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com Marks: /0
Time: 3.00 Hours 15x1=15
Part -I
the best answer.
Note: Answer all the questions. Choose
1) Titanium is purified by Van-Arkel method
a) Mond process
d) Electrolytic refining
c) Zone refining
2) General empirical formula of silicone is d) (RSiH)
Ga) (R,SiO) bYRSIO) c) (R,CO)
3) Shape of XeOFe, is pryramidal c) linear d) T-shaped
a) square pyramidal b)
Assertion : In any transition series the magnetic moment of M2* ions
4)
first increases and then decreases.
: In a transition series, the
number of unpaired electrons
Reason
increases and then decreases.
reason is the correct explantion
a) If both assertion and reason are true and

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of the assertion
but reason is not the correct
b) If both assertion and reason are true
explanation of assertion

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c) If assertion is true, but reason is false,
d) If both assertion and reason are false
S) is used as an antitumor drug in c¡ncer treatment.
6) Ca-EDTA

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a) Sodium thio sulphate
c) Cis-platin d) Nickel chloride
6) An example of covalent crystal is
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bsulphur efamond d) rock salt
a) graphite concentration at t = 0,
7) If (A] is the concentration of A at any time t and [A,] is the
then for the first order reaction, the rate equation can be written as ......
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2.303, A
oj k,=2.303 logA
ak-og t A
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2.303 2.303 Ao
c) k, = t
t
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8) CI is the conjugate base of

a) HCIo, )HCI c) CIO, HCIO,
solution,
9) When one coulomb of electricity is passed through an electrolytic
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the mass deposited on the

a) equivalent weight b) molecular weight
c) electrochemical equivalent onegram
10) Dispersion of a solid in a liquid, a liquid in a gas and liquid in a liquid are
a) aerosol, emulsion, sol b) Emulsion, sol, aerosol
c) Aerosol, sol, emulsion d) Sol, aerosol, emulsion
known as
11) The preparation of glycerol and soap frorp oils and fats is
a) esterification )saponification
c) hydroboration d) trans esterification
12) The acid which reduces Tolen's reagent is
a) acetic acid b) benzoic acid formic acid d) oxalic acid
13) When aqueous solution of benzene diazonium chloride is boiled the produ
formed is
a) benzyl alcohol b) phenol
c) benzene + N, d) Phenyl hydroxylamine
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 14) Aproñgwww.Padasalai.Net
the following the achiral anino acid www.TrbTnpsc.com
b) is
2- methylglycjne
a) 2-ethlyaianine d) Tryptophan
)2-hydroxymethylsenne seguence 'ATGCTTGA', then the sequence
15) Tone strand of the DNA has the
of conplementary strand would be d) TACGRAGT
c) TACGTACT
TACGAACT b) TCCGAACT

Part- II
6x2=12
Answet any 6 Questions in short. Q.No. 24 is compulsorY
concentration
U6) Name sorne common mnethods of ore
Z) What re silicones?
18) Mn, Fe have high magnetic moment. Prove it.
(CN),J
19) Write the IUPAC name of the complex. a) [Fe(NH,),
b) (Cr(NH,), (NC),(H,0)}
V0L What is Schottky defect?
2) he reaction A + 2B Cobeys the rate equation. Rate = K[AJi2 (B]2 what
is the order of the reaction?

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buffer
22) Write the Henderson equation for Acidic and Basic
23) Write Short note on SHE
24) How tereylene is prepared.

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Part- III
Answer any 6 Questions in short. Q.No. 30 is compulsory. 6x3=18
25) Explain the following terms with suitable examples. i) Gangue ii) Slag

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26) Differentiate lanthanides and actinides
27) What are interstitial compounds? Give their properties.
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28) What are the limitations of VB Theory.
29) Sketch the (a) Simple cubic (b) face-centred cubic and (c) body centred cubic
lattices.
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30) A first order reaction is 20% completed in 10 minutes

Calculate the time taken for the reaction to go to 80lo completion
31) Explain Lucas test with examples.
32) Write short notes on Gomberg reaction.
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33) What are Lipids? How is it classified?

Part - IV
Answer all the questions in brief. 5x5=25
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r34) Di) Explain froath floation process? (3)

ii) Explain mond's process (2) (OR)
b) i) Write note on structure of diborane. (3)
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i) Explain Fisher - Tropch synthesis. (2)

35) a) ) How will you prepare chlorine using Decon's process. (3)
i) Give the uses of helium. (2) (OR)
o i) Calculate the packing efficiency of B.C.C (3)
i) Write short note on solvate isomerism (2)
36) a) ) Based onVB theory explain why (Cr(NH,),]" is paramagnetic, while
[Ni(CN),P diamagnetic (3)
i) What is anisotropy (2) (OR)
b) ) Derive the relationship between half life period and first order
reaction. (3)
it) What is arhenius equation? (2)
37) a) i) Derive ostawid diution law (3)
i) Explain buffer asction with examples. (2) (OR)
o) Explain the difterence between physical and chemical adsorption
38) a) What is esterification reaction. Write the mechanism (OR)
b) Discuss the structure of FruUctose.
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