 0115 VA - T-17A Tank Vent .34 15 77
EOT 0116 VB - T-17B Tank Vent .34 15 77
EQT 0118 VG - R-202 Reactor Vent 23.9 8.6 .01 60 160

EOT 0120 VT - BV-20D Bin Vent for HO-200 .17 80
EOT 0121 Z8 - BDC-5A Blower Loop Vent .67 52 77
EQT 0589 E4 - Cooling Tower CT-7000 834060

EDT 0591 B5 - BDC-1B Blower Exhaust 126 5000 .67 52 77
EOT 0718 75 - Boiler F-410 70.4 13264 5 85 106

EQT 0719 76 - Boiler F-420 70.4 13264 5 85 106
Page 3 of 6 TPOR0149
INVENTORIES
Stack Information:
ID Description Velocity Flow Rale Diameter Discharge Area Height Temperature
(ftisec) (cubic It/min-actual) (feet} (square feet) (feet) (oF)
Iliulose Plant
FEW 0866 HA - CMP R-750 THROX 14 5357 3 75 119
EQT 1304 001 - DC-1140 Dust Collector Vent 1.8 37 67 105 77
EOT 1305 002 - DC-1142 Dust Collector Vent 1.8 37 67 105 77
•fdt15ji -23IJC-513 Blower LriotNe7t.-- 1 67 53 77
FUG 0006 D4 - Fugaive Emissions
Relationships:
ID Description Relationship ID Description
EQT 0858 C3(E110-A) - Exchanger Vent • C3(E110-A) !Vents to 1 EQT 0719 76 - Boiler F-420
EOT 0858 C3{E110-A) = Exchanger Vent - C3(E110-A) Vents to EQT 0718 75 - Boiler F-410
EOT 0858 C3(E110-A) • Exthanger Vent • C3(E110-A) Vents to EOT 0866 HA - CMP R-750 THROX
EQT 0859 I C4(E110-8) - Exchanger Vent • C4(E110-B) Vents to EQT 0718 75 - Boiler F-410
EQT0859 C4(E110-B) - Exchanger Vent - C4(E110-6) Vents to EOT 0719 76 - Boiler F-420
EOT 0859 I C4(E110-B) - Exchanger Vent • C4(E110-B) Vents to I EOT 0866 HA - CMP R-750 THROX
EQT 0860 ' AT-200 - Spray Tank - AT-200 Vents to I EQT 0089 C5 • TR-200 Treated Blender Vent
EQT 086U
i.
AT-200 - Spray Tank - AT-200 Vents to I EQT 01361 6A - Treating Chemical System
EQT 0860 i AT-200 - Spray Tank - AT-200 ;Vontsto I EQT 0096 CG - TR-300 Treated Blender Vent
EOT 0861 I AT-300 - Spray Tank - AT-300 Vents to EQT 0051 pA - Treating Chemical System
EOT 0861 AT-300 - Spray Tank - AT-300 Vents to I
EQT 0089 c5 - TR-200 Treated Blender Vent
EOT 0861 AT-300 - Spray Tank - AT-300 Vents to I ECIT 0096 CG - TR-300 Treated Blender Vent
EOT 0862 AT-400 - Spray Tank - AT-400 Vents to EOT 0061 6A - Treating Chemical System
p 0862 AT-400 - Spray Tank - AT-400 Vents to EOT 0089 C5 - TR-200 Treated Blender Vent
FQT 0862 AT-400 - Spray Tank - AT-400 Vents to EQT 0096 CG - TR-300 Treated Blender Vent
Ear 0863 SP-200 - Spray Tank - SP-200 Vents to EOT 0061 BA - Treating Chemical System
EOT 0863 SP•200 • Spray Tank - SP-200 ents to EQT 0089 C5 - TR-200 Treated Blender Vent
EQT 0863 SP-200 - Spray Tank • SP•200 Vents to EQT 0096 CG - TR-300 Treated Blender Vent
QT 0864 SP-300 - Spray Tank - SP-300 ents to EQT 0061 6A - Treating Chemical System
V
FQT 06-64 -- P-300 - Spray Tank - SP-300 Vents to EQT 0096 CG - TR-300 Treated Blender Vent
. ttiT0864 —S—P-300 - Spray Tank - SP-300 Vents to EOT 0089 C5 - TR-200 Treated Blender Vent
EQT 0865 SP-400 - Spray Tank - SP-400 Vents to EQT 0089 P5 - TR-200 Treated Blender Vent
EQT.6865 SP-400 - Spray Tank - SP-400 ents to EOT 0061 pA Treating Chemical System
EID10665 SP-400 - Spray Tank - SP-400 Vents to EOT 0096 CG - TR-300 Treated Blender Vent
EQT 0877 C-120 - Steam Stripper Vents to EOT 0718 75 - Boiler F-410
EQT 0877 C-120 - Steam Stripper Vents to EOT 0719 76 - Boiler F-420
Page 4 of 6 TPORO 149

INVENTORIES
Permit Number: 2227-W
Relationships:
ID Description Relationship ID Description
EQT 0877 C-120 - Steam Stripper Vents to EQT 0866 IHA - CMP R-750 THROX .
EQT 0878 C-121 - Steam Stripper Vents to EQT 0719 76 - Boiler F-420
ECIT 0878 C-121 - Steam Stripper tents to EOT 0718 75 - Boiler F-410
O-1 0878 C-121 - Steam Stripper ents to EQT 0866 ?AA - CMP R-750 THROX
rLP 0098 • . T-120 - Tank \fen! Supplier EQT 0878 C-121 - Steam Stripper
RLP 0099 T-121 - Tank Vent upplier EOT 0878 C-121 • Steam Stripper
RLP 0100 T-75 - Tank Vent Vents to EOT 0718 75 - Boiler F-410
i
-LP 0100 T-75 - Tank Vent . ents to EQT 0719 76 - Boiler F-420
'LP 0100 T-75 - Tank Vent Vents to EOT 0866 HA - CMP R-750 THROX
RLP 0101 T-208 - Tank Vent Vents to EOT 0719 1.76 - Boiler F-420
LP 0101 T-208 - Tank Vent tients to EOT 0718 75 - Boiler F-410
LP 0101 T-208 - Tank Vent Vents to EOT 0866 • A - CMP R-750 THROX
Subject Item Groups:

ID Group Type Group Description .
CRG 0009 Common Requirements Group CRG0009 - Common Requirement Group 9
CRG 0011 Comrnon Requirements Group - CRGO011 - Common Requirement Group 11
CRG 0013 Common Requirements Group CR00013 - Common Requirement Group 13
CRG 0014 Common Requirements Group CRG0014 - Common Requirement Group 14 .
UNF 0002 Unit or Facility Wide Facility - Cellulose Plant
Group Membership:
10 Description Member of Groups
EQT 0061 6A - Treating Chemical System . CRG0000000012 '
EOT 0066 VF - R-201 Reactor Vent CRG0000000014
EQT 0070 7N - 6-203 Blower Exhaust CRG0000000009
EQT 0071 70 - B-205 Blower Exhaust CRG0000000009
EQT 0072 7P - HO-201 Hopper Vent CRG0000000010
EQT 0073 7Q - HO-202 Hopper Vent CRG0000000010
EQT 0076 8N - 8-20 Blower Exhaust . CRG0000000009
EQT 0079 B8 - BOC-30A Blower Exhaust . CRG0000000009 .
EOT 0080 89 - BOC-308 Blower Exhaust CRG0000000009
EOT 0081 BR - A2A Blender CRG0000000010
EQT 0082 BS - A2B Blender CRG0000000010
EQT 0083 BT - A2C Blender • CRG0000000010
INVENTORIES
Group Membership:
ID Description Member of Groups
EOT 0084 I BU - A2D Blender ; CRG0000000010
EQT 0086 •
-1-15:30A Hopper Vent CRG0000000010
EOT 0088 I BZ - HO-30B Hopper Vent I CRG0000000010
I—EOT t1089 7 C5 • TR-200 Treated Blender Vent — 1 CRG0000000011
• EOT 0091 l C7 • 8-1451 Blower Exhaust j CRG0000000011
I EOT 0092 ; C8 • B-232 Blower Exhaust j CR00000000013
I EOT 0093 : C9 - Reactor Blower Exhaust ; CRG000000001r1
' EQT 0095 ; CC - BDC-60 Blower Exhaust i CRG0000000009
—EOT 0096 I CG - TR-300 Treated Blender Vent ; CRG0000000011
Ib f 0098 — • DC • Consolidated Blower Exhaust : CRG0000000011
EDI' 0101 ---i.DZ - 1-B9 Blower Exhaust i CRG0000000009
EQT 0104 l V6 - B-200 Blower Exhaust j CRG0000000013
j EOT 0109 I E6 - CF-221/CF-222/0223 • CRG0000000014
I EQT 0114 1 OB - MC-80 Untreated Packaging Oust Coljecbon t CRG0000000009
: EQ1' 0118 I VG • R-202 Reactor Vent , CRG000000-6014 ---- -
• EDT 0120 I VT • BV-20D Bin Vent tor HO-200 . CRG0000000010
1 EOT 0121 I Z8 • BDC-5A Blower Loop Vent ! CRG0000000009
r EOT 0586 j El - D-221 Reslurry Tank : CRG0000000012
EOT 0588 1 E3 • CF-226 . CRG0000000012
EOT 0591 IBS - BOC-1B Blower Exhaust i CRG0000000009
EQT 0880 : CY-231 - Cyclone CRG0000000009
EOT 0881 I cy•22 - cyclone ; CRG0000000009
EQT 1304 ! 001 • DC-1140 Dust Collector Vent i CRG0000000013
EOT 1305 . 002 - DC-1142 Dust Collector Vent CRG0000000013
EOT 1331 l Z9 - BDC-5B Blower Loop Vent CRG0000000009
NOTE: The UNF group retationshlp is not printed ln this table. Every subject Item Is a member of the UNF group
Annual Maintenance Foe:

