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Materials Science & Engineering A 751 (2019) 183–190

Contents lists available at ScienceDirect

Materials Science & Engineering A


journal homepage: www.elsevier.com/locate/msea

Correlation between arc mode, microstructure, and mechanical properties T


during wire arc additive manufacturing of 316L stainless steel

Leilei Wanga, , Jiaxiang Xuea, Qiang Wangb
a
School of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510641, China
b
Hubei Dayun Automobile Co., Ltd., Shiyan 442500, China

A R T I C LE I N FO A B S T R A C T

Keywords: Wire arc additive manufacturing (WAAM) features advantages such as low cost and high disposition rate, and
Wire arc additive manufacturing thus WAAM is a feasible additive manufacturing process. Although some characteristics of WAAM have been
Stainless steel documented in the literature, the process stability, structural integrity, component morphology, microstructure,
Quality assessment and mechanical properties during WAAM under different arc modes are not comprehensively demonstrated and
Microstructural characterization
understood. Here, we performed WAAM experiments with 316L stainless steel under different arc modes and a
Mechanical properties
constant deposition rate, and then we discussed the mechanism and impact of the arc mode on the manu-
facturing process stability, structural integrity, microstructures, and mechanical properties. The results indicate
that the SpeedPulse and SpeedArc additive manufacturing processes are relatively stable, significantly efficient,
and structurally sound. Although the deposition rate and scanning speed of SpeedPulse WAAM and SpeedArc
WAAM are the same, SpeedArc WAAM has a lower heat input and a higher cooling rate. Therefore, SpeedArc
WAAM produces a finer solidification structure than SpeedPulse WAAM. The ultimate tensile strengths of the
SpeedPulse and SpeedArc additive manufactured specimens along the horizontal direction are greater than
540 MPa and slightly greater than previously reported results. Due to the lower heat input and finer solidifi-
cation structure, a component produced by SpeedArc WAAM has greater tensile strength and hardness than a
component produced by SpeedPulse WAAM.

1. Introduction and electron beams in the manufacture of large-scale metallic compo-


nents.
Additive manufacturing transforms the fabrication of a structurally Wire arc additive manufacturing (WAAM) adopts an arc as the heat
complicated three-dimensional (3D) component into stepwise additions source and metal wire as the feedstock material. Generally, the primary
of thin material layers guided by a digital model [1,2]. Additive man- cost of the metal wire is approximately 10% of the same weight of metal
ufacturing enables the fabrication of structurally complex components powder. During the WAAM process, the metal wire is heated, melted,
without using a mold, which significantly improves production effi- and then transferred to the melt pool and then solidifies at the melt pool
ciency and manufacturing flexibility [3,4]. Laser beams, electron boundary and forms digitally designed components [15,16]. WAAM is a
beams, and electric arcs are commonly used heat sources during ad- kind of droplet-based additive manufacturing process, which is very
ditive manufacturing of metallic components [5–7]. When laser beams promising for the direct fabrication of complex thin-walled parts
or electron beams are selected as the heat source, the energy control is [17,18]. WAAM features a high deposition rate, which is suitable for
accurate, and the component shape is relatively precise [8,9]. There- fabricating large-scale components [19,20]. Furthermore, WAAM fea-
fore, investigations regarding additive manufacturing based on laser tures advantages such as low cost and low wastage rate, and thus
and electron beams are thorough [10–12]. Direct energy deposition and WAAM is an advantageous alternative additive manufacturing process
power bed fusion are the general additive manufacturing processes used to other methods based on laser and electron beams [21,22].
when laser beams or electron beams are selected as the heat source The dominant factor that affects the component morphology, mi-
[13,14]. However, both of these processes adopt metal powder as the crostructure, and mechanical properties during WAAM is the heat
feedstock material, and thus the production efficiency is limited and the input. However, differences in heat input exist when different arc
production cost is high, which restricts the applications of laser beams modes are adopted even if the wire feeding rate is held constant.


