Complete Question Bank English Medium

Prepared By Naseem Ahmad (Islamia Junior College )
Mob : 8208242592
1. SOLID STATE (3/5)
(1) Distinguish between crystalline solid and amorphous solid. (March 2013, 2017) (2)
(2) Gold occurs as face centred cube and has a density of 19.30 kg dm-3. C alculate atomic radius
of gold. (Molar mass of Au = 197) (March 2013) (2)
(3) Calculate the number of atoms present in 2 gram of crystal which has face-centred cubic (FCC)
crystal lattice having edge length of 100 pm and density 10 gcm-3. (Oct. 2013) (3)
d
(4) What are Schottky defect and Frenkel defect ? (Oct. 2013) (2)
(5) Face centred cubic crystal lattice of copper has density of 8.966 g. cm-3. Calculate the volume
of the unit cell. (March 2014) (3)
-1 23
( Given molar mass of copper is 63.5 g. mol and Avogadro number NA is 6.022 x 10
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(6) Distinguish between :Crystalline solid and amorphous solid .(March 2014) (2)
(7) Describe triclinic crystal lattice with the help of a diagram. (Oct. 2014) (2)
(8) A unit cell of iron crystal has edge length 288 pm and density 7.86 g.cm-3. Find the number of
atoms per unit cell and type of the crystal lattice. Given : Molar mass of iron = 56 g.mol-1,
Avogadro’s Number, NA = 6.022 x 1023. (Oct. 2014) (3)
(9) Explain impurity defect in stainless steel with diagram. (March 2015) (3)
-3
(10) Niobium crystallises as body centred cube (BCC) and has density of 8.55 kg/dm . Calculate
the atomic radius of niobium. (Given : Atomic mass of niobium = 93). (March 2015) (3)
(11)
(12)
(13)
(14)
(15)
Ah
What is the hybridization of carbon atom in diamond and graphite ?(Oct.2015)
What is ferromagnetism ? Iron (Z=26) is strongly ferromagnetic. Explain. (March 2016)
-3
Silver crystallizes in FCC structure. If density of silver is 10.51 g.cm , calculate the volume of
Unit cell. (Atomic mass of silver (Ag) = 108 g. mol-1) (March 2016)
A face centred cub (FCC) consists of how many atoms ? Explain (July 2016)
Determine the density of Cesium chloride which crystallizes in BCC type structure with the edg
length 412.1 pm. The atomic masses of Cs and C1 are 133 and 35.5 respectively. Predict the
(1)
(2)
(2)
(2)
coordination No. of Cs+ ion if rcs + = 1.69 A0. (July 2016) (3)
(16) H2O is liquid while H2S is gas at room temperature. Explain. (July 2016) (2)
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(17) Calculate the percentage efficiency of packing in case of simple cubic cell. (March 2017) (2)
(18) An ionic crystal lattice has r + / r - radius ratio of 0.320, its co-ordination number is ___
(a) 3 (b) 4 (c) 6 (d) 8 (March 2018) (1)
(19) Ionic solids are hard and brittle. Explain.(March 2018) (2)
(20) The density of iron crystal is 8.54 gram cm-3. If the edge length of unit cell is 2.8Ao and atomic
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mass is 56 gram mol-1, find the number of atoms in the unit cell.(M.2018) (3)
(Given : Avogadro’s number = 6.022 x 1023, 1Ao = 1 x 10-8 cm)
(21) Classify the following molecular solids into different types . (July 2018) (2)
(a)HCl (b) CO2 (c) Solid ice (d) SO2
(22) The density of silver having atomic mass 107.8 gram mol-1 is 10.8 gram cm-3. If the edge length
of cubic unit cell is 4.05 x 10-8 cm, find the number of silver atoms in the unit cell.
(NA = 6.022 x 1023 , 1Ao = 10-8 cm) (July 2018) (2)
(23) Number of types of orthorhombic unit cell is ________. (july 2018) (1)
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(a) 7 (b) 3 (c) 4 (d) 2

(24) What is the ratio of octahedral holes to the number of anions in hexagonal closed packed structure ?
(March 2019) (1)
(25) Define Anisotropy. Distinguish between crystalline solids and amorphous solids.(M.19) (3)
(26) Give the relation between radius of atom and edge length in body centered cubic .
(July. 2019) (1)
(27) Classify the following solids.(July.2019) (3)
(i)Daimond (ii)NaCl (iii)P4 molecule (iv)Brass
What is Schottky defect ?
(28) The number of atom per unit cell of body centered cube is …(March 2020) (1)
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(a) 1 (b) 2 (c) 4 (d) 6
(29) Classify the following solid into different types . (March.2020) (2)
(A) Silver (B) P4 (C) Diamond (D) NaCl
(30) Unit cell of metal has edge length of 288 pm and density of 7.86 gcm-3 .Determine the type of
Crystal lattice.[Atomic mass of metal = 56 gmol-1] (March.2020) (3)
(31) Define : (July .2020) (2)
(a) Unit Cell (b)Diamagnetic substance
(32) Unit cell of crystalline sodium hydrogen diacetate (molecular mass 142 )has density of 1.4 gmL-1.
d
Its unit cell contains 24 molecules .Calculate the edge length of the unit cell .(July .2020) (3)
(33) What is the coordination number of atoms in simple cubic crystal lattice?(July.2021) (1)
(34) A compound forms hexagonal close packed (hcp) structure. What is the number of
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(i) octahedral voids (i.) tetrahedral voids
(iii) total voids formed in 0.4 mol of it? (July.2021) (3)
(35) Define isomorphism ? (July.2021) (1)
(36) The co-ordination number of atoms in body centred cubic structure (bcc) is __(March.2022) (1)
(a) 4 (b) 6 (c) 8 (d) 12
(37) Write the consequences of Schottky defect with reasons. (March.2022) (2)
-8
(38) Gold crystallises into face-centred cubic cells. The edge length of unit cell is 4.08 x 10 cm.
Calculate the density of gold.[ molar mass of gold = 197 gmol-1] (March.2022) (2)
(39)
(40)
(41)
(42)
(a) 2a = r (b) √3𝑎𝑎 = 4r (c) a = 2r
Ah
The correct relation between edge length and radius of and atom in simple cubic lattice is _
(d) √2𝑎𝑎 = 4r
Distinguish between Schottky and Frenkel defect . (July.2022)
(July.2022)
Calculate the number of atoms and unit cell present in 0.5 g of Niobium if it forms body centred
cubic structure. The density of Niobium is 8.55 g cm-3 and edge length of unit cell is 330.6 pm.
(July.2022)
The relation between radius of sphere and edge length in body centered cubic lattice is given by
(1)
(2)
(2)
formula: (March.2023) (1)

3 3 2
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(a) 3r =4a (b) r = x4 (c) r = a (d) r = xa
a 4 4
(43) Explain the following terms: (March.2023) (2)
i. Substitutional impurity defect. ii. Interstitial impurity defect
(44) Silver crystallizes in fcc structure. If edge length of unit cell is 400 pm, calculate density of
silver(Atomic mass of Ag = 108). (March.2023) (2)
see
(45) Write the number of particles present in FCC per unit cell.(July.2023) (1)
(46) An element with molar mass 27 g/mol forms cubic unit cell with edge length of 405 p.m. If density of
the element is 2.7 g/cm3. what is the nature of cubic unit cell? (July.2023) (3)
(47) Define isomorphism. (July.2023) (1)
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2. SOLUTIONS (4/6)
(1) Define ‘Colligative properties’ (Oct. 2008) (1)
(2) Define ‘Isotonic solution’. (March 2009) (1)
(3) Define : “Ebullioscopic constant’ (Oct. 2009) (1)
(4) Define ‘Solution’. (Oct. 2009, March 2011) (1)
(5) Define osmotic pressure. Derive an equation for determination of molecular weight from osmotic
d
pressure. (Oct. 2010) (2)
(6) Define a solution. Explain the terms solute and solvent. (March 2011) (2)
(7) Derive the relationship between relative lowering of vapour pressure and molar mass of
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non-volatile solute. (March 2013, 2017) (2)
(8) Define osmosis. (March 2013) (1)
(9) State Henry’s law. How does solubility of a gas in water varies with the temperature ?
(Oct. 2013) (2)
(10) Define isotonic solutions. (Oct. 2013) (1)
(11) What is boiling point ? (March 2013) (1)
(12) Calculate the amount of CaCI2 (van’t Hoff factor, i = 2.47) dissolved in 2.5 L solution so that its
osmotic pressure at 300K is 0.75 atmosphere.
(13)
(14)
Ah
(Given : Molar mass of CaCI2 is 111 g. mol-1. R = 0.082 L, atm K-1 mol-1. (March 2014)
Explain, why do aquatic animals prefer to stay at lower level of water during summer ?
(March 2014)
-1
A solution containing 0.73 g of camphor (molar mass 152 g. mol ) in 36.8 g of acetone (boiling point
56.3 oC) boils at 56.55 oC. A solution of 0.564 g of unknown compound in the same weight of acetone
boils at 56.46 oC. Calculate the molar mass of the unknown compound. (Oct. 2014)
(3)
(2)
(3)
(15) Define van’t Hoff factor. How is it related to the degree of dissociation ? (Oct.2014) (2)
(16) Define : Cryoscopic constant. (Oct. 2014) (2)
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(17) -3
1.0 x 10 kg of urea when dissolved in 0.0985 Kg of a solvent, decreases freezing point of the
solvent by 0.211 K. 1.6 x 10-3 kg of another non-electrolyte solute when dissolved in 0.086 of
the same solvent depresses the freezing point by 0.34 K. Calculate the molar mass of the another
solute. (Given Molar mass of urea = 60) (March 2015) (3)
(18) Define ebulliosopic constant. Write its unit. (Oct. 2015) (2)
see
(19) What is the effect of temperature on solubility of gas in a liquid ? (Oct. 2015) (3)
(20) Define boiling point. Write the formula to determine molar mass of a solute using freezing point
depression method. (March 2016) (2)
(21) The vapour pressure of pure benzene is 640 mm of Hg. 2.175x10-3 kg of non-volatile solute is
added to 39 gram of benezene, the vapour pressure of solution is 600 mm of Hg. Calculate molar
mass of solute. (C = 12, H = 1). (March 2016) (3)
(22) Define (a) Osmosis (b) Freezing point. (July 2016) (2)
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(23) 3.795 g of sulphur is dissolved in 100 g of CS2. This solution boils at 319.81 K. What is the
molecular formula of sulphur in solution ? The boiling point of CS2 is 319.45 K.
(Given that K for CS2 = 2.42 K kg mol-1 and atomic mass of S=32)(July 2016) (3)
(24) State Henry’s law. (July 2016) (1)
(25) A solution of a substance having mass 1.8 x 10-3 kg has the osmotic pressure of 0.52 atm at 280K.
Calculate the molar mass of the substance used. (Volume = 1 dm3, R = 8.314 JK-1 mol-1)
(March 2017) (2)
(26) The boiling point of benzene is 353.23 K. When 1.80 gram of non-volatile solute was dissolved
in 90 gram of benzene. The boiling point is raised to 354.11 K. Calculate the molar mass of solute.
(Kb for benzene = 2.53 K mol-1) (March 2017) (2)
(27) Which of the following 0.1 M aqueous solutions will exert highest osmotic pressure ?(M.18) (1)
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(a) Al2 (SO4)3 (b) Na2SO4 (c) MgCl2 (d) KCl
(28) Derive the relation between elevation of boiling point and molar mass of solute.(March 2018) (2)
(29) Define : (a) Semipermeable membrane (March 2018) (1)
(30) State Henry’s law. (March 2018) (1)
(31) 22.22 gram of urea was dissolved in 300 grams of water. Calculate the number of moles of urea
and molality of the urea solution. (Given : Molar mass of urea = 60 gram mol-1) (M.2018) (2)
(32) What is freezing point of a liquid ? The freezing point of pure benzene is 278.4 K. Calculate the
freezing point of the solution when 2.0 gram of a solute having molecular weight 100 gram is
d
added to 100 gram of benzene.(Kf for benzene = 5.12 kg mol-1) (July 2018) (3)
(33) Define the following terms : (March 2019) (3)
(i) isotonic solution (ii) hypertonic solution (iii) hypotonic solution
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(34) Define osmotic pressure . (July .2019) (3)
Write mathematical expression between cryoscopic constant and molar mass of solute .
(35) 0.020 mol of glucose is dissolved in 200 ml of water at 300K.calculate the osmotic pressure of the
Solution .(R = 0.0821 Latm mol-1K-1 ) (July 2020) (1)
(36) Define : (a) Isotonic Solution (July .2020) (1)
(37) Define: (a) Osmosis
Derive the mathematical expression between relative lowering of vapour pressure and molar mass
of Solute. (July.2020) (2)
(38)
(39)
(40)
(41)
Ah
What is the molar mass of a solute if a solution prepared by dissolving 0.822 g of it in 0.3 dm3 of
water has an osmotic pressure of 0.196 atm. at 298 K?
Define Cryoscopic constant.
(July.2021)
Derive the relation between elevation of boiling point and molar mass of solute.(July.2021)
In calculating osmotic pressure, the concentration of solute is expressed in __(March.2022)
(a) molarity (b) molality ( c) mole fraction ( d) percentage mass
Henery’s law constant for CH3Br(g) is 0.159 moldm-3bar-1at 25°C. What is solubility of CH3Br(g)
(2)
(3)
(1)
in water at same temperature and partial pressure of 0.164 bar? (March.2022) (1)
(42) Derive an expression to calculate molar mass of non volatile solute by osmotic pressure
m
Measurement. (March.2022) (2)
(43) Define the following term. (March.2022) (2)
(i) Isotonic solution (ii) Osmosis
(44) Define : (July.2022) (2)
(i) Osmotic pressure (ii) Ebullioscopic constant
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(45) 5% aqueous solution of cane sugar bas freezing point of 27l K. Calculate freezing point of 5%
glucose solution. [Molar mass of cane sugar = 342gmol-1] (July.2022) (2)
(46) The normal boiling point of ethyl acetate is 77.06oC. A solution of 50 g of non volatile solute
in 150g of ethyl acetate boils at 84.27oC.Evaluate the molar mass of solute if Kb for ethyl acetate
is 2.77 Kkgmol-1. (July.2022) (2)
(47) Write the SI unit of cryoscopic constant. (March.2023) (1)
(48) Calculate the mole fraction of solute, if the vapour pressure of pure benezene at certain temperature
is 640 mmHg and vapour pressure of solution of a solute in benzene is 600 mmHg. (March.2023) (2)
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(49) Define Osmosis. How will you determine molar mass of non volatile solute by elevation of boiling
point? (March.2023) (3)
(50) Which solution shows positive deviation from Raoult's law? (July.2023) (1)
(a) Phenol and Aniline (b) Chloroform.and Acetone
(c) Ethanol and Acetone (d) Chloroform and Ethanol
(51) The normal boiling point of ethyl acetate is 77.06 °C. A solution of 50 g of a non-volatile solute
in 150 g of ethyl acetate boils at 84.27 °C. Evaluate the molar mass of solute if Kb for ethyl acetate
is 2.77 °C kg mol-1. (July.2023) (2)
(52) Define: Ebullioscopic constant.
Derive the relation between freezing point depression and molar mass of solute . (July.2023) (3)
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Ionic Equilibria (4/6)
(1) Derive the relationship between pH and pOH. (July.2021) (2)
(2) Define solubility product.
Derive the relationship between solubility and solubility product for PbI2. (July.2021) (3)
+ -1 -5
(3) The value of [H3O ] in mollit of 0.001 M acetic acid solution (Ka = 1.8 x 10 ) is (March.2022)(1)
(a) 1.34 x 10 -1 (a) 1.34 x 10 -2 (a) 1.34 x 10 -3 (a) 1.34 x 10 -4
d
(4) Calculate the pH of buffer solution composed of 0.01 M weak base BOH and 0.02 M of its salt
BA. [ Kb = 1.8 x 10-5 for weak base] (March.2022) (3)
(5) Derive the relationship between pH and pOH . (March.2022) (2)
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(6) The pH of solution is 3.12. Calculate the concentration of H3O+ ion. (July.2022) (2)
(7) Derive an expression of Ostwald’s dilution law for weak acid . (July.2022) (2)
(8) Why does aq. CuSO4 solution turn blue litmus red ? (July.2022) (2)
–
(9) The pH of weak monoacidic base is 11.2, its OH ion concentration is: (March.2023) (1)
(A) 1.585 × 10–3 mol dm–3 (B) 3.010 × 10–11 mol dm–3
(C) 3.010 × 10–3 mol dm–3 (D) 1.585 × 10–11 mol dm–3
(10) Calculate molar conductivity for 0.5 M BaCl2 if its conductivity at 298K is 0.01 Ω–1 cm–1.(M.23)(2)
(11) A weak monobasic acid is 10% dissociated in 0.05 M solution.What is percent dissociation in 0.15 M
(12)
(13)
(14)
solution?
solution is_____.
(a) 0.04242
(March.2023)
(July.2023)
(b) 0.4242 Ah
The dissociation constant of NH4OH is 1.8 x 10-5. The degree of dissociation in its 0.0 l M
(c) 0.004242
Derive Ostwald's dilution law equation for weak acid.
Define: Buffer solution. (July.2023)
Write any four applications of buffer solution.
(d) 4.242
(July.2023)
(3)
(1)
(2)
(3)
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4. CHEMICAL THERMODYNAMICS (6/8)
(1) Give one statement of first law of thermodynamics and give its corollary. (March 2008) (2)
(2) State and explain Hess’s law of constant heat summation and give its four applications.
(March 2008 , Oct. 2008) (4)
(3) Derive the relationship between the heat of reaction at constant pressure and at constant volume.
d
(Oct. 2008) (2)
(4) Prove that, ∆ H = ∆E + ∆nRT. (March 2009) (4)
(5) Write any two statements of first law of thermodynamics. Explain, “Internal energy is a satate
function”. (March 2009) (4)
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(6) Write the applications of Hess’s law. (Oct. 2009) (2)
(7) Derive the expression for the work done by an ideal gas in an isothermal and irreversible process.
Under what conditions work done by a gas is ‘zero ? (Oct. 2009) (4)
(8) Distinguish between isothermal and adiabatic process. (March 2010) (2)
(9) Derive an expression for maximum work done during the expansion of an ideal gas in isothermal
and reversible process. (March 2011) (3)
(10) Derive an expression for the effect of temperature on the heat of reaction at constant pressure.
(Oct. 2010) (2)
(11)
(12)
(13)
(14)
Ah
Define (i) Enthalpy . Show that ∆H = ∆ E + P ∆V, at constant pressure. (Oct. 2010)
Explain the concept of maximum work. Derive an expression for maximum work done in
isothermal reversible expansion of one mole of an ideal gas. (March 2011)
Prove that ∆H = ∆U +∆nRT. What is the condition under which ∆U=∆H?(March 2013)
300 mol of perfect gas occupies 13L and 320 K. Calculate the work done in joules when the gas
expands. (March 2013)
(a) Isothermally against a constant external pressure of 0.20 atm.
(3)
(4)
(2)
(2)
(b) Isothermal and reversible process.

