‫‪1394/04/02‬‬ ‫ﻛﺎﺭﺷﻧﺎﺳﻲ ﻭ ﻛﺎﺭﺷﻧﺎﺳﻲ ﺍﺭﺷﺩ‬

‫‪08:00‬‬

‫ﺳﺭﻱ ﺳﻭﺍﻝ ‪ :‬‬ ‫ﺗﺷﺭﻳﺣﻲ ‪:‬‬ ‫ﺯﻣﺎﻥ ﺁﺯﻣﻭﻥ )ﺩﻗﻳﻘﻪ( ‪ :‬ﺗﺳﺗﻲ ‪ :‬‬ ‫ﺗﺷﺭﻳﺣﻲ ‪:‬‬ ‫ﺗﻌﺩﺍﺩ ﺳﻭﺍﻻﺕ ‪ :‬ﺗﺳﺗﻲ ‪:‬‬

‫‪1   :‬‬ ‫ﻋﻧــﻭﺍﻥ ﺩﺭﺱ‬

‫ﺭﺷﺗﻪ ﺗﺣﺻﻳﻠﻲ‪/‬ﮐﺩ ﺩﺭﺱ ‪   ,( )  ,(   )  :‬‬

‫(‪2( +3 (&$4 567 8  + .90‬‬

‫‪!  " #$ %& '(!) *+ ,- .& / 0‬‬ ‫‪-١‬‬

‫ ‪

   .‬‬ ‫‪
   .‬‬

‫ ‪   .‬‬ ‫
‬ ‫ ‪   .‬‬

‫ ‪!  .&: #; 2( 9< => %> ?@ "-  #‬‬ ‫‪-٢‬‬

‫‪$    .‬‬ ‫ ‪
!"#"   .‬‬ ‫ ‪
   .‬‬ ‫‪     .‬‬

‫‪2( &J; #:K  0 ?67  L!6M( #E 25   CO2 4,!A,! 2B( >C3 8D: CE‬‬ ‫‪-٣‬‬

‫‪MCO2= 44.1 g/mol‬‬

‫ ‪112 .‬‬ ‫ ‪523 .‬‬ ‫ ‪411 .‬‬ ‫‪322 .‬‬

‫ ‪) "- V37  .2( !) 748 Y  L!6M( #E 25  ?XA 0 ( 42/5 V37 # W + #:!:‬‬ ‫‪-۴‬‬

‫‪2( &$; 8!M ?67 + :`  a&  !) 760 ) "- Y & \6]: ?XA 0 ( 52/5‬‬

‫ ‪511 .‬‬ ‫ ‪374 .‬‬ ‫ ‪354 .‬‬ ‫‪270 .‬‬

‫ ‪"> W Y . !E> 8!M 298   "b6 + =! #( > "c>0: + =!  a0, . V37 # d‬‬ ‫‪-۵‬‬

‫‪R = 0.08206lit .atm / molK 2( &J; fd‬‬

‫ ‪5/11 .‬‬ ‫ ‪6/35 .‬‬ ‫ ‪7/25 .‬‬ ‫‪9/78 .‬‬

‫‪.&: #; &$  #0  !E> V* $  #:&E + > g!< # &$:!0: + > h *+  "-  #  8)i‬‬ ‫‪-۶‬‬

‫ !‪&:‬‬

‫ ‪
   .‬‬ ‫ ‪
!"#"   .‬‬ ‫ ‪     .‬‬ ‫‪$   .‬‬

‫<‪!  .&: #; &`  ,!0 !j > 8 =!A,!  #  #M‬‬ ‫‪-٧‬‬

‫ ‪:;< =< #> .‬‬ ‫ ‪8 9 #9  .‬‬ ‫ ‪23! 3 45 6 7 .‬‬ ‫‪#0 1  .‬‬

‫]‪2( #:!D; #06 V06(  + + c: > . #,‬‬ ‫‪-٨‬‬

‫‪.?
B @  C
" ?
@  D‬‬ ‫‪.‬‬ ‫‪.1?
@  "A .‬‬
‫ ‪.1?
B @  "A .‬‬ ‫‪.?
