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YAKEEN 2.0 2023 (Vidhyapeeth Stars)


State of Matter DPP-06

1. Which of the following assumption of kinetic 7. Indicate which of the following statements is
molecular theory states that gases do not have fixed correct?
shape? (1) At constant temperature, the KE of all gas
(1) Particles of a gas move in all possible
molecules will be the same
directions in straight line.
(2) Particles of a gas are always in constant and (2) At constant temperature, the KE of different
random motion. molecules will be different
(3) Total energy of molecules before and after (3) At constant temperature, the KE will be
the collision remains same. greater for heavier gas molecules
(4) None of these
(4) At constant temperature, the KE will be less
for heavier gas molecules
2. Which one of the following is the wrong
assumption of kinetic theory of gases?
(1) Momentum and energy always remain 8. At constant volume, for a fixed number of mole of
conserved. a gas, the pressure of the gas increases with rise of
(2) Pressure is the result of elastic collision of temperature due to
molecules with the container's wall. (1) Increase in average molecular speed
(3) Molecules are separated by great distances (2) Increase in number of mole
compared to their sizes. (3) Increase in molecular attraction
(4) All the molecules move in straight line (4) Decrease in mean free path
between collision and with same velocity.
9. Which one of the following statements is not true
3. Two flasks A and B have equal volumes. A is
maintained at 300 K and B at 600 K, while A about the effect of an increase in temperature on the
contains H2 gas, B has an equal mass of CO2 gas. distribution of molecular speeds in a gas?
Find the ratio of total K.E. of gases in flask A to (1) The area under the distribution curve
that of B. remains the same as under the lower
(1) 1 : 2 (2) 11 : 1 temperature
(3) 33 : 2 (4) 55 : 7 (2) The distribution becomes broader
(3) The fraction of the molecules with the most
4. The ratio among most probable velocity, mean probable speed increases
velocity and root mean square velocity is given by
(4) The most probable speed increases
(1) 1 : 2 : 3 (2) 1 : 2 : 3
(3) 2: 3: 8/  (4) 2: 8/ : 3 10. For a monoatomic gas kinetic energy = E. The
relation with rms velocity is
1/2
5. The root mean square velocity of hydrogen is 5  2E 
1/ 2
u =  3E 
times than that of nitrogen. If T is the temperature (1)  (2) u = 
 m   2m 
of the gas, then 1/2 1/2
TH2 = TN2 TH2  TN2  E   E 
(1) (2) (3) u =  (4) u = 
 2m   3m 
(3) TH2  TN2 (4) TH2 = 7TN2
11. If a gas contains only three molecules that move
6. At what temperature most probable speed of SO2 with velocities of 100, 200, 500 ms–1.
molecules have the same value of root mean square What is the rms velocity of that gas in
speed of O2 molecules at 300 K? 8
(1) 150 K (2) 600 K (1) 100 (2) 100 30
3
(3) 750 K (4) 900 K 800
(3) 100 10 (4)
3
2

17. The distance travelled by a molecule between any two


12. The rms velocity of molecules of a gas of density 4 successive collisions is known as:
kg m–3 and pressure 1.2 × 105 Nm–2 is (1) Wavelength
(1) 300 ms–1 (2) 900 ms–1 (2) Mean free path
(3) 120 ms–1 (4) 600 ms–1 (3) Amplitude
(4) Mean bond length
13. The total KE of 1 mol of an ideal monoatomic gas
at 27°C is 18. What is the relationship between the average
(1) 900 cal (2) 1800 cal velocity (), root mean square velocity (u) and most
(3) 300 cal (4) None probable velocity ()?
(1)  :  : u : : 1 : 1.128 : 1.224
14. The average kinetic energy of 32 g methane (2)  :  : u : : 1.128 : 1 : 1.224
molecules at 270 C is: (3)  :  : u : : 1.128 : 1.224 : 1
(1) 3741.3 J/mol (4)  :  : u : : 1.124 : 1.228 : 1
(2) 6.21  10–21 J/molecule
19. The densities of two gases are in the ratio of 1 : 16.
(3) 6.21  10–21 J/mol
The ratio of their rates of diffusion is
(4) Both 1 and 2
(1) 16 : 1 (2) 4 : 1
(3) 1 : 4 (4) 1 : 16
15. The RMS velocity of methylmethane at 270 C and
720 mm of Hg pressure is: 20. If rate of diffusion of A is 5 times that of B, what
(1) 4.99  104 cm s−1 will be the density ratio of A and B?
(2) 3.99  104 cm s−1 1 1
(1) (2)
(3) 2.99  104 cm s−1 25 5
(4) 1.99  104 cm s−1 (3) 25 (4) 4

16. For a particular gas, at a particular temperature, the 21. 50 mL of each gas A and of gas B takes 150 and
correct order of molecular speeds is: 200 seconds respectively for effusing through a pin
(1) Vrms < Vav < Vmp hole under the similar conditions. If molecular mass
of gas B is 36, the molecular mass of gas A will be
(2) Vrms < Vav > Vmp (1) 96 (2) 128
(3) Vrms > Vav < Vmp (3) 20.25 (4) 64

(4) Vrms > Vav > Vmp


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Note: Kindly find the Video Solution of DPPs Questions in the Quiz Section.

Answer Key
1. (2) 6. (4) 11. (3) 16. (4)
2. (4) 7. (2) 12. (1) 17. (2)
3. (2) 8. (1) 13. (1) 18. (1)
4. (4) 9. (3) 14. (4) 19. (2)
5. (3) 10. (1) 15. (1) 20 (1)
21. (3)

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