Enthusiast/Phase-1/20-12-2023/Paper-2

(4602CJA101021230016) Test Pattern

CLASSROOM CONTACT PROGRAMME JEE (Advanced)

FULL SYLLABUS
(Academic Session : 2023 - 2024)
20-12-2023

JEE(Main + Advanced) : Enthusiast (PHASE : 1)

Test Type : Unit Test # 01
PAPER-2

HINT – SHEET
PART-1-PHYSICS 4. Ans ( A,C,D )
SECTION-I(A) 122.4
Z=√ =3
13.6
1. Ans ( A,B,D ) (Eex)min = 9 × 10.2
W = Δ K. E. = 91.8 eV
1
qE(2a) = m [(2v)2 − v2 ]
For KEinitial = 125 eV
2 KEfinal = 2.6 eV
3mv2
E= Er = 122.4 eV = E1→3
4aq
Rate of workdone at P = PART-1-PHYSICS
→ . →v = qEv cos 0∘ = 3mv3
F SECTION-I(B)
4a
Rate of workdone at Q = F→ . →v = qE2v cos 90∘ = 0 5. Ans ( C )
2. Ans ( A,B,D )

Vemit > VCollector

ε
i= V = – iR
Rx
R1 + r + L hC ϕ 1240
Rx VStop = − = −2=2
ε ( R1 + L
)
eλ e 310
V = ε − ir =
Rx
R1 + r + L
V1 = iR
3. Ans ( A,C )
I
The force exerted = ×A
C
0.84 × 10−3
= × 100 = 0.28 × 10−9 N
8
3 × 10 i = 2 + V ⇒ i = 2 – iR
The no. of photons per unit volume =
I
i (1 + R) = 2
= 7 × 106 2
C × hν i=
1+R

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6. Ans ( A ) PART-1-PHYSICS
4R
P = i2R = 2
SECTION-III
(1 + R)
dP 1. Ans ( 1 )
=0⇒ 4(1 + R)2 – 4R × 2(1 + R) = 0 μ 0i μ 0i
dR a
4 + 4R = 8R B1 = ×r= ×
2 π a2 2 π a2 2
R = 1Ω μ 0i μ 0i
B2 = =
2πr 2 π (2a)
7. Ans ( B ) B1
1 1 =1
2
E0 Z [ − ] = 28.1 ... (i) B2
4 n2
1 1 2. Ans ( 7 )
E0 Z 2 [ − ] = 11.1 ... (ii) Since initially electron and proton are seperated
9 n2
Divide (i) by (ii) by large distance Þ potential energy = 0
Thus when electron & proton combine to form a
n2 − 4 28.1 × 4
= hydrogen atom Δ E = (13.6 + 4.11) eV.
n2 − 9 11.1 × 9
hc 12400
n2 – 4 = 1.125 (n2 – 9) ∴ = ΔE ⇒ λ = Å = 700 Å
λ 17.71
n2 = 49
3. Ans ( 8 )
⇒n=7
λ = 563.3 nm
1 1 d = 5 µm =
13.6 × Z 2 [ − ] = 28.1
4 49 10×10 – 6 m =
Z2 ⇒ 9 ⇒ Z = 3 10,000nm
d 10, 000
8. Ans ( C ) = =
λ 563.3
1 1 8.875
E0 Z 2 [ − ] = 28.1 ... (i)
4 n2 ∴ no. of maxima observed = 8
1 1
E0 Z 2 [ − ] = 11.1 ... (ii) 4. Ans ( 1 )
9 n2
Divide (i) by (ii)
n2 − 4 28.1 × 4
= ΔV 3 1
n2 − 9 11.1 × 9 i= = =
R 300 100
n – 4 = 1.125 (n2 –
2 9)
5. Ans ( 0 )
n2 = 49
W = Uf – Ui
⇒n=7 1
1 1 where Uf = × [( – 2q) ( – 2q) + ( – 2q)(q) +
13.6 × Z 2 [ − ] = 28.1
4 π ε 0a
4 49 (q) ( – 2q)] = 0
Z2 ⇒ 9 ⇒ Z = 3
9. Ans ( A )
Both will move with same velocity
So Δ v = 0 Also, Uf = 0
So, W = 0
6. Ans ( 8 )
qV = 1 mv2
2
(8 0 ) 10 – 9 × 5000 = 1
2– 2
× 10 – 3 v2
2
64 × 10 – 6 = v2
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PART-2-CHEMISTRY PART-2-CHEMISTRY
SECTION-I(A) SECTION-I(B)
2. Ans ( B,C,D ) 5. Ans ( C )