Corresponding author.
E-mail address: lleiwang@scut.edu.cn (L. Wang).

https://doi.org/10.1016/j.msea.2019.02.078
Received 14 February 2019; Received in revised form 20 February 2019; Accepted 22 February 2019
Available online 23 February 2019
0921-5093/ © 2019 Elsevier B.V. All rights reserved.
L. Wang, et al. Materials Science & Engineering A 751 (2019) 183–190

Another particular phenomenon found in WAAM is the transfer of li- spray transfer mode. SpeedArc WAAM is distinguished from the con-
quid droplets across the arc from the wire electrode to the melt pool ventional GMAW process by a short and particularly forceful arc in the
[23,24]. The liquid droplet temperature is higher than the solidus spray arc range and therefore features exceptional directional stability
temperature, and part of heat is transferred to the melt pool by the and high energy density. The primary metal transfer mode during
liquid droplet [25]. However, differences in liquid droplet transfer exist SpeedArc WAAM is the short-circuited transfer mode.
when different metal transfer modes are adopted even if the wire Argon with a 99.99% purity was used as the shielding gas. The
feeding rate is held constant. Therefore, what is essential but seldom length of one single layer is 150 mm. The scanning path was scanned
reported in the literature is to reveal what and how the metal transfer back and forth, which means that the scanning direction in the current
mode affects the component morphology, microstructure, and me- layer is opposite to that in the previous layer. The standstill time during
chanical properties during WAAM. Cong et al. [26] systematically in- the transition to the next adjacent layer is 20 s. The process parameters
vestigated the effects of different metal transfer modes during the cold are shown in Table 2.
metal transfer (CMT) process on the porosity characteristics of addi-
tively manufactured Al-6.3%Cu alloys, and their results indicated that 2.2. Microstructural characterization
heat input is one of the critical factors that enables the CMT pulse ad-
vanced (CMT-PADV) process to control the porosity rate. Luo et al. [27] After deposition, two samples were extracted near the middle of the
conducted WAAM on aluminum alloys using pulsed arcs and nonpulsed component using a wire-electrode cutting machine to reveal the
arcs, and their results indicated that pulsed arcs can achieve higher transverse cross-section. The metallography sample locations are shown
droplet transfer frequencies and that the size of the droplet in the in Fig. 2(a), "A" and "B" represent the metallography sample location of
pulsed arc approach is smaller than that in the nonpulsed arc approach. the bottom layer and upper layer, respectively. Then, the metallography
Although some characteristics of WAAM under various arc modes samples were cleaned, mounted and ground with a series of silicon
have been documented in the literature, the component morphology, carbide papers up to 2000 grit. Metallographic polishing was conducted
integrity, microstructure, and mechanical properties are not compre- with a series of 3 mm and 1 mm polycrystalline diamond suspensions
hensively demonstrated or understood. Stainless steel 316L is a kind of followed by a final polishing with 0.05 mm colloidal silica to obtain a
austenitic stainless steel that is widely used in marine and offshore mirror finish.
equipment, automobiles, and nuclear reactors due to its outstanding The 316L samples were etched by immersion for approximately
corrosion resistance, high strength, high ductility, and relatively low 1 min using a hydrochloric acid: nitric acid: glycerol solution mixed at
cost [28,29]. Here, we established an experimental platform and then 20:10:20 to reveal the grain boundaries and subgrain structure.
carried out WAAM with 316L stainless steel under different arc modes Metallography was performed using a Leica DMI3000M optical micro-
but at the same deposition rate. Arc current and arc voltage data were scope.
collected during the additive manufacturing process to evaluate the
manufacturing process stability. X-ray CT tests were conducted on 2.3. Mechanical property tests
tensile samples of the component to evaluate the structural integrity of
the manufactured component. The microstructures at different loca- After deposition, horizontal-direction tensile specimens were cut
tions in the components were characterized to reveal the relationship from the additive manufactured components; the tensile specimen lo-
between the arc modes and microstructures. Tensile tests were con- cations are shown in Fig. 2(b). Then, the tensile samples were ground to
ducted on the different locations of the components, and the fracture a thickness of 2 mm with water cooling. An AG-IC 50 kN universal
morphologies were analyzed to reveal the relationships between the testing machine was used for the tensile tests; the displacement rate was
metal transfer modes and mechanical properties. set at 2 mm/min, and the average value of four tensile tests was cal-
culated to guarantee accuracy. A Nova Nano SEM 430 was used to in-
2. Materials and methods spect the microstructures and fracture morphologies of the components;
the instrument was operated at a voltage of 20 kV.
2.1. Material fabrication Microhardness measurements were conducted using a Shimadzu
HMV-2T microhardness tester equipped with an optical microscope. A
A commercial 316L stainless steel plate with dimensions of 500 g load with a dwell time of 10 s was applied for all indentations.
250 × 100 × 5 mm3 was selected as the substrate, and 316L stainless Hardness traces were recorded at 2 mm intervals along the vertical
steel wire with a diameter of 1.2 mm was used to deposit the compo- direction from the bottom layer to the top layer of the component.
nents. Table 1 shows the chemical compositions of the stainless steel
plate and wire [30]. 3. Results and discussions
Arc additive manufacturing experiments with two different arc
modes were performed by using a Lorch power source integrated with a 3.1. Process stability and component quality
6-axis FANUC robot. SpeedPulse and SpeedArc modes are the two kinds
of representative arc modes proposed by Lorch Schweißtechnik GmbH. The distribution map of the arc current and arc voltage of the
The actual current and voltage waveform during WAAM were collected SpeedPulse and SpeedArc additive manufacturing processes are shown
and are shown in Fig. 1. in Fig. 3. During SpeedPulse additive manufacturing, short-circuits do
The SpeedPulse mode involves a modified I-I-I-controlled, non- not occur because the arc voltage is always greater than 15 V and the
short-circuiting pulse welding process that operates at a constant fre- arc does not extinguish because the arc current is always greater than
quency and combines the characteristics of a classic pulse arc with 40 A. The arc current and arc voltage repeats well in every cycle during
those of a classic spray arc to achieve high process reliability. The SpeedPulse additive manufacturing, which suggests that the droplet
primary metal transfer mode during SpeedPulse WAAM is a projected transfer and process stability of SpeedPulse additive manufacturing are
favorable. SpeedArc additive manufacturing also features exceptional
Table 1
directional stability because the arc current remains almost constant at
Chemical compositions of 316L substrate and filler wire. 140 A. Therefore, both SpeedPulse and SpeedArc additive manu-
facturing are stable additive manufacturing processes.
Element Cr Ni Mo Mn Si C P S N Fe
Fig. 4 shows a multilayer component produced by SpeedArc ad-
wt% 17.09 10.61 2.38 1.17 0.59 0.013 0.011 0.011 0.09 Bal. ditive manufacturing, and the corresponding process parameters are
shown in case 2 of Table 2. The height of the component is relatively