Fee Number l - Alr Contaminant Source 1 MultIplier Units Of -Measure —I
0630 Orgarn Oxides, Alcohols. Glycols (Raw Capacity) I 23 5 MM lbstyr
SIC Codes:
2869 1 Industrial organic chemicals. nec UNF 002
Pago 6 of 6 TPORD14119
EMISSION RATES FOR CRITERIA POLLUTANTS
AI ID: 1409 - The Dow Chemical Co - Louisiana Operations
PM10 VOC
Subject !tern Avg lb/hr Max lb/hr Tons/Year I Avg lb/hr ' Max lb/hr Tons/Year
Cellulose Plant
EQT 0061
BA <0.01 <0.01 <0.01
EQT 0066
vP 0,11 27.91 0.50
EQT 0070
7N 0.03 0.04 0.12 -
EQT 0071
70 i 0.03 0.04 0.12
EOT 0072
TP 0.09 0.23 0.40
EOT 0073
70 0.09 0.23 0.40
_1
EQT 0076
BN 0.01 0.02 0.03
EQT 0079
88 0.01 0.02 • 0.02
EQT 0080
89 0.01 0.02 0.02
EOT 0081 .
BP <0.01 0.03 0.02
EOT 0082
BS <0.01 • 0.03 0.02
EOT 0083
BT <0.01 0.03 0.02
EOT 0084
BU <0.01 0.03 0.02 '
•
EOT 0086
BW 0.01 0.02 0.02
EQT 0088
BZ 0.01 0.02 0.02
EQT 0089
C5 <0.01 0.08 0.02 l <0.01 <0.01 <0.01
EOT 0091 7
07 0.03 0.06 0.12 8.59 63.71 37.62
EQT 0092
C.8 1 <0.01 <0.01 <0.01 , 3.18 139.09 13.92
EQT 0093
C9 • 0.32 2,86 1.39
EOT 0095
CC 0.01 0.03 0.03
--r
EOT 0096
CG • <0.01 0.08 , 0.02 <0.01 <0.01 <0.01
EQT 0098
DC 0.03 0.16 0.12 <0.01 <0.01 <0.01
EOT 0101
DZ <0.01 <0.01 <0.01
L .
Page 1 of 2 TPORO145
EMISSION RATES FOR CRITERIA POLLUTANTS
PM10 I VOC
Subject Item I Avg lb/hr Max lb/hr Tons/Year Avg lb/hr Max Ibihr Tor
Ceflulose Plant
EQT 0104 •
v6 0 04 I 0 24 0 16 0 06 0.48 l 0 26
EQT 0107
05 <0.01 <0.01 <0.01
EQT 0108
DA
<0,01 <0 01 <0.01
EQT 0109
E6 1 62 3.20 7.11 1
EQT 0113
<0 01 1 35 0.01
EQT 0114
DB <0 01 <0 01 <0.01
EOT 0115
vA • <0.01 0 01 <0 01
_
EQT 0116
VB • <0.01 0 32 i 0.01
____.. _
EQT 0118
0.11 27 91 0 50
EQT 0120
0 01 ooi 0 03
EOT 0121
16 0 01 0 02 0 02
EOT 0586 I
E1 <0.01 <0 01 0.01
— EdT 0587
E2 <0,01 <0 01 0.01
EQT 0588
E3 <0.01 <0.01 0 01
EQT 0589
EA
0 05 0.06 0.21
EOT 0591
<0 01 0 02 0 01
EQT 1304
<0 01 <0 01 <0 01 0.22 1 44 • 0.98 I
_
— EOT 1305 <0 01 <0 01 <0 01 0.22 1 44 0.98
032 I
EQT 1331
Z9 0 01 0 02 0 02
FUG 0006
DA 1 81 2.17 7.92
Note: Emission rates in bold are from alternate scenarios and are not included in permitted totals unless otherwise noted in a footnote.
Page 2 01 2
EMISSION RATES FOR TAP/HAP & OTHER POLLUTANTS
Emission Pt. Pollutant Avg lb/hr i Max lbihr. Tons/Year

i
EQT 0068
VF
Methanol 0.01 3.42 . 0.06
Methyl chloride 0.01 2.25 0.04
Propylene oxide <0.01 0.54 0.01

EOT 0070
7N
Total suspended particulate 0.08 0.10 • 0.34
EOT 0071
70 Total suspended particulate 1 0.08 0.10 0.34
EOT 0072
7P Total suspended particulate 0.59. 1.53 2.60
EQT 0073
70
Total suspended particulate 0.59 1.53 2.60
EOT 0076
tot Total suspended particulate 0.01 0.03 ' 0.05
EQT 0079
ea Total suspended particulate 0.02 0.06 0.09
EQT 0080
89
ECIT 0081
BR Total suspended particulate 0.01 0.10 0.06
EQT 0082
es Total suspended particulate • 0.01 0.10 0.06
EOT 0083
BT Total suspended particulate 0.01 0.10 0.06
EOT 0084
8U
EOT 0086
BNI
Total suspended particulate 0.02 0.06 0.09 .
EOT 0088
82
EQT 0089 -
C5
EQT 0091
, C7
Methanol 0.37 1.23 - 1.61
Methyl chloride <0.01 <0.01 <0.01
Propylene oxide <0.01 <0.01 <0.01

EOT 0092
Ca
Methanol 1.45 69.14 6.33
Propylene oxide <0.01 0.19 0.02
Total suspended particulate <0.01 <0.01 <0.01

EQT 0093
C9
Methanol 0.06 0.56 0.28
Propylene oxide 0.01 0.08 0.04

.
EOT 0095
cc Total suspended particulate 0.03 • 0.10 0.12
EOT 0098
CG Total suspended particulate . 0.01 0.31 0.06
EOT 0098
oc Total suspended particulate 0.10 0.60 • 0.44
EQT 0101
0.Z Total suspended parliculate <0.01 0.01 <0.01
EQT 0104
V6 Methanol 0.03 0.25 0.13 -
TPOR0148
Page 1 of 3
.1 •
Ernisslon Pt. Pollutant Avg tbihr Max Ibihr TonsfYear 1
EOT 0104 0.01

Propyfene oxide <0 01 0.02
v11
Tolal suspended particulate 0 10 0.69 1 0.45
EOT 0109
Mothand <0 01 <0.01 <0 01
ES
Methyl chloride 1 58 3.11 l 6 91
Propylene oxide <0.01 0.01 0 01
EOT 0114
Total suspended particulate <0.01 l 0.01 <0.01
oe
EOT 0118
Methanol 0 01 3 42 0 06
vG
Methyl chloride 0 01 2 25 0 04
Propyfene oxide <0 01 0.54 0 01

..... ..... _ .
•EOT 0120
Total suspended particulate 0 01 0 03 0 05
V7
EQ1 0121
Total suspended particulate 0.02 0.06 0 09
Z6
EOT 0586 <0 01 0 01
Methanol I <0 01
E
EQT 0587 <0 01 . <0 01 0 01
Methanol
E2
• EOT 0588 0.01
Methanol <0.01 <0.01
E3
E OT 0589. !
<0 01 0 02
Chlorine
E
<0 01
Total suspended particulate 0.05 I 0.06 0.21
If01 0591 'Total suspended particulate 0.02 : 0 20 0 10

85
- 0 11 0 74 0.48
Methanol i
001 -----•--•--.
Methyl chloride <0.01 1 0.01 0.01

l
Propylene oxide 0.01 1 0.07 0 04
Total suspended particulate <0.01 I 0 01 .<0 01