(c) Into vaccum until the volume of gas is increased by 3L. (R = 8.314 J mol-1 K-1)
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(15) Explain with reason sign conventions of ∆S in the following reactions :
(i) N2(g) + 3H2(g) 2NH3(g)
(ii) CO2(g) CO2(s) (March 2013) (2)
(16) Calculate ∆Ho for the following reactions-
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2H3BO3( aq ) B
→ 2O3( s ) + 3H 2O( l )
Given that -
o
( a ) H3BO3( aq ) HBO
→ 2( aq ) + H 2O ( l ) , ∆H =
1 − 0.02KJ
o
( b ) H 2 B4O7( s ) 2B
 → 2O3( s ) + H 2O( l ) , ∆H 2 = 17.3 kJ (Oct.2013) (3)
o
( c ) H 2B4O7( s ) + H 2O( l ) 4HBO
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→ 2( aq ) , ∆H 3= −11.58 kJ

(17) What are the conditions for spontaneous and nonspontaneous reactions in terms of free energy
change ? Define entropy. (Oct. 2013) (2)
(18) Derive the relation ∆ H - ∆ U = ∆ nRT (Oct. 2013) (2)
(19) Derive a relation between ∆ H are ∆U for a chemical reaction. (March 2014) (2)
(20) One mole of a gas expands by 3L against a constant pressure of 3 atmosphere. Calculate the
work done in -
(a) L. atmosphere (b) Joules (c) Calories (March 2014) (3)
o
(21) Derive the relation between ∆G and equilibrium constant (K) for the reaction-
(March 2014) (2)
aA + bB cC + dD
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(22) What is the value of ∆Ssurr for the following reaction at 298K ?
6CO2(g) + 6H2O(l) C6H12O6(s) + 6O2(g)
Given that, ∆Go = 2879 kJ mol-1 ∆ S = -210 JK-1 mol-1 (Oct. 2014) (3)
(23) State and explain Hess’s law of constant heat cummation. (Oct. 2014) (2)
(24) Derive the equation : W = -Pext ∆ V. (March 2015) (2)
(25) Define the following terms :
(a) Enthalpy of fusion (b) Enthalpy of atomization (March 2015) (2)
d
(26) Determine whether the reactions with the following ∆H and ∆S values are spontaneous or non-
spontaneous. State whether the reactions are exothermic or endothermic. (March 2015) (2)
-1 -1
(a) ∆H = -110 kJ , ∆S = +40 JK at 400 K (b) ∆H = +40 kJ , ∆S = -120 JK at 250 K
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(27) Write one statement of first law of thermodynamics and its mathematical expression.
(March 2015) (2)
(28) State : (a) Second law of thermodynamics in terms of entropy. (Oct. 2015) (1)
(29) Derive an expression for maximum work in isothermal reversible expansion of two moles of
an ideal gas. (Oct. 2015) (2)
(30) Write mathematical equations of first law of thermodynamics for the following processes:
(a) Adiabatic process (b) Isochoric process (March 2016) (2)
(31) Define Enthalpy of sublimation. How is it related to enthalpy of fusion and enthalpy of
(32)
(33)
(34)
vaporization? (March 2016)
CH3Cl(g) + Cl 2(g)
constant. (July 2016)

Ah
Calculate C – Cl bond enthalpy from following reaction : (March . 2016)
0
CH2 Cl 2(g) + HCl(g) ; ∆ H = - 104 kJ
if C – H, Cl – Cl and H – Cl bond enthalpies are 414, 243 and 431 KJmol-1 respectively
Explain the relationship between Gibb’s standard energy change of the reaction and equilibrium
Calculate the standard enthalpy of the reaction.

(2)
(2)
(2)
→ C2 H 6(g ) , ∆H 0 =
2C(graphite) + 3H 2(g)  ? from the following ∆H0 values
m
( a ) C2H6(g) 7
+ / 2 O 2(g) 2CO

→ + 3H 2O ( l )
2(g) ; ∆H 0= −1560 kJ
→ 2O(l) ; ∆H o= −285.8 kJ

( b ) H 2(g) +1 / 2 O2(g) H
 (July 2016) (3)
0
( c ) C(graphite) + O 2(g) 
→ CO 2(g) ; ∆H= − 393.5 kJ
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(35) Write applications of standard molar entropy. (July 2016) (2)

(36) Define the term ‘enthalpy’.
What will happen to the internal energy if work is done by the system ? (March 2017) (2)
0
(37) Calculate ∆H for the reaction between ethane and water to form ethyl alcohol from the
following data : ∆ cHo C2H5OH(l) = - 1368 kJ ; ∆cHoC2H 4(g) = - 1410 kJ
Does the calculated ∆ H represent the enthalpy of formation of liquid ethanol? (March 2017) (3)
(38) The process in which the value of ∆U = 0 is -------- (March 2018) (1)
(a) Adiabatic (b) Isothermal (c) Isobaric (d) Isochoric
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(39) Calculate the internal energy at 298K for the formation of one mole of ammonia, if the enthalpy
change at constant pressure is -42.0 kJ mol-1. (Given : R = 8.314 JK-1 mol-1) (M.2018) (3)
(40) Define : (a) Enthalpy of atomization (b) Enthalpy of vaporization (M.18) (2)
(41) State and explain Hess’s law of constant heat summation. (July 2018) (2)
(42) 5 moles of helium expand isothermally and reversibly from a pressure 40x10-5 Nm-2 at 300 K.
Calculate the work done, change in internal energy and heat absorbed during the expansion.
(R = 8.314 Jk-1 mol-1) (July 2018) (3)
(43) Write features of reversible process. (July 2018) (2)
(44) A substance which shown highest entropy is ……….. (July 2018) (1)
(a) SrCO3(s) (b) Cu(s) (c) NaCl(aq) (d) Cl2(g)
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(45) A system absorbs 6 kJ of heat and does 1.5 kJ of work on its surrounding. The change in internal
energy……...(March 2019) (1)
(a) - 7.5 kJ (b) - 4.5 kJ (c) + 4.5 kJ (d) + 7.5 kJ
(46) Write the conditions for maximum work done by the system.(March 2019) (2)
(47) Calculate the work done in the following reaction at 50oC. State whether work is done on the
system or by the system. (March 2019) (3)
SO2(g) + 1/2 O2(g) SO3(g)
(48) The standard enthalpy of combustion of formaldehyde ∆cHo = -571kJ. How much heat will
d
be enolved in the formation of 22 g of CO2 ? (March 2019) (3)
(49) Define the term enthalpy.
Classify the following properties into intensive and extensive properties:
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(i) Pressure (ii) Density (iii) Work (iv) Heat (July.2019) (3)
(50) Calculate work done by the following chemical reaction:
373K
2NH 4 NO3(s) 2N
→ 2O(g) + 4H 2O(g)
State whether work is done on the system or by the system . (July.2019) (2)
(51) Determine whether the following reaction is exothermic or endothermic and spontaneous
Or non spontaneous for the given data:
∆H = -110kJ and ∆S = +40JK-1 at 400 K (July.2019) (2)
(52)
(53)
CH4(g) + 2O2 (g) CO2 (g) + 2H2O(g)
Ah
Calculate the work done during the reaction represented by the following thermochemical
equation at 300 K : (R =8.314 JK-1mol-1)
(a) +4.988 kJ (b) -4.988 kJ (c) -49.88 kJ (d) +49.88 kJ

For the reaction :
N2O4 (g) 2NO2(g) (∆Ho = +57.24kJ , ∆So = 175.8 Jk-1)
at what temperature the reaction will be spontaneous ?
(March.2020)
(March.2020)
(1)
(1)
(54) State and explain Hess’s law of constant heat summation. (March.2020) (2)
(55) Define: (March.2020) (4)
m
(a) Reversible process
(b) Standard enthalpy of combustion
Calculate the enthalpy change for the reaction :
N2(g) + 3H2(g) 2NH3(g)
The bond enthalpies are :
see
Bond N≡N H–H N-H

o
∆H kJmol -1 946 435 389
(56) Calculate the work done during the reaction represented by the following thermochemical
equation at 300K : (July.2020) (1)
C2H5OH(l) + 3O2 (g) 2CO2(g) + 3H2O(l) (R = 8.314 JK-1mol-1)
(a) -2.494 kJ (b) +2.494 kJ (c) -24.94 kJ (d) +24.94 kJ
(57) Data : (July.2020) (1)
(a) C2H5OH (l) + 3O2(g) 2CO2(g) + 3H2O(l) ∆H = -1368 kJ
Na
(b) C2H4(g) + 3O2(g) 2CO2(g) + 2H2O(l) ∆H = -1410 kJ

Calculate ∆H for the following reaction:
C2H4(g) + H2O(l) C2H5OH(l)
(58) Write the mathematical equation of the first law of thermodynamics for :
(a) Adiabatic process (b) Isobaric process (July.2020) (2)
(59) 2.8 x 10-2 kg of nitrogen is expanded isothermally and reversibly at 300K from 15.15 x 105 Nm-2
when the work done is found to be -17.33 kJ.Find the final pressure.
[N = 14 , R = 8.314 JK-1mol-1] (July.2020) (4)
(60) In a particular reaction, 2kJ of heat is released by the system and 6 kJ of work is done on the
system. Calculate ∆U. (July.2021) (1)
(61) Calculate the standard enthalpy of (July.2021) (3)
Mob : 8208242592
N2H4(g) + H2(g) 2NH3(g)
If ∆H (N-H) = 389 kJmol-1
o
∆Ho(H-H) = 435 kJmol-1

∆Ho(N-N) = 159 kJmol-1
(62) Define:
(i) Intensive property (ii) Enthalpy of sublimation
2 moles of an ideal gas are expanded isothermally and reversibly from 20L to 30L at 300K :
d
Calculate the work done. [ R =8.314 JK-1mol-1] (July.2021) (4)
(63) One mole of an ideal gas is expanded isothermally and reversibly from 10 L to 15 L at 300 K.
Calculate the work done in the process. (March.2022) (2)
(64) Calculate the standard enthalpy of formation of CH3OH(l) from the following data .(March.22) (3)
ma
3
i)CH3OH (l) + O 2(g)  → CO 2(g) +H 2O(l) ∆H o = -726 kJmol-1
2
ii)C(s) + O 2(g) 
→ CO 2(g) ∆ c H o = -393 kJmol-1
1
iii)H 2(g) + O 2(g)  → H 2O(l) ∆ f H o = -286 kJmol-1
2
(65) Write the mathematical equation for the first law of thermodynamics for (March.2022) (2)
(66)
(67)
(i)
(ii)
isothermal process
adiabatic process
(a) vapourisation (b) fusion

