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1 Given roa chion A ’ B+c (elementary gas phase)

T,So' c= 323 K hy lomin-!
T= |n'c= 390K
Activation energy (Ea) - l03 KJ/moj l03X10's/me
=

Pure A Yan= l (Initial mole faction op A)

lan = l0 atm
Initial Molar Aow rate F= aS mo/min
Conversi on rate = 90-|. XA=0.9

From Arr henius law,

t
n -)
103X10
lo-4 83)4 323 390/

= 6589 2
Io-4

k, = O. 01272 min

Tnitial concen trahon Car= Ao

RT O- 08a1x390

CAn =O-3123 mol,

a5
Volumec fou) rate Vo= o o-3)23
= Ymin
CAp
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Fora frst order veqction in CSTA, KT= XA (1+ 6a XA)

|-XA
’ o 012.)2XV o-9 (1+ o.9)

V= 9x 8x1.9
O.01272
V= 182I. 188L= .88im(cSTR)

For Rrst order *n in PFR, KT= (l+¬n)

h -CnA

V= 401- 61L

V= 0-4076 m3 fora PFR

For a cSTA, SPace time T= V, 23S-1S min

Fora PFR, Space time I= 404:61=S0.95 min

&
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c) for a constant volume bath reacto r, KT= In()

o.01272 X V
An()
V= 253-31A= 0.253 m (batth)

WeKnow t= -J An(i-XA)
K

t= -I An (o-) = 3)623 min

O-01212

t= 31-63 min (batch time)

J) Equilibrium constant Ko=

he Ge ce CAe -’ eqm conc. og
CAe
Now, CAe o Ci-XAe) XAe= euiibium conveYS ion
((+En XAe)

CaoXte Cco = CaoAe 3Ke= 2

|+6nHAe I+EnXAe

’ a=
(1+6nXhe)
Q= CA XAe
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2

6.40u1
|-XAe

Xep= 0.93 (egm converSi on)

For 98|. op XAe XA= 0.98 xo.93

XA= 0.9114

foY a PFR, O-0122 V

V = (1+)n (i1.286 6)- o.914

V= y32-98 L

V= 432-98 L = 0-4 33 m² for PFR

A+B’C
a. Rea ction is given as
T=303K
Bo= 5 mo/L

Data op Ca vs Rate is given. Rate = f (Conc-oç A)

m= order op A only

An(-ha) = Ank+ m n
X-axis= An G
for ate plote An(-SA) Vs An CA Y-axis= AnC-)
Intevcept= Ank
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from grah 1, slope a

Intercept= 5.93
order
m=2 ( Hate op A)
Unk= 5.43 k= 31&.196

Now, if ateis w-rt B = Power I

CBo= S mo/
2
Oueral), -Sa= kCA Ce ’ At start -Sa=KA CBo
4-xio3
1f we use K=
(o-x(s)

we Knouw Ahenius eh K= Ae EayaT

Ank= AnA- Ea (y=mx+c)

Intercept= n A slope-- EalR =K Yeaci onrate
From Graph a, Slope -ta -840S-46
R

Ea = 8-31sx 340S-46

Ea= 2 8313 3mel

Achvaion Energy = 28313 mol

 Chemical Reaction Engineering Graphs

6
Equation y = a + b*x
Plot E
Weight No Weighting
5 Intercept 5.937 ± 0.17635
Slope 2.00887 ± 0.140
Residual Sum of Squ 0.24221
Pearson's r 0.99034
R-Square (COD) 0.98078
4 Adj. R-Square 0.97597
ln (rA)

Linear Fit

1
−2.5 −2.0 −1.5 −1.0 −0.5 0.0
ln(CA)
…….. Question 2

4.2

4.0 Linear Fit

3.8

3.6

3.4
ln(k')

3.2
Equation y = a + b*x
3.0 Plot E
Weight No Weighting
Intercept 14.6401 ± 0.77086
Slope -3405.09798 ± 233.6485
2.8 Residual Sum of Square 0.01204
Pearson's r -0.99532
R-Square (COD) 0.99067
2.6 Adj. R-Square 0.98601

0.0031 0.0032 0.0033 0.0034 0.0035 0.0036

(1/T), Per Kelvin …..Question 2zz
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3. Given L-H Kineic s A’8 (gasphase)
d= loh

VesTA = t00o dm Vege = G00d m P=ISoKPa

o= 4o0 dmmin Yo= 0-s T= 400K

Now, take B= (ooo dm/l

- Sa= RT
I+L000 CA Cto = O-0 22 moldm
WeKnow lo0oCACa >>>|
l00o | :. -9e= lo CA
lo00A

Rate is indep endent op conc-op A.

when B= 0-005 dm /mol
Since CAn <<I
|+000s A
O-005 CA <<I - SA= loA
CArst order xn)

To maximi 3e , we need an arangement.

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Hero VpFR < VcsTR

for such a system, where rate is indepen dent op conc.it

is zer order.

case/) CSTR ’ PFR

For CS TR, V. =

Gasphase
X
T= lO00
400
CAO
KA= Kx a-s 13-636K
o-022

for PFR,

600
Yioo

will take tbo many pemutations, S0 Iwill use 9raphica<

Tt
method.
 csTR

VerR

XA
FoY VesTR > VpEa XA2 is higher for csTR’ PR
olsme in senes
TC we have 2. PFR'S in sernes, N PFRS oP Same v
oe totavolumeV gives same conversion as single PFR oe Ve.
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PFR’ CSTR’ PFR. Each
4 Given non-ideal reactor iS modelled bu
PFA has Same Volume.
Ea=0
Since the roachion is a liguid system, we take constant density
Initial conc-op A=Can= l00mol/L
Rateconstant K= 1s-! (first order reaction)
Feed volumenic tou rate Vo = |00 s
Conversion XA= 0-35

Volume op PER=Vp Volume op cSTR=Ve

Entire volune op system= VptVp +Ve= $0L

2Vp +Vc= SoL
&
Vo=looLS-!

PFR
Cho= (oo mell XA= 0.35
PER

for a first order reaion, t=1

K
|-XA
100
+tAn(i-Xh)
XA,= 1-e

Conversion at end op PFR

 Now for cSTR, V XAz-XA
K(1-XA2)
Ve
|-XA
Ve(l-XA2) XA, -+ e -(Velhoo)
Xa=
XA -loo (e loo)+Ve
|4Ve
1
For a thivd PFR, Ve dXA KA= 0-3S
Vo K(I-XA)

-In (o-6s) + An -1oo (e fliao

|+Ve

We know aVp tV=SoL

Vp= 50-Vc

Substtute ) in 0 to get Ve

50-Ve O.430+83 +AnMooe - )+Ve

Solving this numenically, Ve= 30. ||GL

Vp= 9.942.L
Volume oç cSTR= 30. ||6 L