Exàmens

Ir Partial

Exeruii L

(a)
pase gassosa Vreachr =
?
Ca , CB

⑤
FA '

0
K = 0.001 -1 → Ordre 1
Eguaciéde dissing del CSTR : V = Fao-Fa_ ; ✗ =
FAO -

FA
= 1- TAI
min Fao Fao
Cao ,
ra

Fao
CA
Oo =ct =
14min =
↳ FA = (1 -
X) Fao

A → B ✗ = 0.5 V = Fno-Fa_ =
Fao -
FA
=
FAO -
FA
=
Uo ( Fat H-XlF/n#
-

ra vi. ca K
F÷ Ku
xltyao
-
-

reacuié elemental
-

ra K
-
= CA
↳
¥
V= ☒ 1- 0.25
✓
-
= = 1000 e
, 0.001 '
(1-0.251

(b) ✗z si
'
reactor CSTR V2 __ Vi
s
afegeix on .

☒¥¥µ↳.↳
Fai "±(✗ °°¥_
Cao
" =
( ×, -
✗,) =
z
-
✗ ) ,
= (✗ 2- × ,) = (x
,
- ×, )
.
-

raz K Caz KU ✗ -

Hoh KU Xz) -

-
% .

É
Y÷
✗ ✗ z=
' = 1- → Caz = ( 1- Hca ,
CA ,

1-
u÷×y( X ) (
V2 = ✗z -

,
→ 1000 = Xz -0.51
0.001 (1- ✗ 2)

1- ✗ z = ✗ z
-
0.5 →
2×2=1.5 → ✗ 2=0.75

Exercised

reacuié de descomposicié A → R Ir ordre

en
gas :

c = 0.5m
< >
Can Ca (12
Fao CAO ? PT Vreachr Fao
§ TT
Fa FR R
(a)
= - = - -

r=o . in, ☐

P= loatm Pt = Cao R -
T
,
→ Cao =

¥g → C☐o= 1.812dm} ??
T = 400°C ,

V0 0.001
1m¥ §
=
=

✗ = 0.25

"
(b)
0¥
k= ]
? ra K CA a- Ar Ordre V n 5=0 157dm
-

=
- -
-
= .

✗ ✗ ✗

eguacio
-
de
disseny del reactor : = ra -
☐ V. = Fao
!☐ - ☐ vi. Fao
/ ¥g→ Vi =
FYI ! ,¥,,a .
v.
=ÉY÷f×¥× ,
V.
=¥-oHnH
-
✗ 1)

V.
=¥-oHnH
-
1)
✗ → v1 =

V¥- f -
incl -
✗1) =D v. =
¥ C -
Inu -
X) ) → K =

÷ l -
Inu -
X) ) → k= E-
0.157
C- Incr -0.2511

↳ '
he 0.00183
Is
 (C) L = 100m

§
>

Fa Fi
D= 10mn D

Vreactor =
(°1217100 =
1714
D= looatn

T = 400°C
PAU =
MART → Pa = CART
Uo -2000mi/h
-

←
Pa Pt ya PT __¥÷P
ya CART CA =D G-
.
-_ = =
.
→ -1
,

(d) ✗ =
? Ya - -0.5
Ceguimdarsl ↳ (A=
0.906 M
✗

V = Fao
! 9¥ V = C- In 11 -
X)

✗I
-0¥
↳ = Incl -

"

exp(-Y÷) f- 14-0.001831
1-
expfv¥ ) 1- × ✗ 1- ✗ ✗
→ → =
exp ☐ 0.0026
-
= = =

2000
÷ -

Exercise 3

Reactor Batch de ✓ = 10dm}

A → B
*

3 experiments a
dif T

(a) Det ordre de reuccié .

Mehode
integral :
0,8 - •

017 -

•
Ordre 1 : T -300K
-

0.6 •
-

"
1T¥) t Noes recta
lY÷ )
•
in -
-
unit as -

0 0

50 •
0.1296
0,4 -
122=0.993
0.2445 100
•
150 Inl )
°
0.3475 o, ] -

200
0.440T
250 •

0.5262 0,2 -

300
0.6048
350 •
0.6778 0,1 -

0.7459 400
450
0.8094 l l

160
l l l l l >
I
°
so 150 200 250 400
300 350 480
•
Ordre 2 a t
zz
1- - I •

CAO t
In I.
LA
ka 't
24
-

= -

O O •

3. 1868 50
21 -

6. 3776 100 •

9. 5689 150
1$ '

e5 recta
•
12.753 200

( ' Ordre de la reacciées 2 15.94.56 250

is 7.858415 + 0.03020011
y=
-

19.1329 300 •

350
22.325
12 -
122=0.9999
25.518 yo,
•
450 Inl )
°
2¥ -707
g
.