Ah
The enthalpy change for the chemical reaction H 2O(s) 
( c) combustion
→ H 2O(l) is called enthalpy of……
( d) sublimation (March.22)
The work done during isothermal irreversible expansion of 2 moles of helium from 2 dm3 to
4 dm3 at 1 bar pressure and at 298K is ______. (July.2022)
(1)
(1)
(a) 2.0 kJ (b) -2.0 kJ (c) 0.2 kJ (d) -0.2 kJ
(68) Derive the relationship between ∆H and ∆U for gas phase reactions. (July.2022) (2)
(69) Calculate the standard enthalpy of formation of CH3-OH , if standard heat of combustion of
m
methyl alcohol are -726 kJmol-1. (July.2022) (3)
Given data
3
i)CH3OH (l) + O 2(g)  → CO 2(g) +H 2O(l) ∆H o = -726 kJmol-1
2
see
ii)C(s) + O 2(g)  → CO 2(g) ∆ c H o = -393 kJmol-1

1
iii)H 2(g) + O 2(g)  → H 2O(l) ∆ f H o = -286 kJmol-1
2
(70) State and explain Hess’s law of constant heat summation . (July.2022) (2)
(71) Write the correct condition for spontaneity in terms of Gibbs energy.(March.2023) (1)
(72) Define Extensive property. Calculate the work done during the expansion of 2 moles of an ideal gas
from 10 dm3 to 20 dm3 at 298 K in vacuum.(March.2023) (2)
Na
(73) 2000 mmol of an ideal gas expanded isothermally and reversibly from 20 L to 30 L at 300 K, calculate
the work done in the process (R = 8.314 JK–1 mol–1).(March.2023) (3)
(74) Derive relationship between ΔH and ΔU for gaseous reaction.(March.2023) (2)
(75) Three moles of an ideal gas are expanded isothermally from 15 dm3 to 20 dm3 at constant external
pressure of 1.2 bar. Estimate the amount of work in Joules. (July.2023) (1)
(76) Calculate the standard enthalpy of the reaction: (July.2023) (3)
SiO 2(s) + 3C(graphite) → SiC(s) + 2CO(g)
From the following reaction.
Mob : 8208242592
(i) → SiO 2(s) , ∆ r H o = -911kJ
Si (s) + O 2(g) 
(ii) → 2CO(g) , ∆ r H o = -221 kJ
2C(graphite) + O 2(g) 
→ SiC , ∆ r H o= −65.3kJ
(iii) Si (s) + C(graphite) 
(77) Write any two statements of first law of thermodynamics.
For a certain reaction ∆H° is -224 KJ and ∆S° is -153 JK-1. At what temperature the change over from
spontaneous to nonspontaneous will occur ? (July.2023) (4)
d
ma
*****
Ah
m
see
Na
Mob : 8208242592
5. ELECTROCHEMISTRY(5/7)
(1) Describe the construction and working of standard hydrogen electrode.
Give its two disadvantages. (March 2008, Oct. 2008) (4)
(2) Explain the measurement of e.m.f. of a cell using a potentiometer. (March 2009) (3)
(3) Describe the construction and working of H2-O2 fuel cell. Write its advantages.(March 2009) (4)
(4) Write Nernst equation for single electrode potential and give the meaning of the terms involved
d
in it. (March 2010) (3)
(5) What is electrochemical series ? Explain its applications in the determination of relative
strength of oxidizing and reducing agents. (March 2010, Oct. 2010) (2)
ma
(6) Explain the construction and working of lead accumulator. (March 2011) (4)
(7) State Kahlrausch Law and write mathematical expression of molar conductivity of the given
solution at infinite dilution. (March 2013) (2)
(8) Write the cell reactions in lead storage batterly during discharge. (March 2013) (2)
(9) In electrolysis of AgNO3 solution 0.7 g of Ag is deposited after a certain period of time.
Calculate the quantity of electricity required in coloumb.
(Molar mass of Ag is 107.9 g mol-1) (March 2013) (2)
(10) Write electrode reaction and net cell reaction for fuel cell.
(11)
Zn(s) Zn++ (aq) Cu++ (aq)
Ah
Calculate e.m.f. of the following cell at 25oC-
Cu(s)
Standard reduction potential (SRP) of Zn and Cu are -0.76 V and 0.334 V respectively.
(Oct. 2013)
Resistance and conductivity of a cell containing 0.001 M KCl solution at 298K are 1500 Ω
(2)
and 1.46 x 10-4 S.cm-1 respectively. What is the cell constant ? (March 2014) (2)
(12) Write any ‘four’ applications of electrochemical series. (Oct. 2014) (2)
(13) With the help of the equation.
m
∆Go = nFEocell explain that cell potential is an intensive property. (Oct. 2014) (2)
(14) How much electricity in terms of Faraday is required to produce : (Oct. 2014) (2)
(a) 20 g of Ca from molten CaCl2 (b) 40 g of Al from molten Al2 O3
(Given : Molar mass of Calcium and Aluminium are 40gmol-1 and 27g mol-1 respectively.)
see
(15) Draw neat and labelled diagram of dry cell. (March 2015) (2)
(16) Arrange the following reducing agents in the order of increasing strength under standard state
conditions. Justify the answer. (March 2015) (2)
Element Al(s) Cu(s) Cl(aq) Ni(s)
Eo -1.66V 0.34V 1.36V -0.26V
(17) Calculate Ecell and ∆G for the following at 28oC : (March 2015) (3)
Na
o
Mg(s)+ Sn2+ (0.04M) Mg2+ (0.06M) + Sn(s) E cell = 2.23V. Is the reaction spontaneous?
(18) Can copper sulphate solution be stored in an iron vessel ? Explain. (Oct. 2015) (2)
(19) Resistance of conductivity cell filled with 0.1 M KCl solution is 100 ohms, calculate the
conductivity and molar conductivity of 0.02 M KCl solution.
(Given : Conductivity of 0.1 MKCl solution is 1.29 S m-1.) (Oct. 2015) (3)
(20) Define cell constant. Draw a neat and well labeled diagram of primary reference electrode.
(March 2016) (3)
(21) Conductivity of a solution is 6.23 x 10-5 Ω -1 cm -1 and its resistance is 13710 Ω . If the electrodes
are 0.7 cm apart, calculate the cross-sectional area of electrode. (March 2016) (3)
Mob : 8208242592
(22) Write the Nernst equation and explain the terms involved. (July 2016) (2)
o -3 -1 -1
(23) The conductivity of 0.02 M AgNO3 at 25 C is 2.428 x 10 Ω cm . What is its molar conductivity?
(July 2016) (2)
(24) What are ‘fuel cells’ ? Write cathode and anode reaction in a fuel cell. (March 2017) (2)
(25) 0.05 M NaOH solution offered a resistance of 31.6 Ω in a conductivity cell at 298 K. If the cell
constant of the cell is 0.367 cm-1. Calculate the molar conductivity of NaOH solution.
(March 2017) (2)
(26) In hydrogen-oxygen fuel cell the carbon rods are immersed in hot aqueous solution of __(M.18) (1)
d
(a) KCl (b) KOH (c) H2SO4 (d) NH4Cl
(27) Draw a neat and labeled diagram of lead storage battery.(March 2018) (2)
(28) Define : (a) Reference electrode (March 2018) (1)
ma
(29) How many faradays of electricity are required to produce 13 gram of aluminium from aluminium
chloride solution ? (Given : Molar mass of A1 = 27.0 gram mol-1) (March 2018) (3)
(30) The S.I. unit of cell constant for conductivity cell is _______. (July 2018) (1)
(a) M-1 (b) S.m-2 (c) cm-2 (d) S.dm2.mol-1
(31) How much quantity of electricity in coulomb is required to deposit 1.346 x 10-3 kg of Ag
in 3.5 minutes from AgNO3 solution ? (July 2018) (3)
-3 -1
(Given : Molar mass of Ag is 108 x 10 kg mol )
(32) Represent a cell consisting of Mg2+ Mg half cell and Ag+ Ag half cell and write the cell
(33)
(34)
(35)
(36)
(37)
reaction.(EoAg = 0.799V , EoMg = - 2.37V)
Define the terms :Resistivity (July 2018)
Ah (July 2018)
Define electrochemical series. Write its applications.(March 2019)

How many faradays of electricity are required to produce 6 g of Mg from MgCl2 ?(M.19)
o -1 2 -1
The molar conductivity of 0.05 M BaCl2 solution at 25 C is 223 Ω cm mol . What is its
conductivity ? (March 2019)
The molar conductivity of 0.02M HCl solution is 407.2 Ω-1cm2 mol-1 at 25oC.Calculate its
(2)
(1)
(3)
(2)
(2)
conductivity. (July.2019) (2)

(38) Draw neat ,labeled diagram of standard hydrogen electrode. (July.2019) (2)
m
(39) Draw neat ,labeled diagram of H2-O2 fuel cell. (July.2019) (2)
(40) The standard e.m.f. of the following cell is 0.463 V . (March.2020) (1)
CuCu++  Ag+ Ag
(s) (1M) (1M) (s)
If the standard potential of Ag electrode is 0.800 V, what is the standard potential of Cu electrode?
see
(41) Write the cell of the following electrochemical Eocell of the following electrochemical cell:
Al  Al3+  Zn2+Zn
(s) (aq.) (aq.) (s)
(1M) (1M)
EoAl = – 1.66 V EoZn = – 0.76 V (March.2020) (2)
(42) Define the terms: (March.2020) (4)
a. Electrochemical series
Write two applications of electrochemical series.
Na
(43) Calculate the quantity of electricity required to deposit 0.2 mol of sodium metal during electrolysis
of fused sodium chloride. (July.2020) (1)
(44) The molar conductivity of 0.02M HCl solution is 407.2 Ω-1cm2 mol-1 at 25oC.Calculate its
conductivity. (July.2020) (2)
(45) Write Nernst equation and explain the term involved in it .Draw a neat and labelled diagram
of standard hydrogen electrode(SHE). (July.2020) (4)
(46) Write the value of 2.303RT/ F in Nernst equation. (July.2021) (1)
(47) The molar conductivity of 0.01 M acetic acid at 25°C is18 Ω-1cm2 mol-1 .Calculate its degree of
dissociation in 0.01M solution and dissociation constant, if molar conductivity of acetic acid at zero
concentration is 400 Ω-1cm2 mol-1. (July.2021) (2)
(48) State Kohlrausch law of independent migration of ions.
Mob : 8208242592
Write and explain two applications of electrochemical series.
Write unit of cell constant. (July.2021) (4)
(49) The standard potential of the cell in the following reaction is ______
Cd (s) + Cu 2+(1M) 
→ Cd 2+(1M) + Cu (s) (March.2022) (1)
(EoCd = -0.403V , EoCu = 0.334V)
(a) -0.737 V (b) 0.737 V (c) -0.069 V (d) 0.069 V
(50) How many moles of electrons are required for reduction of 2 moles of Zn2+ to Zn ? How many
d
Faradays of electricity will be required? (March.2022) (2)
(51) Define reference electrode. Write functions of salt bridge . Draw neat, labelled diagram of
standard hydrogen electrode(SHE). (March.2022) (4)
ma
(52) The standard emf of the following cell at 298K is ______ (July.2022) (1)
Zn2+ Cr3+ Cr
Zn(s) (1M) (0.1M) (s)
EoZn = -0.76V , EoCr = -0.74V
(a) -0.02V (b) +0.02V (c) -0. 2V (d) +0. 2V
(53) Write relation between molar conductivity and conductivity of solution n. (July.2022) (1)
(54) State Kohlrausch law of independent migration of ions . Write one application of Kohlrausch
Law of independent migration of ions. (July.2022) (2)
(55) Write any two application of electrochemical series. (July.2022) (2)
(56)
(57)
(58)
Cd (s) + Sn 2+(aq) 
→ Cd 2+ + Sn (s)
E oCd = -0.403V , E oSn = -0.136V

Ah
Calculate molar conductivity for 0.5 M BaCl2 if its conductivity at 298K is 0.01 Ω–1 cm–1.(M.23) (1)
Calculate standard Gibbs energy change at 25°C for the cell reaction.(March.2023)
Draw labelled diagram of H2 – O2 fuel cell. Write two applications of fuel cell.(March.2023)
(2)
(3)
(59) What is reference electrode? (March.2023) (1)
(60) Write the unit of cell constant. (July.2023) (1)
(61) What is the mass of Cu metal produced at the cathode during the passage of 5 ampere current
m
through CuSO4 solution for 6000 seconds. Molar mass of Cu is 63.5 g mol-1.(July.2023) (2)
(62) Deseribe the construction and working of Standard Hydrogen Electrode.
Write any two difficulties in setting SHE. (July.2023) (4)
*****
see
Na
Mob : 8208242592
6. CHEMICAL KINETICS (4/6)
(1) Distinguish between molecularity and order of the reaction.

(March 2008, 2009, 2011 , Oct. 2008 , 2009 2010) (2)
(2) What is ‘rate law’? Show that half life of first order chemical reaction is independent of
d
initial concentration of the reactant. (March 2008) (3)
(3) Define rate of reaction. Derive integrated rate equation for first order reaction.
ma
(Oct. 2008 , 2010 , March 2010 , 2011) (3)
(4) State rate law. Write ‘one’ example of it. (March 2009) (2)
(5) What is half life period of a reaction ? Show that half-life period does not depend upon the initial
concentration for first order reaction. (Oct. 2009) (3)
(6) Define ‘Rate law’ (March 2010) (1)
(7) What is Pseudo first order reaction ? Explain with suitable example.(March 2009 , 2010) (2)
(8) Define ‘Molecularity’ of chemical reaction. (March 2010) (1)
(9) Consider the reaction-
3I- (aq) + S2O2-8(aq)
Ah
I-3(aq) + 2SO2-4(aq) at particular time t, d [ SO2-4 ] = 2.2 x 10-2 M/s.
What are the values of the following at the same time ?
(a) d(I-) (b) - d [ S2O2-8 ] (c) - d [ I-3 ]

dt
dt dt dt (March 2013) (3)

m
(10) Distinguish between order of molecularity and order of reaction. (Oct.2013) (2)
(11) Define activation energy. Calculate activation energy for a reaction of which rate constant
becomes four times when temperature changes from 30 oC to 50 oC.
(Given R = 8.314 JK-1 mol-1). (Oct. 2013) (3)
see
(12) Write molecularity of the following reaction : (March 2014) (1)