6. Ans ( A )

9. Ans ( A )
r = K[A]3
3.2 × 10 – 2 = K(10 – 3)3
3. Ans ( A,D )
k = 3.2 × 107
(A) Chemisorption does not change into
physisorption at higher pressure. 10. Ans ( B )
(D) CO or CO2 gases leave the surfaces. r2 Ea 1 1
log ( ) = ( − )
r1 2.303R T1 T2
Ea 1 1
log 4 = [ − ]
2.303 × 2 300 400
Ea = 3.3 kcal / mol

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PART-2-CHEMISTRY PART-3-MATHEMATICS
SECTION-III SECTION-I(A)

1. Ans ( 4 ) 1. Ans ( A,B,C )

Density == Z×M 2cos−1 (cot(2tan−1 x)) = n π
a3 Nav nπ
cos−1 (cot(2tan−1 x)) = (n ∈ I)
Z = Rank of unit cell 2
density × a3 × Nav n can take only three values 0, 1, 2.
∴Z= ⎧ 0 if n=1
M
3 ⇒ cot(2tan−1 x) = cos n π = ⎨
2.70 × (4.04 × 10−8 ) × 6.022 × 1023 ⎩ 2 ±1 if n = 0, 2
= −1
27.0 From cot(2tan x) = 0, we get
= 3.97 ≈ 4 π
2tan−1 x = k π +
2. Ans ( 2 ) 2
where k = – 1 or 0
(i) Incorrect : → Azeotropes are non-ideal −ππ
solutions so do not obey Rault’s law. ⇒ tan−1 x = or
⇒ x = ±1
4 4
(ii) Incorrect : → for minimum boiling and cot(2tan−1 x) = ±1 ⇒ tan(2tan−1 x) = ±1
azeotropes Δ Hmix > 0. 2x
= ±1
1 − x2
(iii) Correct : → addition of non-volatile solute 1 − x2 = ±2x
decreases vapour pressure However Δ Hvap x2 ± 2x − 1 = 0
remains unaffected. (x ± 1)2 = 2
(iv) Correct : → In case of azeotropes,
x = ±√2 ± 1
composition of vapours formed is same as
Thus x = ±1, ± √ 2 ± 1.
solution after vapourisation.
Correct statement = 2 2. Ans ( A,C )
⎡
u, v1 u1 v2 u, v3 ⎤ ⎡
u1 ⎤
3. Ans ( 9 )
⎢ ⎥ ⎢ ⎥
9 A= ⎢
⎢
u2 v1 u2 v2 u2 v3 ⎥
⎥
=⎢ u
⎢ 2
⎥
⎥
[v1 v2 v3]
⎢ ⎥ ⎢ ⎥

4. Ans ( 5 ) ⎣
u3 v1 u3 v2 u3 v3 ⎦ ⎣
u4 ⎦
The species which are not in ‘their maximum = BC
oxidation state, can be oxidised by KMnO4. tr(A) = u1v1 + u2v2 + u3v3
I – 1 {Max. oxidation state +7} Now A5 = BCB –––– CB
–––– CB
–––– CB
–––– C \ B
–––– –––– –––– ––––
{C max. oxidation state + 4} (CB)4C
⇒ A5 = B [v1 u1 + v2 u2 + v3 u3 ]4 C = B ] λ 4] C
− 2
H2 S {S max. oxidation state +6} ⎡
λ 4 u1 ⎤
+ 6 ⎥
⎢
S O2−
4 {already in their max. oxidation ⇒ A5 = ⎢
⎢ λ 4 u2 ⎥
⎥ [v1 v2 v3] =
⎢ ⎥
state}
+ 5
⎣
λ 4 u3 ⎦
N O−1
3 {already in their max. oxidation λ 4 u1 v1 λ 4 u1 v2 λ 4 u4 v3 ⎤
⎡

state} ⎢ ⎥

Br – 1 {max. oxidation state +7}

⎢
⎢ λ 4 u2 v1 λ 4 u2 v2 λ 4 u2 v3 ⎥
⎥
⎢ ⎥
4
λ 4 u3 v1 λ 4 u3 v2 λ 4 u3 v3 ⎦
+
⎣
S O2 {max. oxidation state of ‘S’ ⇒ +6}
∴ Given λ A = 16A = λ 4 A
4

∴ λ 4 = 16 ⇒ λ = ± 2
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3. Ans ( B,C,D ) PART-3-MATHEMATICS
SECTION-I(B)