I
EOT 1305 0 11 0 74 0 48
Methanol 1
002
Methyl chlonde <0.01 0.01 0 01
Propylene oxide 0.01 0 07 0 04

•
-.• •. • --
Total suspended particulate <0.01 0.01 <0.01

• . ----•-_-_---
EOT 1331 0 09
Total suspended particulate 0.02 0.06
[Zs
• -•
Methyl chlonde 1 02 1 23 4 49
04
Propylene oxide 0.07 0.09 0.31

.. -- --
UNF 0002 0 02
Chlonne
F *Nay 1--
Methanol 9.47
Methyl Chloride 11.53
Propylene oxide 0 50
Total suspended particulate 8 65
PORD146
Page 2 of 3
Al ID, 1409 - The Dow Chemical Co - Louisiana Operations
Note: Emission rates in bold are from alternate scenarios and are not included In permitted totals unless otherwise noted in a footnote. Emission rates
attributed to the UNF reflect the sum of the TAPIHAP limits of the Individual emission points (or caps} under this permit, but do not constitute an
emission cap.
TPORO146
Page 3 of 3
SPECIFIC REQUIREMENTS
Activity Number: PER20,110024
CRG 0009 CRG0009 - Common Requirement Group 9

Group Members: EQT 0070 EQT 0071 EQT 0076 EQT 0079 EQT 0080 EQT 0095 EQT 0101 EQT 0114 EQT 0121 EQT 0591 EQT 0880 EQT 0881 EQT 1331
1 [LAC 33:111.1311.C] Opacity <= 20 percent; except emissions may have an average opacity in excess of 20 percent for not more than one six-minute period in any 60
consecutive minutes.
Which Months: All Year Statistical Basis: Six-minute average
2 [LAC 33:111.501.C.6] The dust filters/baghouses/cyclones shall be maintained and operated properly. Visible emissions shall be checked on a daily basis. The filter
. elements/bags/parts shall be inspected every six months and whenever visual checks indicate maintenance may be necessary. Elements/parts shall
be changed as necessary. Records of visual checks and maintenance inspections of the dust filters/baghouses shall be kept on site and available
for inspection by the Office of Environmental Compliance, Surveillance Division.

Group Members: EQT 0072EQT 0073 EQT 0081 EQT 0082 EQT 0083 EQT 0084 EQT 0086 EQT 0088 EQT 0120
3 (LAC 33:111 l 311.C] Opacity <= 20 percent; except emissions may have an average opacity in excess of 20 percent for not more than one six-minute period in any 60
CRG 0011 CRG001.1 - Common Requirement Group 11

Group Members: EQT 0089 EQT 0091 EQT 0096 EQT 0098
4 [LAC 33:111.1311.C] Opacity <= 20 percent; except emissions may have an average opacity in excess of 20 percent for not more than one six-minute period in any 60
5 [LAC 33:111.2149.C] VOC, Total >= 90 % reduction if the actual average flow rate value (in the units of scfm) is below the value of FR calculated using the applicable
RACT equation for the volatility range (low, moderate or high) of the material being emitted when the annual mass emission total, in the units of
pounds per year, are input. Use the RACT equation specified in LAC 33:111.2149.C.1.
Which Months: Ail Year Statistical Basis: None specified •
6 [LAC 33:111.2149.D.11 Determine the annual mass emissions total using engineering estimates of the uncontrolled emissions from a process vent or group of process
vents within a batch process train and multiplying by the potential or permitted number of batch cycles per year, or by using an emissions
measurement that conforms with the requirements of measuring incoming mass flow rate of VOCs as described in LAC 33:111.2149.E.2.b and
E.2.c.ii and iii.
7 (LAC 33:111.2149.D.2] Measure the flow rates or estimate the flow rates using suitable estimation methods.
8 [LAC 33:111.2149.E.2) Use the methods and procedures specified in LAC 33:111.2149.E.2.a through 2.c to comply with the percent reduction efficiency requirement
listed in LAC 33:111.2149.C.
9 RAC 33:III.2149.G] Equipment/operational data recordkeeping by electronic or hard copy continuously. Keep records of the information specified in LAC
33:111.2149.0.1 and 0.2 for each process vent contained in the batch process.
10 [LAC 33:111.5109.A] No TAP emissions (EQT089, EQT096, EQT098) or No additional control is determined as MACT (EQT091).
, Permit Number: 2227-V7

Group Members: EQT 0061EQT 0586 EQT 0588
11 [LAC 33:111 2149C] VOC, Total >= 90 % reduction if the actual average flow rate value (in the units of scfm) is below thc value of FR calculated using the applicable
RACT equation for the volatility range (low, moderate or high) of thc material being emitted when the annual mass emission total, in the units of
pounds per year, are input. Use the RACT equation specified in LAC 33:111.2149.C. I.
Which Months: All Year Statistical Basis: None specified
12 [LAC 33:111.2149 D 1] Determine the annual mass emissions total using engineering estimates (Ache uncontrolled emissions from a process vent or group of process
vents within a batch process train and multiplying by the potential or permitted numbcr of batch cycles per year, or by using an emissions
measurement that conforms with the requirements of measuring incoming mass flow tate of VOCs as described in LAC 33:III.2149.E.2.b and
and iii.
13 [LAC 33111.2149.D.2] Measure the flow rates or estimate thc flow rates using suitable estimation methods.
14 [LAC 33.111.2149 E 2} Use the methods and procedures specified in LAC 33:II1.2149.E.2.a through 2 c to comply with thc percent reduction efficiency requirement
listed in LAC 33111.2149 C
15 (LAC 33.111.2149 G] Equipment/operational data recordkeeping by electronic or hard copy continuously.. Keep records of the information specified in LAC
33:311.2 149.G.1 and G.2 for each process vent contained in thc batch process.
16 (LAC 33 111 5109 A] Tank emits Class III TAP methanol only; therefore, MACT is not required.

17 [LAC 33111.1311.C] Opacity <= 20 percent: except emissions may have an average opacity in cxccss of 20 percent for not more than onc six-rninute period in any 60
Which Months: All Year Statistical 13asis: Six-minute average
18 [LAC 33:111.2149.C] VOC, Total >= 90 % reduction if the actual average flow ratc value (in the units of scfm) is below the value of FR calculated using the applicable
RACT equation for the volatility range (low, moderate or high) of the material being ernitted whcn the annual mass emission total, in thc units of
pounds per year, arc input. Use the R.ACT equation specified in LAC 33:111.2149.C.1.
19 [LAC 33:111 2149 ] Determine the annual mass emissions total using engineering estimates of the uncontrolled emissions from a process vent or group of process
vents within a batch process train and multiplying by the potential or perrnitted number of batch cycles per ycar, or by using an crnissions
measurement that conforrns with the requirements of measuring incoming mass flow rate of VOCs as described in LAC 33:111.21491.2.b and
E.2.c.ii and iii.
20 [LAC 33:111.2149.D.2] Measure the flow rates or estimate the flow rates using suitable estimation methods.
21 [LAC 33:111:2149.E.2] Use the methods and procedures specified in LAC 33111.2149.E.2.a through 2.c to comply with the percent reduction efficiency requirement
listed in LAC 33 111.2149.C.
22 [LAC 33:111.2149.G] Equipment/operational data recordkeeping by electronic or hard copy continuously. Keep records of the information specified in LAC
33:111.2149.G.1 and G.2 for each process vent contained in the batch process.
Page 2 of 13 TPORO147

23 [LAC.33:111.5109.A] Aggregate emissions from batch process vent streams are reduced by 90%. Reduction is achieved by collecting residual gases from each batch
through the vent gas recovery system. These gases are then condensed and routed back to the process or to the CMP plant for conversion to raw
material feed. Determined as MACT.