@  C
" ?
B @  D‬‬ ‫‪.‬‬

‫ﺻﻔﺣﻪ ‪ 1‬ﺍﺯ ‪6‬‬ ‫ﻧﻳﻣﺳﺎﻝ ﺩﻭﻡ ‪1393-94‬‬ ‫‪1010/101033434‬‬

‫‪WWW.UNIP.IR‬‬
1394/04/02 ‫ﻛﺎﺭﺷﻧﺎﺳﻲ ﻭ ﻛﺎﺭﺷﻧﺎﺳﻲ ﺍﺭﺷﺩ‬
08:00

 : ‫ﺳﺭﻱ ﺳﻭﺍﻝ‬ : ‫ﺗﺷﺭﻳﺣﻲ‬  : ‫ ﺗﺳﺗﻲ‬: (‫ﺯﻣﺎﻥ ﺁﺯﻣﻭﻥ )ﺩﻗﻳﻘﻪ‬ : ‫ﺗﺷﺭﻳﺣﻲ‬ : ‫ ﺗﺳﺗﻲ‬: ‫ﺗﻌﺩﺍﺩ ﺳﻭﺍﻻﺕ‬

1   : ‫ﻋﻧــﻭﺍﻥ ﺩﺭﺱ‬

   ,( )  ,(   )  : ‫ﮐﺩ ﺩﺭﺱ‬/‫ﺭﺷﺗﻪ ﺗﺣﺻﻳﻠﻲ‬

5 V37 + C` 2Y > &* g!< # # 0l> (W +) "!- % 50 >7 #06 V06( > .& %3:  -٩

2( %& =>c ?67  &  \6]: 8!M #E 298  0, 10 V37 # 0,
M Ar = 39.93 g , R = 8.314 J / molK = 0.08206lit .atm / molK

+3151 .  +3251 .  E2151 .  E1251 .

%& =>c ?67  L!6M( #E 95 ) L!6M( #E 25 + h 5- =! 3/2 " %  %+i  &J - ١٠
2(
C=4.184 J/g K , M H2O =18.01 g/ mol

16900 .  19700 .  15250 .  12500 .

!  #30: $!) "!:l %& + "2( 2K &$ *  >$ V06(  c: " #ME - ١١

GHI .  G< .  G" .  " .

: !   "!6)o=>c ?@ g!p$  .!  ( a Y * > \6]: K  + - ١٢

HI 4 JK9 .  HI "  .

HI "  " JK9 .  HI 4 #L . 

2( %& ?)) # "- #:4; W7 !: #j; L( - ١٣

1BA
 E"##

 E"##
 E 1BA  .

"##

 E 1BA
 E"##
 E 1BA  . 
"##
 E"##

 E 1BA  E 1BA
 . 
"##

 E 1BA  E 1BA
 E"##
 . 

#E 373/15  > 0, 5 V37 + C`: 2Y > >  g!< # (W +) "!- + + =!2 W 06( - ١۴
&$ q 2( &J; 8!M ?67 :`  .!  '6]$ 96)  Ej Y  0, 20 V37 # 8!M
3
.2( R 2K V37  "-  2d > 2( >6 Mj Y  Ej Y
2
R = 8.314 J / molK
251/3 .  125/2 .  281/2 .  325/1 .

2( &J + *r0 +  %& - ١۵

 !K .  #  .   . MNO .

