Sanolin Rhodamina B 02

SAFETY DATA SHEET
ABNT NBR 14725 Standard
Sanolin Rhodamine B 02 Page 1(15)

Substance key: 000000167193 Revision Date: 25.08.2021
Version : 2 - 12 / BR Date of printing : 07.12.2021
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Substance or preparation name (trade name)

Sanolin Rhodamine B 02
Internal substance key for identification of product

Material number : 198846
Substance key : 000000167193
Major recommendable usage for substance or preparation

Industry sector : Industrial Performance Chemicals
Paints, lacquers and varnishes industry
Polymers industry
Printing Inks Industry
Type of use : Colouring agent
Name of company / address

Colorants Solutions Deutschland GmbH
Brüningstraße 50
65929 Frankfurt am Main
Telephone no. : +49 6196 757 0
Information about the substance / preparation

BU Pigments
Product Stewardship
e-mail : SDS.PI.Europe@clariant.com
Emergency telephone number : 00800-5121 5121 (24 h)
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification in accordance with ABNT NBR 14725 Standard

Not a hazardous substance or mixture.
GHS label elements in accordance with ABNT NBR 14725 Standard
Not a hazardous substance or mixture.
Other hazards which do not result in classification
Potential dust explosion hazard.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Chemical nature : C.I. Acid Red 52 (xanthene dye stuff)
Components
Chemical name CAS-No. Classification Concentration (% w/w)
Sodium chloride 7647-14-5 Acute toxicity (Oral), >= 1 -< 5
Category 5
1 / 15
SAFETY DATA SHEET

SECTION 4. FIRST AID MEASURES
General advice : Get medical advice/ attention if you feel unwell.
If inhaled : Remove to fresh air.
In case of skin contact : IF ON SKIN: Wash with plenty of soap and water.
In case of eye contact : Rinse the affected eye with plenty of water, at the same time
keep the unaffected eye well protected.
If swallowed : If swallowed do not induce vomiting,seek medical advice and

show safety datasheet or label
Most important symptoms : No symptoms known currently.

and effects, both acute and No hazards known at this time.
delayed
Notes to physician : Treat symptomatically.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Water spray jet

Foam
Unsuitable extinguishing : High volume water jet

media Carbon dioxide (CO2)
Dry powder
Specific hazards during : In case of fire hazardous decomposition products may be

firefighting produced such as:
Carbon dioxide (CO2)
Carbon monoxide
Nitrogen oxides (NOx)
Sulphur dioxide
Specific extinguishing : Wear suitable protective equipment.

methods
Special protective equipment : Self-contained breathing apparatus

for firefighters
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Wear suitable protective equipment.

protective equipment and
emergency procedures
2 / 15
SAFETY DATA SHEET

Environmental precautions : The product should not be allowed to enter drains, water
courses or the soil.
Methods and materials for : Take measures to prevent the build up of electrostatic charge.
containment and cleaning up Use mechanical handling equipment.
Treat recovered material as described in the section "Disposal
considerations".
SECTION 7. HANDLING AND STORAGE
Advice on protection against : Take precautionary measures against static discharges.

fire and explosion Keep away from heat and sources of ignition.
Advice on safe handling : When used and handled appropriately no special measures
are needed
Hygiene measures : Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it
before reuse.
Further information on : Keep container tightly closed.

storage conditions Keep container dry.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters

Contains no substances with occupational exposure limit values.
Engineering measures : Handle only in a place equipped with local exhaust (or other
appropriate exhaust).
Personal protective equipment

Respiratory protection : Respirator must be worn if exposed to dust.
Hand protection
Remarks : Nitrile rubber gloves.
Eye protection : Safety glasses with side-shields
Skin and body protection : working clothes
Protective measures : Wear suitable protective equipment.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : powder
3 / 15
SAFETY DATA SHEET

Colour : dark violet
Odour : not significant
Odour Threshold : not required
pH : 6 (20 °C)
Concentration: 10 g/l
Melting point : not determined
Boiling point : Not applicable
Flash point : Not applicable
Evaporation rate : Not applicable
Flammability (solid, gas) : not determined
Self-ignition : no data available
Burning number : 2 (22 °C)