2NO(g) + O2(g) 2NO2(g)
(13) The decomposition of N2O5(g) at 320K according to the following equation follows first order reaction:
N2O5(g) 2NO2(g) + O2(g)
The initial concentration of N2O5(g) is 1.24 x 10-2 mol.L-1 and after 60 minutes, 0.20 x 10-2 mol L-1.
Calculate the rate constant of the reaction at 320K.(March 2014) (3)
Na
(14) Derive the relation between half-life period and rate constant for first order reaction.
(March 2014) (2)
(15) Sucrose decomposes in acid solution to give glucose and fructose according to the first order
rate law. The half life of the reaction is 3 hours. Calculate fraction of sucrose which will remain
after 8 hours. (Oct. 2014, March 2015) (3)
(16) Distinguish between order and molecularity of reaction. (Oct. 2014) (2)
(17) Derive the relation between half life and rate constant for a first order reaction.(March 2015) (2)
(18) Define : (a) Average rate of reaction (b) Instantaneous rate of reaction. (Oct. 2015) (2)
(19) : 8208242592
Mob Ammonia and oxygen react at high temperature as : 4NH3(g) + 502(g) 4NO(g) + 6H2O(g)
-3 -1 -1
In an experiment, rate of formation of NO(g) is 3.6 x 10 mol L . S
Calculate : (a) Rate of disappearance of ammonia. (b) Rate of formation of water. (Oct. 2015) (3)
(20) Explain graphical method to determine activation energy of a reaction. (March 2016) (2)
(21) In a first order reaction x y, 40% of the given sample of compound remains unreacted
in 45 minutes. Calculate rate constant of the reaction. (March 2016) (2)
d
(22) Describe isolation method in determination of rate law and order of reaction. (July 2016) (2)
-1 -1
(23) The rate constant of a first order reaction are 0.58 s at 313 K and 0.045 s at 293 K. What is the
energy of activation for the reaction ? (July 2016) (3)
ma
13 -1
(25) In the Arrhenius equation for a first order reaction, the values of ‘A’ and ‘E’ are 4x10 sec
and 98.6kJ mol-1 respectively. At what temperature will its half life period be 10 minutes ?
(R = 8.314 JK-1 mol-1) (March 2017) (3)
(26) The half-life period of zero order reaction A Product is given by ----(March 2018) (1)
(A)0 (b) 0.693 (c) (A)0 (d) 2(A)0
K K 2K K
(26) A certain reaction occurs in the following steps ---(March 2018) (2)
(27)
(i)
(ii)
(a)
(b)
Cl(g) + O3(g)
ClO(g) + O(g)
Ah
ClO(g) + O2(g)
Cl(g) + O2(g)
What is the molecularity of each of the elementary steps ?
Identify the reaction intermediate and write the chemical equation for overall reaction.
The reaction A+B products is first order in each of the reactants.
How does the rate of reaction change if the concentration of A is increased by factor 3?
What is the change in the rate of reaction if the concentration of A is halved and concentration
of B is doubled ? (March 2018) (2)
(28) Define the order of chemical reaction.and find the overall order of the following reactions:
(a) CHCI3(g) + Cl2(g) CCI 4(g) + HCI (g),
m
Rate = k (CHCI3) (CI2)
(b) 2NO(g) + O2(g) 2NO2 (g),
Rate = k (NO)2 (O2) (July 2018) (2)
(29) In a first order reaction A – product, 80% of the given sample of compound decomposes in
40 min. What is the half life period of the reaction ? (July 2018) (3)
see
(30) The kinetic order for the following reaction is _______. (July 2018) (1)
pt
2N2O(g) 2N2(g) + O2(g)
Zero (b) first (c) second (d) third
(31) Write Arrhenius equation. Derive an expression for temperature variations.(March 2019) (3)
(32) The rate of a first order reaction, A B is 5.4 x 10-6 Ms-1 when (A) is 0.3 M. Calculate the
rate constant of the reaction. (March 2019) (1)
(33) The helf life period of a first order reaction is 6.0 h. Calculate the rate constant.(March 2019) (1)
(34) The Half life of first order reaction is 6.0 hours .How long it will take for the concentration of
Na
reactants to decrease from 0.8M to 0.25M. (July.2019) (3)

(35) For a certain second order reaction energy of activation is 240 KJmol-1.Calculate its rate constant
at 1023K if the rate constant at 923K is 0.0113 M-1S-1.(R= 8.314 JK-1mol-1) (July.2019) (3)
(36) Write the mathematical relation between half life of zero order reaction and its rate constant .
(March.2020) (1)
(37) Distinguish between order and molecularity of reaction .(March .2020) (2)
(38) Define instantaneous rate of reaction .Explain pseudo first order reaction with suitable example .
(March .2020) (3)
(39) Derive an expression for integrated rate law for zero order reaction .(July.2020) (2)
(40) A complex reaction take place in two steps as follows . (July.2020) (3)
(i) NO(g) + O3(g)
Mob : 8208242592 NO3(g) + O(g)
(ii) NO3 (g) + O(g) NO2(g) + O2(g)
(a) Write overall reaction.
(b) Identify the reaction intermediate .
(c) Identify the rate determining step if the predicted rate law is rate = K[NO][O3]
(41) What is pseudo -first order reaction? Explain with suitable example. (July.2021) (2)
(42) Derive integrated rate law expression for first order reaction. (July. 2021) (3)
(43) Identify the molecularity of following elementary reaction: (March.2022) (1)
d
NO(g) + O3(g) 
→ NO3(g) + O(g)
(44) Explain pseudo-first order reaction with suitable example. (March.2022) (2)
(45) Define half life of first order reaction. Obtain the expression for half life and rate constant of the
ma
first order reaction. (March.2022) (3)
(46) Show that time required for 99.9% completion of a first order reaction is three times the time
Required for 90% completion. (July.2022) (2)
(47) A chemical reaction occurs in the following steps : (July.2022) (2)
(i) NO 2(g) + F2(g) 
→ NO 2 F(g) + F(g) (slow)
(ii) F(g) + NO 2(g) 

→ NO 2 F(g) (fast)
(a) Write equation of overall reaction .
(48)
(49)
(b)
(c)
Write down rate law .
Identify the reaction intermediate .
in gas phase: (March.2023)

(a) k =
2.303
x log10 i
p
(b) k =
Ah
Explain pseudo first order reaction with suitable example . (July.2022)
Which of the following correctly represents integrated rate law equation for a first order reaction
2.303
x log10
pi
(2)
(1)
t pi - p t 2pi - p
2.303 2pi 2.303 p -p
(c) k = x log10 (d) k = x log10 i
m
t pi - p t 2pi
(50) What is Pseudo first order reaction? Derive integrated rate law equation for zero order reaction.
(March.2023) (3)
(51) Show that, time required for 99.9% completion of a first order reaction is three times the time
required for 90% completion.(March.2023) (2)
see
(52) Half-life of a first order reaction is 30 minutes at 300 K. The value of its rate constant, K is…
(a) 2.31min-1 (b) 0.0231 min-1
(c) 0.231 min-1 (d) 2.310x10-3 min-1 (July.2023) (1)
(53) Derive integrated rate law for zero order reaction. (July.2023) (2)
(54) Write Arrhenius equation. Derive an expression to determine activation energy for two
different temperatures T1 and T2. (July.2023) (3)
Na
*****
Mob : 8208242592
7. Elements of Groups 16 ,17 & 18 (6/8)
(1) Explain the trends in the following properties with reference to group 16:
(a) Atomic radii and ionic radii (b) Density (c) Ionisation enthalpy
(d) Electronegativity (March 2013) (4)
(2) What is the action of chlorine (CI) on the following : (Oct.2013) (3)
d
(a) Cold and dilute caustic soda. (b) Hot and concentrated caustic soda.
(3) Write electronic configuration and two uses of neon (Z = 10). (Oct.2013) (2)
(4) Write resonating structures of ozone. (March 2014) (1)
ma
(5) Describe anomalous behaviour of fluorine with the other elements of group 17 with reference to :
(a) Hydrogen bonding (b) Oxidation state (c) Polyhalide ions (March 2014) (3)
(6) Describe anomalous behaviour of oxygen as compared with other elements of group 16 with
reference to- (a) Magnetic property (b) Oxidation state (c) Hydrides (Oct. 2014) (3)
(7) Explain the structure of sulphur dioxide. (March 2015) (2)
(8) Write molecular formulae and structures of the following compounds :
(1) Dithionic acid (2) Peroxy monosulphuric acid
(3) Pyrosulphuric acid (4) Dithionous acid (March 2015) (4)
(9)
(10)
(11)
(12)
(13)
Write ‘four’ uses of hydrochloric acid. Ah
Draw structures of (a) Chlorine trifluoride (b) Chlorine pentafluoride
What is the action of dioxygen on : (a) Calcium (b) Iron
(Oct. 2015)
Write chemical formula of the following oxoacids of chlorine:

(c) Carbon disulphide ?
(a) Hypochlorous acid (b) Chlorous acid (c) Chloric acid (d) Perchloric Acid (Oct. 2015) (2)
What are neutral oxides ? Explain the nature of zinc oxide with the help of the reactions.
(2)
(3)
(2)
(March 2016) (2)

(14) What happens when dilute sulphuric acid is treated with (a) Fe (b) CaF2 ? (July 2016) (2)
m
(15) What happens when thin copper leaves are thrown in jar containing chlorine? (July 2016) (2)
(16) Write the electronic configuration of the following elements :
(a) Sulphur (Z = 16) (b) Krypton (Z = 36) (March 2017) (2)
(17) Write any ‘two’ uses of each of the following : (a) H2SO4 (b) Chlorine (March 2017) (2)
(18) What is the action of chlorine on : (a) CS2 (b) Excess NH3 (March 2018) (2)
see
(19) Write balanced chemical equations for the following :( March 2018) (1)
(a) Action of ozone on hydrogen peroxide.
(20) Draw the structure of IF7. Write its geometry and the type of hybridization.(March 2018) (2)
(21) Write the molecular and structural formulae of . (March 2018) (2)
(a) Thiosulphuric acid (b) Dithionous acid
(22) Arrange the following oxyacids of chlorine in decreasing order of their thermal stability. Give
reason. HOCIO , HOCI, HCIO4 , HOCIO2….(July 2018) (2)
(23) Explain the following with the help of balanced chemical equation : (July 2018) (2)
Na
(a) Bleaching action of SO2.

(24) Write structure and molecular formula for the following compounds : (July 2018) (2)
(a) sulphurous acid
(25) Write any ‘four points’ of difference between fluorine and other halogens.(July 2018) (2)
(26) Write chemical reactions for different steps in the manufacture of sulphuric acid by lead chamber
process. (March 2019) (3)
(28) What are oxides ? Write different types of oxides with one example each.(March 2019) (4)
(29) Explain the following properties of group 16 elements : (March 2019) (4)
(i) Electro negativity (ii) Melting and boiling points
(iii) Metallic character (iv) Allotropy
(30) Write the name of an inert gas element used in the treatment of cancer by radiotherapy.(J.2019) (1)
(31) Write two uses of each of the following: (March.2020) (2)
a. Helium
Mob : 8208242592 b. Neon
(32) Draw the structure of sulphurous acid.
(33) Explain interhalogen compounds. How is oxygen prepared from the following compounds?
a. KClO4 b. PbO2 (March.2020) (4)
(34) Explain the structure of sulphur dioxide molecule on the basis of hybridization.(July.2020) (2)
(35) Write the chemical reaction involved in Deacon process for the manufacture of chlorine.
What is action of chlorine on :
(a) Excess of ammonia (b) Copper (July.2020) (3)
(36) Explain anomalous behavior of oxygen with respect to :
d
(a) Magnetic behavior (b) Multiple bonds
(c) Hydrogen bonding
Write the name and molecular formula of basic oxide . (July.2020) (4)
ma
(37) Write the name of interhalogen compound of chlorine which has square pyramidal structure.(J.21)(1)
(38) Draw the structure of sulphurous acid. Write two uses of helium .(July.2021) (2)
(39) Write chemical equations involved during manufacture of sulphuric acid by contact process.
Write two uses of sulphur dioxide.(July .2021) (3)
(40) What is the action of concentrated H2SO4 on, (July .2021) (2)
(i) CaF 2 (ii) Cane sugar
(41) What is the action of selenium on magnesium metal ? (March.2022) (1)
(42) Explain the trends in the following atomic properties of group 16 elements ? (March.2022) (2)
(43)
(44)
(45)
(i) Atomic radii
(iii) Electronegativity
(ii)
(iv)
Ah
Ionisation enthalpy
Electron gain enthalpy
Write the names and electronic configurations of first two elements of group 17.(March.22)
Write chemical equation for preparation of sulphur dioxide from sulphur. Write uses of sulphur.
(March.2022)
In the following oxyacid , chlorine has +7 oxidation state :
(a) HOCl (b) HOCl2 (c) HOCl3 (d) HOCl4
(July.2022)
(2)
(3)
(1)
(46) What is the action of chlorine on the following . (July.2022) (2)

(i) NH3 (excess) (b) Phosphorous
m
(47) What happens when : (July.2022) (3)
(i) Ethene reacts with iodine monochloride. (ii) Sulphur dioxide is oxidised in presence of V2O5
(iii) Cu heated with concentrated H2SO4
(48) What are interhalogen compounds ? Write two uses of neon . (July.2022) (2)
(49) Draw structures of the following compounds: (March.23) (2)
see
i. chloric acid ii. peroxy disulphuric acid

(50) Explain anomalous behaviour of oxygen in group 16 with respect to: (March.23) (3)
i. Atomicity ii. Magnetic propert iii. Oxidation state
(51) Give reason: Bleaching action of ozone is also called dry bleach. (March.23) (1)
(52) Give reason: Group 16th elements have lower ionisation enthalpy compared to group 15th elements.
Write two uses of dioxygen. (March.23) (2)
(53) Write the name of radioactive element in group 16. (July.2023) (1)
(54) Why fluorine shows anomalous behavior ? (July.2023) (2)
Na
(55) Write molecular formula and structure of: (July.2023) (3)

(a) Sulphuric acid (b) Peroxy monosulphuric acid (c) Thiosulphuric acid
(56) What are interhalogen compounds? (July.2023) (2)
Write any two general characteristics of interhalogen compounds.
******
8. Transition and inner transition elements (6/8)

Mob : 8208242592
(1) Give names and formulae of any two ores of zinc. (March 2008 , 2010) (6)
(2) Give the observed outer electronic configuration of copper (Z = 29).
Why are compounds of copper ‘coloured while those of zinc colouless ? (March 2008) (3)
(3) Explain the position of d-Block elements in the periodic table. (Oct. 2008) (2)
(4) Why do the d-block elements form the coloured compound ? (March 2009) (2)
(5) Give reasons :
d
(a) Zinc salts are white (b) Transition metal shows catalytic properties.
(c) Manganese shows variable oxidation states (Mn, Z = 25) (Oct. 2009) (3)
(6) Write the position of zinc (Z = 30) in the periodic table and write its electronic configuration.
ma
(Oct. 2009) (2)
(7) What is the general outer electronic configuration of transition series elements ?(March 2010) (1)
(8) Explain the following characteristics of transition elements :
(a) Tendency to form complexes (b) Catalytic property. (Oct. 2010) (2)
(9) Transition elements show variable oxidation states. Explain. (March 2011) (2)
(10) What are transition elements ? Explain their position in Modern Periodic Table and write the
electronic configuration of Co (At. No. 27) (March 2011) (2)
(11) Distinguish between Lanthanides and Actinides. (March 2008 , 2010) (2)
(12)
(13)
(14)
(15)
(16)
Ah
Why do lanthanides form coloured compounds ? (March 2008)
Why does the basicity of hydroxides of lanthanide series elements decrease with increase in
atomic number. (Oct. 2008)
Write the outer observed electronic configuration of :
(a) Gadolinium (64) (b) Ytterbium (70). (Oct. 2008)
What are lanthanons ? Give names and symbols of any ‘two rare earths. (March 2009)
Explain why does lanthanum forms La3+ ion, while cesium forms Ce4+ ion.
(2)
(2)
(2)
(2)
(At. No. La = 57, Ce = 58) (March 2009) (2)