6 ‫ ﺍﺯ‬2 ‫ﺻﻔﺣﻪ‬ 1393-94 ‫ﻧﻳﻣﺳﺎﻝ ﺩﻭﻡ‬ 1010/101033434

1394/04/02 ‫ﻛﺎﺭﺷﻧﺎﺳﻲ ﻭ ﻛﺎﺭﺷﻧﺎﺳﻲ ﺍﺭﺷﺩ‬
08:00

 : ‫ﺳﺭﻱ ﺳﻭﺍﻝ‬ : ‫ﺗﺷﺭﻳﺣﻲ‬  : ‫ ﺗﺳﺗﻲ‬: (‫ﺯﻣﺎﻥ ﺁﺯﻣﻭﻥ )ﺩﻗﻳﻘﻪ‬ : ‫ﺗﺷﺭﻳﺣﻲ‬ : ‫ ﺗﺳﺗﻲ‬: ‫ﺗﻌﺩﺍﺩ ﺳﻭﺍﻻﺕ‬

1   : ‫ﻋﻧــﻭﺍﻥ ﺩﺭﺱ‬

   ,( )  ,(   )  : ‫ﮐﺩ ﺩﺭﺱ‬/‫ﺭﺷﺗﻪ ﺗﺣﺻﻳﻠﻲ‬

2( %& $!) => "!:l @ " - ١۶

∆U = w + q . ∆U = dw + dq .

U =w + q . dU = w + q .

 #X,s  #$ %& !j +-  =>c l- - ١٧

(∂U / ∂V )T ,n . (∂U / ∂V ) P ,n . (∂U / ∂P )T ,n . (∂U / ∂T ) p , n .

&J .!  t # W&]) C` 2Y !u # 96)  2K Y  > L!6M( #E 9<  h 5- =! 2 - ١٨

5- ,!A,! %E > 2( %  =>c o333/5   5- .b> v,0:- r) 2( %& =>c ?67 .& #,] 
.2( =!  % 18/02  

. . . .
1.35 × 104 2.23 × 103 − 2.215 ×103 − 1.202 × 104
2( #$ %& =X 2K V37  $>  - ١٩

∆G . ∆U . ∆H . ∆S .

=!  =>c!M ?67 + * . + .90(  8!M #E 298/15  + $> &:0( 2,7 v,0:- r) - ٢٠

2( %&
N 2O 4( g ) → 2NO 2( g )
∆H (oNO 2 ) = 33.095KJ / mol , ∆H (oN 2O 4 ) = 9.079KJ / mol
34/12 .  46/12 .  57/11 .  66/11 .

26: 9<  %& &:0( WAY) v,0:- - ٢١

H2 . CO 2 . O2 . (:3) C .

- ٢٢
2( %& =!  =>c !M ?67  8!M #E 298/15   + $>  ∆(PV ) &J

2 H 2 ( g ) + O2 ( g ) → 2 H 2O (l ) , R = 8.314 J / molK

6/737 .  E9/274 .  8/231 .  E7/437 .

6 ‫ ﺍﺯ‬3 ‫ﺻﻔﺣﻪ‬ 1393-94 ‫ﻧﻳﻣﺳﺎﻝ ﺩﻭﻡ‬ 1010/101033434

1394/04/02 ‫ﻛﺎﺭﺷﻧﺎﺳﻲ ﻭ ﻛﺎﺭﺷﻧﺎﺳﻲ ﺍﺭﺷﺩ‬
08:00

 : ‫ﺳﺭﻱ ﺳﻭﺍﻝ‬ : ‫ﺗﺷﺭﻳﺣﻲ‬  : ‫ ﺗﺳﺗﻲ‬: (‫ﺯﻣﺎﻥ ﺁﺯﻣﻭﻥ )ﺩﻗﻳﻘﻪ‬ : ‫ﺗﺷﺭﻳﺣﻲ‬ : ‫ ﺗﺳﺗﻲ‬: ‫ﺗﻌﺩﺍﺩ ﺳﻭﺍﻻﺕ‬

1   : ‫ﻋﻧــﻭﺍﻥ ﺩﺭﺱ‬

   ,( )  ,(   )  : ‫ﮐﺩ ﺩﺭﺱ‬/‫ﺭﺷﺗﻪ ﺗﺣﺻﻳﻠﻲ‬

* 2d .2( =!  =>c!M o241/82  8!M #E 298/15  + 2,7  5- WAY) &:0( v,0:- - ٢٣
WJ06  * 2d #A$ q  .2( + l # $>  .&$$ 2 !  2K Y  ,! 
2( &J; =!  =>c !M ?67 L!6M( #E 100  5- WAY) &:0( v,0:- .&$06*  +
C H 2 ( g ) = 28.84 J / K .mol, C H 2O ( g ) = 33.58 J / K .mol, CO2 ( g ) = 29.37 J / K .mol

327/12 .  E987/32 .  256/12 .  E322/11 .