Short flaring up without spreading
Upper explosion limit / upper : not determined

flammability limit
Lower explosion limit / Lower : not determined

flammability limit
Vapour pressure : Not applicable
Relative vapour density : not determined
Relative density : no data available
Density : not determined
Solubility(ies)
Water solubility : 70 - 80 g/l (20 °C)
Partition coefficient: n- : not determined

octanol/water
Auto-ignition temperature : not determined
Decomposition temperature : 210 °C

Method: isoperibolic decomposition test
4 / 15
SAFETY DATA SHEET

Viscosity
Viscosity, dynamic : Not applicable
Oxidizing properties : no data available
Molecular weight : no data available
Minimum ignition energy : > 1.000 mJ

with inductive electrical resistance
Particle size : not determined
SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable
Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions
Conditions to avoid : None known.
Incompatible materials : not known
Hazardous decomposition : No decomposition if stored and applied as directed.

products
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Acute oral toxicity : LD50 (Rat): > 5.000 mg/kg
Acute inhalation toxicity : Remarks: no data available
Acute dermal toxicity : Remarks: no data available
Components:
Sodium chloride:
Acute oral toxicity : LD50 (Rat, male): 3.550 mg/kg
Method: No information available.
GLP: no data available
Skin corrosion/irritation
Product:
Species : Rabbit
Result : No skin irritation
5 / 15
SAFETY DATA SHEET

Components:
Sodium chloride:
Species : Rabbit
Method : No information available.
GLP : no
Serious eye damage/eye irritation

Product:
Species : rabbit eye
Result : No eye irritation
Components:
Sodium chloride:
Species : Rabbit
Method : OECD Test Guideline 405
GLP : no
Respiratory or skin sensitisation

Product:
Remarks : no data available
Components:
Sodium chloride:
Test Type : Local lymph node assay (LLNA)
Exposure routes : Dermal
Species : Mouse
Method : Other
Result : Not a skin sensitizer.
GLP : no data available
Germ cell mutagenicity

Product:
Genotoxicity in vitro : Remarks: no data available
Germ cell mutagenicity - : No information available.

Assessment
Components:
Sodium chloride:
Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Concentration: 0,25 - 5,85 mg/ml
Metabolic activation: without
Method: Other
6 / 15
SAFETY DATA SHEET

Result: positive
Test Type: Ames test

Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Genotoxicity in vivo : Test Type: Chromosome Aberration Test

Species: Rat (female)
Strain: Long-Evans
Cell type: Bone marrow cells
Application Route: Intraperitoneal injection
Exposure time: 3-6-12-18-24 h
Dose: 10 - 20 - 40 mmole/kg
Result: positive
Germ cell mutagenicity - : Mutagenicity not fully evaluated.

Assessment
Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment
Components:
Sodium chloride:
Species : Rat, male
Application Route : oral (feed)
Exposure time : 2a
Dose : 4% NaCl and 2% KCl+2% NaCl
Control Group : yes
Frequency of Treatment : daily
: 2.533 mg/kg bw/day
Carcinogenicity - : Animal testing did not show any carcinogenic effects.

Assessment
Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment
7 / 15
SAFETY DATA SHEET

Components:
Sodium chloride:
Effects on foetal : Remarks: The study is not necessary from a scientific
development perspective.
Reproductive toxicity - : No reproductive toxicity to be expected.