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Fig. 1. Arc current and voltage waveform of SpeedPulse and SpeedArc modes.

Table 2 Defects such as macroporosity and cracking are not found on the pre-
Process parameters during arc additive manufacturing. sented surfaces. The SpeedPulse additive manufactured component has
Arc mode SpeedPulse WAAM SpeedArc WAAM
a larger average width than the SpeedArc additive manufactured
component when the wire feeding rate is the same. The overall height
Mean current I /A 22.1 19.5 of the SpeedPulse and SpeedArc additive manufactured components are
Mean voltage U /V 135 140 37 mm and 44 mm, respectively.
Arc power P /W 2984 2730
Consequently, the layer thickness of the SpeedPulse and SpeedArc
Layer n 30 30
Scanning speed v1/(mm s−1) 10 10 additive manufactured components are 1.23 mm and 1.47 mm, re-
Wire feeding rate v2/(m min−1) 4.5 4.5 spectively. During SpeedPulse additive manufacturing, the peak current
Gas flow rate Q/(L min−1) 25 25 reaches as high as 220 A, and the metal transfer mode is projected spray
Layer thickness δ/(mm) 1.5 1.8
transfer. The filler wire is rapidly melted, and a droplet is generated in
this short time interval when the peak current is applied. The over-
heated droplet is accelerated by the electromagnetic force and then
impinges into the melt pool at a high speed [32]. Therefore, heat is
introduced to the interior zone of the melt pool, and the SpeedPulse
additive manufactured component features a smaller layer thickness
and a larger layer width.
X-ray CT tests were conducted on every four tensile samples for both
of the additive manufacturing processes. Fig. 6 demonstrates typical X-
ray CT photographs of the tensile specimens from the SpeedPulse and
SpeedArc additive manufactured components. Macroporosity and
cracking in the X-ray CT photograph appear white in tensile specimens.
However, no white zones are observed in the X-ray CT photographs,
which indicates that defects such as macroporosity and cracking do not
exist in the tensile samples. Therefore, SpeedPulse and SpeedArc ad-
ditive manufacturing are structurally sound additive manufacturing
processes.