 &) h) %&  $!) %> "!:l - ٢۴

7"5 .  83 45 C . 
S 5 . 
"# C .

- ٢۵
2( #$ %&   (qc ) ( h]$ # (q h ) % h]$  2]6: !: #j;

1 − T h /T c .
1 − T c /T h .
− T c /T h .
− T h /T c .

.Cv c: r) ">&  "& Vx$  8A . > + A &:!0 T=0 &E 2,7  CO =!A,! #A$ q  - ٢۶

2( %& 8!M =!  =>c ?67  8  CO (s ) + =! y `>0:-

2/925 .  5/764 .  4/367 .  6/256 .

- ٢٧
2( %& ∫ dq /T #06 zs( =D0: &J L!+{ >6: L(

HI "  "JK9 .  HI .

HI 4 JK9 .  HI "  "#L . 

2( %& dq/T #06 zs( =D0: &J C` 2Y #j;   - ٢٨

HI 4 JK9 .  HI .

HI "  " JK9 .  HI 4 #L . 

 24: #E 40 ( *;  > 24: #E 70 % #Y;  8 # !:  !)!  ?@ - ٢٩

2( %& a&$ 

17/6 .  15/3 .  22/7 .  19/22 .

6 ‫ ﺍﺯ‬4 ‫ﺻﻔﺣﻪ‬ 1393-94 ‫ﻧﻳﻣﺳﺎﻝ ﺩﻭﻡ‬ 1010/101033434

1394/04/02 ‫ﻛﺎﺭﺷﻧﺎﺳﻲ ﻭ ﻛﺎﺭﺷﻧﺎﺳﻲ ﺍﺭﺷﺩ‬
08:00

 : ‫ﺳﺭﻱ ﺳﻭﺍﻝ‬ : ‫ﺗﺷﺭﻳﺣﻲ‬  : ‫ ﺗﺳﺗﻲ‬: (‫ﺯﻣﺎﻥ ﺁﺯﻣﻭﻥ )ﺩﻗﻳﻘﻪ‬ : ‫ﺗﺷﺭﻳﺣﻲ‬ : ‫ ﺗﺳﺗﻲ‬: ‫ﺗﻌﺩﺍﺩ ﺳﻭﺍﻻﺕ‬

1   : ‫ﻋﻧــﻭﺍﻥ ﺩﺭﺱ‬

   ,( )  ,(   )  : ‫ﮐﺩ ﺩﺭﺱ‬/‫ﺭﺷﺗﻪ ﺗﺣﺻﻳﻠﻲ‬

26: z< #ME %& - ٣٠

.1 6A 9 1T
B M3<
7"5 U"##
1V  A # .

.:<
HV UW 0  A1V  
7"5 33XT . 
.1

 : Y  Z
7"5 U >7 : 1V  A # . 
.1
6 L  Z
7"5 U >7  : 1V  A # . 

2( B =- .& + =!  > A =- .& + =! 2 "& \!M~ `>0:- r) D: + * #$ + & - ٣١

36/3R .  909/2R .  97/2R .  1/9R .

>   # ‚> %& a8!M 1 + ) 8` * # "&(  - ٣٢

 TE"C 6 45 .  "C 6 45 .

"##

4 83\ VX .  T"T D1;  . 

2( %& ƒ,>&:> +  Mj Y g]B - ٣٣

. . b . -b .
n 2 /V 2 an 2 /V 2

2( %& (G) ƒ] +- c:  ƒ] h) - ٣۴

H −TS . H + TS . U + PV . U −TS .