Assessment No teratogenic effects to be expected.
STOT - single exposure

Product:
Components:
Sodium chloride:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, single exposure.
STOT - repeated exposure

Product:
Components:
Sodium chloride:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.
Repeated dose toxicity

Product:
Remarks : This information is not available.
Components:
Sodium chloride:
Species : Rat, male
LOEL : 2533 mg/kg bw/day
Application Route : oral (feed)
Exposure time : 2a
Number of exposures : daily
Dose : 4% NaCl and 2% KCl+2% NaCl
Control Group : yes
Application Route : Inhalation

Method : Repeated dose toxicity
Remarks : The study is not necessary from a scientific perspective.
8 / 15
SAFETY DATA SHEET

Aspiration toxicity
Product:
no data available
Components:
Sodium chloride:
No aspiration toxicity classification
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
Toxicity to fish : LC50: > 100 mg/l
Exposure time: 96 h
Toxicity to daphnia and other :

aquatic invertebrates Remarks: no data available
Toxicity to algae/aquatic :
plants Remarks: no data available
Toxicity to fish (Chronic : Remarks: no data available

toxicity)
Toxicity to microorganisms : Remarks: no data available
Components:
Sodium chloride:
Toxicity to fish : LC50 (Lepomis macrochirus (Bluegill sunfish)): 5.840 mg/l
End point: mortality
Exposure time: 96 h
Test Type: flow-through test
Analytical monitoring: no
Method: Other
GLP: no
Toxicity to daphnia and other : LC50 (Daphnia magna (Water flea)): 4.136 mg/l
aquatic invertebrates End point: Immobilization
Exposure time: 48 h
Test Type: static test
Analytical monitoring: yes
GLP: no
Remarks: Acute Immobilisation Test
Toxicity to algae/aquatic : ErC50 (Nitzschia sp.): 2.430 mg/l

plants End point: Growth rate
Exposure time: 120 h
9 / 15
SAFETY DATA SHEET

GLP: no
IC50 (Lemna minor (common duckweed)): 6.870 mg/l

End point: Growth rate
Exposure time: 96 h
Remarks: The details of the toxic effect relate to the nominal
concentration.
Toxicity to fish (Chronic : NOEC (Pimephales promelas (fathead minnow)): 252 mg/l
toxicity) End point: mortality
Exposure time: 33 d
GLP: no
LOEC (Pimephales promelas (fathead minnow)): 352 mg/l

Exposure time: 33 d
GLP: no
Toxicity to daphnia and other : NOEC (Daphnia pulex (Water flea)): 314 mg/l
aquatic invertebrates Exposure time: 21 d
(Chronic toxicity) Test Type: semi-static test
GLP: no
LOEC (Daphnia pulex (Water flea)): 441 mg/l

Exposure time: 21 d
Test Type: semi-static test
GLP: no
Toxicity to microorganisms : EC10 (activated sludge): <= 35.000 mg/l

Test Type: aquatic
Method: Other
GLP: no
Test Type: Soil

Remarks: Not applicable
Toxicity to soil dwelling : Test Type: artificial soil
10 / 15
SAFETY DATA SHEET

organisms NOEC (Eisenia fetida (earthworms)): 3.507 mg/kg

Exposure time: 70 d
GLP: no
Test Type: artificial soil

LOEC (Eisenia fetida (earthworms)): 4.675 mg/kg
Exposure time: 70 d
GLP: no
Test Type: artificial soil

LOEC (Eisenia fetida (earthworms)): 1.169 mg/kg
Exposure time: 70 d
End point: Reproduction
GLP: no
Plant toxicity : IC50: 500,8 mg/kg

Exposure time: 7 d
End point: emergence
Species: Lepidium sativum (cress)
Method: OECD Guide-line 208
GLP: no
concentration.
NOEC: 360 mg/kg

Exposure time: 7 d
End point: Growth
GLP: no
concentration.
LOEC: 640 mg/kg

Exposure time: 7 d
End point: Growth
GLP: no
concentration.
IC50: 1.890 mg/kg

Exposure time: 7 d
End point: emergence
Species: Hordeum vulgare
11 / 15
SAFETY DATA SHEET

GLP: no
concentration.
NOEC: 296 mg/kg

Exposure time: 7 d
End point: Growth
GLP: no
concentration.
LOEC: 528 mg/kg

Exposure time: 7 d
End point: Growth
GLP: no
concentration.
Toxicity to terrestrial : LD50 (Passer domesticus (house sparrow)): 8.000 mg/kg

organisms Exposure time: 12 h
Method: Other
GLP: no
Persistence and degradability