24 [LAC 33:III.2149.C] VOC, Total >= 90 % reduction if the actual average flow rate value (in the units of scfm) is below the value of FR calculated using the applicable
RACT equation for the volatility range (low, moderate or high) of the material being emitted when the annual mass emission total, in the units of
pounds per year, are input. Use the RACT equation specified in LAC 33:111.2149,C.1.
25 [LAC 33:111.2149.D.1) Determine the annual mass emissions total using engineering estimates of the uncontrolled emissions from a process vent or group of process
vents within a batch process train and multiplying by the potential or permitted number of batch cycles per year, or by using an emissions
measurernent that conforrns with the requirements of measuring incoming mass flow rate of VOCs as described in LAC 33:111.2149.E.2.b and
E.2.c.ii and iii.
26 [LAC 33:III.2149.D.2] Measure the flow rates or estimate the flow rates using suitable estimation methods.
27 [LAC 33:III.2149.E.2] Use the methods and procedures specified in LAC 33:111.2149.E.2.a through 2.c to comply with the percent reduction efficiency requirement
listed in LAC 33:11L2149.C.
28 [LAC 33:III.2149.G] Equipment/operational data recordkeeping by electronic or hard copy continuously. Keep records of the information specified in LAC
33:111.2149.G.1 and G.2 for each process vent contained in the batch process.
29 [LAC 33:IH.5109.A) Aggregate emissions from batch process vent streams are reduced by 90%. Reduction is achieved by collecting residual gases from each batch
through the vent gas recovery system. These gases are then condensed and routed back to the process or to the CMP plant for conversion to raw
material feed. Determined as MACT.
EQT 0587 E2 - D-222 Water Recovery Tank

30 [LAC 33:III.5109.A] •Tanks emit Class III TAP methanol only; therefore, MACT is not required.
EQT 0589 E4 - Cooling Tower CT-7000

31 [LAC 33:111.5109.A] Cooling tower emits the Class III TAP chlorine only; therefore, MACT is not required; however, facility-wide emissions of C12 are above its
MER, so compliance with the AAS and reporting C12 emissions is required.
EQT 0879 - Group 1 Wastewater Streams

32 [40 CFR 63.5505(a)] 40 CFR 63 Subpart UUUU refers to HON Subpart G, 40 CFR 63.132 through 40 CFR 63.140. Will meet option 40 CFR 63. 138(1) and
associated requirements. [40 CFR 63.5505(a)]
FUG 0006 04 - Fugitive Emissions

33 [40 CFR 63.162-179] Refers to apphcable parts of 40 CFR 63.162 through 40 CFR 63.179 - Subpart UUlill
34 (40 CFR 63.162(c)] Identify each piece of equipment in a process unit such that it can bc distinguished readily from equipment that is not subject to 40 CFR 63
Subpart H. Subpart H. (40 CFR 63.162(c))
35 140 CFR 63.16309(1 )) Purnps in light liquid service: Organic HAP monitored by 40 CFR 60, Appendix A, Method 21 monthly to detect leaks, except as provided in 40
CFR 63.162(b) and 63.I63(c) through (j). If a reading of 10,000 ppm (phase!), 5,000 ppm (phase II); or 5,000 ppm (phase III, pumps handling
polymerizing monomers), 2,000 ppm (phase 111, pumps in food/medical service), or 1,000 ppm (phase 111, all other pumps) or greater is
recorded, a leak is detected. If a leak is detected, initiate repair provisions specified in 40 CFR 63.163(c). Subpart H. [40 CFR 63.163(b)(1))
36 [40 CFR 63 163(b)(3)] Pumps in light liquid service: Presence of a leak monitored by visual inspection/determination weekly (calendar). Monitor for indications of
liquids dripping from the pump seal If there are indications of hquids dripping from the pump seal, a leak is detected, If a leak is detected,
initiate the repair provisions specified in 40 CFR 63.163(c). Subpart H. [40 CFR 63.163(b)(3))
Which Months: All Year Statistical Basis. None specified
37 [40 CFR 63 163(c)] Pumps in light liquid service: Make a tirst attempt at repair no later thin 5 calendar days after a leak is detected, and complete repairs no later
than 15 calendar days after the leak ls detected, except as provided in 40 CFR 63,163(c)(3) and 40 CFR 63.171 Subpart 11 (40 CFR 63.163(c))
38 [40 CFR 63.163(d)(2)J Pumps in light liquid service, implement a quality improvement program for pumps that complies with thc requirements of 40 CFR 63.176, if, in
Phase 111, calculated on a 6-month rolling average, the greater of.either 10 percent of thc pumps in a process unit or three pumps in a process unit
leak. Subpart H. [40 CFR 63.163(d)(2)]
39 [40 CFR 63.163(d)(4)] Pumps in light liquid service: Determine perceni leaking pumps using the equation in 40 CFR 63. I 63(d)(4). Subpar: 11. [40 CFR 63.163(04))
aci [40 CFR 63.163(0(2)) Pumps in light liquid service (dual mechanical seal system): Ensure that the barrier fluid is not in light liquid service. Comply with this
requirement instead of the requirements in 40 CFR 63.163(a) through (d). Subpart H. [40 CFR 63.163(e)(2)]
41 [40 CFR 63 163(e)(3)] Pumps in light liquid service (dual mechanical seal system): Equip barner fluid system with a sensor that will detect failure of the seal system,
barrier fluid system, or both. Comply with this requirement instead of the requirements in 40 CFR 63.163(a) through (d). Subpart H. [40 CFR
63.163(e)(3)]
42 [40 CFR 63.163(0(4)1 Pumps in light liquid service (dual mechanical seal system): Presence of a leak monitored by visual inspection/determination weekly (calendar).
Monitor for indications of liquids dripping from thc pump seal. If there are indications of liquid dripping from the pump seal at the time of the
weekly inspection, monitor the pump as specified in 40 CFR 63.180(b) to determine if thcrc is a leak of organic HAP in the barrier fluid. lf an
instrument reading of 1,000 ppm or greater is measured, a leak is detected. If a leak is detected, initiate thc repair provisions in 40 CFR
63.163(e)(6). Comply with this requirement instead of the requirements in 40 CFR 63.163(a) through (d). Subpart H. [40 CFR 63.163(e)(4)]
Which Months: All Year Statistical Basis; None specified
43 [40 CFR 63.163(e)(6)(i)] Pumps in light liquid service (dual mechanical seal system): Determine, based on design considerations and operating experience, criteria that
indicates failure of the seal system, the barrier fluid system, or both. Comply with this requirement instead of the requirements in 40 CFR
63.163(a) through (d). Subpart H. [40 CFR 63.163(e)(6)(i)]
44 [40 CFR 63.163(e)(6)) Pumps in lighi liquid service (dual mechanical seal sysiem). Make a ftrst attempt at repair no later than 5 calendar days after each leak is
detected, and complete repairs no later than 15 calendar days after the leak is detected, except as provided in 40 CFR 63.171 Comply with this
requirement instead of the requirements in 40 CFR 63.163(a) through (d). Subpart H. [40 CFR 63.163(e)(6)]
TP0440147
Page 4 of 13
Activity Number: PER20110024 .
FUG 0006 D4 - Fugitive Emissions

45 [40.CFR 63.163(e)] Pumps in light liquid service (dual mechanical seal system - sensor): Equipment/operational data monitored by visual inspection/determination
daily, or equip with an audible alarm unless the pump is located within the boundary of an unmanned plant site. If the sensor indicates failure of
the seal system, the barrier fluid system, or both based on the criteria established in 40 CFR 63.163(e)(6), a leak is detected. If a leak is detected,
initiate repair provisions specified in 40 CFR 63.163(e)(6). Comply with this requirement instead of the requirements in 40 CFR 63.163(a)
through (d). Subpart H. [40 CFR 63.163(e)]
46 •[40 CFR 63.164(a)] Compressors: Equip with a seal system that includes a barrier fluid system and that prevents leakage of process fluid to the atmosphere, except
as provided in 40 CFR 63.162(b) and 40 CFR 63.164(h) and (i). Subpart H. [40 CFR 63.164(a)]
47 [40 CFR 63.164(b)] Compressors: Operate the seal system with the barrier fluid at a pressure that is greater than the compressor stuffing box pressure; or equip with
a barrier fluid system degassing reservoir that is routed to a process or fuel gas system or connected by a closed-vent system to a control device
that complies with the requirements of 40 CFR 63.172; or equip with a closed-loop system that purges the barrier fluid directly into a process
stream. Subpart H. [40 CFR 63.164(b)]
48 [40 CFR 63.164(c)] Compressors: Ensure that the barrier fluid is not in light liquid service. Subpart 1-1: [40 CFR 63.164(c)]
49 [40 CFR 63.164(d)] Compressors: Equip each barrier fluid system as described in 40 CFR 63.164(a) through (c) with a sensor that will detect failure of the seal
system, barrier fluid system, or both. Subpart H. [40 CFR 63.164(d)]
50 [40 CFR 63.164(e)(2)] Compressors (sensor): Determine, based on design considerations and operating experience, a criterion that indicates failure of the seal system,
the barrier fluid system, or both. Subpart H. [40 CFR 63.164(e)(2)]
51 [40 CFR 63.164(g)] Compressors: Make a first attempt at repair no later than 5 calendar days after each leak is detected, and complete repairs no later than 15
calendar days after each leak is detected, except as provided in 40 CFR 63.171. Subpart H. [40 CFR 63.164(g)]
52 [40 CFR 63.164(i)(2)] Compressors (no detectable emissions): Organic HAP monitored by 40 CFR 60, Appendix A, Method 21 once initially and annually, and at
other times requested by DEQ. Comply with this requirement instead of the requirements in 40 CFR 63.164(a) through (h). Subpart H. [40 CFR
63.164(0(2)1
53 [40 CFR 63.164] Compressors (sensor): Equipment/operational data monitored by visual inspection/determination daily, or equip with an alarm, unless the
compressor is located within the boundary of an unmanned plant site. If the sensor indicates failure of the seal system, the barrier fluid system,
or both based on the criterion determined under 40 CFR 63.164(e)(2), a leak is detected. Tf a leak is detected, initiate repair provisions specified
in 40 CFR 63.164(g). Subpart H.
54 [40 CFR 63.165(a)] Pressure relief device in gas/vapor service: Organic HAP < 500 ppm above background except during pressure releases, as determined by the
method specified in 63.180(c). Subpart H. [40 CFR 63.165(a)]
Which Months: All Year Statistical Basis: None specified.
55 [40 CFR 63.165(b)(1)] Pressure relief devices in gas/vapor service: After each pressure release, return to a condition indicated by an instrument reading of less than 500
ppm above background, as soon as practicable, but no later than 5 calendar days after each pressure release, except as provided in 40 CFR
63.171. Subpart H. [40 CFR 63.165(b)( I )] •
AI ID: 1409 - The Dow Chemical Co - Louisiana Operations