6 -

•
3 -

⑧ l l l l
l l l I 1 )
☐
50 100 150 200 250 400
300 350 480

t
(b)
¥ ¥
calculates constants de Cada T → - = ka -
t

÷zg ÷
-1=50
Ynds
a T -300k
-
a s 50 KA 0.0638
-
= Ka . →
,
__

,, ☐ ,

a t -320k a T -50s
¥y ÷ Ka 50 KAz= 0.0883 Ynds
- -
-
→
→
-
=

,,

-1=3404 -1=80
0¥ ÷g 50 0.1197 '
KA] fois
→
a a , →
- = Ka -
=

¥ ¥
's
(C) Kaf -1--3000-1 =
0.0638%1 In K , = 1nA -
.

Kaz (T = 320K ) :
0.0883%15 a
1603.565
→ 1nA = 2.59031
y= 2.59031 ✗
-

•&
↳ A 13.33
=

Uas ( T = 340K ) = 0.1197 '

fol
's
0,1
- ^ ° "" "

Inu
-

Fi =
-1603.565

o.o ,

/
I 1 >
Ea =
13332.043mg,
I

300 320 340 +

4-

(d) guposa -1=360%+273 =

633k

Cao = 0.5M t=
? Ca -
-0.001M Kal 6331=13.33 .

exp (-673%1%-3) =
1.0584 →
¥ -

¥ = Ka -
t

¥ -

¥ = 1.0184 t

LD t
-942,7s
-

Exeraii 4

reaccio A B
300m04s
→
:
Fao =

Serie
Reactors en Dades del lab
Grirfic
-

( STR t PFR or PER t CSTR

Ir reactor ✗ = 0.3

1%1 %
,

2n reactor ✗ z= 0.7

""
X
-

FA%a 0.3 0ft

est
(a) Quince la minor
configuracié ?

(
0.0 15000

0.1 9999
Simpson
'

per relacio de

0.2 7143
Ir PFR CSTR

¥ [ fcxo)
+

f(Xz) )
.
0.3 5883
Open = +
311×11+391×21 +

0.4 6522

,=µ=(°" [15000+3.9999+3.7143+5883]
0.5 8571
"TR
0.6 13044
↳ Up =
2711.58in
§) & ☐
, , , .gg ,
+ I

(÷g÷ )
Vcs-112 (0,7-0.3) 7500 > U ]

l02-dm
dm
-
= ✗ :
-
-1 :

✗ = 0.7
✗ 1=0.3
✗ 2=0.7
 ✗ Faolra
f (X , Xo)
-

Vestre
-

(b) CSTR =
-

Ir .
c- PFR

①
0.0 15000 = , ,

l 999g
(
-

(STR
0.2 7143 is

§P
or 0 0.3 5883 5883 (0.3-0.0)
Vcs , , 1764.9dm}
'
=
=
☐

0.4 6522

(
0.5 8571
✗, = 0.3 ✗ 2=0.7 PFR
0.6 13044

DX y
0.7
-

18750 Up ,=p= ( f +
4f -1212+4 fstfu)
-3 , ,

(0.7%3)-15883 +4-6522+2 8571+4-13044-118750 )

'

↳ Up ,=µ=

Ut= 5766.2dm] Up,=µ

:
4001.30€
=
'
La Miller configurauio es es -112 + PFR
pergue

dona on VT Menor .

⇐ "

( ) f
" "" "

}
→ ^
" "" "" ° " "" " " "
"" " " "

→ M
Dif
si et use trace el pocinomio
Novel initiates .

gemultiblica Fac,
Ne vida media .

unidadec de la A →
unidades dek

el
depended
order dela
reaction

si orden 1 i 2 →
motif in int

si da ! !
no →
m.dif.NO Ios

th esta en exeso

yo,ip
si
Bif 131 Bente → se tiene
que recirculate difenie H 6
Entrain sale,
.

t separate
z ca z z ,
2¥
, z,
→ Cos
p p
Pure
f Signe recirulan lot
gases del Real tht Cky
H2 Toi No some una
parte
Bif
pg
-
thes care
Exercicis T -
3

① Det coston de 2 Reactors CSTR Un = 6 m3 i Vz= 15nF

se imerpda
??

② A → B

reauié
ca ↳ Ir Ordre
Vreacfor __
? CA = U -
X) Cao

F¥%
-
ra = Kca
↳
T-n-q-rata-n.uo.LY#-n--?bkn-o-H-xKn-o1=Uo=ct--lOdm'
1min
V=
-
Kcr XICAO -

"
A → B K = 0.23min

✗ = 90-1 .

0.9
CAX.ua#=0o.X-K(y.xy-DV--
10 .

391.3¥
V = =
}

-
KH
Xo - X) 0.2311 og, -

Si hubiese Sido un PFR ?