5. Ans ( D )
f ′ (x) = (|x| − x2 ) e−x + (|x| − x2 )e−x , x ⩾ 0
2 2

f ′ = 2 (x – x2) e−x ....(1)

2

hence option (D) is correct

g' (x) = xe−x2 2x
g ′ (x) = 2x2 e−x ....(2)
2

⇒ g'(x) ≥ 0 ∀ x ∈ R
hence (C) is wrong
4. Ans ( A,B,C ) by (1) + (2)
f ′ (x) + g ′ (x) = 2 × e−x
2
dy
If the curve traced by P is y = f(x) then
dx 2
f(x) + g(x) = −e−x + c
= slope of line 2

joining P and Q as f(x) + g(x) = −e−x + 1 as f(0) = g(0) = 0

1 2
P is always moving F (√ ℓ n3) + g (√ ℓ n3) = 1 − = (option (A)
3 3
towards Q is wrong)
Let Q ≡ (0, β ) and H(x) = ψ 1(x) – 1 – α x = e – x + x – 1 – α x,
P(x, y), (0 – x)2 + x ≥ 1 & α ∈ (1, x)
( β – y)2 = k2 H (1) = e – 1 + 1 – 1 – α < 0
⇒ β − y = √K 2 − x2 H' (x) = – e – x + 1 – α > 0
dy β −y √K 2 − x 2
⇒ H (x) is ↓ ⇒ option (B) is wrong
= =
dx 0−x −x
Solving the differential equation with initial
condition f(K) = 0 gives
K + √K 2 − x 2
y = −K ln( ) − √K 2 − x2
x

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6. Ans ( D ) 7. Ans ( D )
(A) ψ 1 (x) = e−x + x, x ≥ , 0 ƒ(x) = x ∀ x ∈ R
ψ 1′ (x) = 1 − e−x > 0 ⇒ ψ 1 (x) is ↑ ­ g(x) = |x| + |x – 1| |x + 1| ∀ x ∈ R
g(ƒ(x)) = g(x),
ψ 1 (x) ⩾ ψ 1 (0) ∀ x ⩾ 0 ⇒ ψ 1 (x) ⩾ 1 Hence, g(ƒ(x)) is non-derivable at x = – 1,0,1
(B) ψ 2 (x) = x2 − 2x + 2 − 2e−x x ⩾ 0 9. Ans ( B )
ψ 2′ (x) = 2x − 2 + 2e−x = 2 ψ 1 (x) − 2 ⩾ 0 ∀ x ⩾ 0 2 3 4 1 2 4 2 2 3 1 3 3
⇒ ψ 2 (x) is × × + × × + × × + × ×
3 5 7 3 5 7 3 5 7 3 7 5
↑ ⇒ ψ 2 (x) ⩾ ψ 2 (0) ⇒ ψ 2 (x) ⩾ 0 24 + 8 + 8 + 9 53
=
x
2 1 105 105
(C) f(x) = 2 ∫ (t − t2 )e−t dt & x ∈ ( 0, )
0 2 10. Ans ( C )
x x
2 2 1 2 4 1 3 1 11
=∫ 2te−t dt − ∫ 2t2 e−t dl × × + × × =
0 0 5 3 7 3 7 5 105
2 x
= −e−x ∣∣ − PART-3-MATHEMATICS
0
Let H(x) = f(x) –1 + SECTION-III
−x2 2 2 1
e + x3 − x5 , x ∈ (0, )
1. Ans ( 0 )
3 5 2
H (0) = 0 f'(x) 2 ( – cosec2 x) + (2a + 1) ( – cot x) + (2 – a)
H' (x) = 2 (x – x2) e−x2 − 2xe−x2 + 2x2 − 2x4 = – 2(1 + cot2 x) – (2a + 1) cot x + (2 – a)
since cot x ∈ (0, ∞ ), as x ∈ (0, π )
2
= −2x2 e−x + 2x2 − 2x4
2 2
= 2x2 (1 − x2 − e−x ) = – 2cot2 x – (2a + 1) cot x – a
∵ e−x ⩾ 1 − x ∀ x ⩾ 0 Now we want f'(x) < 0 ∀ x ∈ 0, π( )
2
⇒ H'(x) ≤ 0 ∴ (let cot x = t)
1
⇒ H(x) is ↓ ⇒ 1-1(x) < 0 ∀ x ∈ ( 0, ) ⇒ – 2t2 – (2a + 1) t – a < 0, ∀ ∈ (0, ∞ ),
2
Let P(x) = g(x) ⇒ −2t2 − 2at − t − a < 0, ∀ ∈ (0, ∞ )