56 [40 CFR 63 165(b)(2)1 Pressure relief devices in gas/vapor service: Organic HAP monitored by 40 CFR 60, Appendix A, Method 21 within 5 days (calendar) after the
pressure release and being returned to organic HAP service, to confirm the condition indicated by an instrument reading of less than 500 ppm
above background, as measured by the method specified in 40 CFR 63.180(c). Subpart H [40 CFR 63.165(b)(2)]
57 (40 CFR 63 165(d)(2)) Pressure relief devices in gas/vapor service (rupture disk): After cach pressure release, install a new rupzure disk upstream of the pressure relief
device as soon as practicable, but no later than 5 calendar days after each pressure release, except as provided in 40 CFR 63.171. Comply with
this requirement instead of thc requirements in 40 CFR 63. I65(a) and (b). Subpart H. [40 CFR 63.165(d)(2)] .
58 140 CFR 63 1661 Sampling connection systems Equip with a elosed-purgc, closed-loop, or closed-vent system, except as provided in 40 CFR 63.162(b). Operate
the system as specified in 40 CFR 63.166(b). Subpart H.
59 140 CFR 63 167) Open-ended valves or lines: Equip with a cap, blind flange, plug, or a second valve, except as provided in 40 CFR 63.162(b) and 40 CFR
63.167(d) and (c). Ensure that the cap, blind flange, plug or second valve seals the open end at all times except during operations requiring
process fluid flow through the open-ended valve or line, or during maintenance or repair. Operate cach open-ended valve or line equipped with a
second valve in a manner such that the valve on the process fluid end is closed before thc second valve is closed. Subpart H.
60 (40 CFR 63.168(d)(1)) Valves in gas/vapor service or light liquid service (Phase III, 2 percent or greater leaking valves): Organic HAP monitored by 40 CFR 60,
Appendix A, Method 21 monthly, as specified in 40 CFR 63. I80(b); or implement a quality improvement program for valves that complies with
the requirements of 40 CFR 63.175 and monitor quarterly. lf an instrument reading of 500 ppm or greater is recorded, a leak is detected. If a
leak is detected, initiatc repair provisions in 40 CFR 63.168(0. If electing to implement a quality improvement program, follow the procedures in
40 CFR 63_175. Subpart 11. [40 CFR 63.168(d)(I)]
Which Months: All Year Statistical Basis. None specified
61 140 CFR 63.1 68(d)(2)) Valves in gas/vapor service or light liquid service (Phase 11(, less than 2 percent leaking valves): Organic HAP monitored by 40 CFR 60,
Appendix A, Method 21 quarterly, as specified in 40 CFR 63.180(b). lf an instrument reading of 500 ppm or greater is recorded, a leak is
detected If a leak is detected, initiate repair provisions in 40 CFR 63 168(f). Permitter may elect to comply with the alternate standards in 40
CFR 63.168(d)(3) and (d)(4). Subpart H. [40 CFR 63.1 68(d)(2))
62 [40 CFR 63.168(e)(1)] Valves in gas/vapor service or light liquid service. Deterrnine percent leaking valves using the equation in 40 CFR 63.168(0(1). Subpart H. [40
CFR 63.168(0(1)]
63 [40 CFR 63.168(0(3)] Valves in gas/vapor service or light liquid service (after leak repair): Organic HAP monitored by 40 CFR 60, Appendix A, Method 21 once
within three months (at least) after repair to determine whether the valve has resumed leaking, Subpart H. [40 CFR 63.168(f)(3))
Which Months: All Year Statistical Basis None specified
64 [40 CFR 63.168(0) Valves in gas/vapor service or light liquid service: Make a first attempt at repair no later than 5 calendar days after a leak is detected, and
complete repairs no later than 15 calendar days after the leak is detected, except as provided in 40 CFR 63.171. Subpart H. [40 CFR 63.168(f))
65 [40 CFR 63.168(i)(1)) Valves in gas/vapor service or light liquid service (difficult-to-monitor): Demonstrate that the valve cannot be monitored without elevating thc
monitoring personnel morc than 2 meters above a support surface or it is not accessible at anytime in a safe manner. Comply with this
requirement instead of the requirements in 40 CFR 63.168(b) through (d). Subpart IL (40 CFR 63.168(i)(t)]
TPORO147
Page 6 of 13
Al ID: 1409 - The Dow Chemical Co - LOuisiana Operations
FUG 0006 04 r Fugitive Emissions

66 140 CFR 63.168(0(3)] Valves in gas/vapor service or light liquid service (difficult-to-monitor): Organic HAP monitored by 40 CFR 60, Appendix A, Method 21
annually. Maintain a written plan that requires monitoring of the valves at least once per calendar year. Comply with this requirernent instead of
the requirements in 40 CFR 63.168(b) through (d). Subpart H. [40 CFR 63.168(i)(3)]
Which Months: An Year Statistical Basis: None specified
67 [40 CFR 63.170] Surge control vessels and bottoms receivers: Equip with a closed-vent system that routes the organic vapors vented from the surge control vessel
or bottoms receiver back to the process or to a control device that c6mplies with the requirements of 40 CFR 63.172, except as provided in 40
CFR 63.162(b), or comply with the requirements of 40 CFR 63.119(b) or (c), if surge control vessel or bottoms receiver is not routed back to the
process and meets the conditions specified in 40 CFR 63 Subpart H Table 2 or Table 3. Subpart H.
68 [40 CFR 63.172(0( 1 )(W Closed-vent system (hard-piping): Organic HAP monitored by 40 CFR 60, Appendix A, Method 21 once initially according to the procedures in
40 CFR. 63.180(b). If an instrument reading greater than 500 ppm above background is recorded, a leak is detected. If a leak is detected, initiate
repair provisions in 40 CFR 63.172(h), Subpart H. [40 CFR 63.172(f)(1)(i)]
69 [40 CFR 63.172(0(1)0in Closed-vent system (hard-piping): Presence of a leak monitored by visual, audible, and/or olfactory annually. If a leak is detected, initiate repair
provisions in 40 CFR 63.172(h). Subpart H. [40 CFR 63.172(f)(1)(ii))
70 [40 CFR 63.172(h)] Make a first attempt at repair no later than 5 calendar days after each leak is detected, and complete repairs no later than 15 calendar days after it
each leak is detected, except as provided in 40 CFR 63.172(i). Subpart H. [40 CFR 63.172(h)]
71 [40 CFR 63.172(j)(1)] Closed-vent systern (bypass lines): Flow recordkeeping by electronic or hard copy once every 15 minutes. Generate records as specified in 40
CFR 63.118(a)(3). Subpart H. [40 CFR 63.172(j)(1)]
72 [40 CFR 63.172(j)(2)] Closed-vent system (bypass lines): Seal or closure mechanism monitored by visual inspection/determination monthly to ensure the valve is
maintained in the non-diverting position and the vent stream is not diverted through the bypass line. Subpart H. [40 CFR 63.172(j)(2)]
73 [40 CFR 63.172(1)(1)] Closed-vent system (difficult-to-inspect): Demonstrate that the equipment cannot be inspected without elevating the inspecting personnel more
than 2 meters above a support surface. Comply with this requirement instead of the requirements in 40 CFR 63.172(0(1) and (f)(2). Subpart H.
[40 CFR 63.172(1)(1)]
74 [40 CFR 63.172(1)(2)] Closed-vent system (difficult-to-inspect): Organic HAP monitored by 40 CFR 60, Appendix A, Method 21 once every five years. Maintain a
written plan that requires inspection of the equipment at least once every five years. Comply with this requirement instead of the requirements in
40 CFR 63.172(f)(1) and (0(2). SubPart H. [40 CFR 63.172(1)(2)1
75 [40 CFR 63.172(m)] Ensure that the clošed-vent system or control device is operating whenever organic HAP emissions are vented to the closed-vent system or
cOntrol device. Subpart H. [40 CFR 63.172(m)]
76 [40 CFR 63.173(a)] Agitators in gas/vapor service or light liquid service: Organic HAP monitored by 40 CFR 60, Appendix A. Method 21 monthly to detect leaks,
as specified in 40 CFR 63.180(b). If an instniment reading of 10,000 ppm or greater is recorded, a leak is detected. If a leak is detected, initiate
repair provisions in 40 CFR 63.173(c). Subpart H. [40 CFR 63.173(a)1
Which Months: All Year Statistical Basis: None _specified
Air • Title V Regular Permit Renewal

