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2 0 1 6;5(1):58–67
www.jmrt.com.br
Original Article
a r t i c l e i n f o a b s t r a c t
Article history: The EOF reactor was developed in Brazil in the eighties with unique features. The pre-
Received 25 August 2015 heating of scrap and distribution of injection points oxidizing gases and fuels make up
Accepted 22 October 2015 these features. This paper aims to reproduce the behavior of the metal bath an EOF of
Available online 4 December 2015 45 tons comparing their top three gas injection equipment: supersonic lances, atmospheric
injectors and tuyeres. The lances and tuyeres promoted greater agitation of the bath with
Keywords: atmospheric injectors a great opportunity for improvement.
EOF © 2015 Brazilian Metallurgical, Materials and Mining Association. Published by Elsevier
Supersonic lances Editora Ltda. All rights reserved.
Injector
Tuyere
Cold model
∗
Corresponding author.
E-mail: breno.totti@lumarmetals.com.br (B.T. Maia).
http://dx.doi.org/10.1016/j.jmrt.2015.10.001
2238-7854/© 2015 Brazilian Metallurgical, Materials and Mining Association. Published by Elsevier Editora Ltda. All rights reserved.
j m a t e r r e s t e c h n o l . 2 0 1 6;5(1):58–67 59
11
5
6 9
7
8
Fig. 1 – EOF conception: (a) Draft and (b) model (catalogue of Companhia Siderúrgica Pains, 1978) [2].
273mm 733mm
Top view
Supersonic lance entrance
110mm
150mm
167mm
320mm 903mm
Back view
The collection time was a factor influenced by the configura- color at the bath. This was an alternative method used by
tions tested, so the volume found was divided by the time, Maia [6] and Diaz et al. [7], to measure the mixing time in
generating an average rate of fluid loss. turbulent environments.
In all tests, caustic soda was added in water. It was To determine the mixing time, during testing, phenolph-
considered the time since from the compressor activation, thalein was added to the static bath and then the points of air
achievement of stability in maximum capacity, added a injection were triggered. With the activity profile achieved, it
solution of phenolphthalein until homogenization in pink was added 50 ml of caustic soda solution 0.2 g/ml. The mixing
Tap Hole
Tuyere 2 Tuyere 1
Equip. # Vertical Distance
33º 33º an gle bath lance
(º) (m)
3
Injector 1 1 35 0.333
Injector 2 2 30 0.450
2
Injector 3 3 35 0.425
126º
Injector 4 4 30 0.433
Supersonic 1 6 23 0.066
Supersonic 2 5 25 0.066
4 1
88º
54º 54º
5 6
36º 36º
Slag door
Distributor
Flow meter
Press meter
Dome
Supersonic
lances
Atmospheric
injectors
Hearth
Tuyeres
0 1 2 1-4 0
1 3. Results and discussion
2
2-3 0 3.1. Bath behavior
1
2 The EOF as described was designed so that the decarburiza-
1-2-3-4 0
tion reactions were carried out through the mechanism of
1
diffusion of carbon from the atmosphere to the oxidant liquid
2
bath above the slag. The equipment also had oxygen burners
to accelerate scrap melting. With the enhancements were
introduced supersonic lances that produced a reduction in
distance lance-bath through its movement into the reactor,
Fig. 5 – Colorimetric method. (a) Water plus phenolphthalein and (b) Water plus phenolphthalein plus caustic soda.
62 j m a t e r r e s t e c h n o l . 2 0 1 6;5(1):58–67
Supersonic
lance 0 1 2
Tuyere
but also due to the considerable increase in the speed of tuyeres causes a reduction in apparent density of water in
oxygen. this region. The liquid alongside with greater density force
Nowadays, the EOF has eight points of oxygen injection to the flow direction of the densest to least dense in the
being two points submerged in liquid bath through tuyeres, counterclockwise direction. Fig. 8 shows the behavior of the
four points through the injectors atmospheric, which has interaction of tuyeres with the metal bath.
low penetration in the bath due to the character of post- In Fig. 9, with the input of only one supersonic lance is
combustion, and two points with supersonic speeds and large possible to notice the penetration in the liquid bath and the
proximity to bath through the lances with forward motion. initial formation of a deep pit, formed by the penetration of
However, the discussion is in the amount of oxygen, about the jet. The plunge of mass moved with the formed wave with
70% applied in the four atmospheric injectors for energy dur- the hole is toward the center of the furnace.
ing the post-combustion, given the need to increase the rate of It was prepare a matrix considering a pair of injectors like
decarburization of the bath. After nearly three decades since showed in Fig. 10. One difficulty faced during the execution
its start-up, it is believed that this is an unprecedented study of the experiments was to ensure orthogonality between the
to describe the behavior of the liquid bath in this reactor. supersonic jet and the surface of the bath. The setting was
Depending on the test matrix, the analyses were carried out not prepared to contain the high speeds applied at the point.