3.2. Microstructures

Fig. 2. (a) Metallography sample locations. (b) Tensile sample dimensions.


Fig. 7 displays an electron backscattered diffraction (EBSD) map of a
component produced by SpeedArc WAAM. The EBSD map is vertical to
the scanning direction, and the deposition direction is marked. The
equal, which proves that the distortion is acceptable. However, the various colors correspond to the orientation of grains with respect to
lateral surface of the component exhibits a slightly corrugated mor- the crystal lattice, and each color corresponds to a unique combination
phology due to layer-by-layer deposition. A smooth surface can be of Euler angles. The grain growth orientation map along the vertical
achieved by further machining if necessary. The part is well fabricated, direction is shown in Fig. 7(a); almost the whole map shows red and
and the width is relatively uniform; rare defects can be found on the yellow colors. The results indicate that most grain orientations are
surface of the component. along the 001 direction, which is the same as the vertical direction. The
The scanning speed and wire feeding rate of the WAAM process are austenite (γ) distribution map is shown in Fig. 7(b), and the results
10 mm/s and 75 mm/s, respectively. The calculated deposition rates of indicate that the primary phase of the WAAM component is austenite.
the SpeedPulse and SpeedArc additive manufacturing processes are Fig. 8 shows the optical micrographs along the transverse section of
2.4 kg/h, which are obviously higher than the deposition rates of ty- a specific layer of the wire arc additive manufactured component.
pical powder bed fusion-laser, powder bed fusion-electron beam and Ferrite (δ), which is shown in gray, distributes within the austenite (γ)
direct energy deposition-powder feed additive manufacturing ap- matrix, which is shown in white [33]. Fig. 8(b) and (c) show higher-
proaches [31]. Therefore, SpeedPulse and SpeedArc additive manu- magnification micrographs of the top and bottom locations of the spe-
facturing are significantly efficient additive manufacturing processes. cific layer. The grains grow nearly along the vertical direction, which
The cross-sectional morphologies of components fabricated by shows good agreement with Fig. 7. Cellular structures were observed
SpeedPulse and SpeedArc additive manufacturing are shown in Fig. 5. adjacent to the fusion line, as shown in Fig. 8(c). Then, the cellular

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Fig. 3. Distribution map of the arc current and arc voltage of SpeedPulse and SpeedArc additive manufacturing.

component, the microstructures were obtained from the same layer of


the component to make a meaningful comparison. Secondary dendrite
arm spacing (SDAS) is an essential index in the evaluation of arc ad-
ditive manufactured components. The mechanical properties are im-
proved when the SDAS is smaller.
The measured SDAS of the components produced by SpeedPulse
WAAM and SpeedArc WAAM are shown in Table 3. From the com-
parison of the SDAS of the bottom layer and SDAS of the top layer, a
conclusion can be made that the SDAS of the top layer is larger than
Fig. 4. Full appearance of a multilayer component by SpeedArc WAAM. that of the bottom layer. The results show good agreement with the
previously observed results reported by Hofmeister [34].
The two reasons responsible for this phenomenon are as follows.
First, the deposit starts although the previous layer does not cool to
room temperature. As a result, the initial temperature of both the
component and substrate increases at higher layers. Second, heat can be
lost by both the component and substrate at the bottom layer, while less
heat can be lost by the substrate at higher layers. In other words, the
effective surface area for heat loss decreases at higher layers [35].
When the initial temperature increases and the effective surface area for
heat loss decreases at higher layers, the cooling process becomes longer,
and the cooling rate becomes lower. Note that the scale of the solidi-
Fig. 5. Cross-sectional morphology of multilayer components produced by (a) fication structure is significantly affected by the cooling rate. The re-
SpeedPulse WAAM and (b) SpeedArc WAAM. lation between the SDAS (λ2 ) and cooling rate (GR ) is given as follows
[36,37]:

λ2 = 50(GR)−0.4 (1)

where GR is the cooling rate in K/s. Eq. (1) indicates that the SDAS
increases as the cooling rate decreases. Therefore, the solidification
structure becomes coarser at higher layers because of the lower cooling
rate.
From the comparison of the SDAS of the SpeedPulse WAAM with the
SDAS of the SpeedArc WAAM, a conclusion can be made that the SDAS
produced by SpeedArc WAAM is smaller than that produced by
SpeedPulse WAAM at both the bottom layer and top layer. Although the
deposition rates of SpeedArc WAAM and SpeedPulse WAAM are the
Fig. 6. X-ray CT photographs of the tensile specimens produced by (a) same, SpeedArc WAAM has a lower heat input. Therefore, SpeedPulse
SpeedPulse WAAM and (b) SpeedArc WAAM. WAAM has a larger melt pool, wider layer width, and a lower cooling
rate. According to Eq. (1), SpeedArc WAAM produces a finer solidifi-
structures develop into fine columnar structures far away from the fu- cation structure in both the bottom layer and higher layer due to the
sion line. Finally, the fine columnar structures develop into coarse co- higher cooling rate.
lumnar structures, and secondary dendrites can be clearly observed
farther away from the fusion line, as shown in Fig. 8(b). For the next 3.3. Mechanical property
layer, the grains grow in the same manner.
Fig. 9 shows the microstructures from the central transverse sections Fig. 10 displays the Vickers hardness values of the SpeedPulse and
of the components produced by SpeedPulse and SpeedArc additive SpeedArc additive manufactured components. The hardness measure-
manufacturing with different layers. To reveal the effect of the metal ment were performed at 2 mm intervals from the bottom layer to the
transfer mode on the microstructure of the additive manufactured top layer. The Vickers hardness values of the SpeedPulse and SpeedArc

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Fig. 7. EBSD map of a component produced by SpeedArc WAAM: (a) grain growth orientation map and (b) austenite (γ) distribution map.

additive manufactured components are greater than 175 HV. The heat Although the heat input of SpeedArc WAAM is slightly lower than
input of SpeedArc WAAM is slightly lower than that of SpeedPulse that of SpeedPulse WAAM, the heat dissipation path and heat dissipa-
WAAM, and the substrate acts as a good heat sink during the deposition tion effect become worse during the deposition of the top layer.
of the bottom layer. Therefore, there is no significant difference in SDAS Therefore, the SDAS of SpeedArc WAAM is smaller than the SDAS of
between the SpeedArc and SpeedPulse WAAM at the bottom layer. SpeedPulse WAAM at the bottom layer. According to the Hall-Petch
Furthermore, no significant difference in Vickers hardness is observed relationship, the Vickers hardness at the bottom layer of the component
between the SpeedPulse and SpeedArc additive manufactured compo- produced by SpeedArc WAAM is higher than that of the component
nents in the bottom layer. produced by SpeedPulse WAAM.

Fig. 8. (a) Optical micrographs along the transverse section of a specific layer of a component produced by WAAM. Figures (b) and (c) show higher-magnification
micrographs of the top and bottom locations of the specific layer.

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Fig. 9. Optical metallurgy graphs at the transverse cross-sections of the wire arc additive manufactured 316L components: (a) bottom layer of the component
produced by SpeedPulse WAAM, (b) bottom layer of the component produced by SpeedArc WAAM, (c) top layer of the component produced by SpeedPulse WAAM,
and (d) top layer of the component produced by SpeedArc WAAM.

Table 3
Measured SDAS values of the components produced by SpeedPulse WAAM and
SpeedArc WAAM.
Arc mode SpeedPulse WAAM SpeedArc WAAM

SDAS of the bottom layer 10.40 ± 0.43 µm 9.60 ± 0.92 µm


SDAS of the top layer 12.02 ± 1.69 µm 10.74 ± 0.38 µm

Fig. 11. Stress-strain curves of the SpeedPulse and SpeedArc additive manu-
factured tensile specimens along the horizontal direction.