(17) Write expected electronic configurations of (a) Nd (Z = 60) (b) Tm (Z = 69). (Oct. 2009) (2)
m
(18) Explain 63Eu and 70Yb show +2 oxidation state. (Oct. 2009) (2)
(19) Write the general outer electronic configuration of lanthanides and actinides. (March 2010) (2)
(20) Write the expected electronic configurations of (a) Europium (Z = 63)
(b) Erbium (Z = 68) (Oct. 2010) (2)
(21) What are ‘Actinides’? Write their position in the periodic table. (Oct. 2010) (2)
see
(22) Explain the cause of lanthanide contraction. (March 2011) (2)

(23) Name ‘two elements’ that form a pair of chemical twins. Explain, why are those elements
known as chemical twins. (March 2011) (2)
(24) Write the different oxidation states of manganese. Why +2 oxidation state of manganese is more
stable? (March 2013) (3)
(25) Write observed electronic configuration of elements from first transition series having half filled
d-orbitals. (Oct. 2013) (2)
(26) What is lanthanoid contraction ? Explain the cause and effects of lanthanoid contractioin.
Na
(Oct. 2013) (3)

(27) Write balanced chemical equations for action of potassium permanganate on :
(a) Hydrogen (b) Warm conc. sulphuric acid
Explain why Mn2+ ion is more stable than Mn3+ ? (Given : Mn Z = 25) (Oct. 2013) (3)
(28) What are lanthanoids ? What is the position of actinoids in periodic table ? (March 2014) (2)
(29) What is the action of acidified potassium dichromate on-
(a) SO2 (b) KI (Oct.2014) (2)
Draw structure of dichromate ion.
(30) What are chemical twins ? Write ‘two’ examples. (Oct. 2014) (2)
(31) What are interstitial compounds ? Why do these compounds have higher melting points
than corresponding pure metals ? (March
Mob : 8208242592 2015) (2)
(32) Define lanthanoid contraction. Explain its effects. (March 2015) (3)
(33) Distinguish between Lanthanoids and Actinoids. (Oct. 2015) (2)
(34) What is the position of iron (Z = 26) in periodic table ?
Explain why is Fe3+ more stable than Fe 2+ ? (Oct. 2015) (3)
(35) Why is Sc3+ colourless while Ti3+ colured ? (Atomic rumber Sc = 21, Ti = 22) (March 2016) (2)
(36) What are f-block elements ? Distinguish between lanthanoid and actinoids. (March 2016) (3)
(37) Explain the terms- Interstitial compounds. (March 2016) (1)
d
(38) Write four points of distinction between Lanthanoids and Actinoids. (July 2016) (2)
(39) Write reactions involved in preparatioin of potassium dichromate from chrome iron ore. (J.16) (3)
(40) Write the factors which are related to the colour of transition metal ions. (March 2017) (2)
(41) Write the different oxidation states of iron. Why oxidation state of manganese is more stable ?
ma
(Z of Mn = 25.) (March 2017) (3)
2- 2-
(42) Write balanced chemical equations for the conversion of CrO4 to Cr2O7 in acidic medium
and Cr2O72- to CrO42- in basic medium. (March 2018) (2)
(43) What is lanthanide contraction ? Explain the cause of lanthanide contraction. (M.2018) (3)
(44) What are ‘d’ and ‘f’ block elements ? (July 2018) (2)
(45) What is the action of the following on lanthanoids ? (July 2018) (3)
(a) Water (b) sulphur, heat (c) nitrogen. Heat
(46) How is potassium dichromate prepared from chrome iron ore ? (March 2019) (4)
(47)
(48)
(49)
(50)
Ah
Explain the position of actionoids in the periodic table.
What is the action of sulphur on lanthanoids ? & Calculate the magnetic moment of divalent ion
in aquenous solution if its atomic number is 24.
Distinguish between Lanthanoids and Actinoids.
(March 2019)
(July.2019)
Write a note on lanthanoid contraction .Write two uses of KMnO4. (July.2019)
What is the action of acidified potassium dichromate on the following .
(a) KI (b) H2S (March.2020)
(4)
(2)
(3)
(2)
(51) Write the general electronic configuration of lanthanoids.Why are most of the compounds
of transition metals coloured ? (March .2020) (3)
m
(52) Distinguish between Lanthanoids and Actinoids. (July.2020) (2)
(53) What are interstitial compounds ?Write two uses of potassium permanganate.
Calculate the magnetic moment in K2MnO4. (July.2020) (3)
(54) Write the chemical formula of Haematite. (July.2021) (1)
(55) Iron exhibits +2 and + 3 oxidation states. Write their electronicconfiguration.
see
Which will be more stable? Why? (July.2021) (2)

(56) Why La(OH)3 is the strongest base, while Lu(OH)3 is the weakest base? Write two applications
of catalytic properties of transition metals and compounds. (July.2021) (3)
(57) Define mineral. (July.2021) (1)
(58) Which of the following transition element shows maximum oxidation state? (March.2022) (1)
(a) Sc (b) Fe (c) Mn (d) V
(59) Write the name of the alloy used in Fischer Tropsch process in the synthesis of gasoline. (M. 22) (1)
(60) Write chemical composition of haematite. (March.2022) (1)
Na
(61) Calculate spin only magnetic moment of diavalent cation of transition metal with atomic
number 25. Salt of Ti4+ are clourless. Give reason. (March.2022) (3)
(62) What is lanthanoid contraction ? (March.2022) (1)
(63) Genral electronic configuration of ‘3d ‘ series of d block elements is _______ (July.2022) (1)
(a) [Ar]3d1-104s2 (a) [Xe]3d1-106s2 (a) [Kr]3d1-105s2 (a) [Rn]3d1-107s2
(64) Write the molecular formula of the following minerals . (July.2022) (2)
(i) chalcopyrite (ii) calamine
(65) What is a Lanthanoid contraction'?Write similarities between lanthanoids and actinoids.(Jul.22) (3)
(66) Why compounds of transition metal ions are coloured ? (July.2022) (2)
(67) The spin only magnetic moment of Mn2+ ion is _______. (March.2023) (1)
(A) 4.901 BM (B) 5.916 BM (C) 3.873 BM (D) 2.846 BM
Write the chemical composition of cryolite. (March.2023)
(68) : 8208242592
Mob (1)
(69) Distinguish between lanthanides and actinides. (March.2023) (2)
(70) What are interstitial compounds? Give the classification of alloys with examples. (March.2023) (3)
(71) Nichrome is an alloy of _ (July.2023) (1)
(a) Cu , Sn (b) Cu , Ni (c) Ni , Cr (d) Fe , Cr
(72) Which alloy is used in Fischer Tropsch process in the synthesis of gasoline ? (July.2023) (1)
(73) Why do d-block elements form coloured compounds? (July.2023) (2)
(74) Write different oxidation states of manganese. Why+ 2 oxidation state of manganese is more
d
Stable ? (July.2023) (3)
(75) Define : Gangue (July.2023) (1)
*****
ma
Ah
m
see
Na
Mob : 8208242592
9. CO-ORDINATION COMPOUNDS (5/7)
(1) Calculate magnetic moment of Fe2+(aq) ion (Z = 26). (March 2013) (2)
(2) Write the formulae of the following compounds-
(a) Sodium hexanitro-N-cobaltate (III).
(b) Tetraaquodichlorochromium (III) chloride.
(c) Potassium tetracyanoaurate (III). (March 2013) (3)
d
(3) State the superiority of crystal field theory over valence bond theory. (Oct.2013) (2)
(4) Write applications of co-ordination compounds in medicine and electroplating. (Oct. 2013) (2)
(5) What is effective atomic number (EAN) ?
ma
Calculate EAN of cobalt (Z=27) in [CO(NH3)6]+3 and of zinc (Z=30) in [Zn(NH3)4]SO4
(March 2014) (3)
(6) Classify the following ligands into monodentate and polydentate-
(a) Ammonia (b) Carbon monoxide (c) Ethylene diamine
(d) Ethylene diamine tetra acetate ion (Oct. 2014) (2)
(7) Write ‘four’ characteristics of co-ordinate complex ion. (Oct. 2014) (2)
(8) On the basis of valence bond theory explain the nature of bonding in [CoF6]3- ion. Write the
(9)
(10)
(11)
(12)
IUPAC name of [Co(NO2)3 (NH3)3].
(Oct. 2015)
Ah(March 2015)
Explain Sidgwick’s electronic theory with suitable example. (Oct. 2015)
Explain cationic complexes and anionic complexes of co-ordinationation compounds.
Illustrate with example, the difference between a double salt and a co-ordination compound.
(March 2016)
Explain the terms- Ligand (March 2016)
(3)
(2)
(2)
(2)
(1)
(13) Write the formula of Tetraminodichloroplatinum (iv) chloride. (March 2016) (1)
(14) Define ligand. Write four postulates of Werner’s theory. (July 2016) (3)
m
(15) What is ‘effective atomic number’ (EAN) ?
Calculate the effective atomic number of the central metal atom in the following compounds:
(a) K4Fe (CN)6 (b) Cr(CO)6
Fe (Z = 26) Cr (Z = 24 ) (March 2017) (3)
(16) The ligand diethylene triamine is __(March 2018) (1)
see
(a)Monodentate (b) bidentate (c) tridentate (d) tetradentate

(17) Explain the geometry of (Co(NH3)6)3+ on the basis of hybridization. (Z of Co = 27)(M.2018) (2)
(18) Write the formula of the complex copper (II) hexacyano ferrate (II). (March 2018) (1)
(19) Explain the geometry of [Cu(NH3)4]2+ on the basis of hybridisatioin (At. No. Cu = 29).(Jul 18) (2)
(20) Write the formula for pentaammine chlorocobalt (II) sulphate. (July 2018) (1)
(21) What is effective atomic number ? Calculate effective atomic number of copper (Z=29) in
[Cu(NH3)4]2+ …(March 2019) (3)
(22) Write IUPAC name of [Pt(en)2Cl2]2+ complex ion.(July.2019) (1)
Na
(23) Explain linkage isomerism. (July.2019) (2)

(24) Identify complex ion in which effective atomic number of the central metal ion is 35.
(Given atomic no.of Co = 27 ,Fe = 26 , Zn =30) (March.2020) (1)
(a)[Zn(NH3)4]2+ (b)[Fe(CN)6]4- (c) )[Fe(CN)6]3- (d)[Co(NH3)6]3+
(25) Calculate the effective atomic number of copper in [Cu(NH3)4]2+, [Z of Cu =29].
Explain ionization isomerism in coordination compound with a suitable example .(March .2020)(3)
(26) Explain the formation of [CoF6]3- ion on the basis of Valence Bond Theory .Identify whether the
Mob : 8208242592
Ligand is weak field or strong field . (July.2020) (3)
(27) What are bidentate Ligands? Give one example. (July.2021) (2)
(28) Illustrate with example, the difference between a double salt and coordinate compounds.
Write two applications of coordinate compounds. (July.2021) (3)
(29) Write IUPAC name of [Fe(CO)5] complex. (July.2021) (1)
(30) The correct formula for the complex compound, sodiumhexacyanoferrate(III) is ….
(a) Na [Fe(CN)6] (b) Na2 [Fe(CN)6] (M.2022) (1)
d
(c) Na3 [Fe(CN)6] (d) Na4 [Fe(CN)6]
(31) Write the name or isomerism in the following complexes: (M.2022) (1)
[Cu(NH3)4] [PtCl)4] and [Pt(NH3)4] [CuCl4]
(32) Explain monodentate and ambidentate ligand with example . (July.2022) (2)
ma
(33) Explain cationic , anionic and neutral sphere complexes with example . (M.2022) (3)
(34) Calculate effective atomic number of Co3+ in [ Co(NH3)6]3+ complex. (July.2022) (1)
(35) Explain linkage isomerism in complexes with one example. (July.2022) (2)
(36) Write two postulate’s of Werner theory of coordination complexes. (July.2022) (2)
(37) Explain homoleptic and heteroleptic complexes with examples. (July.2022) (2)
(38) The correct formula of a complex having IUPAC name Tetraamminedibromoplatinum (IV)
bromide is ________. (March.2023) (1)
(A) [PtBr (NH3)4] Br2 (B) [PtBr2 (NH3)4] Br
(39)
(40)
(41)
(C) [PtBr2 (NH3)4] Br2
i. Hybridisation ii. Magnetic properties

Define: Distereoisomers. (March.2023)
Give cis and trans isomers of [Co(NH3)4Cl2]+.
Ah
(D) [PtBr (NH3)4] Br
Write the name of platinum complex used in the treatment of cancer.
Explain formation of [CoF6]3– complex with respect to . (March.2023)
(March.2023)
iii. Inner / outer complex iv. Geometry

(1)
(3)
(2)
(42) The coordination number of cobalt in [CoC12( en)2]+ is… (July.2023) (1)
(a) 6 (b) 4 (c) 2 (d) 0
(43) Write four postulates of Werner theory of coordination complexes. (July.2023) (2)
m
(44) On the basis of valence bond theory explain the nature of bonding in [Ni(Cl)4]2-
complex ion. (July.2023) (3)
(45) Define : Ionisation isomer (July.2023) (1)
see
******
Na
Mob : 8208242592
10. HALOGEN DERIVATIVE (5/7)
(1) Write a note on Wurtz reaction and mention any two uses of iodoform. (March 2008) (3)
(2) Explain the alkaline hydrolysis of bromomethane. (March 2008) (4)
(3) Define optical activity. Explain optical activity of 2-chlorobutane. (March 2008, Oct.2008) (4)
d
(4) State and explain ‘Markownikoff’s rule’ with a suitable example. (Oct. 2008) (2)
(5) Define asymmetric carbon atom. (Oct. 2008 , March 2011) (1)
(6) What is the action of following reagents on ethyl iodide ? (March 2009) (3)
ma
(a) Aq. KOH (b) Alcoholic KCN (c) Silver acetate
(7) Explain the alkaline hydrolysis of tert-butyl bromide. (March 2009 , 2010) (4)
(8) Give the structural formula and IUPAC name of iso-butyl bromide. (March 2009) (1)
(9) Complete the following reaction and identify A,B, C and D with correct formulae.
Ag O/H O pyridine C H ONa coldHI
C2 H5Br 
2 2
→ A → B 
2 5
→ C 
→D (Oct. 2010) (4)
SOCl2
(10) Write balanced chemical equations for the action of-
(a) Phosphorus trichloride on propan-2-o1.
(11)
(12)
(13)
(b)
(c)
Ah
Hydrogen bromide on styrene in the presence of a peroxide.
Methyl bromide on silver propanoate. (March 2013)
Explain optical activity of 2-chlorobutane. (Oct. 2013)
Distinguish between SN1 and SN2 mechanisms. (March 2014)
Write the structures of -
(a) 3-chloro-3-ethylhex-l-ene
(c) 1,3,5-tribromobenzene
(Oct. 2014)
(b) l-Iodo-2, 3-dimethylbutane
(3)
(2)
(2)
(3)
(14) State and explain Markownikoff’s rule with suitable example. (Oct. 2014) (2)
(15) Draw structure of DDT. Write its environmental effects. (March 2015) (2)
m
(16) Identify ‘A’ and ‘B’ in the following reaction :
CH3-CH = CH2 HBr ‘A’ alc. KOH ‘B’ (Oct. 2015) (2)
(17) Discuss the alkaline hydrolysis of bromomethane. (Oct. 2015) (4)
(18) How is chlorobezene prepared from aniline? How is chlorobenzene converted into
diphenyl? (March 2016) (2)
see
(19) Explain the terms- Optical activity. (March 2016) (1)