on two conditions. The first analyzing the presence of all the This change was reflected in the behavior of the bath. With
injectors in operation and the second only in pairs. Fig. 6 dis- increasing supersonic lances and tuyeres, the movement of
plays a frame image, from left to right tests with the increased the bath is enhanced by reducing the mixing time.
use of supersonic lances and bottom upwards the increased In Fig. 10, the behavior was similar to that of the bath with
use of tuyeres. Below are presented the four injectors that were the use of all the injectors and again showing the preponder-
in operation. ance of supersonic lances and tuyeres in bath motion and, as
During execution of the test matrix shown in Fig. 6, it was seen earlier in the mixing time.
found a standard drive joint bath characterized by a rotation During the execution of the test matrix to determine the
in a counterclockwise direction. The behavior observed during mixing time in EOF by the colorimetric method, we prepared
tests was described by Lee et al. [8] in previous work. The bath a device for collecting the bath that was going through the
liquid showed light waves rotation in the counterclockwise slag door. The collected volume was divided by the test time,
direction without the formation of pits (dimpling), as shown resulting in an average loss. The results of this evaluation are
in Fig. 7. presented in Fig. 11.
With just one tuyeres, it can be seen bubbling close to the Fig. 11 shows that the greatest loss occurs with the use of
center of the furnace and the incidence of gush. The tuy- the two supersonic lances. The behavior expected was that the
eres enhance the speed of the bath. The air injected through rate was higher with two tuyeres in operation. The tests were
j m a t e r r e s t e c h n o l . 2 0 1 6;5(1):58–67 63
Injector 4
Supersonic
lance
Wave
Injector 1
Fig. 7 – Interaction behavior between injectors and liquid bath into EOF.
Bubbling
Tuyere
Fig. 8 – Interaction behavior between tuyeres and liquid bath into EOF.
Splashing
Supersonic
jet
Jet
penetration
Dippling
Gush
Fig. 9 – Interaction behavior between supersonic lances and liquid bath into EOF.
64 j m a t e r r e s t e c h n o l . 2 0 1 6;5(1):58–67
Supersonic
lance 0 1 2
Tuyere
performed with only the EOF position 0◦ , without any tilting. Based on these results, a suggestion for improving the EOF
The observation of the images allows describing bath behav- process is the redistribution of supersonic lances, mainly for
ior. The tuyeres promote reduction of the apparent density the steel casting region, a position in which the EOF remains
and rotation in the counterclockwise direction. This makes the tilted to +8◦ to replace atmospheric injectors.
bath, passing the region of supersonic lances, to be atomized, The injectors did not have any influence in the rate of liquid
generating mix fraction. When the supersonic lances are the lost by slag door. This result shows an opportunity for the EOF.
only ones blowing, the apparent liquid bath density is close First, to promote new arrangement of the devices, mainly a
to real, increasing the resistance to jet penetration and the new distribution of supersonic lances for the tap side, that
incidence of spills and splashes in the opposite jet. As the needs more penetration and in operation, most part of the
supersonic lance is positioned perpendicular to the liquid bath time, the EOF is tilting 8◦ for the tap side. Second, remove the
and close to the slag door increases the volume of fluid passing environmental injectors due work with low pressure and low
through this opening. penetration.
Atmospheric injectors present in all matrices did not affect
the rate of loss, and may be noted in Fig. 11 for the condi-
3.2. Mixing time
tion that tuyeres and lances supersonic were not in operation.
2000 tuyere is responsible for reducing the mixing time. This fact is
1500-1750
1750
1500 1250-1500 characterized by the tendency of the lines of iso-mixing time
1250 being close to the horizontal. Using just the four injectors it is
1000 1000-1250
observed a slight decrease tendency, showing its low influence
750 750-1000
500 on the mixing time of the EOF.
250 500-750 On the top left hand side frame, the surface is generated
2 0 250-500 based only on the operation of one tuyere. In this condition,
Su 1 0-250 the shortest time was obtained only for the operation of the
pe
la n r s o n 0 two supersonic lances. The curves also demonstrate that the
ce ic
s
entry of all jets increases the mixing time. From these first
two analyses it is possible to verify that the injectors do not
Fig. 11 – Rate liquid lost by EOF slag door. have a large influence on the mixing time. On the bottom left
j m a t e r r e s t e c h n o l . 2 0 1 6;5(1):58–67 65
Supersonic
7.5 7.5 2 – 3
3 – 4
Tuyere
5.0 5.0 4 – 5
5 – 6
> 6
2.5 2.5
Hold values
0.0 0.0 Injector 23
30 60 90 120 30 60 90 120
Tuyere 1
Supersonic *tuyere Injectors Supersonic 1
Time grow
10.0
7.5
Injector 14 23 123
5.0 0
Supersonic 1 12
2.5 0 1 12
Tuyere
0.0
0.0 2.5 5.0 7.5 10.0
Tuyere
Fig. 12 – Contour surface for mixing time in EOF – Average hold values.
