Ai2TS-2 (XI) - Test - (18-12-2023) - Final Paper

Ai2TS-2(XI) Date: 18-12-2023
Physics
PART-A(01-06) (Maximum Marks: 24)
• This section contains THREE (06) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of
these four option(s) is(are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : + 4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks : + 1 For darkening a bubble corresponding to each correct options,
provided NO incorrect option is darkened ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks :–2 In all other cases.
• For example, in a question, if (A), (C) and (D) are the ONLY three options corresponding
to correct answers, then
choosing ONLY (A), (C) and (D) will get +4 marks;
choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (A) and (B) will get -2 marks, as wrong option is also darkened
Q1. The potential energy of a particle of mass m at a distance r from a fixed point O is
given by V (r) = kr2/2, where k is a positive constant of appropriate dimensions. This
particle is moving in a circular orbit of radius R about the point O. If v is the speed of
the particle and L is the magnitude of its angular momentum about O, which of the
following statements is (are) true?
k k
(A) v = R (B) v = R
2m m
mk 2
(C) L = mkR2 (D) L = R
2
Q2. A particle of mass m is initially at rest at the origin. It is subjected to a force and starts
moving along the x-axis. Its kinetic energy K changes with time as dK/dt = t, where 
is a positive constant of appropriate dimensions. Which of the following statements is
(are) true?
(A) The force applied on the particle is constant
(B) The speed of the particle is proportional to time
(C) The distance of the particle from the origin increases linearly with time
(D) The force is conservative
Q3. A point mass of 1 kg collides elastically with a stationary point mass of 5 kg. After
their collision, the 1 kg mass reverses its direction and moves with a speed of 2 ms −1.
Which of the following statement(s) is (are) correct for the system of these two
masses?
(A) Total momentum of the system is 3 kg ms−1
(B) Momentum of 5 kg mass after collision is 4 kg ms−1
(C) Kinetic energy of the centre of mass is 0.75 J
(D) Total kinetic energy of the system is 4J
Q4. Two balls, having linear momenta p1 = piˆ and p2 = −piˆ , undergo a collision in free
space. There is no external force acting on the balls. Let p1' and p'2 be their final
momenta. The following option(s) is (are) NOT ALLOWED for any non-zero value of
p, a1, a2, b1, b2, c1 and c2.
(A) p' = a î + b ˆj + c kˆ (B) p' = c kˆ
1 1 1 1 1 1
ˆ
p = a i +b j
' ˆ p = c kˆ
'
2 2 2 2 2
1
(C) p1' = a1î + b1ˆj + c1kˆ (D) p1' = a1î + b1ˆj
p'2 = a2 î + b2 ˆj − c1kˆ p'2 = a2 î + b1ˆj
V
Q5. Two blocks A and B each of mass m are connected L
by a massless spring of natural length L and spring C A B
constant K. The blocks are initially resting on a
smooth horizontal floor with the spring at its natural
length, as shown in figure.
A third identical block C, also of mass m, moves on the floor with a speed v along the
line joining A and B, and collides elastically with A. Then
(A) The kinetic energy of the A-B system at maximum compression of the spring, is
zero
(B) The kinetic energy of the A-B system, at maximum compression of the spring, is
mv2/4
(C) The maximum compression of the spring is v (m / K )
(D) The maximum compression of the spring is v (m / 2K )
Q6. A ball hits the floor and rebounds after an inelastic collision. In this case,
(A) the momentum of the ball just after the collision is the same as that just before the
collision.
(B) the mechanical energy of the ball remains the same in the collision.
(C) the total momentum of the ball and the earth is conserved.
(D) the total energy of the ball and the earth is conserved
PART-C( 01-06) (Maximum Marks: 18)

• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER, ranging from 0 to 9.
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered.
Negative Marks : –1 In all other cases.
Q1. A bomb of mass 9 kg explodes into two fragments of masses 3 kg and 6 kg. The
velocity of mass 3 kg is 16 m/sec. The energy of explosion in mechanical form is
x
equal to x Joule. The value of is…………
96
Q2. A umbbell consisting of two masses of mass m each, connected m m
by a light rigid rod of length , falls on two pads of equal height
(one steel and the other brass) through a height h = 16m. The co-
efficients of restitution are e1 = 0.6 and e2 = 0.4 (e1 < e2). To what h
maximum height ( in metre) will the centre of mass of the umbbell
rise after bouncing off the pads?
brass Steel
e1 e2
Q3. Consider an elliptically shaped rail PQ in the vertical plane with OP Q