(20) How is propene converted into 1-bromopropane and 2-bromopropane ? (March 2016) (2)
(21) Write a note on Sandmeyer’s reaction. (July 2016) (2)
(22) Identify ‘A’ and ‘B’ and rewrite the reactions.
NaNO2
(1) C6H5NH2 (A) Cu2Br2 (B) + N2
HBr/273K
Alcoholic
(2) H3C – CH2 – CHBr – CH3 (A) + (B) + 2KBr + 2H2O (July 2016) (2)
KOH, ∆
Na
(23) Define racemic mixture. (March 2017) (1)

(24) Explain only reaction for alkaline hydrolysis of tert-butylbromide.(March 2018) (2)
aq.alkali
(25) 1 – chloro -2, 4 – dinitro benzene ? (July 2018) (1)
368K,H+
(26) Write a short note on Sandmeyer’s reaction. (July 2018) (2)

(27) What are recemates ? (July 2018) (1)
(28) C2H5 – Br + Nal dry acetone C2H5 – I + NaBr The above reaction is…(July 2018) (1)
(a)Wurtz reaction (b) Balz-Schiemann reaction (c) Swarts reaction
(d)Finkelstein reaction
(29) What is the action of the following on ethyl bromide. (March 2019) (2)
(i) alcoholic solution of potassium hydroxid (ii) silver acetate ?
Mob : 8208242592
(30) Define Enantiomers. (March 2019) (1)
(31) What is Grignard reagent ? (March 2019) (1)
(32) Write conversion of 2-bromobutane into unsaturated hydrocarbon by using alcoholic KOH.
(July.2019) (2)
(33) Write the reaction for preparation of Grignard’s reagent.(July.2019) (2)
(34) Define optical activity .How many optical isomers are possible for glucose .(March.2020) (2)
(35) Write the chemical reaction of chlorobenzene with repect to . (March.2020) (3)
(a) Sulphonation (b) Acetylation (c) Nitration
d
(36) Write the balanced chemical equation for the following reaction. (July.2020) (2)
(a) Propene is treated with HBr in the presence of peroxide.
(b) 2-bormo -2-methyl propane is heated with alcoholic KOH solution.
ma
(37) Explain the optical activity of 2-chlorobutane .What is racemic mixture ? (July.2020) (3)
(38) What is action of the following on chlorobenzene ?
i. Methyl chloride in presence of anhydrous AlC13
ii. Fuming H2SO4 (July.2021) (2)
(39) Explain SN2 reaction of alkaline hydrolysis of bromomethane.(July.2021) (3)
(40) How will you convert methyl iodide to methyl isocyanide.(July.2021) (1)
(41) Write the product formed when alkyl halide reacts with silver nitrite.(March.22) (1)
(42) What is the action of following on ethyl bromide: .(March.22) (2)
(43)
(44)
(45)
(i)
(i)
Na in dry ether
Convert ethyl bromide to :

i) ethyl iodide
(ii)
Ethyl bromide to ethyl methyl ether. (ii)

(iii) Bromobenzene to toluene.
ii) ethyl fluoride

Write four salient features of SN1 mechanism.
Ah
Mg in dry ether
Write chemical reactions for the following conversions: .(March.22)
(iv)
(July.2022)
Ethyl bromide to ethene.
Chlorobenzene to biphenyl .
(July.2022)
(4)
(2)
(2)
(46) Complete the following reaction and identify A and B . (July.2022) (2)
PBr
Isopropylalcohol 
3
→ A 
→B
m
NH 3 excess
dry ether H2O
Cl + Mg A B
(47) (July.2022) (1)
The product B is …
Mg Mg-Cl
see
a)
b)
Cl
c) Mg d)
(48) The allylic halide ,among the following is _______. (March.2023) (1)
a) R - CH -R = CH - x X = CH - CH -X
b) CH2 c) d) CH2 2
Na
X
(49) Write the structure of the product formed when chlorobenzene is treated with sodium metal in the
presence of dry ether. (March.2023) (1)
(50) Write the chemical reactions for the following.. (March.2023) (2)
i.Chlorobenzene is heated with fuming H2SO4 ii.Ethyl bromide is heated with silver acetate.
(51) Explain dehydrohalogenation reaction of 2-chlorobutane. Write use and environmental
effect of CFC. (March.2023) (3)
(52) Identify' A' in the following reaction (July.2023) (1)
A + 2Na dry ether
+ 2NaCl
Mob : 8208242592
(a) Bromobenzene (b) 1,4-dichlorobenzene (c) Naphthalene (d) Chlorobenzene
(53) What is Grignard reagent? How it is prepared? (July.2023) (2)
(54) Explain optical activity of 2-chlorobutane. (July.2023) (3)
(55) Write the use and environmental effect of methylene chloride. (July.2023) (1)
*****
d
ma
Ah
m
see
Na
Mob : 8208242592
11. ALCOHOLS, PHENOLS AND ETHERS (4/6)
(1) How is cumene converted into phenol ? Give test to distinguiush between phenol and ethanol.
(March 2008 , 2010 , Oct. 2010) (3)
(2) How are monohydric alcohols classified ? Give suitable examples.
Draw the structure of 2-methyl-propan-1-01. (March 2008) (4)
d
(3) From methyl magnesium iodide how are the ethanol and propan-2-01 are prepared ?
(Oct. 2008) (2)
(4) What is the action of the following on phenol ?
ma
(a) Bromine in CS2 (b) Conc. H2SO4 in presence of conc. HNO3
(c) Conc. H2SO4 at room temperature. (Oct. 2008) (3)
(5) What is the action of following on 2-methyl propan-2-ol ?
(a) 20% H2SO4 at 360 K
(b) NaBr and conc. H2SO4 (Oct 2008) (2)
(6) Write the chemical test to distinguish between propan-1-o1, propan-2-ol and
2-methyl-propan-2-o1. (March 09) (3)
(7) What are phenols? How is carbolic acid prepared from aniline ?
(8)
(9)
(c)
Ah
Write a chemical test to distinguish between alcohol and phenol. (March 2009)
What is the action of the following reagents on ethanol ?
(a) Thionyl chloride (b) Mixture of red phosphorus and bromine
Acidified potassium dichromate. (Oct. 2009 , March 2011)
How is carbolic acid prepared from benzene sulphonic acid ?
What is the action of conc. H2SO4 on phenol at 373 K ? (Oct. 2009)
(4)
(2)
(2)
(10) How is phenol prepared from (a) Aniline (b) Chlorobenzene (March 2010 , Oct. 2010) (2)
(11) What is the action of sulphuric acid at different temperatures and different concentrations on the
following compounds ?
m
(a) Ethanol (b) Propan-2-ol (c) 2-Methyl-propan-2-ol (March 2010) (3)
(12) How are ethyl alcohol, iso-propyl alcohol and tertiary butyl alcohol distinguished from each other ?
(Oct. 2010) (3)
(13) How is carbolic acid prepared from cumene ? Give two uses of phenol. (March 2011) (3)
(14) Boiling point of alcohols are much higher than those of the corresponding alkanes. Explain.
see
(March 2011) (2)

(15) Write IUPAC name of ethyl-methyl ether and explain action of cold HI and hot HI on it.
(March 2008) (3)
(16) What are ethers ? (Oct. 2008 , March 2011) (1)
(17) Write a note in Williamson’s synthesis. Mention two uses of ethoxyethane. (March 2009) (3)
(18) What happens when, ethyl methyl ether is hydrolysed by using dil. H2SO4 ? (Oct. 2009) (1)
(19) How are simple ethers and mixed ethers prepared by Williamson’s synthesis ?(March 2010) (2)
Na
(20) What is the action of dilute sulphuric acid under pressure, on ethoxy ethane ? (Oct. 2010) (1)
(21) How is ethyl methyl ether prepared from
(a) Sodium ethoxide ? (March 2011) (2)
(22) How is ethanol prepared from methanal by using Grignard reagent ? (March 2013) (2)
(23) How is phenol converted into the following ?
(a) benzene (b) benzoquinone (c) picic acid (Oct. 2013) (3)
(24) How is methoxy benzene prepared from carbolic acid ? (Oct. 2013) (2)
(25) Write the structural formula and IUPAC names of all possible isomers of the compound
with molecular formula C3H8O.Write ‘two’ used of phenol. (March 2014) (4)
(26) How is methoxyethane prepared from :
Mob : 8208242592
(a) Methyl iodide (March 2014) (2)
(27) What is the action of the following reagents on phenol-
(a) Bromine in CS2 at low temperature.
(b) Conc. H2SO4 at room temperature. (Oct. 2014) (2)
(28) How is carbolic acid prepared from the following compounds :
(1) Aniline (2) Chlorobenzene March 2015) (2)
(39) Mention ‘two’ physical properties of carbolic acid. (March 2015) (1)
d
(30) How are the following compounds prepared ?
(a) Benzl alcohol from benzyl chloride. (b) Propan -1 – o1 from peopanal (Oct. 2015) (2)
(31) How is carbolic acid prepared from chlorobenzene ?
ma
What is the action of bromine water on carbolic acids ?
Write chemical test to distinguish between carbolic acid and alcohol. (Oct. 2015) (3)
(32) Write the reactions involved in dehydration of 1o , 2o and 3o alcohols. (March 2016) (2)
(33) Write the structure and IUPAC name of ‘methyl-n-propyl ether.
What is the action of hot HI on it ? (July 2016) (3)
(34) Define carbolic acid. How carbolic acid is prepared from benzene sulphonic acid ? (March 2017)(2)
(35) Propene on oxidation with diborane in presence of alkaline hydrogen peroxide gives_(M.2018) (1)
(a) Propan -1-o1 (b) propan -2-o1 (c) allyl alcohol (d) propan-1,2-diol
(36) Why ethanol has higher boiling point than ethane ? (March 2018) (2)
(37)
(38)
(39)
Ah
Prepare carbolic acid from benzene sulphonic acid. Write a chemical equation for the action
of neutral ferric chloride on phenol. (March 2018)
What is the action of the following on isopropyl methyl ether ?
(a) hot HI
(March 2018)
Write a preparation of phenol from cumene ? What happens when phenol is heated with
zinc dust ? (July 2018)
(3)
(2)
(2)
(40) Identify A and B respectively in the following reaction : (July 2018) (1)
20% H2SO4 HBr
Tert-butyl alcohol A+H2O B
363K H2O2
m
(a) 2-methylpropene, 1-bromo-2-methylpropane (b)2-methylpropene,2-bromo-2-methylpropane
(c) 2-methylpropane,1-bromo-2-methylpropane (d)2-methylpropane,2-bromo-2-methylpropane
(41) What are ethers ? How are they classified ? (March 2019) (2)3
(42) Write balanced chemical equations for the following : (March 2019) (2)
(i) Action of sodium metal on ethanol (ii) Action of zinc dust on phenol
see
(43) Write the following conversion.

(i) Ethoxyethane into ethanol
(ii) Carbolic acid into p-phenol sulphonic acid (July.2019) (2)
(44) Write IUPAC name of pyrogallol. (July.2019) (1)
(45) Write the IUPAC name of (CH3)3C-CH(OH)-C2H5. (July .2019) (1)
(46) Explain continuous etherification process for the preparation of diethyl ether .(March.2020) (2)
(47) How are ethanol prepared from the following compounds. (March.2020) (3)
(a) Ethanal (b) Ethene (c) Bromoethane
Na
(48) Name the gas liberated when sodium metal reacts with ethanol. (July.2020) (1)
(49) What is the action of the following reagents on methoxy ethane ?
(a) Cold HI (b) Hot HI (July.2020) (2)
(50) Write the chemical reaction when phenol is treated with : (July.2020) (3)
(a) Bromine water (b) Dilute HNO3 (c) Conc.H2SO4 at room temperature
(51) Write a note on Kolbe reaction . (July.2021) (2)
(52) Convert the following : (July.2021) (3)
(i) chlorobenzene to phenol (ii) ethanal to ethanol
(iii) iodomethane to methoxy methane
(53) Write preparation of Phenol from aniline ? (March.22) (2)
Mob : 8208242592
(54) Writ the chemical reaction of following reagents on methoxy ethane ?
(i) Hot HI (ii) PCl5 (iii) dilute H2SO4 (March .22) (3)
(55) Correct IUPAC name of tert-butyl alcohol is ------ (July.2022) (1)
a) 2-methyl butan-1-ol b) 2-methyl butan-2-ol
c) 2-methyl propan-2-ol d) 2-methyl propan-1-ol
(56) Write the name of reaction during conversion of phenol to salicylic acid .(July.2022) (1)
(57) Write balanced chemical reactions of the following reagents on carbolic acid.(July.2022) (2)
i) Br2 water ii) concentrated HNO3
d
(58) What happen when vapour of 1o and 2o alcohols are passed over hot Cu metal ? (July.22) (2)
(59) The product of following reaction is
i)LiAlH
CH3 -CH=CH-CH 2 -CHO → ______? (March.2023) (1)
ma
4
+
ii)H 3 O
(A) CH3 – CH2 – CH2 – CH2 – CH2 – OH (B) CH3 – CH = CH – CH2 – CH2 – OH
(C) CH3 – CH2 – CH2 – CH2 – COOH (D) CH3 – CH = CH – CH2 – COOH
(60) Convert the following: (March.2023) (3)
i. Ethyl alcohol into ethyl acetate ii. Phenol into benzene iii. Diethyl ether into ethyl chloride
(61) Write Dow process for preparation of Phenol.
What is the action of bromine water on phenol? (March.2023) (2)
(62) Anisole on heating with concentrated HI gives______ (July.2023) (1)
(63)
(64)
(a) lodobenzene
(c) Iodobenzene + Methanol
How is phenol prepared from cumene?
Ah
(b) Phenol + Methanol
(d) Phenol + lodomethane
(July.2023)
Prepare the following by using methyl magnesium iodide : (July.2023)
(a) Ethanol (b) Propan-2-ol (c) 2-Methylpropan-2-ol
(2)
(3)
******
m
see
Na
Mob : 8208242592
12. ALDEHYDES, KETONES AND CARBOXYLIC ACIDS (6/8)
(1) What is the action of following reagents on acetaldehyde ?