Vreauor = ?

✗ ✗ ✗
→
✗

= dudes
V= Fao )¥
•
.
→
" " '

n-o.tl?-n.-- 0¥ !¥n↳=÷¥f¥× ,
-
-

¥1 " " ""

↳
V= I C- Incr -0.9 ) ) '
miller
0.23
=
loo.in 4 vegades ??

③ A →
B no Ordre 1- de Maceio'
per ✗ = 0.95% Ca = 11 -
X) Cao

"
NA -
- ( 1- XI Nao
K 0.01997min
ra CA
=
→ -

= K -

NAO Nao NAO

Nao

1¥
"
"

m.
-
raw
→
+
=/
NA
dnt
K.CA V -
=/ !Y÷=÷f%÷=É1nwaY=EYnYnn¥=
NA NA
NA

'

n(¥nµ) ¥ in
/ ¥) E- linen N ) =D 1- =L (-1^(1-0.95))
'
-
= = =
0.019Gt

list = 150.01min
=

④ A → B en un reactor Contino isotonic calendar V del reactor CSTR i PFR ✗ = 0.99

per

(a) CSTR

§|
" " ✗ = 0.99 ( a. 1)
-

rA=K
" "
"☐

Fao 5m01 / h

lt-n-o-U-XF-n-o-Fn-p-X-bv.gg
__
Cao
92dm
>

Fao }
Ves, ,, :
,~= =
Uo = 10dm / h=ct K

A ☐
-
B

Vest,z= FYr-n.FI la -2) -

ra = KCA

Fao ✗ 0-99--10-3=60.0
2750¥
}
Vain =
-

= =
-
ra k Cri X)
k Cr Fox
-
= -

0.0001 . (2-0.99)
( 3) To
Vasta
F☐FA uo.ca/o- ✗
.e=%i÷nI=E ? ?
a-
=
=

Kanin
 (b) PFR

✗ = 0.99
(a) -
ra = V-

Fao -_ 5m01 / h
✗

→ suo
J tag ✗
}
= 10dm / h=ct v =
Fao =
= 5- . 0.99 = 99dm]
PER

✗
k e. 05
o

v = Fao
! ¥a (b) -

ra = th CA

✗ ✗ ✗

(C) -
ra = K ( AZ
Upz t-n-of.IN?---Fn-o/d---00ln-0f#x,--Y-C-lnC1-x))--DU--IiEo0-.C-
o KCA 0.0001
Incr -0.94 =

l2d_m
,

✗
✗
✗ ✗

Yoni Fao -

! = Fao
!¥m=%f¥¥a 0
;
= I
=/ am •
-

¥1 "
÷ %÷i 3¥ ?? -
.

⑤ A → Btl

Reactor Batch Cal Ir Ordre ra KIA

-
=

V -20dm]
"
-
b- =
0.865 min NA = 0.2

NAO NAO
NAO
NA
,
__
20m01s + =

f.IT?j--ist--/nd.Yn.?----L-fdnNI--'-u1nn-I)-Dt-- ÷.info?-)-. 5.3min

-1 Na Na Na

(b) ra V. ( AZ a 2 dm]
fomin
-
= -
=

Nao = 20 mots

NA = 20-19 = 1m01
NAO NAO Nao
Nao
Nao ""

I =/ ! :!÷÷.=fIYn÷=¥fTu÷ 1- =÷t :# f)
"☐
"
-
#
ra V -

K.cn?V
= =

NA
→ ⇐
÷ + =

Na na
NA NA

XI Si Ti = 127°C Pi =
? Pta = ?

^t
>
°→?→
"
U Put

65.ba#pi=20-0-08z2-lM-tHN-=32.8a--m
Pi -
= ni R Ti =
=
=

⑥ Hz 0,
t
Yz →
the Aumulacio '
:
110kg / ,
-

rth
i -

roz =
?

§
0
¥2
= 60m = 0 -6m
U reactor = tr -
.
0.75 = 0.212 m3

L = 0.75m

✗ = 100-1 .

t.IQ?-z,zmj,g-y
14m01
mesck perfecta rtlzo =
= 28.82 KI
m3 .
S

rtlz 5th =

28.821k¥
-

rheo = -
= →

!;?÷
-
ro , = 14.41

=
⑦ Reactor Batch 2A -1 3B → 4C
0.751
(a) t=
? ✗
☐
=
.