Product:
Biodegradability : Remarks: This property is substance-specific and therefore
cannot be given for the preparation.
Components:
Sodium chloride:
Biodegradability : Remarks: Not applicable for inorganic compound.
Physico-chemical : Remarks: Not applicable

removability
Stability in water : Remarks: Not applicable
Bioaccumulative potential
Product:
Bioaccumulation : Remarks: not tested.
12 / 15
SAFETY DATA SHEET

Components:
Sodium chloride:
Partition coefficient: n- : Remarks: Not applicable
octanol/water inorganic
Mobility in soil
no data available
Other adverse effects
Product:
Environmental fate and : Remarks: not tested.
pathways
Results of PBT and vPvB : Remarks: No information is available as no chemical safety

assessment report (CSR) is required.
Additional ecological : no data available

information
Components:
Sodium chloride:
Environmental fate and : not available
pathways
Results of PBT and vPvB : The substance is inorganic, thus a PBT and vPvB criteria
assessment assessment is not applicable according to Annex XIII of
Regulation (EC) 1907/2006.
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Product should be taken to a suitable and authorized waste
disposal site in accordance with relevant regulations and if
necessary after consultation with the waste disposal operator
and/or the competent Authorities
Contaminated packaging : This material and its container must be disposed of in a safe
way.
SECTION 14. TRANSPORT INFORMATION
Terrestrial (railways, not restricted

highways) - ANTT:
Air - ANAC: not restricted
13 / 15
SAFETY DATA SHEET

Ship (sea, rivers, lakes) - not restricted

IMDG:
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or

mixture
The product is classified and labelled in accordance with GHS regulation and the relevant
national laws.
SECTION 16. OTHER INFORMATION
Full text of other abbreviations
AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer;
IATA - International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No
Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines
Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity
Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals;
SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan
Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TECI - Thailand
Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United
Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials
Information System
14 / 15
SAFETY DATA SHEET

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.
BR / EN
15 / 15

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SAFETY DATA SHEET

ABNT NBR 14725 Standard

Sanolin Rhodamine B 02 Page 1(15)

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Substance or preparation name (trade name)

Internal substance key for identification of product

Major recommendable usage for substance or preparation

Name of company / address

Information about the substance / preparation

Emergency telephone number : 00800-5121 5121 (24 h)

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification in accordance with ABNT NBR 14725 Standard

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : C.I. Acid Red 52 (xanthene dye stuff)

Sanolin Rhodamine B 02 Page 2(15)

SECTION 4. FIRST AID MEASURES

General advice : Get medical advice/ attention if you feel unwell.

If inhaled : Remove to fresh air.

If swallowed : If swallowed do not induce vomiting,seek medical advice and

Most important symptoms : No symptoms known currently.

Notes to physician : Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray jet

Unsuitable extinguishing : High volume water jet

Specific hazards during : In case of fire hazardous decomposition products may be

Specific extinguishing : Wear suitable protective equipment.

Special protective equipment : Self-contained breathing apparatus

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Wear suitable protective equipment.

Sanolin Rhodamine B 02 Page 3(15)

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Take precautionary measures against static discharges.

Further information on : Keep container tightly closed.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Personal protective equipment

Eye protection : Safety glasses with side-shields

Skin and body protection : working clothes

Protective measures : Wear suitable protective equipment.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Sanolin Rhodamine B 02 Page 4(15)

Colour : dark violet

Odour : not significant

Odour Threshold : not required

Melting point : not determined

Boiling point : Not applicable

Flash point : Not applicable

Evaporation rate : Not applicable

Flammability (solid, gas) : not determined

Self-ignition : no data available

Burning number : 2 (22 °C)

Upper explosion limit / upper : not determined

Lower explosion limit / Lower : not determined

Vapour pressure : Not applicable

Relative vapour density : not determined

Relative density : no data available

Density : not determined

Partition coefficient: n- : not determined

Auto-ignition temperature : not determined

Decomposition temperature : 210 °C

Sanolin Rhodamine B 02 Page 5(15)