= 3 m and OQ = 4 m. A block of mass 1 kg is pulled along the rail
from P to Q with a force of 18 N, which is always parallel to line PQ
(see the figure given). Assuming no frictional losses, the kinetic 4m
energy of the block when it reaches Q is (n×10) Joules. The value 90°
of n is (take acceleration due to gravity = 10 ms–2)
O 3m P
2
Q4. A particle of mass 0.2 kg is moving in one dimension under a force that delivers a
constant power 0.5 W to the particle. If the initial speed (in m/s) of the particle is
zero, the speed (in m/s) after 5 s is ……….
Q5. The magnitude of the force (in Newton) acting on a C
800
body varies with time t (in microseconds) as shown in
the figure. AB, BC and CD are straight line segments. 600
The magnitude of the total impulse of the force on the 400

body from t = 4 s to t= 16 s is ……… 10−3 Ns.
Force N
A B
200
E D
F
O 2 4 6 8 10 12 14 16
Time(S)
Q6. A bob of mass m , suspended by a string of length 1 is given a minimum velocity

required to complete a full circle in the vertical plane. At the highest point, it collides
elastically with another bob of mass m suspended by a string of length 2 , which is
initially at rest. Both the strings are mass-less and inextensible. If the second bob,
after collision acquires the minimum speed required to complete a full circle in the
1
vertical plane, the ratio is………………..
2

• This section contains SIX (06) questions. The answer to each question is a
NUMERICAL based questions.
• The answer may be positive or negative numbers or decimals ( e.g. 6.25, 7.00, -3.00
, 30.27, -127.30). If the numerical value has more than two decimal places,
truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking
scheme:
Full Marks : +4 If ONLY the correct numerical value is entered;
Zero Marks : 0 In all other cases.
Q7. A particle slides along a track with elevated ends and a flat A
D
central part as shown in the figure. The flat part has a length 
h
= 3 m. The curved portions of the track are frictionless. For
the flat part, the coefficient of kinetic friction is K = 0.2. The B C
E
particle is released at point A which is at height h = 1.5 m
above the flat part of the track. The particle finally comes to 
rest at point-E. The distance BE ( in metre) is………
Q8. An advertisement claims that a certain 1200 kg car can accelerate from rest to a
speed of 25 m/s in a time of 8 s. What average power ( in kW) must the motor
produce to cause this acceleration ? (Ignore friction losses)
Q9. A dog of mass 10 kg is standing on a flat 10 m long boat so that

it is 20 meters from the shore. It walks 8 m on the boat towards
the shore and then stops. The mass of the boat is 40 kg and
friction between the boat and the water surface is negligible. 20 m
How far ( in metre) is the dog from the shore now?
Q10. An explosion blows a rock in to three parts. Two pieces of mass 1 kg and 2 kg go off
at right angle to each other; 1 kg piece with a velocity of 12 m/sec and 2 kg piece with
a velocity of 8 m/sec. The third piece flies off with a velocity 40 m/sec. Compute the
mass ( in kg) of third part of rock.
Q11. A rubber ball is dropped from a height of 5 m on a planet where the acceleration due
to gravity is not known. On bouncing, it rises to 1.8 m. Find the ratio of velocity of the
ball just after and before the collision.
3
Q12. A particle is moved along a path AB-BC- y
CD-DE-EF-FA, as shown in figure, in
( )
A B
presence of a force F = yiˆ + 2xjˆ N , 1.0
where x and y are in meter and  = – 1 Nm–

1. The work done on the particle by this D
0.5 C
force F will be ……………Joule.
F E
x
0 0.5 1.0
4
Chemistry
Q1. Which of the following statements is/are correct ?

(A) Group 12(IIB) elements do not show characteristic properties of transition metals
(B) Among transition elements, tungsten has the highest melting point
(C) Among transition elements, group 3 (IIIB) elements have lowest densities
(D) Transition metals are more electropositive than alkaline earth metals. [A,B,C]
Q2. Which of the following trends of ionic radii are correct ?

(A) F¯ > Na+ > Mg2+ (B) Al3+ > O2– > N3+
(C) P3 > S2– > Cl– (D) H– > H+ > He+
–
Q3. The statements that are true among the followings are-
(A) The bond order in CO molecule is 3
+
(B) The order of stability is O2– –
2 > O2 > O2 > O2
(C) KHF2, KHCl2 and KHBr2 are known but KHI2 is not
(D) NO is paramagnetic while NO+ is diamagnetic
Q4. Li does not resemble other alkali metals in following properties -

(A) Li2CO3 decomposes into oxides while other
alkali carbonates are thermally stable
(B) LiCl is predominantly covalent
(C) Li3N is stable
(D) LiCl is non-conducting in molten state
Q5. Choose the correct statement(s) regarding Na2O2 -

(A) is diamagnetic in nature
(B) is salt of dibasic acid H2O2
(C) oxidizes Cr3+ (green) to CrO 24 − (yellow)
(D) is paramagnetic in nature
Q6. Among KO2, AlO2– , BaO2 and NO2+ , unpaired electron is present in -
(A) NO2+ , (B) BaO2
(C) KO2 (D) AlO2–
5
Q1. How many statement of the followings are false

(I) AlCl3 exists as Al2Cl6 in vapour state
(II) All the Al-Cl bonds in Al2Cl6 are equivalent
(III) Borax when heated with Ammonium chloride forms ammonium tetraborate
(IV) AlF3 is a high m.pt. solid while AlCl3 is a low m.pt volatile solid
Q2. The number of resonating structures exist for the azide ion, N3– are ……………
Q3. In H2O (s) one H2O molecule is surrounded by ……… other H2O molecules by
hydrogen bonds.
Q4. On heating CaC2O4 , ………type of gases are produced
Q5. IE1 and IE2 of Mg are 178 and 348 kcal mol−1. The energy required for the
x
→Mg2+ + 2e− is x, then the value of
reaction Mg ⎯⎯
526
Q6. The enthalpy of sublimation of aluminium is 330 kJ/mol. Its I st, IInd and IIIrd ionization
enthalpies are 580, 1820 and 2740 KJ respectively. If heat has to be supplied to
convert 13.5 gram of aluminium into Al3+ ions and electrons at 298 K is x kJ, then
x
is……
547

scheme:
Q7. Proton affinity is the enthalpy change due to acceptance of 1 mole of H + (g) by a
species. Determine the proton affinity of NH3 (g) from the following data in kcal/mol .
LE of NH4 F (s) = – 181 kcal/mol
Dform of NH4 F (s) = –112 kcal/mol
Dform of NH3 (g) = –280 kcal/mol
Datom of H2 (g) = 104.2 kcal/mol
IE of H (g) = 311.9 kcal/mol
Datom H (F2 ,g) = 37.8 kcal/mol
Deg H (F,g) = –79.6 kcal/mol
6
Q8. The observed dipole moment of H 2O = 1.85 D. The H – O bond distance is 0.94 Å
and HOH bond angle is 105º.
cos 52.5º = 0.609 ; cos 105º = – 0.26
Determine the percentage fractional charges on each oxygen atom in terms of charge
of electron.
Charge of electron = 4.8 × 10–10 e. s. u.
Q9. The crystal structure of LiI and KI are shown below
Li+ I– K+ I–
I– I–
Li+ I– Li+ 6Å K+ I– K+ 7.2Å
– –
I I – –
Li+ I K+ I
Determine the radius of K+ in pm.
1
Q10. Given : H2 (g) →H (g), H = 50 kcal/mole
2
PH3 (g) →P (g) + 3H (g). H = 243 kcal/mole
Determine P-P bond dissociation energy in kcal / mol
Q11. Ionisation potential and electron affinity of fluorine are 17.42 eV and 3.48 eV
respectively. Determine the electronegativity of fluorine on Mlliken scale. [10.45]
Q12. 10 mL of H2O2 solution on treatment with KI and titration of liberated I 2, required 10

mL of 1N hypo. If the volume strength of H2O2 is x volume, then the value of x
is……..
7
Mathematics
2 2 2 2
Q1. Consider the circles x + y = 1 & x + y – 2x – 6y+6 = 0. Then equation of a common
tangent(s) to the two circles is/are
(A) 4x – 3y – 5 = 0 (B) x + 1 = 0 (C) 3x + 4y – 5 = 0 (D) y – 1 = 0
2 2
Q2. The equation( s) of a circle with centre (4, 3) and touching the circle x + y = 1 is/are
2 2 2 2
(A) x + y – 8x – 6y – 9 = 0 (B) x + y – 8x – 6y + 11 = 0
2 2 2 2
(C) x + y – 8x – 6y – 11 = 0 (D) x + y – 8x – 6y + 9 = 0
Q3. Point M moved along the circle (x – 4)2 + (y – 8)2 = 20. Then it broke away from it
and miving along a tangent to the circle, cuts the x-axis at the point (–2, 0). The co-
ordinates of the point( s)on the circle at which the moving point broke away can be
 3 46   2 44 
(A)  − ,  (B)  − ,  (C) (6, 4) (D) (3, 5)
 5 5   5 5 
Q4. If p and q are odd integers, then the equation x2 + 2px +2 q = 0

(A) has no integral roots (B) has no rational roots
(B) has no irrational roots (D) has no imaginary roots.
Q5. Consider the equation x2 +x – a = 0, a  N. If equation has integral roots then

(A) a = 2 (B) a = 6
( C) a = 12 (D) a = 20
Q6. If a1, a2, …. an, (ai  R+) are in A.P. with common difference d, then
1 + a1a 2  1 + a 2 a 3  1 + a 3 a 4  1 + a n a n−1 
cot −1   + cot −1   + cot −1   + …. + cot −1   is
 d   d   d   d 
equal to
(A) tan–1an - tan–1a1 (B) cot–1a1 + cot–1an
(C) cot–1a1 - cot–1an (D) None

Q1. The least integral value of k such that (k –2)x2+ 8x +k + 4 is positive for all real
values of x is …………..
8
Q2. If all the real solutions of the equation 4x – ( a – 3)2x + ( a – 4) =0 are non positive,
then the maximum value of a is ………
Q3. Let p, q, r  R+ and 27pqr  (p + q + r)3 and 3p + 4q + 5r = 12 then p3 + q4 + r5 is

equal to ……………….
Q4. The weighted arithmetic mean of first 10 natural numbers whose weights are equal to
the corresponding numbers is equal to………
Q5. The smallest value of k, for which both the roots of the equation x 2 − 8kx + 16(k2 − k +
1 ) = 0 are real, distinct and have values at least 4, is….
Q6. The sides of a right angled triangle are in arithmetic progression. If the triangle has
area 24, then the length of its smallest side is………….

scheme:
Q7. The value of 40 2 − 57 − 40 2 + 57 is equal to …………
Q8. If xi > 0, i = 1, 2, …., 50 and x1 + x2 + …. + x50 = 50, then the minimum value of
1 1 1 k
+ + ... + equals to k. The value of is…………..
x1 x 2 x 50 4
Q9. If roots of the equation x2 − 10cx − 11d = 0 are a, b and those of x2 − 10ax − 11b = 0
k
are c, d, then the value of a + b + c + d is k. The value of is ………………………
100
(a, b, c and d are distinct numbers)
Q10. Let AP(a; d) denote the set of all the terms of an infinite arithmetic progression with
first term a and common difference d > 0. If AP(1; 3)  AP(2; 5)  AP(3; 7) = AP (a;
d) then a + d equals………….
Q11. The centres of two circles C1 and C2 each of unit radius are at a distance of 6 units
from each other. Let P be the mid point of the line segment joining the centres of C 1
and C2 and C be a circle touching circles C1 and C2 externally. If a common tangent
to C1 and C passing through P is also a common tangent to C2 and C. If the radius of
k
the circle C is k,then value of is ………………………
5
Q12. Let the point B be the reflection of the point A(2, 3) with respect to line 8x – 6y – 23 =
0. Let A and B be circles of radii 2 and 1 with centres A and B respectively. Let T be
a common tangent to the circles A and B such that both the circles are on the same
side of T. If C is the point of intersection of T and the line passing through A and B,
then the length of the line segment AC is ………..
9
ANSWER:
PHYSICS CHEMISTRY MATHEMATICS
PART-A PART-A PART-A
Ans1. B,C Ans1. A,B,C Ans1. A,B, C, D
Ans2. A,B,D Ans2. A, C Ans2. C,D
Ans3. A,C Ans3. A,B Ans3. B,C
Ans4. A, D Ans4. A,B,C Ans4. A,B
Ans5. B,D Ans5. A,B,C Ans5. A,B,C,D
Ans6. C,D Ans6. C Ans6. A, C
PART-C PART-C PART-C
Ans1. 6 Ans1. 2 Ans1. 5
Ans2. 4 Ans2. 3 Ans2. 5
Ans3. 5 Ans3. 2 Ans3. 3
Ans4. 5 Ans4. 1 Ans4. 7
Ans5. 5 Ans5. 1 Ans5. 2
Ans6. 5 Ans6. 5 Ans6. 6
Ans7. 1.50 Ans7. 45.70 Ans7. -10.00
Ans8. 46.90 Ans8. 67.20 Ans8. 12.25
Ans9. 13.60 Ans9. 147.90 Ans9. 12.10
Ans10. 0.50 Ans10. 65.61 Ans10. 157.00
Ans11. 0.60 Ans11. 10.45 Ans11. 1.60
Ans12. 0.75 Ans12. 5.60 Ans12. 10.00
10
SOLUTION:
PHYSICS
PART-A
kr 2 dV
Sol1. V= F= − = −kr
2 dr
mv 2 k
 = kr  v = R
r m
k 2
Angular momentum L = mvr = m R = mkR2
m
dK t 2
Sol2. = t , So K =
dt 2
1 t 2 
mv 2 = or v = t
2 2 m
dv 
=
dt m
F = m
(i) force is constant.
(ii) speed is proportional to t
(iii) Force is constant, so it is conservative
Sol3.
By conservation of linear momentum 1 kg 5 kg 2 m/s 5 kg
u = 5v − 2 …(i) u v
By Newton’s experimental law of collision
before collision after collision
u=v+2 …(ii)
using (i) and (ii) we have
v = 1 m/s and u = 3 m/s
1 2
Kinetic energy of the centre of mass = msystem vcm = 0.75 J
2
Sol4. P = P1 + P2 = P1 + P2
Fext = 0
P =0
Sol5. As mass of A and C are same so, after collision C stops and A moves with a velocity
v. At maximum compression, block A and block B will move with same velocity v.
Applying conservation of momentum
mv+mv=mv
v
 v =
2
1 1 1
 K.E. of system = mv 2 + mv 2 = mv 2
2 2 4
Let x is compression of spring at maximum compression. Using conservation of
energy
1 1 1 m
mv 2 + kx2 = mv 2  x = v
4 2 2 2k
Sol6. Momentum of the colliding system remains conserved.
Some energy gets converted to heat and sound therefore energy of the system (ball
and earth) will not be conserved.
PART-C
Sol1. Conservation of momentum just before and after the impact yields
pi = pf
 0 = m1v1 + m2v2  m1 v1 = m2 v2 = p (say)
11
p2 p2 p2  m1 
 Energy of explosion =  K.E.system = + = 1 + 
2m1 2m2 2m1  m2 
Putting p = m1 v1, and m1 = 3 kg, M2 = 6 kg , v = 16 m/sec, we obtain,
(3  16)2  3 
E= 1+  E = 576 J.
2 3  6 
Sol2. The centre of mass of the system after collision will move up with velocity
( e1 + e2 ) 2gh
2
 ( e + e2 ) ( e + e2 ) h
2 2

0=  1 2 gh  − 2gh , h = 1
 2  4
Sol3. Using work energy theorem
Wmg + WF = KE
– mgh + Fd = KE
–1×10×4 + 18(5) = KE
KE = 50
n=5
dW
Sol4. Power = W = 0.5  5 = 2.5 = KEf – KEi
dt
M 2
2.5 = (v f − vi2 )  vf = 5
2
Sol5. The magnitude of the total impulse of the force on the body form t = 4 s to t= 16 s =
Area EBCD
= Area of trapezium EBCFE + Area of CFD
1 1
=  (200 + 800)  2  10−6 +  800  10  10−6 = 5  10−3 N -s
2 2
Sol6. The initial speed of 1st bob (suspended by a string of length 1 )is 5g 1 .
The speed of this bob at highest point will be g 1 .
When this bob collides with the other bob there speeds will be interchanged.
g 1 = 5g 2  1
=5
2
Sol7. The particle will finally come to rest on the flat part. Hence, displacement of the
particle along vertical is h. If Wg be the work done on the particle by the gravity, then
Wg = mgh where m = mass of the particle. …( 1)
If distance travelled by the particle on the flat part is x, the work done on the particle
by the friction is
Wf = −mgx …( 2)
Since initially particle was at rest and finally it comes to rest again. Hence, change in
its K.E. is zero.
From work–energy theorem
Wg + Wf = K.E.
 mgh − mgx = 0
h 1.5
 x= = m
 0.2
 x = 7.5 m
Since x > , the particle will reach C and then will rise up till the remaining K.E. at
C is converted into potential energy. It will then again descend to C and will have the
same kinetic energy as it had when ascending but now will move from C to B. At B,
same thing will be repeated (because 7.5 > 2) and finally, the particle will stop at E
such that
BC + CB + BE = 7.5
12
BE = 7.5 − 6 = 1.5 m
Sol8. The work done in accelerating the car is given by

W = K = m ( v 2f − vi2 ) = (1200)[(25)2 − 0]
1 1
2 2
or W = 375 kJ
W 375
Power = = = 46.9kW
t 8
Sol9. Take boat and dog as a system. Initially, centre of mass of the system is at rest.
Since no external force is acting on the system, hence centre of mass of the system
will remain stationary.
Let initially distance of the centre of mass of the boat from the shore be x m. Then,
40  x + 10  20
x1c.m. = m . . . (i)
40 + 10
where x1.cm. = distance of the C.M. of the system from the shore. Since dog moves
towards the shore, for the centre of mass of the system to be at rest, the boat has to
move away from the shore. Let distance moved by the boat be x. Then,
40 ( x + x ' ) + 10 ( 20 − 8 + x ' )
x2c.m. =
40 + 10
As x1c.m. = x2c.m.
40x + 200 40 ( x + x ' ) + 10 (12 + x ' )
 =
50 50
 50x = 80  x = 1.6 m.
Hence, distance of the dog from the shore is (20 − 8 + 1.6) m = 13.6 m
Second Method:
As there is no external force acting on the system (dog +
boat) along the x-axis and initially centre of mass of the X
system is at rest, therefore the motion of the dog will not
change x-coordinate of the centre of mass of the system
20 m Y
m x + mb xb
i.e. Xcm = d d =0 . . . (i)
mb + md
Let the displacement of boat be s î .
The displacement of the dog with respect to boat,  rd, b = − î
The displacement of the dog,
 rd = rd, b + rb = − î + siˆ = (− + s)iˆ
From (i),
md 10  8
md (− + s) î + mbs î = 0s = = = 1.6 m
(md + mb ) (10 + 40)
hence position of dog from the shore
L = L + rd = 20 î + (−8 + 1.6)iˆ = 13.6 î .
13
Sol10.
Initial momentum = 0
Along x – axis : –
V2m2
0 = m1v1 – m3v3cos …(1)
Along y – axis : –
0 = m2v2 – m3v3sin ……(2)
from (1) & (2); squaring and adding •
 V1m1
m12v12 + m22v22 = m32v32
v3m3
m12v12 + m22v 22 12  122 + 22  82 1
m3 = = = kg
v 32 402 2
Sol11. A ball dropped from a height h1 on reaching the planet’s surface will have a velocity
given by v1 = 2gh1 , where g is acceleration due to gravity on the planet’s surface.
Let v2 be the velocity with which the ball bounces. It will attain a height h 2 given by
v h2 1.8
v2 = 2gh2  2 = = = 0.6
v1 h1 5
1
Sol12. WAB =  ydx = −1
0
0.5
WBC =  2xdy = +1
1
0.5
WCD =  ydx = +0.25
1
0
WDE =  2xdy = +0.5
0.5
WEF = wFA = 0
Wnet = 0.75
14
CHEMISTRY
PART-A
Sol1. Option A: - Transition elements are elements that have partially filled d-orbitals. While
in group 12 (11B) d- orbital is completely filled
 It shows difference in properties.
Option B: - Tungsten has highest melting point
Option C: - Sc has lowest density
Option C:- Transition elements have more zeff, outer shell electrons experience more
attraction from nucleus
 S- block elements are more electropositive.
Sol2. The correct options are:

(A) F−  Na+  Mg+2
(C) P3 −  S2 −  Cl−
In option (A) & (C) all the species are iso-electronic & in iso-electronic species, the
ionic radii decreases with increase in atomic number.
Sol3. Bond order O2–2 = 1

O2– = 1.5
O2 = 2
O2+ = 2.5
 stability ; O2+ > O2 > O2– > O2–2
Sol4. Only Li2CO3 is decomposed

Li2CO3 ⎯⎯→ Li2O + CO2
Sol5. Na2O2 has peroxide ion O 22 − (18e–).
It has all paired electrons and is thus diamagnetic.
H2O2 → 2H+ + O 22 −
Thus, it is also salt of dibasic acid H2O2 . Cr3+ is oxidised to CrO 24 − in acidic medium
Cr3+ + O 22− + 2H+ → CrO 24 − + H2O
Sol6. KO2 is paramagnetic due to presence of unpaired electron in O2– (Super oxide).
PART-C
Sol1. Option II & III are false
In Al2Cl6, four chlorine atoms (terminal) are equivalent and two chlorine atoms form
bridges through coordination between two aluminium atoms. These are different from
terminal chlorine atoms. Borax when heated with NH4Cl forms boron Nitride and boric
anhydride. Anhydrous AlCl3 hydrolyses in moist air and gives fumes of HCl.
Sol2. Resonating structures of N3– are
.. .. .. .. –
[:N = N = N:]– . . – N  N:]
[:N –
[:N  N – .N:]
.
Sol3. H-bonded structure of H2O(s) is
15
H H H
O O O
H H H

Sol4. CaC2O4 ⎯⎯→ CaCO3 + CO(g)
→Mg(g) + e− , IE1 = 178kcalmol−1
Sol5. (i) Mgf(g) ⎯⎯
(ii) Mg(g) ⎯⎯
→Mg2+(g) + e− , IE2 = 348kcalmol−1
Adding (i) and (ii) we have
→Mg2+(g) + 2e−
Mg(g) ⎯⎯
 E − IE2 + IE2 = 178 + 348 = 526kcal
Sol6. Heat needed to be supplied per mole
= 330 + 580 + 1820 + 2740 = 5470 kJ
13.5
no. of moles of Al taken = = 0.5 mol
27
Heat required = 0.5 × 5470 kJ = 2735 kJ
1 1
Sol7. N2 (g) + 2H2 (g) + F2 (g) ® NH4 F (s) DH = –112
2 2
1 3
N2 (g) + H2 (g) ® NH3 (g) DH = –280
2 2
NH3(g) + (1/2) H2 (g) + (1/2) F2(g) ⎯→ NH4F (s) H = + 168
52.1 18.9
H (g) F(g)
311.9 –79.6
NH3(g) H+(g)
–
F (g) LE = –181
PA
–
F (g)
+
NH4 (g)
52.1 + 18.9 + 311.9 – 79.6 + PA – 181 = 168

or 122.3 + PA = 168
or PA = 45.7 kcal/mol
Sol8.
–
2
µO-H O µO-H
 +H H +
Resultant dp moment
= 2 µ 2 O − H + 2  µ 2 O − H  cos 105º
16
= 2  µ 2 O − H −  2  µ 2 O − H  0.26
= 2 × µO–H × 0.74 = 1.216 × µO–H

1.85
 µO–H = = 1.52 D = 1.52 × 10–18 esu-cm.
1.216
 µO–H) cal = 4.8 × 10–10 × 0.94 × 10–8
= 4.8 × 0.94 × 10–18 esu-cm
1.52
 fractional negative charge on oxygen atom for each O – H bond = = 0.336
4.8  0.94
 total fractional negative charge on oxygen atom = 0.336 × 2 = 0.672
 % fractional negative charge on oxygen atom = 67.2 %
Sol9. In LiI anion-anion contact along the diagonal is maintained.

 4rI– = 6 2 Å
6 2 61.414
or rI– = = = 2.121 Å
4 4
In KI cation-anion contact is maintained along the edge.
2rK+ + 2rI– = 7.2Å
or rK+ + rI– = 3.6Å
 rK+ = 3.6 – 2.121 = 1.479 Å = 1.479 × 10–10 m = 147.9 × 10–12 m = 147.9 pm
Sol10. DH –H = 100 kcal/mol
243
DP –H = = 81 kcal/mol
3
Xp – XH = 0.208  ; X stands for electronegativity
Since XP = XH , hence  = 0
 = DP–H – (D P−P )(D H−H ) = 0
or D2 P–H = DP–P × DH–H
D 2 P −H 81 81
or DP–P = = = 65.61 kcal/mol
D H −H 100
(IE + EA)
Sol11. (XF)M = where IE and EA both are taken in eV.
2
17.42 + 3.48
 (XF)M = =10.45
2
–
Sol12. H2O2 + 2I → I2
I2 + 2S2O 32 – → S4O 62 – + 2I–
H2O2  I2 2S2O 32 –
N1V1 = N2V2
H2O2 hypo
101
N1(H2O2) = = 1N
10
Conc. = N × E = 17 g/litre
Volume strength = 5.6 × normality= 5.6 × 1 = 5.6 volume
17
MATHEMATICS
PART-A
Sol1. x2 + y2 = 1 center (0, 0), radius 1
x2 + y2 -2x -6y + 6 = 0 center (1, 3) radius 2
dividing (0, 0), (1, 3) in the radio 1 : 2
internally and externally
the points are (1/3, 1) and (-1, -3)
 1
Let a tangent by y − 1 = m  x −  i.e. 3mx – 3y + 3 – x = 0
 3
3− m
Then =1
9m 2 + 9
i.e 9 + m 2 − 6m = 9m 2 + 9
i.e 9m 2 + 6m = 0 m = 0, m = -3/4
9 3
 tangent are y = 1 and − x − 3 y + 3 + = 0
4 4
i.e y = 1 and 3x + 4y – 5 = 0
Again let equation of common tangent through (-1, -3) be y + 3 = m(x + 1)
i.e. mx – y + m – 3 = 0
m−3
 =1 i.e m 2 − 6m + 9 = m 2 + 1
m +1
2
m = 4/3
4 4
 common tangent to are x = -1 and x− y + −3= 0
3 3
i.e x = -1 and 4x – 3y – 5 = 0
Sol2. Distance between (4, 3) and (0, 0) is 5
Radius of the circle x2 + y2 = 1 is 1
 radii of the required circles are 4, 6
 Equations of the circles are
(x – 4)2 + (y – 3)2 = 16, 36
i.e x2 + y2 – 8x – 6y + 9 = 0 or x2 + y2 -8x – 6y – 11 = 0
Sol3. x2 + y2 – 8x – 16y + 60 = 0
Equation of chord contact from (-2, 0)
-2x – 4(x – 2) – 8y + 60 = 0
-6x – 8y + 68 = 0
3x + 4y – 34 = 0
2
 34 − 3x   34 − 3 x 
x +
2
 − 8 x − 16   + 60 = 0
 4   4 
16x2 + 1156 – 204x + 9x2 – 128x – 2176 + 192x + 960 = 0
25x2 – 140x – 60 = 0
5x2 – 28x – 12 = 0
28  784 + 240 28  1024
x= =
10 10
28  32 2
= = 6, −
10 5
 2 44 
(6, 4),  − , 
 5 5 
Sol4. x can not be odd integer for if x is odd, x2 is odd but 2px + 2q is even;
so x2+2 px + 2q  0
x can not be even integer for if x is even, x2 +2 px is a multiple of 4 but 2q is
not.
So x2 + 2px + 2q  0
Also (x +p)2 = p2 – 2q
18
 If x is fraction then (x +p)2 is also a fraction but p2 –2q is an integer. So, roots
cannot be integer or rational numbers.
Sol5. Discriminant, D= 1+ 4a
 1+4a should be a perfect square.
As 1+4a is always odd
 1+4a = (2+1)2, I+
 a= (+1).
1 + a1a 2  −1  1 + a 2 a 3  −1  1 + a 3 a 4  1 + a n a n−1 
Sol6. cot −1   + cot   + cot   + …+ cot–1  
 a 2 − a1   a3 − a2   a4 − a3   a n − a n −1 
= cot-1a1 – cot-1a2 + cot-1a2 – cot-1a3 + . . . + cot-1an-1 – cot-1an
= cot–1a1 – cot–1an = tan–1an – tan–1a1
PART-C
Sol1. For ( k-2) x2 + 8x +k +4 > 0
(k-2 ) > 0 and (8)2 – 4( k-2)( k +4) < 0
i.e. k > 2 . . . . (1)
and 24 – k2 – 2k < 0
i.e. k2 +2k – 24 > 0
i.e. ( k+6) ( k-4) > 0
 k < -6 or k > 4 . . . . . (2)
From (1) and (2), we have k > 4 .
 The least integral value of k = 5 .
a−3 (a − 3 )2 − 4(a − 4 )
Sol2. 2x = =a – 4 , 1
2
It is given that roots are non-positive
i.e x  0  2x  1
 0 < 2x  1  4 < a  5 .
p+q+r 
Sol3. 27 pqr  (p + q + r)3  (pqr)1/3   
 3 
p=q=r
Also 3p + 4q + 5r = 12  p = q = r = 1.
1.1 + 2.2 + .... + 10 .10
Sol4. Weighted mean =
1 + 2 + ... + 10
=
(10 )(10 + 1)(2  10 + 1)/ 6 = 7
(10 )(10 + 1)/ 2
Sol5.
x2 − 8kx + 16 (k2 − k + 1) = 0
D > 0  k > 1… ( 1)
−b 8k
4  4
2a 2 4
 k > 1……… ( 2)
f (4)  0  16 − 32 k + 16 (k2 − k + 1)  0
k2 − 3k + 2  0
k  1  k  2…..… ( 3)
Using (1), (2) and (3)
kmin = 2.
Sol6. Let sides be a – d, a, a + d, (d > 0)
 a2 + (a – d)2 = (a + d)2a = 4dsides are 3d, 4d, 5d
As area is 24
1
  3d  4d = 24 d = 2
2
 sides are 6, 8, 10smallest side is 6.
19
Sol7. 
I2 = 57 − 40 2 + 57 + 40 2 − 2 (57 ) − 80  40
2