y
2 2 1 1
− x3 + x5 − x7 x ∈ (0, )
3 5 7 2
Now y = – 2t2 – (2a + 1) t – a < 0; ∀ ∈ (0, ∞ )
2 e−x2 − 2x2 + 2x4 − x6 Case- I
P' (x) = 2 x
x2 x4 x6 2 4 D<0
= 2x2 (1 − + − +. . .) – 2 x + 2x – } ⇒a∈ϕ
1 2 3
6 a<0
x
x8 x10 Case - II
=− + ..........
3 12

⇒ P'(x) ≤ 0
⇒ P(x) is ↓
⇒ P(x) ≤ 0
option (D) is correct or

D⩾0 ⎫
⎪
⎪
⎪
⎪
⎪
−b
condition for case II 2a
<0 ⎬ ⇒ a ∈ [0, ∞ )
⎪
⎪
⎪
⎪
⎪
⎭
f(0) ⩽ 0
hence m=0

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2. Ans ( 8 ) 4. Ans ( 2 )
2 n 1 5
2(x2 − 1) ∣ ∣

g(x) = ∣ ∣ N
(x − 2)x(2x − 1) Un = ∣
n 2
2N + 1 2N + 1
∣
⇒ ∑ Un =
∣ ∣
4(x2 − 1)(x4 − 5x3 + 6x2 − 5x + 1) ∣ ∣ n=1
g ′ (x) = n3 3N 2 3N + 1
(x2 − 2)x2 (2x − 1)2
∣ ∣

∣ N(N+1) ∣
g ′ (x) = 0 ⇒ x = ±1, 2 ± √3 ∣ 2
1 5 ∣
∣ ∣
⇒ g(2 + √3) = 8 ∣ N(N+1)(2N+1) ∣
∣ (2N + 1) (2N + 1) ∣
6
3. Ans ( 4 ) ∣
∣
∣
∣
2
∣ → → → → → →∣ 1 1 1 ∣ N(N+1)
3N 2
(3N + 1)
∣

∣
a .a a .b a .c ∣
∣
2 2
∣
∣
[
2
]
∣
∣ ∣

→→→
2 ∣
→ → → → →∣
∣ ∣ ∣
1 N(N + 1)(2N + 1)
[ a bc ] = ∣∣ b . →
a b .b b .c ∣ =
∣ 1
1 1 ∣
= =
∣ ∣
∣
∣
2 2 ∣
∣
2 2
∣ 1 1 5 ∣
→ →
∣ ∣
∣
→ →∣ 1 1
∣
→ →
c .a c .b c .c ∣ ∣ 2 2
1∣ ∣ ∣

→→→
∣ 1 ∣
1 1 1
∴ [ a bc ] = ∣ 3 ∣
∣ ∣
2 √
∣ N(N+1) ∣
→ → → 2
→ → → →
a × b + b × c = p a + q b + rc ∣ 3N 3N + 1 ∣
Applying R1 → R1 – R2
2
2
Dot product with c → ∣
3
0 4 ∣
∣ ∣

→→→ → → → → N(N + 1)(2N + 1) ∣

1
∣

[ a bc ] = p (a . c ) + q (b . c ) +r ∣
1 1 ∣
=
3
2 ∣
∣
∣
∣
1 p q
= + +r ... (i) ∣ N(N+1)
3N 2 3N + 1
∣

√ 2 2 2 ∣ 2 ∣

→ N
Dot product with a 2 ∑ n2
→→→ q r n=1
[ a bc + ] =p+ N
2 2
1 q r Compare with λ ∑ n2
=p+ + .. (ii) n=1
√2 2 2 λ = 2.
→
Dot product with b 5. Ans ( 5 )
p r 5
+q+ =0 ... (iii)
2 2
Solving this we will get – 6. Ans ( 1 )
1
p = −q = r = ƒ:A
2
√

p2 + 2q 2 + r2 ƒ3(x) + x3 + 1 = 3x.ƒ(x)
∴ =4
q2 ƒ(x) = – x – 1 a3 + b3
3
+c = 3abc
a+b+c=0
ƒ(ƒ(x)) = x & ƒ – 1(x) = – x – 1

2x2 + 3x + 1 = 0
& – 1 (reject)

because and and domain of ƒ –

1(x) is Net domain is .

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