Fig. 11 displays the stress-strain curves of the SpeedPulse and


SpeedArc additive manufactured tensile specimens along the horizontal
direction. The samples were cut from the middle layer of the additive
manufactured component. All samples experienced elastic deformation
and plastic deformation prior to fracture. It is clear that the ultimate
tensile strengths of all samples were greater than 540 MPa.
Fig. 10. Vickers hardness of the SpeedPulse and SpeedArc additive manu-
Experimentally measured and previously reported tensile properties
factured components.
of additive manufactured 316L stainless steel are shown in Table 4. The
tensile strength and elongation of the SpeedArc additive manufactured
component along the horizontal direction is higher than that of the

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Table 4
Experimentally measured and previously reported tensile properties of additive
manufactured 316L stainless steel.
Metal transfer mode UTS/MPa YS/MPa

SpeedPulse WAAM 550 ± 6 418.0


SpeedArc WAAM 553 ± 2 417.9
Cold metal transfer-based WAAM [38] 533 ± 23 235 ± 6
Wrought [39] 525–623 255–310

SpeedPulse additive manufactured component. Microstructural refine-


ment is known to have a significant influence on the strengths of metals
and alloys. Some literature has described the effect of grain size on yield
strength in the recognized Hall-Petch relation [40,41]:

ky
σy = σ0 +
d (2)

where d is the grain size, σy is the yield strength, and σ0 and k y are
material constant properties of materials that represent the yield stress
of a grain-free material and the strengthening coefficient, respectively.
According to the Hall-Petch equation, a finer microstructure indicates a
higher tensile strength. Therefore, the SpeedArc additive manufactured
component features higher tensile strength due to its finer solidification Fig. 13. Energy-dispersive spectroscopy results of the particle elements in the
structure. dimples of the components produced by (a) SpeedPulse WAAM and (b)
Another conclusion that can be drawn is that the experimentally SpeedArc WAAM.
measured ultimate tensile strengths of the components produced by
SpeedPulse and SpeedArc WAAM are higher than previously reported that the component fabricated by SpeedArc WAAM has better ductility.
tensile strength by cold metal transfer-based WAAM. The commercial The inference agrees reasonably with the experimental test results, as
criterion for the tensile strength of wrought 316L stainless steel is shown in Table 4.
525–623 MPa. Therefore, the ultimate tensile strengths of the compo- Some particles located at the bottom of the dimples are observed in
nents produced by SpeedPulse and SpeedArc WAAM lie in this range, Fig. 12. Energy-dispersive spectroscopy (EDS) is used to identify the
which indicates that the tensile strengths of the components produced elements of the particles. Fig. 13 shows the EDS results of the particle
by SpeedPulse and SpeedArc WAAM are up to standard. elements in the dimples of the components produced by (a) SpeedPulse
Fig. 12 shows representative SEM images of the fracture morphol- WAAM and (b) SpeedArc WAAM. According to the EDS results, the
ogies of the components produced by SpeedPulse WAAM and SpeedArc atomic percentage of oxygen reaches 42.93% for SpeedPulse WAAM
WAAM. Enormous dimples with a relatively uniform distribution are and 37.85% for SpeedArc WAAM. The EDS results indicate that the
observed on the fracture surface, which proves that the fracture mode is particles in the dimples are oxidizing impurities. Oxidizing impurities
a ductile fracture and that the as-formed materials feature good commonly act as a brittleness phase and ultimately become the initia-
toughness [39,42]. However, apparent differences regarding the dimple tion points of cracks. Therefore, the oxidation on the substrate should
dimensions and depths can be observed between the components pro- be removed entirely prior to the deposit, and the manufacturing process
duced by SpeedPulse and SpeedArc WAAM. The dimple dimensions and should be absolutely protected against oxidative invasion.
depths of the component produced by SpeedArc WAAM are slightly
greater than those produced by the SpeedPulse WAAM, which indicates

Fig. 12. Representative scanning electron microscopy (SEM) images of the fracture morphologies of the components produced by (a) SpeedPulse WAAM and (b)
SpeedArc WAAM.

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