hand side frame, the response surface was generated based In Fig. 13, the left hand side frame compares the perfor-
on the operation of the injectors 2 and 3, and the amount mance of injectors and tuyeres considering the operation of
of mixing time exceeds 5 s when the supersonic lances and two supersonic lances. It can be notice a large area with time
the tuyeres are turned off. In this condition, it is possible to between 1 s and 2 s from the origin of the axes until the opera-
note that the lowest mixing time was achieved with the use of tion with two tuyeres. This result demonstrates the influence
the two tuyeres and two injectors. Furthermore, for the con- of supersonic lances at the time of mixing. The injectors have
dition of maximum utilization of the equipment, the results low penetration and so, low mixing time of the bath. On the top
are shown in Fig. 13. right hand side frame, the value fixed considers the operation
7.5 7.5 2 – 3
3 – 4
Tuyere
5.0 5.0 4 – 5
5 – 6
> 6
2.5 2.5
Hold values
0.0 0.0 Injector 123
30 60 90 120 30 60 90 120
Tuyere 12
Supersonic *tuyere Injectors Supersonic 12
Time grow
10.0
7.5
Injector 14 23 123
5.0 0
Supersonic 1 12
2.5 0 1 12
Tuyere
0.0
0.0 2.5 5.0 7.5 10.0
Tuyere
Fig. 13 – Contour surface for mixing time in EOF – Maximum hold values.
66 j m a t e r r e s t e c h n o l . 2 0 1 6;5(1):58–67
12 12
t<4s t<4s
10 10
Tuyere
8
4 seconds
6 6
4 4
2 2
t<4s t<4s
0 0
12 12
t<2s t<2s
10 10
8 8
Tuyere
6 2 seconds 6
4 4
2 2
t<2s t<2s
0 0
0 2 4 6 8 10 12
0 2 4 6 8 10 12
Supersonic Supersonic
Injectors 1 e 4 Injectors 1, 2, 3, 4,
Fig. 14 – Contour surface over layer for 2 s and 4 s in EOF cold model.
of all tuyeres. In this configuration, the reduction of the mix- • The use of tuyeres causes bubbling in the surface of the bath
ing time is determined by the number of supersonic lances in with the formation of squirts;
operation. Only in the field of operation of the four injectors, it • Gas injection by tuyeres causes a reduction in effective den-
is possible to note a reduction in the mixing time of 1 s. Finally, sity of the liquid, contributing to the movement of the bath;
on the bottom left hand side frame, it is possible to note the • The supersonic lances penetrate the bath, forming a deep
low efficiency of the four injectors working with mixing times ditch which moves toward the leakage channel;
longer than 6 s. As tuyeres and lances supersonic come into • The supersonic lances make a scattering region ahead of
operation, the mixing times are reduced. From the analysis of the initial pit;
the behavior of the equipment and its variations of configu- • Atmospheric injectors, due to bath’s slow movement did not
rations, we designed a graph showing overlapping areas for a causes significant losses of the bath liquid throw the slag
mixing time pre-set, as shown in Fig. 14 door;
Fig. 14 shows that the mixing time of 4 s is achieved in half • The supersonic lances caused the greatest loss because of
of the equipments, but it demonstrates a contrary behavior to the proximity of the slag door;
expectations with regard to the injectors. The behavior that • The supersonic lances, when associated with the tuyeres,
was expected was to reduce the mixing time with the increas- show a loss for the slag door below the use of only super-
ing of agitation of the bath sources. In this case, the reduction sonic lances.
of two injectors provided a wider field of values less than 4 s.
The same behavior can be detected for a mixing time of 2 s, About the mixing time the conclusions are:
drastically limiting this field. This strengthens the indication
that the supersonic lances and tuyeres are the main agents • EOF is excellent to promote a mixer gas-bath;
handling the bath. Because of the flow, supersonic lances have • The atmospheric injectors have little influence on mixing
a predominant role in the production process by elevating rate time;
of decarburization. • The supersonic lances and tuyeres are responsible for
smaller mixing times;
• The tuyeres promote changes in the density of the bath,
4. Summary providing rotational movement;
• The supersonic lances have sufficient flow to ensure good
The main conclusions drawn from the analysis of the activity penetration in the bath.
profile EOF are: