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Wastewater Treatment Processes

(Sep 12th-15th, 2016)


by Dr. Arun Kumar (arunku@civil.iitd.ac.in)

Objective: To learn about processes used in wastewater


treatment plant
Courtesy: Dr. Irene Xagoraraki, MSU, USA

September 27, 2016 Arun Kumar 1


(arunku@civil.iitd.ac.in)
Minor 1 copies
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• Minor 1 copies next week Monday


afternoon in different slots
• Slot timings will be emailed.

September 27, 2016 2


Characteristics of Domestic
Wastewater
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September 27, 2016


4
Wastewater characteristics
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• Compare wastewater (WW)characteristics


of
– Domestic WW
– Industrial WW (for ex: tannery industry;
distillery industry)

September 27, 2016 5


Wastewater Management
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Different
sources
http://dnr.metrokc.gov/WTD/homepage/process.htm
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Wastewater Management

www.oconomowocusa.com/ wastewater.gif
Municipal Wastewater
Treatment Systems
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• Preliminary treatment (removes


materials that can cause operational
problems, equalization basins are
optional)
• Primary treatment (remove ~60% of
solids and ~35% of BOD)
• Secondary treatment (remove ~85% of
BOD and solids)
• Advanced treatment (varies: 95+ % of
BOD and solids, N, P)
• Final Treatment (disinfection)
• Solids Processing (sludge management)
Pre-Treatment of Industrial
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Wastewaters
• Industrial wastewaters must be pretreated prior to being
discharged to municipal sewer system
• Pretreatment requirements set by regulatory agencies
• Why: remove materials that will not be treated by
municipal system, remove materials that inhibit the
biological processes in secondary treatment
• For example: silver ions are toxic to bacteria which
might affect biological process. Thus silver ions are
removed at pre-treatment before biological process so
that bacterial performance do not get affected.
Basic Wastewater Treatment Note down parameters removed
in different unit processes
and order of their removals
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Preliminary TreatmentPrimary
TreatmentSecondary
TreatmentFinal Treatment and
Solids Processing
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Sludge Disposal
Q0, Ceff
• Method depends on RCRA regulations
Q0,C0
– Land Spreading
• lawns, gardens
• agricultural land
• forest land
• golf courses and other public recreational areas
Qw,Xw
– rate
Q0,=flow Municipal Solid Waste Landfill
C0,=initial concentration
– Utilization
X=biomass in other materials
concentration
Qw=sludge withdrawal rate
Xw= biomass concentration in
secondary settling tank
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Preliminary treatment
Upon arrival via the sewer system, the wastewater is
sent through a bar screen, which removes large solid
objects such as sticks and rags.

Leaving the bar screen, the wastewater flow is slowed


down entering the grit tank, to allow sand, gravel and
other heavy material that was small enough not to be
caught by the bar screen to settle to the bottom. All the
collected debris from the grit tank and bar screen is
disposed of at a sanitary landfill.
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Primary treatment
Primary treatment is the second step in wastewater
treatment. It allows for the physical separation of solids
and greases from the wastewater. The screened
wastewater flows into a primary settling tank where it is
held for several hours allowing solid particles to settle to
the bottom of the tank and oils and greases to float to the
top.
Secondary treatment
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-biological treatment process that removes dissolved


organic material from wastewater. The partially treated
wastewater from the settling tank flows by gravity into an
aeration tank.

-mixing of water to solids containing that use oxygen to


consume the remaining organic matter in the wastewater
as their food supply (use of air bubble for mixing and
oxygen supply)

-liquid mixture (i.e., solids with micro-organisms and


water) is sent to the final clarifier.
-In clarifier, solids settle out to the bottom where some of
the material is sent to the solids handling process and
some is recycled back to replenish the population of
micro-organisms in the aeration tank to treat incoming
wastewater.
Final treatment
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Treated water is disinfected and then it is send out for


wastewater reuse activities or for discharging in
river/streams. mostly chlorination and/or ultra violet
irradiation is used for disinfection purposes.
Solids processing
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The primary solids from the primary settling tank and the
secondary solids from the clarifier are sent to a digester.
Micro-organisms use the organic material present in the
solids as a food source and convert it to by-products such
as methane gas and water.

Digestion results in a 90% reduction in pathogens and the


production of a wet soil-like material called “biosolids” that
contain 95-97% water.

In order to remove some of this water, mechanical


equipment such as filter presses or centrifuges are used
to squeeze water from the biosolids to reduce the volume
prior to being sent to landfill, incinerated or beneficially
used as a fertilizer or soil amendment.
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Wastewater Treatment
• Preliminary Treatment (screening)
• Primary Treatment (primary settling)
• Secondary Treatment (e.g. activated sludge)
• Advanced Treatment (e.g. P removal)
• Final Treatment (disinfection)
• Solids Processing (sludge treatment)
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Bar racks
• Purpose: remove
larger objects
• Solid material stored
in hopper and sent to
landfill
• Mechanically or
manually cleaned
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Grit Chambers
• Purpose: remove inert
dense material, such
as sand, broken
glass, silt and pebbles
• Avoid abrasion of
pumps and other
mechanical devices
• Material is called “grit”
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– Wastewater flow has daily


Equalization fluctuations
– Purpose: To dampen the variation
Basins in wastewater flow into a WWTP
– Flow equalization is not a treatment
process
– Improves effectiveness of primary
& secondary treatment
– Usually achieved by large basins to
collect wastewater and pumped to
treatment plant at a constant rate
– Adequate aeration and mixing need
to be provided to prevent odors and
deposition of solids

Source: Davis and Cornwall, Introduction to Environmental Engineering, 2008


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Wastewater Treatment
• Preliminary Treatment (screening)
• Primary Treatment (primary settling)
• Secondary Treatment (e.g. activated sludge)
• Advanced Treatment (e.g. P removal)
• Tertiary Treatment (disinfection)
• Solids Processing (sludge treatment)
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Primary Treatment (settling)


• Primary treatment separates suspended solids
and greases from wastewater. Wastewater is held
in a tank for several hours allowing the particles to
settle to the bottom and the greases to float to the
top.
• The solids drawn off the bottom and skimmed
off the top receive further treatment as sludge.
The clarified wastewater flows on to the next
stage of wastewater treatment.
Settling/Sedimentation
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• Solid liquid separation process in which a


suspension is separated into two phases –
– Clarified supernatant leaving the top of the
sedimentation tank (overflow).
– Concentrated sludge leaving the bottom of the
sedimentation tank (underflow).
• Purpose of Settling
– To remove coarse dispersed phase.
– To remove coagulated and flocculated impurities.
– To remove precipitated impurities after chemical
treatment.
– To settle the sludge (biomass) after activated sludge
process / tricking filters
September 27, 2016 arunku@civil.iitd.ac.in
Arun Kumar 23
(arunku@civil.iitd.ac.in)
Some basic definitions
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• Sedimentation, also known as settling, may be defined as the


removal of solid particles from a suspension by settling under
gravity.

• Clarification is a similar term, which usually refers specifically to the


function of a sedimentation tank in removing suspended matter from
the water to give a clarified effluent. In a broader sense, clarification
could include flotation and filtration.

• Thickening in sedimentation tanks is the process whereby the


settled impurities are concentrated and compacted on the floor of
the tank and in the sludge-collecting hoppers.

• Concentrated impurities withdrawn from the bottom of sedimentation


tanks are called sludge, while material that floats to the top of the
tank is called scum.

September 27, 2016 arunku@civil.iitd.ac.in


Arun Kumar 24
(arunku@civil.iitd.ac.in)
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http://www.geocities.com/RainForest/5161/wwtps.htm
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Basins
Primary Settling
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Primary Settling Tank Design Example


• Size:
– rectangular: 3-24 m wide x 15-100 m long
– circular: 3-90 m diameter
• Detention time: 1.5-2.5 hours
• Overflow rate: 25-60 m3/m2·day
• Typical removal efficiencies:
– solids: 50-60%
– BOD5: 30-35%
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Example 1
Question: A rectangular primary clarifier (2.4 m deep &
4.0 m wide) is designed to settle a flow of 2000 m3/day
and have an overflow rate of 32 m3/m2.day

I) How long should it be?


II) What detention time will it have?
Example 1
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I) Length:
m3
2000
flow rate day m3
Overflow rate = = = 32 2
area 4 m × Length m ⋅ day

2000
Solve for length: Length = = 15.6 m
4 × 32
Example 1
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II) Detention time:

volume 2.4 m × 4 m × 1 5.6 m


Detention time = = 3
= 1.8 hr
flow rate m day
2000 ×
day 24 hr
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Wastewater Treatment
• Preliminary Treatment (screening)
• Primary Treatment (primary settling)
• Secondary Treatment (e.g. activated sludge)
• Advanced Treatment (e.g. P removal)
• Final Treatment (disinfection)
• Solids Processing (sludge treatment)
Secondary Treatment
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• Secondary treatment is a biological


treatment process that removes dissolved
organic matter from wastewater.
• Sewage microorganisms are cultivated and
added to the wastewater. The microorganisms
use organic matter from sewage as their food
supply. This process leads to decomposition or
biodegradation of organic wastes.
Secondary Treatment
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• Basic approach is to use aerobic biological


degradation:

microorganisms
organic carbon + O2 CO2 + new cells

• Objective is to allow the BOD to be exerted in the


treatment plant rather than in the stream
How is this accomplished?
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Create a very rich


environment for growth
of a diverse microbial
community
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Basic Ingredients
• High density of microorganisms (keep
organisms in system)
• Good contact between organisms and wastes
(provide mixing)
• Provide high levels of oxygen (aeration)
• Favorable temperature, pH, nutrients (design
and operation)
• No toxic chemicals present (control industrial
inputs)
Dispersed (suspended) growth
vs Fixed growth
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• Two approaches of secondary treatment


– fixed film, and suspended film systems
• Dispersed Growth (suspended organisms)
– Activated sludge
– Oxidation ditches/ponds
– Aerated lagoons, stabilization ponds
• Fixed Growth (attached organisms)
– Trickling filters
– Rotating Biological Contactors
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Activated Sludge
• Process in which a mixture of wastewater and
microorganisms is agitated and aerated
• Leads to oxidation of dissolved organics
• After oxidation, separate sludge (mostly microbial cells,
water, and other contaminants) from wastewater
• Induce microbial growth
– Need food, oxygen
– Want Mixed Liquor Suspended Solids (MLSS) of
3,000 to 6,000 mg/L
Activated Sludge Process
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http://www.geocities.com/RainForest/5161/wwtps.htm
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Activated Sludge Process


raw
Return wastewater
Activated
Sludge
(RAS) Mixed
Air Liquor Air

treated
wastewater Discharge to
Waste Secondary River or Land
Activated clarifier Application
Sludge
(WAS)
Activated Sludge Process with
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secondary clarifier

East Lansing WWTP


East Lansing WWTP
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F/M Parameter
• Low F/M (low rate of wasting)
– starved organisms
– more complete degradation
– larger, more costly aeration tanks
– more O2 required
– higher power costs (to supply O2)
– less sludge to handle
• High F/M (high rate of wasting)
– organisms are saturated with food
– low treatment efficiency
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Activated Sludge Design


• Detention time: td = approximately 6 - 8 hr
• Long rectangular aeration basins
• Air is injected near bottom of aeration tanks
through system of diffusers
• Aeration system used to provide mixing
• MLVSS and F/M controlled by wasting a portion
of microorganisms
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Other options

September 27, 2016 43


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Low-tech solutions

• Aerobic ponds
• Facultative
ponds
• Anaerobic
ponds
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1. Aerobic ponds
• Shallow ponds
(<1 m deep)
• Light penetrates to
bottom
• Active algal
photosynthesis
• Organic matter con-
verted to CO2, NO3-,
HSO4-, HPO42-, etc.
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2. Facultative ponds
• ponds 1 - 2.5 m deep
• td = 30 - 180 d
• not easily subject to Aerobic
upsets due to Facultative
fluctuations in Q,
Anaerobic
loading
• low capital, O&M costs
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3. Anaerobic Ponds
• Primarily used as a pretreatment process
for high strength, high temperature wastes
• Can handle much high loadings
• 2 stage:
– Acid fermentation: Organics → Org. acids
– Methane fermentation Org. Acids → CH4 and
CO2
Example 1: Performance of a “AA” WWTP
(Grit chamber PST Activated sludge unitSST Nitrification
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unit Effluent)
Performance in a “AA” WWTP
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Influent flow rate 1 MLD (million liters per day)

Influent parameters Take highest value of parameters from


previous slide
Remaining Suspended solids 100 mg/L (inf: 300mg/L)
after primary sedimentation tank
remaining BOD5 after primary 250mg/L(inf: 350mg/L)
sedimentation tank
BOD5 after activated sludge 100mg/L
process
TKN after biological nitrification 50 mg/L as N(inf: 80mg/L)
process

Question: Find out efficiency of different unit processes;


remaining conc. Of different parameters?
Is it meeting the standards of river?
How much is sludge generation? What information are required?
September 27, 2016 49
Performance in a “AA” WWTP
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Influent flow rate 1 MLD (million liters per day)

Influent parameters Take highest value of parameters from


previous slide
Removal Suspended solids after =((350-100)/350)*100
primary sedimentation tank
Removal BOD5 after primary =(300-250)*100/300
sedimentation tank
Removal of BOD5 after =(250-100)*100/250
activated sludge process
Removal of TKN after biological ??
nitrification process
Conc. Of bacteria in SST 10000mg/L

Sludge withdrawal rate from 0.1MLD


SST

September 27, 2016 50


Performance in a “AA” WWTP
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Influent flow rate 1 MLD (million liters per day)

Influent parameters Take highest value of parameters from


previous slide
Remaining Suspended solids 100 mg/L
after primary sedimentation tank
remaining BOD5 after primary 250mg/L
sedimentation tank
BOD5 after activated sludge 100mg/L
process
TKN after biological nitrification 50 mg/L as N
process

Question: Find out efficiency of different unit processes;


remaining conc. Of different parameters?
Is it meeting the standards of river?
How much is sludge generation? What information are required?
September 27, 2016 51
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