HOLIDAY HOMEWORK (summer vaca on)

CLASS-XII
SUBJECT: CHEMISTRY
SESSION 2023-24 Prepared by: P. Da a.
PGT CHEMISTRY
1Mark ques ons (MCQ)
1. 58.5 grams of NaCl is added to 2 kg of water. What is the molality
of the solu on?
A. 29 m
B. none of these
C. 1 m
D. 0.50 m
2. The freezing point of a solu on is ____ the freezing point of the
pure solvent.
A. no rela on to
B. lower than
C. the same as
D. higher than
3. Colliga ve proper es depend on the _____ of solute par cles in
solu on.
A. type
B. pH
C. nature
D. number
4. What is the van't Hoff factor for the compound Na 2 SO4 (assuming
its complete dissocia on in water)
A. 1
B. 3
C. 7
D. 5
5. What is the van't Hoff factor for the compound C 6 H12O6 ?
A. 0
B. 1
C. 3
D. 24
6. A solu on has 10 moles of ammonia in 2L of solu on. What is the
molarity?
A. 20 M
B. 0.2 M
C. 5.0 M
D. 0.5 M
7. Molality is measured in
A. mol per kg
B. mol per L
C. mol per mL
D. mol per kJ
8. What is the freezing point of a 1.0 m solu on of sucrose in water?
(K = 1.86 K kg mol )
A. -1.2°C
B. 0.81°C
C. -0.81°C
D. -1.86°C
9. When the pressure of a solu on is raised, the solubility of the gas
___.
A. pressure has no effect on solubility
B. increases
C. remains constant
D. decreases
10. What is the molarity of 2.5 mol of NaOH in 12.0 L of solu on?
A. 0.21 M
B. 4.8 M
C. 20.8 M
D. 30 M
11. The movement of water through a semi-permeable membrane is
called?
A. diffusion
B. osmosis
C. cell membrane
D. respira on
12. When both inside and outside of a cell have the same amount of
water it is said that the cell has reached a state of ___________.
A. osmosis
B. hypertonic
C. diffusion
D. equilibrium
13. A mixture of chloroform and acetone shows a nega ve devia on
from Raoult’s law. It is due to
A. dipole-dipole a rac on
B. London force between chloroform and acetone
C. H-bonding between chloroform and acetone
D.. less a rac on between chloroform and acetone
14. What is NOT true regarding azeotropes?
A boil at a constant temperature
B. 68% (w/w) nitric acid in water is an azeotrope.
C. binary mixtures having the same composi on in liquid and vapour
phase
D. 95% by volume of ethanol in water is a maximum boiling
azeotrope
15. According to Raoult's law, the rela ve lowering of vapour
pressure for a solu on is equal to
A. mol frac on of solute
B. moles of solvent
C. moles of solute
D. mol frac on of solvent
16. Which of the following is NOT a colliga ve property of solu on?
A. lowering of vapour pressure
B. depression of f.pt
C. eleva on of b.pt
D. osmo c pressure
17. Blood cells retain their normal shapes in solu ons which are
A. hypotonic to blood
B. isotonic to blood
C. hypertonic to blood
D. equinormal to blood
18. A pressure cooker reduces cooking me for food because
A. heat is more evenly distributed in the cooking space
B. cooking involves chemical changes helped by a rise in temperature
C. boiling point of water involved in cooking is increased
D. the higher pressure inside the cooker crushes the food material
19. Standard hydrogen electrode has an arbitrarily fixed poten al of
___________
A. 0.00 volt
B. 1.00 volt
C. 0.10 volt
D. -1.00 volt
20. Which one of the following represents the same net reac on as
the electrolysis of aqueous H2 SO4
A. electrolysis of water
B. electrolysis of aqueous HCl
C. electrolysis of molten NaCl
D. electrolysis of aqueous NaCl
21. In a salt bridge KCl is used because
A. agar–agar forms a good jelly with it
B. KCl is also present in the calomel electrode
C. it is an electrolyte
D. K and Cl transfer easily
22. In the electrolysis the process of oxida on occurs at
A. both cathode and anode
B. cathode
C. anode
D in electroly c solu on 2 4 + –

23. The e.m.f. of Daniell cell can be increased by

A. increasing the concentra on of oxidising ion in the solu on
B. adding the dil H2 SO4
C. increasing the area of electrode
D. increasing the concentra on of reducing ion in the solu on
24. A cell in which an electric current drives a non–spontaneous
reac on is called
A. voltaic cell
B. biological cell
C. galvanic cell
D. electroly c cell
25. Asser on(A): Galvanised iron does not rust
Reason(R) : Zinc has a more nega ve electrode poten al than iron.
A Both A and R are true but R is not the correct explana on of A.
B A is true but R is false.
C Both A and R are true and R is the correct explana on of A.
D A is false but R is true.
26. Asser on(A): On increasing dilu on, the conduc vity keeps on
increasing.
Reason(R): On increasing dilu on, the degree of ioniza on of weak
electrolytes increases.
A. A is false but R is true.
B. A is true but R is false.
C. Both A and R are true but R is not the correct explana on of A.
D. Both A and R are true and R is the correct explana on of A.
27. The difference between the electrode poten als of two
electrodes when no current is drawn through the cell is called
___________.
A. Poten al difference
B. Cell emf
C. Cell poten al
D. Cell voltage

2- marks ques on
What do you mean by reverse osmosis? Give an example.
28. What kind of non-ideal solu on forms on mixing ethanol into
water? Explain?
29.The boiling point of benzene is 353.23 K. When1.80 g of a non-
vola le-solute was dissolved in 90 g of benzene, the boiling point is
raised to 354.11K. Calculate the molar mass of the solute. K b for
benzene is 2.53 K kg mol -1 .
30. State Henry’s law. Write the expression of Henry’s law.
31. Write two applica ons of Henry’s law.
32. Define colliga ve proper es. Name the colliga ve proper es of
solu on.
33.Draw the diagram of eleva on of boiling point.
34.Wite the differences between Galvanic cell and electroly c cell.
35.What is salt bridge? Write its func ons.
36. Write the cell representa on of zinc in zinc sulphate solu on and
copper in copper sulphate solu on.

3 marks ques ons:

37.Draw the vapour-pressure vs temperature curves for a pure
solvent and its solu on. Find the boiling point of an aqueous solu on
having ∆T b 0.052K (water boils at 373.15 K at 1.013bar).
38.Why osmo c pressure method is most preferred to measure the
molecular mass of
macromolecules?
39.Define Azeotropic Mixture. What do you mean by maximum
boiling azeotropes? Give an example.
40.Find the emf of the following cell:
Zn(s)/ZnSO4(0.01M)//CuSO4(0.001M)/Cu(s)
Standard electrode poten al of Zn and Cu are -0.76volt and 0.34volt
respec vely.

5 Marks ques ons:

41.a. State Raoult’s law. Derive the expression to determine the
molecular mass of solute using rela ve lowering of vapour pressure
colliga ve property of a solu on.
b. Define the following terms:
i. anoxia. ii. Bends
42. a. What are isotonic solu on and hypotonic solu on? Give an
example for each.
b. Why Vant Hoff’s factor for NaCl is more than 1 but ace c acid is
less than 1 ?
c. Find the value of Vant Hoff’s factor (i) for the following:
i. K4[Fe (CN)6] ii. Na2SO4

NUMERICAL BASED QUESTIONS:

CHAPTER: SOLUTION
EXERCISE QUESTION NO 15. 16,17,18,19,20.40 and 41.

THE END