77 [40 CFR 63 173(b)] Agitators in gas/vapor service or light liquid service: Presence of a leak monitored by visual inspection/determination weekly (calendar) for
indications of liquids dripping from the agitator. If there arc indications of liquids dripping from thc agitator, a leak is detected. !fa leak is
detected, initiate repair provisions in 40 CFR 63.173(c). Subpart H. 140 CFR 63 173(h))
Which Months: All Year Statistical Basis None specified
78 [40 CFR 61173(c)] Agitators in gas/vapor service or light liquid service: Make a firs: attempt at repair no later than 5 calendar days after each leak is detected, and
complete repairs no later than 15 calendar days after it each leak is detected, except as provided in 40 CFR 63.171. Subpart H. [40 CFR
63.173(c)]
79 [40 CFR 63.173(d)( )j Agitators in gas/vapor service and light liquid service (dual mechanical seal system): Operate with the barrier fluid at a pressure that is at all
times greater than the agitator stuffing box pressure, or equip with a barrier fluid degassing reservoir that is routed to a process or fuel gas system
or connected by a closed-vent system to a control device that complies with the requirements of 40 CFR 63_172; or equip with a closed-loop
system that purges the barrier fluid into a process stream. Comply wnh this requirement instead of the requirements in 40 CFR 63.173(a).
Subpart H. (40 CFR 63.173(d)(1)]
80 [40 CFR 63.173(d)(2)[ Agitators in gas/vapor service and light liquid service (dual mechanical seal systcm): Ensure that the barrier fluid is not in light liquid organic
HAP service. Comply with this requirement instead of the requirements in 40 CFR 63.173(a). Subpart H. [40 CFR 63.173(d)(2)]
81 [40 CFR 63.173(d)(3)1 Agitators in gas/vapor service and light liquid service (dual rnechanical seal system): Equip barrier fluid system with a sensor that will deteCt
failure of the seal system, barrier fluid system, or both. Comply with this requirement instead of the requirements in 40 CFR 63.173(a). Subpart
H. [40 CFR 63.173(d)(3)]
82 [40 CFR 63.173(d)(4)] Agitators in gas/vapor service or light liquid service (dual mechanical seal system). Presence of a leak monitored by visual
inspection/determination weekly (calendar). Monitor for indications of liquids dripping from the agitator seal. If there arc indications of liquid
dripping from thc agitator seal at the time of the weekly inspection, monitor the agitator as specified in 40 CFR 63.180(h) to determine the
presence of organic HAP in the barrier fluid. If an instrument reading of 10,000 ppm or greater is measured, a leak is detected. lf a leak is
detected, initiate the repair provisions in 40 CFR 63.173(d)(6) Comply with this requirement instead of the requirements in 40 CFR 63.1 73(a).
Subpart H. [40 CFR 63.173(d)(4))
Which Months: All Year . Statistical Basis: None specified
83 [40 CFR 63.173(d)(61(0j Agitators in gas/vapor service and light liquid service (dual mechanical seal system)! Determine, based on design considerations and operating
experience, criteria that indicates failure of the seal system, the barrier fluid system, or both. Comply with this requirement instead of thc
requirements in 40 CFR 63.173(a). Subpart H. (40 CFR 63.173(d)(6)(i))
84 [40 CFR 63.173(06)1 Agitators in gas/vapor service and light liquid service (dual mechanical seal system). Make a first attempt at repair no later than 5 calendar days
after cach leak is detected, and complete repairs no later than 15 calendar days after the leak is detected, except as provided in 40 CFR 63.171.
Comply with this requirement instead of the requirements in 40 CFR 63.I73(a). Subpart H. [40 CFR 63.173(d)(6)]
85 [40 CFR 63.173(d)] Agitators in gas/vapor service or light liquid service (dual mechanical seal system - sensor): Equipment/operational data monitored by visual
inspection/determination daily, or equip with an audible alarm unless thc agitator is located within the boundary of an unmanned plant site. If the
sensor indicates failure of the seal system, the barricr fluid system, or both based on the criteria established in 40 CFR 63.173(d)(6), a leak is
detected. If a leak is detected, initiate repair provisions specified in 40 CFR 63.173(d)(6). Comply with this requirement instead of the
requirements in 40 CFR 63.173(a). Subpart H. [40 CFR 63, 173(d)]
Page 8 of 13 111()R0147
• Al ID: 1409 - The Dow Chemical Co - Louisiana Operations

86 [40 CFR 63.173(h)(1)) Agitators in gas/vapor service or light liquid service (difficult to monitor): Demonstrate that the agitator cannot be monitored without elevating
the monitoring personnel more than two meters above a support surface or it is not accessible at anytime in a safe manner. Comply with this
requirement instead of the requirements in 40 CFR 63.173(a) through (d). Subpart H. [40 CFR 63.173(h)(1)]
87 [40 CFR 63.173(h)(3)) Agitators in gas/vapor service or light liquid service (difficult-to-monitor): Organic HAP monitored by 40 CFR 60, Appendix A, Method 21
annually. Maintain a written plan that requires monitoring of the agitator at feast once per calendar year. Comply with this requirement instead
of the requirements in 40 CFR 63.173(a) through (d). Subpart H. [40 CFR 63.173(h)(3)]
88 [40 CFR 63.174(b)(1)[ Connectors in gas/vapor service or light liquid service: Organic HAP monitored by 40 CFR 60, Appendix A, Method 21 once within 12 months
after the compliance date, except as provided in 40 CFR 63.174(f) through (h). If an instrument reading of SOO ppm or greater is recorded, a
leak is detected. If a leak is detected, initiate repair provisions in 40 CFR 63.174(d). Subpart H. [40 CFR 63.174(b)(1)]
89 [40 CFR 63.174(b)(2)1 Connectors in gas/vapor service or light liquid service: Organic HAP monitored by 40 CFR 60, Appendix A, Method 21 once within the first 12
months after initial startup or by no later than 12 months after the date of promulgation of a specific subpart that references 40 CFR 63 Subpart
H, whichever is later, except as specified in 40 CFR 63.174(1) through (h). If an instrument reading of 500 ppm or greater is recorded, a leak is
detected. If a leak is detected, initiate repair provisions in 40 CFR 63.174(d). Subpart H. [40 CFR 63.174(b)(2)]
90 [40 CFR 63.174(b)(3)(i)) Connectors in gas/vapor service or light liquid service (0.5% or greater leaking): Organic HAP monitored by 40 CFR 60, Appendix A, Method
• 21 annually. Subpart H. [40 CFR 63.174(b)(3)(i)1
91 [40 CFR 63.174(b)(3)(ii)1 Connectors in gas/vapor service or light liquid service (less than 0.5% leaking): Organic HAP monitored by 40 CFR 60, Appendix A, Method
21 once every two years. Subpart H. [40 CFR 63.174(b)(3)(ii)]
92 .[40 CFR 63.174(c)(1)(i)] Connectors in gas/vapor service or light liquid service (opened or otherwise had the seal broken): Presence of a leak monitored by 40 CFR 60,
Appendix A, Method 21 within three months after being retUrned to organic HAP service or when it is reconnected. If monitoring detects a leak,
repair according to the provisions of 40 CFR 63.174(d), as specified, except as provided in 40 CFR 63.174(c)(1)(ii). Subpart H. [40 CFR
63.174(c)(1)(i)]
93 [40 CFR 63.174(c)(2)(i)] Connectors in gas/vapor service or light liquid service (2 inches or less in nominal diameter): Comply with the requirements of 40 CFR 63.169.
Subpart H. [40 CFR 63.I74(c)(2)(i))
94 [40 CFR 63.174(e)(2)(ii)] Connectors in gas/vapor service or light liquid service (2 inches or less in nominal diameter): Organic HAP monitored by technically sound
method within three months after being returned to organic HAP service after having been opened or otherwise had the seal broken. If
monitoring detects a leak, implement repair provisions in 40 CFR 63.174(d). Subpart H. [40 CFR 63.174(c)(2)(ii)1
95 [40 CFR 63.174(d)] Connectors in gas/vapor service or light liquid service: Make a first attempt at repair no later than 5 calendar days after each leak is detected,
and complete repairs no later than 15 calendar days after it each leak is detected, except as provided in 40 CFR 63.171 and 63.124(g). Subpart
H. [40 CFR 63.174(d)]
A110: 1409 - The Dow Chemical Co - Louisiana Operations