2( #$ %&  dU a$!)  M6:9 > (( giX L( - ٣۵

VdP − SdT . −PdV − SdT . TdS + PdV . TdS − PdV .

2( z< #ME %& - ٣۶

.:< W 0 6V9" "#" 1? ∆G 〉 o  .  .:< W 0 3] 6V9" 1? ∆G 〈o  .

.:< 4 @ # 9 6V9" 1? ∆G 〉 o  .  .:<3 @ # 9 6V9" 1? ∆G 〈o  .

- ٣٧
2( g!< #; # @ $>   K x ,K p 8 #s

Kx = K p /P . K p = Kx /P . .
K x = K p P − ∆n .
K x = K p P ∆n

6 ‫ ﺍﺯ‬5 ‫ﺻﻔﺣﻪ‬ 1393-94 ‫ﻧﻳﻣﺳﺎﻝ ﺩﻭﻡ‬ 1010/101033434

‫‪1394/04/02‬‬ ‫ﻛﺎﺭﺷﻧﺎﺳﻲ ﻭ ﻛﺎﺭﺷﻧﺎﺳﻲ ﺍﺭﺷﺩ‬
‫‪08:00‬‬

‫ﺳﺭﻱ ﺳﻭﺍﻝ ‪ :‬‬ ‫ﺗﺷﺭﻳﺣﻲ ‪:‬‬ ‫ﺯﻣﺎﻥ ﺁﺯﻣﻭﻥ )ﺩﻗﻳﻘﻪ( ‪ :‬ﺗﺳﺗﻲ ‪ :‬‬ ‫ﺗﺷﺭﻳﺣﻲ ‪:‬‬ ‫ﺗﻌﺩﺍﺩ ﺳﻭﺍﻻﺕ ‪ :‬ﺗﺳﺗﻲ ‪:‬‬

‫‪1   :‬‬ ‫ﻋﻧــﻭﺍﻥ ﺩﺭﺱ‬

‫ﺭﺷﺗﻪ ﺗﺣﺻﻳﻠﻲ‪/‬ﮐﺩ ﺩﺭﺱ ‪   ,( )  ,(   )  :‬‬

‫‪- ٣٨‬‬
‫‪ ∂T ‬‬
‫‪2( + g]B +‬‬ ‫‪&„ =X ‬‬ ‫(‪ g]B a=!6„ giX L‬‬
‫‪ ∂P  S‬‬

‫ ‪ ∂S  .‬‬ ‫ ‪ ∂P  .‬‬ ‫ ‪ ∂P  .‬‬ ‫‪ ∂V  .‬‬

‫‪− ‬‬ ‫‪− ‬‬ ‫‪‬‬ ‫‪‬‬ ‫‪‬‬ ‫‪‬‬
‫‪ ∂P  T‬‬ ‫‪ ∂S V‬‬ ‫‪ ∂T V‬‬ ‫‪ ∂S  P‬‬

‫‪- ٣٩‬‬
‫(‪8!M #E 500   $> 8 =X) 2Ka2‬‬ ‫‪6 × 105‬‬ ‫‪  8!M #E 298  †:!- 0$( =X) 2K‬‬
‫‪R = 8.314 j / molK .&   −92.2kj / mol &:0( $> v,0:- .&$ 567‬‬

‫ ‪0/12 .‬‬ ‫ ‪3/23 .‬‬ ‫ ‪0/18 .‬‬ ‫‪2/12 .‬‬

‫‪- ۴٠‬‬
‫‪2( %& HCN (aq ) a5-  &( :(>&* i! 0/2 =!M pH‬‬

‫‪pK a = 9.31‬‬
‫‪3 .‬‬ ‫‪5 .‬‬ ‫‪7 .‬‬ ‫‪6 .‬‬

‫ﺻﻔﺣﻪ ‪ 6‬ﺍﺯ ‪6‬‬ ‫ﻧﻳﻣﺳﺎﻝ ﺩﻭﻡ ‪1393-94‬‬ ‫‪1010/101033434‬‬