(a) Sodium bisulphate (March 2008) (1)
(2) How will you obtain propan-2-one using
(a) CH3CN
d
What is the action of the following reagents on propan-2-one ?
(a) Hydrogen cyanide (b) Hydrazine. (March 2008) (4)
(3) What is the reaction of acetaldehyde with
ma
(a) Ammonical silver nitrate (b) Fehlings solution ? (Oct. 2008) (2)
(4) Write a note on Cannizarro’s reaction. (Oct. 2008 , 2010, March 2011) (2)
(5) Write a note on aldol condensation. (March 2009 , 2010) (4)
(6) How is carbonyl group converted into -
(a) - CH2 OH (b) > CHOH (c) - CH2 - (d) - C – OH (Oct. 2009 , 2010) (2)
(7) What is the action of following reagents on ethanal ?
(a) Fehling solution (b) Tollen’s reagent (March 2010) (2)
(8)
(9)
(10)
(11)
How will you obtain (a)
Ah
How is ‘Carbonyl group’ converted into - C C - (Oct. 2010)
OH OH
Explain : (a) Cannizzaro’s reaction (b) Clemensen’s reduction. (Oct. 2010)

Acetaldoxime from acetaldehyde ? (March 2011)
What are aldehydes and ketones ? Write a note on Cannizzaro’s reaction. (March 2011)
(1)
(2)
(1)
(4)
(12) How is ethyl ethanoate prepared from
(a) Carboxylic acid (b) Acid chloride. (March 2008) (2)
(13) How will you bring about following conversions ?
m
(a) Acetic acid to acetyl chloride (b) Methyl cyanide to acetic acid
(c) Acetyl chloride to ethyl acetate (Oct. 2008) (3)
(14) Convert the following :
(a) Dry ice into acetic acid (March 2009) (2)
(15) How is ethyl acetate obtained from - (a) Silver acetate (b) Acetic acids ? (Oct. 2009) (2)
see
(16) How is acetic acid converted into

(a) Acetamide (b) Acetic anhydride ? (Oct. 2009) (2)
(17) How is acetic acid prepared from (a) Dry ice (b) Methyl cyanide ? (March 2010) (2)
(18) What happens when -
(a) Acetic acid is heated with P2O5 ?
(b) Silver acetate is heated with methyl iodide ?
(c) Acetic acid is treated with sodium bicarbonate ? (Oct. 2010) (3)
(19) How is 4-methylpent-3-en-2-one obtained from propan-2-one ? (March 2013) (2)
Na
(20) How are the following compounds prepared ? (a) Benzaldehyde from benzene.
(b) Acetophenone from benzene. (c) Benzaldehyde from benzoyl chloride. (March 2013) (3)
(21) Mention ‘two’ uses of propan -2-one. (March 2013) (1)
(22) Explain the reaction of aldol condensation- (Oct. 2013) (3)
(23) How is benzophenone prepared from benzonitrile ? (Oct. 2013) (2)
(24) Explain the structure of carbonyl functional group. (Oct. 2013) (1)
(25) Write a note on aldol condensation. (March 2014) (2)
(26) Write a note on self oxidation-reduction reaction of aldehyde with suitable example.
(March 2014) (2)
Mob : 8208242592 Dry ether PCI5
(27) Identify ‘A’ and ‘B’ in the following reaction : C6 H 5 MgBr + CO 2 
H + /H O
→‘A’ 
→ ‘B’
2
(Oct. 2014) (2)

(28) Write a note on Friedel Craft’s acylation. (March 2015) (2)
(29) Explain, why are boiling points of carboxylic acids higher than corresponding alcohols.
(March 2015) (2)
(30) Write the structures and IUPAC names of the following compounds: (March 2015)
(a) Adipic acid (b) α - methyl butyraldehyde. (2)
d
(31) Write reaction of Aldol addition. (March 2015) (3)
(32) What is Stephen reaction ? (Oct. 2015) (2)
(33) Write the structure and IUPAC names of isomeric aldehydes having molecular formula C5H10O.
(Oct. 2015) (4)
ma
(34) What are ketones ? How are ketones classified ? (March 2016) (2)
(35) How is Benzonitrile converted to Benzophenone ? (July 2016) (2)
(36) Write two uses of formaldehyde. (July 2016) (1)
(37) How is ethanoic acid prepared from dry ice ? (March 2017) (2)
(38) Give IUPAC name of CH3-CH2-CH-CHO (March 2017) (1)
(39) Write only reactions for the preparation of benzophenone from benzonitrile. (March 2018) (2)
(40) Complete and rewrite the balanced chemical equations __(March 2018) (2)
(a)isobutyraldehyde 50% KOH ?
(41)
(42)
(43)
(b)Butanone + 2,4 dinitro-phenyl hydrazine H+
(b)PCl3 , heat Ah ?
What is the action on the following reagents on ethanoic acid ?
(a)LiAlH4/H3O+ (c)P2O5 , heat
Write balanced equations for the following conversions : (July 2018)
(a)Cyclopropane carboxylic acid to cyclopropyl methanol.
(b)Acetyl chloride to benzyl methyl ketone using dialkyl cadmium.
(March 2018)
Complete and rewrite the balanced chemical equation for the following reactions: (July 2018) (2)
(3)
(2)
(a) Benzaldehyde 50% KOH ?

(b) Acetone + phenylhydrazine H+ ?
m
(44) Write the preparation of benzoic acid from the following: (July 2018) (3)
(a)Styrene (b) benzamide (c) dry ice
(45) Write chemical equation for the following: (March 2018) (2)
(i) Gatterman – Koch formylation (ii) Rosenmund reduction
(46) How will you convert….(March 2018) (3)
see
(i) acetone to acetone cyanohydrin

(ii)sodium acetate to methane (iii) benzoic acid to m-bromobenzoic acid?
(47) Write chemical equation for the following: (March.2019) (4)
(i) Gatterman–Koch formylation ii) Rosenmund reduction
(48) Convert the following : (July.2019) (2)
(i)Ethanal into ethanal cyanohydrins.
(ii)3,5-dinitrobenzoic acid into 3,5-dinitrobenzoyl chloride.
(49) How are the Dry ice converted into ethanoic acid . (July.2019) (1)
Na
(50) Write aldol condensation reaction between ethanal and propanal.(July.2019) (2)
(51) Write structural formula of the alcohol that results when acetaldehyde is reacted with CH3MgBr
in the presence of dry ether and the product is hydrolysed. (March.2020) (1)
(52) Write balanced chemical reaction for preparation of acetic anhydride using acetic acid.(Mar. 20) (1)
(53) Explain the aldol addition reaction. Mention two uses of carboxylic acids. (March.2020) (4)
(54) Write a note on Cannizzaro reaction ? (July.2020) (2)
(55) Write the name of reagent used during conversion of acetaldehyde to acetaldehyde
cyanohydrin. (July.2021) (1)
(56) How is benzophenone prepared from benzonitrile ? (July.2021) (2)
(57) Write a note on 'aldol' condensation reaction of ethanal.
Write chemical reaction involved when benzaldehyde is
Mob : 8208242592 treated with concentrated caustic
potash. (July.2021) (3)
(58) How will you convert methyl cyanide to ethanoic acid. (July.2021) (1)
(59) Write the name of product formed, when acetone is treated with 2, 4-dinitrophenyl hydrazine.
(March.2022) (1)
(60) Identify A and B from the following reaction. (March.2022) (2)
CH3
-C=O Ba(OH)2 Β + Η2Ο
2 CH3 Α
d
(61) Write the structure of adipic acid . (March.2022) (1)
(62) Write preparation of acetic acid from (March.2022) (2)
(i) dry ice (ii) acetyl chloride
ma
(63) Write the classification of aliphatic ketones with example . What is the action of sodium
Hypoiodite on acetone ? (March.2022) (3)
(64) Write the IUPAC name of α–methyl propionic acid . (July.2022) (1)
(65) What is the action of the following on carboxylic acid : (July.2022) (2)
(i) SOCl2 (ii) P2O5
(66) Write a note on’ aldol’ condensation . (July.2022) (3)
(67) Convert carboxylic acid to , (July.2022) (2)
(i) Ester (ii) acid amide
(68)
(69)
(70)
________.
(A) acetaldehyde
(C) acetone
Explain Aldol condensation of ethanal.
Ah
Ozonolysis of 2, 3 dimethyl but-2-ene, followed by decomposition by Zn dust and water gives
(March.2023)
(B) propionaldehyde and acetone
(D) acetaldehyde and butyraldehyde
(March.2023)
Write chemical reactions for the following conversions: (March.2023)
i. Acetic acid into acetic anhydride ii. Acetic acid into ethyl alcohol
(1)
(3)
(2)
(71) Write a note on Haloform reaction. (March.2023) (2)

CHO
CO , HCl
m
high Pressure
Anhydrous AlCl3
(72)
The name of above reaction is __________. (July.2023) (1)
(a) Etard reaction (b) Friedel craft acylation reaction
(c) Stephen reaction (d) Gatterman-Koch reaction
see
(73) Write the IUPAC name of isobutyraldehyde. (July.2023) (1)

(74) Write a note on Wolf-Kishner reduction reaction . (July.2023) (2)
(75) Convert : (July.2023) (3)
(a) Acetic acid to acetamide (b) Acetyl chloride to acetic anhydride
(c) Sodium acetate to methane
(76) Define : Aromatic ketones (July.2023) (1)
Na
*****
Mob : 8208242592
13. Amines(3/4)
(1) How is ethanamine prepared by using. (a) Methyl cyanide (March 2008) (2)
(2) Write acetylation reaction of (a) Ethyl amine (b) Diethyl amine. (March 2008) (2)
(3) What are amines ? What is the action of acetyl chloride on ehtanamine, N-Ethylethanamine
d
and N-N-dimethylethanamine ? (Oct. 2008) (4)
(4) How is ethylamine prepared from - (a) Nitro-alkane.
Explain basic nature of amines. (March 2010 , Oct. 2009) (4)
ma
(5) What is the action of - (a) Nitrous acid on ethyl amine
(b) Mixture of sodium and alcohol on acetonitrile ? (Oct. 2010) (2)
(6) What is a ‘Quaternary ammonium salt’ ? (Oct. 2010) (2)
(7) What are amines ? Give IUPAC name of ethyl methyl amine. (March 2011) (2)
(8) How will you convert ? (a) - C = N into - CH2 - NH2 b) - NH2 into - OH (March 2011) (2)
(9) Write a short note on Hoffmann bromamide degradation. (March 2013) (3)
(10) Explain Hoffmann bromamide degradation reaction. (Oct. 2013) (2)
(11) What is the action of the following reagents on aniline ?
(12)
(13)
(14)
(15)
(16)
(a) Ethyl amine (b) Aniline
Ah
(a) Bromine water (b) Acetic anhydride (c) Hot and conc. sulphuric acid. (March 2014) (3)
What will be the action of the mixture of sodium nitrite and dilute hydrochloric acid on:
How is ethyl amine prepared from methyl iodide ? (March 2015)

Write a note on Gabriel phthalimide synthesis. (March 2015)
(Oct. 2014)
What is the action of acetic anhydride on : (a) Ethyl amine (b) Diethyl amine (Oct 2015) (2)
What is the action of benzene diazonium chloride on
(2)
(2)
(3)
(a) Phenol in alkaline medium (b) Aniline (July 2016) (2)

(17) Identify ‘A’ and ‘B’ and rewrite the reactions.
C2 H 5 – N + ( CH 3 )3 I − A B → + ( CH 3 )3 N + H 2 O (July 2016)
m
Ag 2 O/H 2 O ∆
 →  (1)
(18) What is the action of Benzene Sulphonyl Chloride on primary, secondary and tertiary amines?
(July 2016) (3)
(19) Write a note on Hofmann bromamide degradation. (March 2017) (2)
see
(20) What is the action of mixture of NaNO2 and dil.HCl, on :

(a) Ethylamine (b) Aniline (March 2017) (2)
(21) What is the action of p – tolunesulphonylchloride on ethylamine and diethylamine ?(M.2018) (2)
(22) How are ethylamine and ethyl methyl amine distinguished by using nitrous acid ?(March 2018) (2)
(23) Explain Hoffmann bromamide degradation reaction.(March 2018) (2)
(24) Write a short note on Hoffmann elimination. (March 2018) (3)
(25) What are amines ? (March 2018) (1)
(26) Write the structure of Phenylmethanamine. (March 2018) (1)
Na
(27) Write a short note on Hoffmann elimination. (March.2019) (3)