( ( Bo
Nba Bo

=/ ¥Yj- / d÷ =/ ¥
& 20¥ ucñ=É[÷ )
E- = . =
13.79mi/h c- = =

| |
NB (B

@ ( = 100 met
Bo
Fms
-
-

RB = U Cpi k= 0.0065
dmymoih 1- =
In -

f- ¥ ÷ ] + =
¥ +
↳ of =
( ×,( If ☐
=

t=G÷£%÷g
.no/-.4.62h-Cb)V--l0dm3rc=
↳

? (c) ra i r☐
-
-

re :

1T¥ 1.3820¥ =
IT :-# =

= -

ra = 1.37912 = 0-6895 noydn.sk

-

RB 1.034
rdfdniih
-

⑧
?÷
( 31-160 + H2O →
↳ Hoo Oz
↳Hoo -
-
A (a) Cao =
? Pa -_
1040g / e Ma -76.09g /•I
-
Vadditius ( I

✗☐
Klaus1.7<10-35
= 0.23 lrordre → -

ra -
-

'
y = 0.23
7.5 M
Fnz =D inert
Xp ,
0.77 Cao = =

¥
Vo 350dm> Is et
7¥09 ÷
= = 0.23 -
to .tt -
. =
.

(b) V reactor =
? tres :
? ✗
f- 0.90

FAO FA
Uocn 350.0€
85dm3
-

'
UCSTR = = = = '

uh -
✗
1¥ 44.x , 1. 7.10-3 .
,=
(n o,

.85
UJ; ÷oo
I
tres = → 1- =
= 5294s -
= I

350 ,

(c) 2h Ordre -

ra = K CAZ K = 1.7-10-3 dmyn.is

X
Calo 350

O.q.i-F-o.si?--a
V0 .

Ucreachr = =

" ( 1- XI Yao,
 it is i
⑨ ( 31-160 + 1-40 → ↳Hoo Oz Cal v -650dm]
-

"

4j÷
"
Ar ordre
-

ra
-
- u ca ; v. = 5- to Min re =
? rc = =
6.52.10

=
rc= 4.24
noym .
-

NAO Cao

t=§%÷ n' #
¥1T
'"
Baton t
÷ t-s.to c- inn -0.8611
→ → c- = ' = in - :
,
a- Nine

✗ -0.86
, t=3
-

④ PFR

¥g ¥É☐
in x-o.ae ,
✗ ✗

Veer : Fao / 0¥ →
open =

§ -✗ ,
= 1- Incant =
5¥ ,
C Inu
- -

o.astl-2582.SI#
0

A + 2B → 3C

"
Ar Ordre -
ra = Uca K -0.58h
-

(b) Znorche Fao to

dn÷ 3¥
0.58 150
v0 = 500dm]
K =
dmynd .
) =
moyh Vo = .

,,
= 0.1389

/h ✗ ✗

} ff¥p =°i"°÷;%÷
00 Cao
#
OPEN Fao
15.16¥
= = - = =
:
'

u Cal ucn.ie K Cao

0.58 .
150 1-
.
,

(c) (a) CSTR

Vesta =
F☐÷a = =

o.gg ,=
1637901€

What ? mwyiarp

NAO NAO NAO

① A → Btc Nordre t 5min ( Efa) t =/ DNA

↳
=/÷÷=H%÷=÷f¥÷]
NA NA

1¥
1- =
Bath ? ✗ = 0.75

,
Na -
-
Iwao
E- 5min
s=Éf÷+ =Ef÷+÷]= [
e-
E. 1- ¥ -1¥]
.
-

El i wit
§ = U -

NAO →
Nao =

¥ ,
Mal

=Él÷ =E;÷µ=¥s¥÷=E÷→t= *
= is

Nao Cao

ty, = 0-5 ( no t =/ DNA

manga,
=
/ ?¥- =
¥ In
CA
CA

1- = 0.25 ( use
3/4

¥ Ino?^÷µ
"
the =
=
In 1h12 ) → 5 = In 121 -1s the 0.1386 min

1-
314 =
¥ In
*
=
¥ In 141 → t
}, " _-o÷ ,,
' 1h41 =

10n
?⃝
 ✗ ✗

@ V -2dm}
Cao / ¥☐ Y¥É|¥×i=÷
-
-
- lmdk U= Fao =
. =

_§-)-☒ R /men
Uo = 0.5

?÷
'
Ordre ra = K CA 2
¥ H
-

In = .
→ = 12 → ✗ = 12-12 x CA = -
X) ( ne
2A → B
,
"✗ = 12
LA ( n -0.921 I
o og
dmyao, ,
=
w = ,
✗ = 0.923

cA=O.O77M-
Ca =
?

