Chemical Thermodynamics-I

WT-1 practice Paper: II

DPS-MIS
1. How much work can be done by 200 calories of heat?
2. A system is provided 50 J of heat & work done on the system is 10 J. What is the change
in internal energy?
3. The work done by a system is 8 J, when 40 J heat is supplied to it. Calculate the increase
in internal energy of system.
4. A gas occupies 2 litre at STP. It is provided 300 J heat so that its volume becomes 2.5 litre
at 1 atm calculate change in its internal energy.
5. Calculate work done of the process when one mole of gas is allowed to expand freely into
a vacuum.
6. 28 g of N2 gas at 300 K and 20 atm was allowed to expand isothermally against a constant
external pressure of 1 atm. Calculate ∆E, q & w for the gas.
7. A gas present in a cylinder fitted with a frictionless piston expands against at constant
pressure of 1 atm from a volume of 2 litre to a volume of 6 litres. In doing so, it absorbs
800 J heat from surroundings. Determine increase in internal energy of process.
8. Calculate the maximum work done in expanding 16 g of oxygen at 300 K and occupying
a volume of 5 dm3 isothermally until the volume becomes 25 dm3.
9. What work is to be done on 2 mole of a perfect gas at 27°C if it is compressed reversibly
and isothermally from a pressure of 1.01 × 105 Nm–2 to 5.05 × 106 Nm–2.
10. One mole of an ideal gas is heated at constant pressure from 0°C to 100°C. (a) Calculate
work done. (b) If the gas were expanded isothermally & reversibly at 0°C from 1 atm to
some other pressure Pt, what must be the final pressure if the maximum work is equal to
the work involved in (a).
11. Calculate the change in entropy for the fusion of 1 mole of ice. The melting point of ice is
273 K & molar enthalpy of fusion for ice = 6.0 kJ mole–1.
12. 1 mole of an ideal gas at 25°C is subjected to expand reversibly ten times of its initial
volume. Calculate the change in entropy of expansion.
13. for a reaction at 25°C enthalpy change (∆H) & entropy change (∆S) are –11.7 × 103 J mole–
1 and –105 J mole–1 K–1 respectively. Find out whether this reaction is spontaneous or not.

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