• 96 f40 CFR 63.1740] Connectors in gas/vapor service or light hquid service: Calculate percent kaking connectors as specified in 40 CFR 63.174( )(1) and ( )(2).
Subpart H. [40 CFR 63.174(01
97 (40 CFR 63 180] Comply with the test methods and procedures requirements provided in 40 CFR 63.180. Subpart H
98 (40 CFR 63 ] Submit reports semiannually per Section R. Reports shall include the number of components monitored (valves and connectors only), number
found to be leaking, nurnber not repaired, and percent leaking for valves, pumps, compressors, and connectors. Also include the dates of any
process unit shutdown, revisions to the initial report, and the results of all performance tests to determine compliance with D.5, E.9, G.1 and N.6.
99 [LAC 33:111.2111] Equip all rotary pumps and compressors handling volatile organic compounds having a true vapor pressure of 1.5 psia or greater at handltng
conditions with mechanical seals or other equivalent equipment.
100 ILAC 33:1111.501.C.6] Perrnince shall comply with a streamlined equipment leaks monitoring program. Compliance with the streamlined prograrn in accordance with
this specific condition shall serve to comply with each of the applicable fugitive emission monitoring programs bcing streamlined, as indicated in
the following table. Noncompliance with the streamlined program in accordance with this specific condition may subject the perrnittee to
enforcement action for one or more of the applicable fugitive emission programs.
a. Permittee shall apply the streamlined program to the combined universe of components subject to any of the programs being strearnlined. Any
component type which does not require periodic monitoring under thc overall rnost stringent program (HON) shall bc monitored as required by
the most stringent requirements of any other program being streamlined and will not be exempted. The streamlined program will include any
exemptions based on size of component available in any of the programs being streamlined.
b. Perminee shall use leak definitions and monitoring frequency based on the overall most stringent program. Percent leaker performance shall
be calculated using the provisions of the overall most stringent program. Annual monitoring shall be defined as once every 4 quarters. Some
allowance may be made in the first year of the streamlined program in order to allow for transition from existing monitoring schedules. .
101 [LAC 33111.5109.A] Fugitive emissions from components that contain or contact a volatile fluid.(liquid or gas) that is at least 5 percent by weight the sum of Class]
and 11 organic TAP shall bc controlled by an LDAR monitoring program conforming to the Louisiana MACT Determination for Non-Hon
Equipment Leaks dated March 30, 1995. Will comply with HON as the most stringent program under consolidated program.
102 [LAC 33 111 5109 CI Monitor affected components quarterly or annually, as appropriate, in accordance with Method 21. Conduct weekly visual inspections of pumps
in light liquid service.
When a leak is detected, record the instrument, operator, and equipment ID, the date the leak was detected and the dates of each attempt to repair
the leak, repair methods applied, "repair delayed" information, and the date of successful repair. Maintain other records required by Section O.
Records shall be kept for five years_
RLP 0102 VENTS - Process Vents

103 140 CFR 63.5555] Demonstrate continuous compliance with each emission limit, operating limit, or work practice standard in Tables 1 and 2 to this subpart that
applies to you according to methods specified in Tables 5 and 6 of this subpart.
Page 10 of 13 TPORI1147
Al ID: 1409 - The Dow.Chemical Co Louisiana Operations
RLP 0102 VENTS - Process Vents

104 [40 CFR 63.] Reduce total uncontrolled organic HAP emissions by at least 99% per 40 CFR 63.5505(a). Demonstrated by NOCS due 240 days after effective
date. Subpart III.JUU.
105. [40 CFR 63.1 For each existing cellulose ether operation using a material balance compliance demonstration: reduce total uncontrolled organic HAP emissions
by at least 99% based on a 6-month rolling average ¿ i) maintaining a material balance that includes pertinent data u,sed to deterrnine the percent
reduction of total organic HAP (Table 5 3.b.i 1&2 ).
UNF 0002 Facility - Cellulose Plant

106 [40 CFR 61 145(11)(l )1 Provide DEQ with written notice of intention to demolish or renovate prior to performing activities to which 40 CFR 61 Subpart M applies.
Delivery of the notice by U.S. Postal Service, commercial delivery service, or hand delivery is acceptable. Subpart M. [40 CFR 61.145(b)(1)]
107 [40 CFR 61.148] Do not install or reinstall on a facility component any insulating materials that contain commercial asbestos if the materials are either molded and
friable or wet-applied and friable after drying. Subpart M.
108 [40 CFR 61.] AB affected facilities shall comply with all applicable provisions in 40 CFR 61 Subpart A.
109 [40 CFR 61 ] The Cellulose Plant does not generate benzene waste. Initial report per 40 CFR 61.357(a) is required. The Louisiana Operations complex, as a
whole, is subject to the rule.
110 [40 CFR 63.] All affected facilities shall comply with all applicable provisions in 40 CFR 63 Subpart A.
111 [40 CFR 63.1 Submit an initial notification no later than 120 days after June I 1, 2002, as specified in 40 CFR 63.9(b)(2. 40 CFR 5577, Table 7. Monitoring
required by Cellulose MACT. NOCS to be submitted 240 days after compliance date ofJune 13, 2005 - Subpart UUUU.
112 (40 CFR 821 Label containers of Class I or II ozone depleting substances, along with products manufactured with or containing the substances.
113 [LAC 33:111.1103] Emissions of smoke Which pass onto or across a public road and create a traffic hazard by impairment of visibility as defined in LAC 33:111.111
or intensify an existing traffic hazard condition are prohibited.
114 [LAC 33:11L1305] Prevent particulate matter from becoming airborne by taking all reasonable precautions. These precautions shall include, but not be limited to,
those specified in LAC 33:111.1305.A.I-7.
115 [LAC 33:111.2113.A] Maintain best practical housekeeping and maintenance praCtices at the highest possible standards to reduce the quantity of organic compounds
emissions. Good housekeeping shall include, but not be limited to, the practices listed in LAC 33:111.2113.A.I-5.
116 [LAC 33:111.219] Failure to pay the.prescribed application fee or annual fee as provided herein, within 90 clays after the due date, will constitute a violation of
these regulations and shall subject the person to applicable enforcement actions under the Louisiana Environmental Quality Act including, but
noi limited to, revocation or suspension of the applicable permit, license, registration, or variance.
117 [LAC 33:111.5105.A.1] Do not construct or modify any stationary source subject to any standard set forth in LAC 33:1II.Chapter 51.Subchapter A without first obtaining
written authorization from DEQ in accordance with LAC 33:111.Chapter 51.Subchapter A, after the effective date of the standard.
118 [LAC 33:111.5105.A.2] Do not cause a violation of any ambient air standard listed in LAC 33:111.Table 51.2, unless operating in accordance with LAC 33:111.5I09.B.
119 [LAC 33111.5105.A.3] Do not build, erect, install, or use any article, machine, equipment, process, or method, the use of which conceals an emission that would
otherwise constitute a violation of an applicable standard.
120 [LAC 33:111.5105.A.4] Do not fail to keep records, notify, report or revise reports as required under LAC 33:HI.Chapter 51.Subchapter A.
A1 ID: 1409 - The Dow Chemical Co - Louisiana Operations
Perrnit Number: 2227-V7

121 [LAC 33:111 5107.A.21 Include a certification statement with thc annual emission report and revisions to any emission report that attests that the information contained in
the emission report is true, accurate, and complete, and that is signed by a responsible official, as defined in LAC 33:111.502. Include the full
namc of the responsible official, title, signature, date of signature and phone number of the responsible officiaL
122 [LAC 33:111.5107 A] Submit Annual Emissions Report: Due annually, by the 31st of March unless otherwise directed by DEQ, to the Office of Environmental
Services in a format specified by DEQ. Identify the quantity of emissions in the previous calendar year for any toxrc air pollutant listed in Table
51.1 or Table 51.3.
123 [LAC 33:111.5107.B.1] Submit notification: Due to thc Department of Pubhc Safety 24-hour Louisiana Emergency Hazardous Materials Hotline at (225) 925-6595
immediately, but in no case later than 1 hour, after any discharge of a toxic air pollutant into the atmosphere that results or threatens to result in
an emergency condition (a condition which could reasonably be expected to endanger the health and safety of the public, cause significant
adverse impact to the land, water or air environment, or cause severe damage to property).
124 [LAC 33 111 5107 B 2) Submit notification: Due to SPOC, except as provided in LAC 33:1I1.51 07.F3.6, no later than 24 hours after the beginning of any unauthorized
discharge into the atmosphere of a toxic air pollutant as a result of bypassing an emission control device, when the emission control bypass was
not the result of an upset, and the quantity of the unauthorized bypass IS greater than or equal to the lower of the Minirnum Emission Rate (MER)
tn LAC 33:111.5112, Table 51.1, or a reportable quantity (RQ) in LAC 33:1.393i, or the quantity of the unauthorized bypass is greater than one
pound and there is no MER or RQ for the substance in question. Submit notification in the manner provided in LAC 33:1 3921
125 (LAC 33.111 5107 13 3] Submit notification. Due to SPOC, except as provided in LAC 33.111.5107.13_6, immediately, but in no case later than 24 hours after any
unauthorized discharge of a toxic air pollutant into the atmosphere that does not causc an emergency condition, the rate or quantity of which is in
cxccss of that allowed by permit, compliance schedule, or variance, or for upset events that exceed the reportable quantity in LAC 33:1 3931.
Submit notification in the rnanner provided in LAC 33:1.3923.
126 !LAC 33:111.5107 BA) Submit written report: Due by certified mail to SPOC within seven calendar days of learning of any such discharge or equipment bypass as
referred to in LAC 33:H1.5107111 through 8.3. include the information specified in LAC 33:111.5107.B.4.a.i through 13.4.a.viii.
127 [LAC 33JI1.5107.B.5] Rcport all discharges to the atmosphere of a toxic air pollutant from a safety relief device, a line or vessel rupture, a sudden equipment failure, or
a bypass of an emission control device, regardless of quantity, IF THEY CAN BE MEASURED AND CAN BE RELIABLY QUANTIFIED
usrNG GOOD ENGTNEERING PRACTICES, to DEQ along with the annual emissions report and where otherwise specified. Include the
identity of thc source, the date and time of the discharge, and thc approximate total loss during the discharge.
128 (LAC 33:111.5109.C] Develop a standard operating procedure (SOP) within 120 days after achieving or demonstrating compliance with the standards specified in LAC
33:111.Chapter 51. Detail in the SOP all operating procedures or parameters established to ensure that compliance with the applicable standards
is maintained and address operating procedures for any monitoring system in place, specifying procedures to ensure compliance with LAC
33:111.5113.C.5. Make a written copy of thc SOP available on site or at an alternate approved location for inspcction by DEQ. Provide a copy
of the SOP within 30 days upon request by DEQ.'
129 [LAC 33:111.5151.F I .f] An individual or company contracted to perform a demolition or renovation activity which disturbs RACM must bc recognized by the Licensing
Board for Contractors to perform asbestos abatement, and shall rnect the requirements of LAC 33:111.515 I.F.2 and F.3 for each demolition or
renovation activity.
130 [LAC 33 III 535] Pet-mince shall comply with the Part 70 General Conditions as set forth in LAC 33:111.535 and the Louisiana General Conditions as set forth in
LAC 33:111.535. [LAC 33:111.535, LAC 33:111.537J
Page 12 of 13 TPORQ147

131 [LAC 33:111.5611.A] Submit standby plan for the reduction or elimination of ernissions during an Air Pollution Alert, Air Pollution Warning, or Air Pollution
Emergency: Due within 30 days after requested by the administrative authority.
132 [LAC 33:111.5611.B] During an Air Pollution Alert, Air Pollution Warning or Air Pollution Emergency, make the standby plan available on the premises to any person
authorized by the department to enforce these regulations. •
133 [LAC 33:111.5901.A] Comply with the provisions in 40 CFR 68, except as specified in LAC 33:111.5901.
134 ILAC 33:111.5907] Identify hazards that may result from accidental releases of the substances listed in 40 CFR 68.130, Table 59.0 of LAC 33:111.5907, or Table
59.1of LAC 33:111.5913 using appropriate hazard assessment techniques, design and maintain a safe facility, and minimize the off-site
consequences of accidental releases of such substances that do occur.
135 [LAC 33:111.5911.A] Submit registration: Due January 31, 1998, or within 60 days after the source becomes subject to LAC 33:1II.Chapter 59, whichever is later.
Include the information listed in LAC 33:111.5911.B, and submit to the Department of Environmental Quality, Office of Environmental
Compliance, Emergency and Radiological Services Division.
136 [LAC 33:111.5911.C] Subrnit amended registration: Due to the Department of Environrnental Quality, Office of Environmental Compliance, Emergency and
Radiological Services Division, within 60 days after the information in the submitted registration is no longer accurate.
137 [LAC 33:111.919.D] Submit Emission Inventory (EI)JAnnual Emissions Statement: Due annually, by the 31st of March for the period January 1 to December 31 of
the previous year unless otherwise directed. Submit emission inventory data in the format specified by the Office of Environmental Services. Air
Quality Assessment Division. Include all data applicable to the emissions source(s), as specified in LAC 33:11L9 I 9.A-D.

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AIR PERMIT ROUTING/APPROVAL SLIP-Permits 641

Approved Date.rec'd Date FW Comments .

Technical Advisor D a,... 7 1,6 I

OES PN mailout Date - •

Certified Mail No. 7005 1820. 0002 2091 0698

Dear Mr. Reed:

Done this day of a , 2011.

Permit No.: 2227-V7

cc: US EPA Region VI

A permit application and Emission Inventory Questionnaire were submitted by Dow

The Cellulose Plant produces a range of hydroxypropyl methylcellulose (HPMC) products

With this renewal/modification, Dow requested the following:

EQT062 7Z - 1DC-1A Dust Collector Vent

Total permitted emissions in tons per year are as follows:

Pollutant Before After Change

*VOC 184.48 71.3 -113.18

*VOC LAC 33:111 Chapter 51 Toxic Air Pollutants (TAPs):

IV. TYPE OF REVIEW

PSD Significance Level

Notwithstanding any other provisions of any applicable rule or regulation or requirement

VI. PUBLIC NOTICE

VII. Effects on Ambient Air

Dispersion Model(s) Used: None

VIII. General Condition XVII Activities

Work Activity Schedule VOC (TPY)

IX. Insignificant Activities

X. Consolidated Fugitives Program

a_ Permittee shall apply the streamlined program to the combined universe of

Unit or programs Being Streamlined Stream Overall Most

XI. Table 1. Applicable Louisiana and Federal Air Quality Requirements

CRG0009 Common Requirement Grou_p 9

CRG0010 Common Requirement Group 10 . 1

XI. Table 1. Appiicable Louisiana and Federal Air Quality Requirements

EQT0088 BZ —110-30B Hopper Vent 1 .

EQT1304 001-DC-1140 Dust Collector Vent 1 • 3 1

XI. Table 1. Applicable Louisiana and Federal Air Quality Requirements

-- 5A 9 11 13 15 2103 2107 2111 2113 2115 2122 2149 2153 51 56 59

XL Table I. Applicable Louisiana and Federal Air Quality Requirements

UNF0002 Cellulose Plant 1 1 l 1 , 1 2 I 1 I

Requirements" report specifically states that the regulation is State Only.

XI. Table I. Applicable Louisiana and Federal Air Quality Requirements

CRG0009 Common Requirement Group 9

CRG0010 Common Requirement Group 10

XI. Table 1. Applicable Louisiana and Federal Air Quality Re uirements

EQTI304 001-DC-1140 Dust Collector Vent

XI. Table 1. Applicable Louisiana and Federal Air Quality Re uirements

XI. Table 1. Applicable Louisiana and Federal Air Quality Requirements

XII. Table 2. Explanation for Exemption Status or Non-Applicability of a Source

RAL-020 Recognized Asbestos Landfill Asbeslos 12-15-2006

44945 Dow Chemical USA TEMPO Merge 05-22-2001

52295 Dow Chemical USA - COal Gasification TEMPO Merge 05-22-2001

Page 1 of 4 'MORO 148

Mailing Address: PO Box 150

Related People: Name . Mailing Address Phone (Type) Relationship

Related Organizations: Name Address Phone (Type) Relationship

Subject Item Inventory:

Subject Item Inventory:

r EQT 0859 1C4(E110-B) • Exchanger Vent - C4(E110-13)

Page 2 01 6 7 PORD t4S

EQT 3080 B9 - BDC-30B Blower Exhaust 238 5000 .35 17 77

EOT 0088 BZ -1-10-30B Hopper Vent ..17 65 77

EQT 0096 CG - TR-300 Treated Blender Vent .5 64 170