① Evie
 Exevciuis T -
4

① 4A → B + 6C I = 649°C torch -

ra = U Ca K = 10 151

✗ ✗
✗

(a) -1=6499 P : 460hPa ← c. reactor U = Fao / DX

→ U= Fao
/ u¥ =Ff☐of¥× ,
=

¥¥# C Inu
- -
✗D=

Cao CA Crs (R ✗A = 0.8

¥É☐F 6%-56-1 Ina 0.87 )

107.3-0=3
'
yomdlh
- -
=
Fa =
=

p in RT do É-1641+-2+3)
0.6665m£ 666.64¥
o, = → = =
=

460.103

(b) Reactor Batch V

VPFn
'

h 1- =
? Po = 800hPa
=
Butch T -6490C
-

N.no LAO CAO

⇐
JONI-
ra V
=

f d÷g =

/ 9¥ =
IT in
/Y÷ / = in
/¥¥,µ|=÷ c- incr -
HI = •
C- in 1^-0-81--0.1614 =
9.66min
Ng CA CA

(C) si ✗ = 1007 .

PTU = n, R T
??
Py =
280 .
8.31
-164912T€ ,

0.1073

② Reactor Batch A → R Cao = Umollt

3.6 → 0.4
min)
[A
?
→
t =
Ca ( M)
-
ra Cmoydm } -
✗

0.010
0.4

1. 2 0.050
3.6
?
1. 6 0.100 Nao Cao

1. ÷÷=f:÷=f:÷=
2. 0 0.125 ⇐
2.8 0.230
3. 2 0 .
450 CA 0.4

3. 6 0.500

4. 0 0.650

③ ✗ -
racmoydms.mil (a) ✗ =D -8
0.8 0.010

V= Fao
°↳
0.6 0.050 ✗ '

° 'S
0.100
-
ra
= =
°j =
1

0.4
0.125
0.3 0.230

0.2 0 .
450

0 I
.
0.500
0.0
0.650
@ A → 412

( nohihaperdues
W=
? nen PBR de
iarregal
✗ ✗ ✗
"

¥¥÷|×
"

/ /
DX DX
Fao
¥
'

✗ W= Fao
= 0.35 -
ra -_
9314h V51 - .
calm = = = C -
incl -
H = c- inn -
✗it

o
¥ o-u.ca ,

↳
Expo = 2000
moyh k=93 Choy

P= 3. Laton / T 17°C W
2-
É2÷t3 C 92.58
Inu 03511 =
llgcat
-
= .
-

gz
=

⑤ A → UR Fae = 1000 moth ✗ = 0.2

CAO = 0.1 not / L
✗

cn-1-rni-w-t-af.dr.LY
0.0390 3.4
=

0.0575 5. Y

0.0750 7.6

0.0920 9.1 Ca = (1-0.2)-0.1 = 0.08 not / p

'
-
ra = E. 04

✗ 0.0780

g)
=
,

✗2=0.0920
-

ra'= 7.6 +
(9.1-7.6)=8.04

Yi = 7.6

y ,
= 9. I

@ ✗ -
ra
(a)
per ✗ 1=0.3 i ✗ 2=0.8

0.00 0.00530
0 I 0.00520
.
PFR -1 ( STR

0.2 0.0050

¥ [ fcxo) f(Xz) )
0.3 0 -00450
v. =
+
311×11+391×21 +

0.4 0.004
0.5 0.0033
°i3g [
(
V , = 157.23 + 3 .
160.26 + 3 .
166.67 t 185.19 ] = 49.62 dm>
D. 6 0.0025
0.7 0.00180 /
0.8 0-00125
0.85 0.00100 -

Uz
/( Xz
= -
✗ ,) = 866.67 ( a. 78 - 0.3) = 433.33 dm]

4=0.8
Comsinaué PFR c- (STR ✗ 2=0.8

Fao
5ZmIn
=

4=0.3
o
✗ 2=0.7
④ reactor CSTR → U = 250dm]

A → B
¥g
✗ = 0.8 ✗ =

↳
CA CA = ✗ ( Ao
-
ra

I 1

F^°,r¥
FAO - X .

2 2 u =
=
=p
=

3 3

4 y

5 s
6
6

8 8

10
10

⑨ Vesta = 5L A → 2B

'
V0 = 2dm / min Cao = 0.1 M K = 0.71 min
"

✗a
(a) =
?

F_=A Uo (Ao ✗

ez¢ ¥
2 O

¥, X=0
'

✓= → v = → 5- = →
1.75 1.75 ✗ = ✗ → 1.75 = 2.75 ✗ →

,cao=
-
=
- ra y (n -
× ,

(b) (B =
? CA = (n -
X) Cao → Ca = 0.0367

↳ (Cao -
ca )=2(0.1 -0.0367)=

(c)
Up,=p= Fao / FaDX =
¥ l Inu
- -
Hl =
÷ f -
Incl -
0.63 ) ) =
2dn
]

④ Reactor CSTR 2n ordre

A → B ✗ = 0.5

'
cal ✗ = ? 6V

u=¥÷×
'
6- u = X

6.FI#x--FI/-n- ×
'

' '
6X = X → ✗ = 6.0.15

① A →
P 2n Ordre
Cao = 4M Up ,=, = 3 Vcs , ,z ✗, =
{÷ =
° -25

(A I M
=
✗z
*
Can = ?
= →

Cai = ? CA
CA (p (A1 (P

µ
,

Cao Pl
FAO Fa
=°%!÷¥'
-

± Vcstiz =
.
-
ra
-

✗~
✗2 ✗
z Xz

vi. er -
- Fa
/ ¥ .
-
-
" '
at =

K fd÷=¥1¥×.EE.IE#.--E..-i.iiiii* ,
✗I ✗i
✗,
✗,

'" "
3
-6¥
3¥÷"=¥e☐iji '¥_
-

×
'

÷ ×°g
6.7s a- o.rs
→
=
→
9 =
→ 6.D= → =

, ,, iz s ,

CA,=0SM
4> 0.925
Xz = →
① A Fao 100
-4min 0.8

F☐?ja
2.5 P 00 ✗
.
→ =
(a)
Vcs, ,z= = = =
2°dm]_
Cao = 2 not / I K ,, -
✗, ¥ ,, ,

✗ = 0.8

it
"
u = no min
-
-

?
'
(b) ✗ = U= 30dm

u?× %¥✗
FAO
U FA
¥
-

6- 6X=X
= =

,
☐
- 30 =
→
6 = - ☐
→
X=0
-
ra
t) Foto =? FB
100M¥
-

11=0.8
-

Fa = (7 -
X' Fao

FB = (Fao -
Fa) 2.5

100 = ( Fao - (1-0.81) Fao) 2.5

2¥ 502¥
'
= Fao -
0.8 → Fao =

Nao Cao

1③
LAO

=/ ÷% =/ 1¥ # [ 2K£↳ 2T¥ Fi Fx ]
"
Batch A
f¥?
B
Fine
#frae ] In frae
→
(a) + = = -
2Fa =
-
=
-

✗ -0.5 Na
ca ca
Cao
1m¥ ra
3.cn?.5t=2T-F1-F.5 ]
= -
=

0.195h
3
= =
11.7min

④ Ucstr ? =
11=0.95 a- =

in
.

00=25
min

Cao = 20 molle
CA = (1 -
X) (Aa

(1+0-54×-140)
%n(y?Yj×
Fao Fa Uolaox ) ( v0 -10.51×+0-5
Vesna
-
-

4.9m¥
=
→ VCSTR = = = =
4945 dm> =

-
r☐ 0.1 ( l X) -

Cao , , ,,
,
-
×,
Eiamene

② A → B

{
T
,= BOOK
V= 1dm } 3T
Reactor Batch diferert -12=3104

T] = 320K

(a) ordre de reauié ?

MeErel
:

-1=3004

2.8 -
•

Ordre 1 :
In (
¥-0 ) = ka t -

2. 6-
•
2. 4-

•
2. 2-

Ln(¥=)
2-
t •

1. B -

O
O
1. 6-
•
.
>
0.31897 50 1. 5065.10-4 + 6.3776-10 ✗
1. y
y =
-

0.6379 100 1.2 - •

0.95685 150
'
n({÷) y -

•
R? 0.9999

200 0,8 -

1- 2758
0,6 •
250
-

1. 59455
300 0.4 -

1.91393
@
0.2
350
-

2- 23213
400
2. 55105

2.86998 450 ⑥ " °

ifs too 2150 3100 Iso too
,

so if yso

1- (s )

ordre 1

?
(b) U de ueloalat
in
[9¥] = Kait

F- 300k → in
/ ¥gµ ] ,
= K
,
•
50 →
by = 6.379.10-35 '

-12=3104 → In
[ ,°÷gy ,,
] = he -50 → 42=8.826.10-351

3204 1.196-10-25 '

↳
[o¥ so Kz
=
Q,
'

→ in = → =

In "=hA
¥ ¥
'

f) A=
? Ea=?
-

-
Ytcui

Inu Yy
0.0031
00032,0-0033 1nA = 1. 6515-10-3 A =
'
l ' J

5.055 0.0033 "

-3.32756-10-4
-

-
4.73 0.00323
Ink
- y -

•
y=
1.6515 -10-3-3.32756-15 X -

E§ = → Ea=

-
4.426 0.00313 -5 -
•

✓
 FA%☐
'