1/ 2
= 114 – 2 { 2500 + 49 + 700 – 3200 }1/2

= 100  I = –10, as I is negative.
 1 1 1 
Sol8. We have (x1 + x2 + x3 + …. + x50 )  + + ... +   (50)2
 x1 x 2 x 50 
[ since A.M.  H.M. ]
 1 1 1 
  + + ... +   50.
 x1 x 2 x 50 
Sol9. As a + b = 10c and c + d = 10a
ab = −11d , cd = −11b
 ac = 121 and (b + d) = 9(a + c)
a2 − 10ac − 11d = 0
c2 − 10ac − 11b = 0
 a2 + c2 − 20ac − 11(b + d) = 0  (a + c) = 121 or −22 (rejected)
 a + b + c + d = 1210.
Sol10. AP (1, 3)  {1, 4, 7, 10, ....} = {n / n = 3k + 1, k  W}

AP (2, 5)  {2, 7, 12, .... } = {n / n = 5k + 2, k  W}
AP (3, 7)  {3, 10, 17, ...} = {n / n = 7k + 3, k  W}
Let common term is M
M  1 (mod 3), M  2(mod 5), M  3(mod 7)
 M  52(mod 105)
so a = 52, d = 105 and a + d = 157
Sol11.
C1
2 2
cos =
3
C2
1 2 2
sin =
3 A P 1


2 2 3
tan = B
R
2 2
R= = 8 units.
tan  R 
Alternate:
(R + 1)2 = (R – 1)2 + ( 4 2 )
2
 R = 8.
C
Sol12.
APC and BQC are similarly T P
BC 1
= Q
AC 2 r=2
 2(AC – AB) = AC r=1
A R B C
AC = 2AB = 10
8x – 6y – 23 = 0
AR = 5/2, AB = 5
20
21

Ai2TS-2 (XI) - Test - (18-12-2023) - Final Paper

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Ai2TS-2 (XI) - Test - (18-12-2023) - Final Paper

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Ai2TS-2(XI) Date: 18-12-2023

PART-C( 01-06) (Maximum Marks: 18)

Q3. Consider an elliptically shaped rail PQ in the vertical plane with OP Q

The magnitude of the total impulse of the force on the 400

Q6. A bob of mass m , suspended by a string of length 1 is given a minimum velocity

PART-C( 07-12) (Maximum Marks: 24)

Q9. A dog of mass 10 kg is standing on a flat 10 m long boat so that

where x and y are in meter and  = – 1 Nm–

Q1. Which of the following statements is/are correct ?

Q2. Which of the following trends of ionic radii are correct ?

Q4. Li does not resemble other alkali metals in following properties -

Q5. Choose the correct statement(s) regarding Na2O2 -

Q1. How many statement of the followings are false

Q4. On heating CaC2O4 , ………type of gases are produced

PART-C( 07-12) (Maximum Marks: 24)

Q9. The crystal structure of LiI and KI are shown below

Determine the radius of K+ in pm.

Q12. 10 mL of H2O2 solution on treatment with KI and titration of liberated I 2, required 10

Q4. If p and q are odd integers, then the equation x2 + 2px +2 q = 0

Q5. Consider the equation x2 +x – a = 0, a  N. If equation has integral roots then

PART-C( 01-06) (Maximum Marks: 18)

Q3. Let p, q, r  R+ and 27pqr  (p + q + r)3 and 3p + 4q + 5r = 12 then p3 + q4 + r5 is

PART-C( 07-12) (Maximum Marks: 24)

Q7. The value of 40 2 − 57 − 40 2 + 57 is equal to …………

Sol8. The work done in accelerating the car is given by

Sol2. The correct options are:

Sol3. Bond order O2–2 = 1

Sol5. Na2O2 has peroxide ion O 22 − (18e–).

It has all paired electrons and is thus diamagnetic.

Cr3+ + O 22− + 2H+ → CrO 24 − + H2O

NH3(g) + (1/2) H2 (g) + (1/2) F2(g) ⎯→ NH4F (s) H = + 168

52.1 + 18.9 + 311.9 – 79.6 + PA – 181 = 168

= 2 × µO–H × 0.74 = 1.216 × µO–H

Sol9. In LiI anion-anion contact along the diagonal is maintained.

= 114 – 2 { 2500 + 49 + 700 – 3200 }1/2

Sol10. AP (1, 3)  {1, 4, 7, 10, ....} = {n / n = 3k + 1, k  W}

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