(28) Write the structure of phenylmethanamine. (March.2019) (1)
(29) What are amines? (March.2019) (1)
(30) Amines are basic in nature.Explain. (July.2019) (2)
(31) What is the action of benzene sulphonyl chloride on ethanamine. (July.2019) (2)
(32) Quaternary ammonium salt. (March.2020) (1)
(33) Write IUPAC name of (CH3)2N-C2H5. (July.2020) (1)
(34) Write a note on Hoffmann bromamide degradation .
Write the chemical reaction for the action of Aniline on Benzene diazonium chloride in
alkaline medium. (July.2020) (3)
(35) Write reactions to prepare ethanamine from
Mob : 8208242592 (July.2020) (3)
(i) acetonitrile (ii) nitroethane (iii) propionamide
(36) Acid anhydride on reaction with primary amine gives compound having a functional group….
(a) amide (b) nitrile (c) secondary amine (d) imine (March.22) (1)
(37) Write chemical reaction to prepare ethanamine from . (March.22) (2)
(i) acetonitrile (ii) nitroethane
(38) The most basic amine amongst the following is _____ (July.2022) (1)
(a) CH3-NH2 (b) (CH3)2-NH (c) (CH3)3-N (d) C2H5-NH2
(39) Write the formula of Hinsberg’s reagent . (July.2022) (1)
d
(40) Complete the following reaction . (July.2022) (1)
Sn / HCl conc
R-NO 2  →?
ma
(41) Write chemical reaction for carbylamines test. (July.2022) (1)
(42) Write the name of the product formed by the action of LiAlH4/ ether on acetamide.(March.2023)(1)
(43) What is the action of the following reagents on ethyl amine (March.2023) (2)
i. Chloroform and caustic potash ii. Nitrous acid
(44) Write IUPAC name and structure of methylphenylamine. (March.2023) (1)
(45) Which amine does NOT react with Hinsberg reagent? (July.2023) (1)
(a) Ethanamine (b) N-ethylethanamine
(c) N,N-diethylethanamine (d) 2-methyl-propan-2-amine
(46)
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Write a note on Hofmann bromamide degradation.
Convert benzene diazonium chloride into benzene.
******
(July.2023) (3)
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14. BIO-MOLECULES (3/4)
(1) Give chemical reactions of glucose with
(a) Hydroxyl amine (b) Bromine water. (March 2008) (2)
(2) How will you convert glucose into - (a) Gluconic acid (b) Saccharic acid (Oct. 2008) (2)
(3) Classify proteins on the basis of hydrolysis products and give examples. (Oct.2008) (2)
(4) How is the glucose prepared from sucrose ? (March 2009) (2)
d
(5) Define the term ‘Simple protein’. (Oct. 2009) (1)
(6) Explain the term ‘proteins. (March 2008) (1)
(7) Classify the following carbohydrates -
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(a) Cellulose (b) Maltose (c) Raffinose (d) Fructose. (Oct. 2009) (2)
(8) What are proteins ? How is peptide linkage fromed in proteins ? (March 2010) (3)
(9) What is the action of the following on glucose ?
(a) Acetic anhydride (b) Hydroxyl amine. (Oct. 2010) (2)
(10) write the structures of nucleotide and nucleoside. (March 2013) (2)
(11) Enlist the properties of glucose that can not be explained on the basis of open chain
structure of it. (Oct. 2013) (3)
(12) What happens when glucose is treated with-
(13)
(14)
(15)
(16)
(17)
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(a) Bromine water (b) Dilute nitric acid (c) Hydrogen cyanite (HCN)(March 2014)
Describe laboratory method for preparation of glucose. Write the reaction that indicates the
presence of -CHO group in glucose. (Oct. 2014)
Draw the simple Fisher projection formulae of D-(+)-glucose and D-(-)- fructose.(Oct. 2014)
How are proteins classified on the basis of molecular shapes ? (March 2015)
Define carbohydrates. What are reducing and non-reducing sugars ? (March 2015)
What are monosaccharides ? Draw ring structure of α - D – (+) – glucopyranose ? (Oct. 2015)
(3)
(3)
(2)
(2)
(3)
(2)
(18) What is peptide linkage ? How is tripeptide formed ? (Oct. 2015) (3)
(19) What are carbohydrates ? (March 2016) (1)
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(20) Write the structures of (a) nucleoside (b) nucleotide (March 2016) (2)
(21) What is the action of following reagents on glucose ?
(a) bromine water (b) dilute HNO3 (c) Hydroxyl amine (July 2016) (3)
(22) What are ‘nucleic acids’ ? (March 2017) (1)
(23) The number of primary and secondary hydroxyl groups in ribose are __(March 2018) (1)
see
(a) 1,3 (b) 2,3 (c) 3,1 (d) 3,2

(24) What are amino acids ? Write the correct reaction for formation of peptide bond between
amino acids. (March 2018) (2)
(25) Draw the structures of chloroxylenol and adenine. (March 2018) (1)
(26) How glucose is prepared from cane sugar ? (March 2018) (2)
(27) How is glucose prepared from starch ? (July 2018) (2)
(28) What is the action of following reagents on glucose ? (July 2018) (2)
(a) Bromine water (b) Hydroxylamine
Na
(29) Write the number of hydroxyl groups present in α-D-(+)- Glucopyranose (trans).(March 2019) (1)
(30) How is glucose prepared by commercial method ? How is peptide linkage formed ?(March 19) (3)
(31) Define enzyme . (July.2019) (1)
(32) How are following conversion carried out ?
(i) Glucose into n-hexane
(ii) Glucose into glucoxime ? (July.2019) (2)
(33) Name the reagent which on reation with glucose confirms the presence of five hydroxyl groups
In glucose . (March.2020) (1)
(a)Hydroxyl amine (b)Bromine water (c) Dilute nitric acid (d) Acetic anhydride
(34) Write Howorth projection formula of α-D-(+)- Glucopyranose . (March .2020) (2)
Mob : 8208242592
(35) What are monosaccharides ? Explain denaturation of proteins. (March.2020) (3)
(36) Name the reagent which on reaction with glucose confirms presence of primary alcoholic
group in glucose . (July.2020) (1)
(a) Hot HI (b) Bromine water (c) Dilute HNO3 (d) Hydroxyl amine
(37) Define carbohydrates .
What are reducing sugars and non – reducing sugars ?(July .2020) (3)
(38) Write the name of sugar present in RNA. (July.2021) (1)
(39) Write classification of proteins on the basis of molecular shapes with example. (July.2021) (2)
d
(40) What is nucleotide? (July.2021) (1)
(41) Explain formation of peptide linkage in protein with an example.(March.22) (2)
(42) Write commercial method for preparation of glucose. (March.22) (2)
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(43) Lactose on hydrolysis gives ….. (July.2022) (1)
(a) galactose + glucose (b) 2 moles of glucose
(c) fructose + glucose (d) fructose + galactose
(44) Write the preparation of glucose from sucrose . (July.2022) (1)
(45) What is denaturaion of protein ? (July.2022) (1)
(45) What is the action of hot HI on glucose ? (July.2022) (1)
(46) The glycosidic linkage present in maltose is ________. (March.2023) (1)
(A) α, β-1, 2-glycosidic linkage (B) α-1, 4-glycosidic linkage
(47)
(48)
(49)
(50)
(51)
(C) β-1, 4-glycosidic linkage
Write structure of D-ribose.

What is peptide bond? (March.2023)
Write the structure of glycine ?
How is glucose prepared from sucrose?
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(D) α-1, 6-glycosidic linkage
Write chemical reaction for the preparation of glucose from sucrose.
(March.2023)
(July.2023)
(July.2023)
Draw the Fischer projection formula for α – D - (+) glucose. (July.2023)
(2)
(1)
(1)
(2)
(1)
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15. Introduction to Polymers Chemistry (3/4)
(1) Write chemical reactions involved in preparation of Nylon-66.

(March 2008 , Oct. 2009 , March 2010) (2)
(2) What are synthetic fibres ? How is terylene prepared ? (Oct. 2008) (3)
(3) Define ‘Fibre’. (March 2009 , Oct. 2009 , 2010 , March 2011) (1)
(4) Write two properties and two uses of nylon-6. (March 2009) (2)
d
(5) Write the two uses of ‘Terylene’. (March 2010) (1)
(6) Write names and chemical formulae of the chemical substances used in the preparation of
nylon-66. (Oct. 2010) (2)
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(7) Give chemical reactions involved in preparation of Terylene. (March 2011) (2)
(8) Write the chemical reaction to prepare novolac polymer. (March 2013) (2)
(9) Explain the following terms :
(a) Homopolymers (b) Elastomers (March 2013) (2)
(10) How are polymers classified on the basis of polymerisation process ? (Oct. 2013) (2)
(11) Write the structure of melamine. (Oct. 2013) (1)
(12) What are thermoplastic polymers ? (March 2014) (1)
(13) Write names and chemical formulae of monomers used in preparing Buna-S.(March 2014) (2)
(14)
(15)
(16)
(17)
(18)
Ah
How is Nylon 6,6 prepared ? Write any ‘two’ uses of terylene. (Oct. 2014)
Explain with examples, branched and linear polymers. (March 2015)
Whar are biodegradable polymers and non-biodegradable polymers ? Write ‘one example’
of each. (March 2015)
Write the reactions involved in the preparation of –
(a) Teflon (b) Orlon (c) PVC. (Oct. 2015)
Write the reaction for the preparation of Nylon-6. (March 2016)
(3)
(2)
(2)
(3)
(1)
(19) How are polythene and neoprene prepared ? (March 2016) (2)
(20) Write the formulae of the raw materials used for preparation of (a) Buna-S (July 2016) (1)
m
(21) How are the following polymers prepared ? (a) Orlon (b) Teflon (July 2016) (2)
(22) Explain the following terms : (a) Homopolymers (b) Elastomers (March 2017) (2)
(23) How is nylon 6,6 prepared ? (March 2017) (1)
(24) A polymer used in paints is __(March 2018) (1)
(a) Nomex (b) Thiokol (c) Saran (d) Glyptal
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(25) Explain the preparation and uses of nylon-2-nylon-6.(March 2018) (2)

(26) What are elastomers ?Distinguish between thermoplastic polymers and thermosetting
polymers. (July 2018) (3)
(27) A polymer which contains ester linkage is…..(July 2018) (1)
(a) Teflon (b) Buna – N (c) Dextron (d) Neoprene
(28) Write chemical reactions to prepare the following polymers. (March 2019) (3)
(i) Teflon (ii) Nylon-6 (iii) Dextron
(29) Write the reaction for the preparation of polymers by using the following monomers.(July.2019) (2)
Na
(i) Vinyl chloride (ii) Tetrafluoroethene.

(30) Define condensation polymer .(July .2019) (1)
(31) Define non-biodegradable polymer.Write the preparation of terylene .(March.2020) (3)
(32) Identify the addition polymer amongst the following .(July.2020) (1)
(a) Nylon-6,6 (b) Terylene (c) Dextron (d) Teflon
(33) Write the answers. (July.2020) (1)
(a) The structural formula of monomer used in the preparation of Nylon-6.
(34) Write names and structure of monomers used in the preparationof Nylon 6, 6 polymer. (July.2021)(2)
(35) Write reaction for the preparation of polyacrylonitrile (PAN). (July.2021) (1)
(36) Write the name of biodegradable polyamide copolymer. (March.2022) (1)
(37) Write classification of polymers on the basis of structure. (March.2022) (3)
(38) Write the name of monomer used for preparation of nylon-6 . (July.2022) (1)
(39) Define Elastomer. (July.2022) (1)
(40)
PreparedWrite chemical
By Naseem reaction
Ahmad forJunior
(Islamia preparation ) Teflon . (July.2022)
College of (1)
(41) : 8208242592
Mob The monomer of natural rubber is ________. (March.2023) (1)
(A) Isoprene (B) Acrylonitrile (C) ε-Caprolactam (D) Tetrafluoroethylene
(42) Write the reactions for the formation of nylon 6,6 polymer. (March.2023) (2)
(43) Define: Vulcanization , (March.2023) (1)
(44) Which is an example of thermoplastic polymer? (July.2023) (1)
(a) Bakelite (b) Polystyrene (c) Nylon 6, 6 (d) Urea formaldehyde resin
(45) How is Nylon 6,6 prepared ? (July.2023) (2)
(46) Write reaction involved in the formation of Teflon. (July.2023) (1)
d
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Green chemistry and Nano Chemistry (3/4)
(1) Write the name of nanostructural material used in tyres to increase their life. (July.2021) (1)
(2) Explain three principles of green chemistry. (July.2021) (3)
(3) Define green chemistry. Write two disadvantages of nanotechnology. (March.2022) (3)
(4) The name of metal nanoparticle which acts as highly effective bacterial disinfectant in water
purification process is __ (March.2022) (1)
d
(a) carbon black (b) silver (c) gold (d) copper
(5) ZWT in green chemistry stands for (July.2022) (1)
(a) zero waiting time (b) zero waste technology
(c) zubl water technology (d) zhen wu tang
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(6) Define : Nanochemistry (July.2022) (1)
(7) Define : Nanotechnology. (July.2022) (1)
(8) Define : Green Chemistry. (July.2022) (1)
(9) Write the name of the technique used to know geometry of nanoparticles. (March.2023) (1)
(10) Define: Green chemistry.Write two advantages of nanoparticle and nanotechnology. (March. 23)(2)
(11) Write the name of nano structured material used in car tyres to increase the life of tyres.(M.23) (1)
(12) Name the γ - isomer of BHC. (July.2023) (1)
(13) Write any three advantages and disadvantages of nanoparticles and nanotechnology. (July.23) (3)
Ah
*****
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Prepared By Naseem Ahmad (Islamia Junior College )

(a) 7 (b) 3 (c) 4 (d) 2

formula: (March.2023) (1)

(b) Isothermal and reversible process.

→ 2( aq ) , ∆H 3= −11.58 kJ

constant. (July 2016)

Calculate the standard enthalpy of the reaction.

→ 2O(l) ; ∆H o= −285.8 kJ

(35) Write applications of standard molar entropy. (July 2016) (2)

(a) +4.988 kJ (b) -4.988 kJ (c) -49.88 kJ (d) +49.88 kJ

Bond N≡N H–H N-H

(b) C2H4(g) + 3O2(g) 2CO2(g) + 2H2O(l) ∆H = -1410 kJ

∆Ho(H-H) = 435 kJmol-1

(a) vapourisation (b) fusion

ii)C(s) + O 2(g)  → CO 2(g) ∆ c H o = -393 kJmol-1

Eo -1.66V 0.34V 1.36V -0.26V

Define electrochemical series. Write its applications.(March 2019)

conductivity. (July.2019) (2)

E oCd = -0.403V , E oSn = -0.136V

6. CHEMICAL KINETICS (4/6)

(1) Distinguish between molecularity and order of the reaction.

What are the values of the following at the same time ?

(a) d(I-) (b) - d [ S2O2-8 ] (c) - d [ I-3 ]

dt dt dt (March 2013) (3)

(12) Write molecularity of the following reaction : (March 2014) (1)

reactants to decrease from 0.8M to 0.25M. (July.2019) (3)

(ii) F(g) + NO 2(g) 

in gas phase: (March.2023)

7. Elements of Groups 16 ,17 & 18 (6/8)

Write chemical formula of the following oxoacids of chlorine:

(March 2016) (2)

(a) Bleaching action of SO2.

(46) What is the action of chlorine on the following . (July.2022) (2)

i. chloric acid ii. peroxy disulphuric acid

(55) Write molecular formula and structure of: (July.2023) (3)

8. Transition and inner transition elements (6/8)

(At. No. La = 57, Ce = 58) (March 2009) (2)

(22) Explain the cause of lanthanide contraction. (March 2011) (2)

(Oct. 2013) (3)

Which will be more stable? Why? (July.2021) (2)

(a)Monodentate (b) bidentate (c) tridentate (d) tetradentate

(23) Explain linkage isomerism. (July.2019) (2)

i. Hybridisation ii. Magnetic properties

iii. Inner / outer complex iv. Geometry

10. HALOGEN DERIVATIVE (5/7)

(19) Explain the terms- Optical activity. (March 2016) (1)

(23) Define racemic mixture. (March 2017) (1)

(26) Write a short note on Sandmeyer’s reaction. (July 2018) (2)

Convert ethyl bromide to :

Ethyl bromide to ethyl methyl ether. (ii)

ii) ethyl fluoride

(March 2011) (2)

(43) Write the following conversion.

12. ALDEHYDES, KETONES AND CARBOXYLIC ACIDS (6/8)

(1) What is the action of following reagents on acetaldehyde ?

Explain : (a) Cannizzaro’s reaction (b) Clemensen’s reduction. (Oct. 2010)

(16) How is acetic acid converted into

(Oct. 2014) (2)

(a) Benzaldehyde 50% KOH ?

(i) acetone to acetone cyanohydrin

(71) Write a note on Haloform reaction. (March.2023) (2)

(73) Write the IUPAC name of isobutyraldehyde. (July.2023) (1)

How is ethyl amine prepared from methyl iodide ? (March 2015)

(a) Phenol in alkaline medium (b) Aniline (July 2016) (2)