② ✗ -1ha
-

cat Up ,=µ= ? 11--0.5

0.0 12-82 1282

0.1 14.65 1465 as

§
1667
0.2 16.67
Up,=R = (320-9×4 -
236.01×3-192.019×2 -18.0425×+12.895 ) DX =

0.3 19.61 1961

o
0.4
24.24 2424
0.5 30.30

[
3030

]?
's
0.6 41.67 =
320.9×5 236-01×4 92-019×3 8.0425×2+12 .gqg× =
4167 -
+ +

5 4 3 2
0.7 59 52
.
5952
0.8 88 .gg 8889

320.9 Costs " >

=

-g
-

236.0=1,9 +
92.0k¥ +
8 + 12.895 .
0.5 = 9.605dm}

Vpfn = 9.605 -
100 =
960.54 dm)

(b)

Vcs-1,2 = 2500L Nest ,z= 4167 -

0.6 =
2500.2€
}

/
FAI
Venn X-
-

= -
✗
Et

③ A → R Ir Ordre

Vpe ,z=(¥) 1.02.10'm

' >

2
L=lm

3
(a) K = ? - l →
vpeir =
(0-{36-1}) -
z = = 1.0179dm}

Lab : § = 0.036m
↳ U = Fao )d×
Tra
P -

Vpflz =
Fao RT -

P=5atm
1- = 350°C = 623K ( Ao = → (
AO-j.at?-z.gzy- =
0.0979 M

✗ = 0.6 ✓
☒
> ✗
Uo 500dm 1h
/
=

¥¥#f¥×
U 004-0 C- Incl 0.61 )
5
= = = tina x) ) - 1.04-a =
-

o
KCA

↳ U = 450.1 %
(b) L=
?

✗
✗

§ t . U = Fao
f¥a =
uocao
)u¥a = IF C- Incr -
X) )

0
o
17=25 atn

1- = 350°C = 623K
↳
¥
U = l -
Inu X)
Yinert
{
-

YA -_
Fo =
320mi/h
YA --0.5

Y inert :O 5

¥6!L
.

C- incl -0.81
¥
' =
7. - L = C- incr -0.87 →

11=0.8
↳ ( = 562069.88 M
P Vo =
Fo R T

25 . 320000
Fo =
= 156598.68 moyh
0.082 -
623

Fao = Fro -

ya = 156598.68 -
0.5 = 78299.34 month

P Una = Fao RT

78299.34 -
0.082 '
623
↳ uoa = = 160000
dm3/h =
160mi/h
25
 ④ A →
Btc

-1¥
"

F^n ÷¥g
k 0.0001 min T
? UcsTR=
=
= 100°C (a) Vesta =
=

.
Ea = 105k] /not

A lzatm
1-D VCs-112 = 12.3-0.52
→ Pa =

}vo=F☐T
0.0328<(1-0.5)
Ta = 1770C → ↳ =
4-0.082-(177-1273)
P☐
A Btc
→ Fa = Ymoymin '2
↳
Vesta = 374.780m€
↳ V0
✗ = 0.5 = 12.3
driymun

Ea 1
Ink , = 1nA -

IF ,

In 0.0001 = In A -
.

¥3 → In A = 24.648

✓
In Viz = In A -

EI ¥
In K2 = 24.648
-10,5¥ .
1-
777+273
= -3-4167

-
l
↳ V12 = 0.0328 min
 Examen_
A
integral ! !
+ B → c + D Metode torta
-

( 0.5M
t CA ( ✗ 103) Bo
=

0 50.0
50

100
38.0
30.6
si Ordre respect A
? In f- 8¥ )=inuA + a. encca) -

(1¥ )n= ↳nh

En -
En -
,

150 25.6

200 2212
"

250 19.5 t CA ( ✗ 103) - DCA / ☐f. 10-4 -

dln-ldt.IO
300 17.4
0 80.0
3.0
2. y
50 38.0 1.9
1. 48
100 30.6
1. 25
1 -0°
150 25.6
^
0.75
200 22.2 0.68
0.6
th 19.5 0.54
z -
0.5
300 17.4 0.42 0 4
.

2.5 - -
=
vicar
• •

2 -

>
'

10-4 CA :( O
1.9286
dca / It
0.095 X
.

✗ I 1.9286
Y
-

1.5 -
=
• •

3. 0 50
R' = 0.995 ✗ → 2
1- • • e. q zg -

1- 25
• • 30,6
p
-

? -75
•
e. s 0
-
25.6
• cakuladora
0.6 22.2
0 5
-
19.5
56 too the
I '
l
° 4
zoo 250 zoo
-

( 7,4

⑦ A → Btc Viator = 200dm } (a)

P☐= ya PT
Nao -_
?
D= 20 atm
Batch PA = 0.75-20 = 15 atm

#
0.75
YA =

YI = 0.25 PA . V = Nao
-
R -

Tr 227°C : -500K
=

-
NAO = → Nao
=o¥gj?g÷ =73.l7mdsA-

(b) Cao =
N- -
☐ Cao =

732.jo?--=0.37M-
NAO
Cao Cao

t.ua/dY#.r-=Jdfan--=tufqfn--='-u(in(YI-1)-o.- (
f) Nordre → -
ra -
-
" 'A
in
D= I 1- unit -0.9911
,
-_
4605min
0.1
' '
✗ CA CA
K = min = 0.99

CA = (n -
X )(Ao

(d) CB =
? CA = CB

( D= (1-0.99)^0.37 =
3.7-10--304
③ 2 reactors PFRICSTR

A → B

Levenspiel
FY÷ ✗
(a) T 12=830 kPa Fao
us Sook 0.4 mys
-
: -

- =

b ? •

X -
ra
-
÷ ¥1T
+ .

0 0.450 2.22 0.889

0.370 2.703 6-
0,1 i. 081

0.2 0.300 3.33 1.333

•
g.
0.195 5.128L 2.0513
0.4

.gg , , ,, g. gya , g. , , , ,
y ,

0.7 0.079 12.6582 5.0633 •

0-050
0.8 20.0 8.0 3 -

csttr
2- •

n -
•
PFF
•

(b) Vpfp= ? Vcs-112=7

.
I I 1 I 1 I 1

Oil 0.2 0.4 0.6 0,7 0.8

Per poder aplicar Simpson hen de heure el pont 0.1

UPFR =
%¥[f( ✗ ol -131×17 +
31×21+11×31 ]

open =
10.6T¥ [ 0.889+3-1.333 -13-2.0513-1 3.5398 ) I
1.093601€

Vesta =
f-¥÷)× , , ;
✗6 = 3.5398 -0.6 =
2.1240mi

④ reactor Contino 7- 227°C

rA=K( a cry Pgoz
-

PT
yso, Poi-yoz.PT
-
=

Ki 200
↳ l " 't
1>802 = ° '
= 4- " 6 atm
28oz TO , → 2- So,
↳ 14.7=2.223 Atm
p☐z= o.gg,z .

PT = 1485hPa ( 14.7 atm) Psoz ' V =

Fso ,
RT

-49502=0-28 Gozo =
→ Go, -_ 4.116
Fo
Yaie = 0.72-1 . 0.082 .
g-Oo
=
0.1004g

o?¥6÷gy 0.0542J
↳ (
0.72 -0.21=0.1512
lot →
or = =

Yo ,
-_
You're . 0.21 =
,
⑤ PFR 2 Noel ZNO Clz
.

→ +

ZA D 2B C
-
+

-
ra = K CAZ

T= 425°C = 698K

P = 16.2 atm

3¥ ¥0K
20 S
Fp =
tones Idia
0.021m¥
'
=
. .

. . .

any 365 dies 24h ,

✗
A = 0.85

k = 0.29
dniym ,, a -1=500 K ans Ea = 24kcal not
/

in Fao =
?

FA = 0
-021m¥ .

z☐A = 0.021
m
A

FA = Ch -
X) Fao → Foto =
gtr → Fao =
??÷ ,
= 0.14

-
molls

(b) Oo i v =
?
M . I 2

h 2 react ten exeese

'

. my pores

Ex : A + B → Ct D

-
ra = K Cat CBB CB > 3) (a

CBO = CB
-
VA = U -

CBOB .
( ad
in

Cat apligves metode

'
-

rn
-
=
K →

Equations del metodo

Viener de
integral
✗ i K
'
→ a' = vi. GP el reactor Batch
↳
v

E①
supesarorilre -ra-vicn.tn or U' =
KCBS
✓
01=2 b
- -
ra = Vi CAZ

¥ ,
= K -
t

E- ÷ t

recta 0.1173 0.12479

e2
+ ✗
Y = ✓ es una reeth
.

calm
0
0 ME 0.99996

50
6. 315

12.6797 100
'
B
K = 0.12479 → K' = Q -

CBO
19.0625 150 °

0.24¥ Yasir
"
a--
:

25.0456 200

250
31.282

17.47126 300
2­
 FAO
Fne
CAO CAO

J
fa, CAO

fdt-a.ir =/
Ofa
U =

Fa
-

ra
=

FAK CA 't
FA
v=
UFA
flea "=uf%÷=÷fo÷
[a
(A
CA CA
=
' n'
÷

③ A → B Iroide

-20dm>
uo
1min
-

-4 )→ 4A = 0.25 min
"

(a) 11=0.6
✗ ✗
✗

/ ¥a= / u¥a ¥3m " -0-61

dm'
¥¥-JY¥
0=1%-0 Fao = c- incr -
✗ 11 → v=
=

O
O
O

ti th = 20 ✗ =? 146.61 = 2-0 C- Inu -

X)
0.25

- 1.83 = In ( 1 -
X)

1.83
e- = 1 -
✗ → 0.16 = l -
X

X=