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Test / Exam Name: Equilibrium Standard: 11TH SCIENCE Subject: CHEMISTRY

Student Name: Section: Roll No.:

Questions: 19 Time: 60 Mins Marks: 51

Instructions
1. 1-10 questions are for physical & chemical equilibrium .
2. If student is only taking CE & PE attempt only 2 mark questions.
3. If taking CE & PE + Theory of ionic equilibrium, then attempt 5 Questions 2 marks & followed by all questions of 3 marks.
4. If attempting complete chapter; take 5 Questions 2 marks each & 4 questions 3 marks and all questions for 4 marks.
5. Chemical & physical equilibrium .

Chemical and physical equilibrium

Q 1. Calculate the equilibrium constant for the following equilibrium system at 1120K. 2 Marks
Kp ​
C(s) + CO2 ​(g) + 2Cl2 ​ ⇌ ​2COCl2 ​(g)
Given the following equations and equilibrium constants:
CO(s) + Cl2 ​(g) ⇌ COCl2 ​(g)
Kp1 ​ = 6.0 × 10 − 3 … (1)
CO(s) + Cl2 ​(g) ⇌ CO2 ​(g)
Kp2 ​ = 1.3 × 1014 … (2)

Q 2. Reaction between N2 and O2– takes place as follows: 2 Marks

​ ​ ​
2N2 (g) + O2 (g) ⇌ 2N2 O(g)
If a mixture of 0.482mol N2 and 0.933mol of O2 is placed in a 10L reaction vessel and allowed to form N2O at
a temperature for which Kc ​= 2.0 × 10−37 , determine the composition of equilibrium mixture.
Q 3. 2 Marks
i. Hydrolysis of sucrose give

Sucrose + H2 ​O ⇌ Glucose + Fructose

Equilibrium constant Kc for the reaction is 2 × 1013 at 300K. Calculate ΔG∘ at 300K.(log 2 = 0.3010)

ii. The concentration of hydrogen in two sample of soft drinks A and B 4.0 × 10-7 and 3.2 × 10-

6 respectively. Which of these two soft drinks has higher pH?

Q 4. The equilibrium constant for the following reaction is 1.6 ×105 at 1024K H ​(g) + Br (g) ⇌ 2HBr (g) Find 2 Marks
2
the equilibrium pressure of all gases if 10.0 bar of HBr is introduced into a
sealed container at 1024K.
Q 5. 2 Marks
i. The reaction quotient of a reversible reaction is QC and the equilibrium constant is Kc. What do you

conclude for the reaction if Qc < Kc?

ii. State Le Chatelier's principle.

iii. In qualitative analysis, NH4Cl is added before adding NH4OH solution for testing of III group radicals

[Fe3+, Cr3+ and Al3+]. Explain by using concept of common ion effect.

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Q 6. 2 Marks
i. Consider the following endothermic reaction:

CH4 ​(g) + H2 ​O(g) ⇌ CO(g) + 3H2 ​(g)

a. Write expression for Kp for the above reaction.
b. How will the values of Kp and composition of equilibrium mixture be affected by.
1. increasing the pressure.
2. increasing the temperature.
3. using a catalyst?

ii. Calculate the pH of the resultant mixture of 10ml of 0.1M H2SO4 + 10 ml of 0.1M KOH.

Q 7. A mixture of 1.57 mol of N2, 1.92 mol of H2 and 8.13 mol of NH3 is introduced into a 20L reaction 2 Marks
vessel at 500K. At this temperature, the equilibrium constant, Kc for the reaction N2 ​(g) + 3H2 ​(g) ⇌
2NH3 ​(g) is 1.7 × 102 . Is the reaction mixture at equilibrium? If not, what is the direction of the net reaction?
​ ⇌ PCl3 ​(g) + Cl2 ​(g) is 0.04 at 25∘ C.
Q 8. Kc ​for PCl5 (g) 2 Marks
How much moles of PCl5 must be added to 3L flask to obtain a chlorine concentration of 0.15M.

Q 9. A ⇌ B ​ K1 ​= 1 ​ B ⇌ C ​ K2 ​= 2 ​ 2 Marks
C ⇌ D K3 ​= 3 D ⇌ E K4 ​= 4
What is value of K for A ⇌ E?
Q 10. What is meant by reaction quotient? Give its expression. 2 Marks
Theory for ionic equilibrium
Q 11. Write two equations to show the amphiprotic (acid as well as base) property of water. 3 Marks

Q 12. Why solution of sugar in water does not conduct electricity whereas that of common salt in water 3 Marks
does?
Q 13. Explain the following: 3 Marks

i. Common ion effect.

ii. Bronsted Lowry concepts of acids and bases.

Q 14. Neutral solutions have pH = 7 at 298K. A sample of pure water is found to have pH < 7. Does it mean 3 Marks
that it is acidic? Explain.

Q 15. What do you understand by following? 3 Marks

i. Dissociation constant of an acid.

ii. Buffer solution.

iii. Solubility product.

Numericals for ionic equilibrium

Q 16. If K = 49 × 10-14, what will be neutral pH of H O? 4 Marks
w 2

Q 17. The solubility of silver chloride (AgCl) in water at 25°C is 1.06 × 10-5mol L-1. Calculate the solubility 4 Marks
product of AgCl at this temperature.
Q 18. Calculate the pH of 1 × 10-8M solution of HCl. 4 Marks

Q 19. 4 Marks
i. Which of the following are Lewis acids?

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 H2 ​O, BF3 ​, H+ and NH+
4​
ii. The pH of a sample of vinegar is 3.76. Calculate the concentration of hydrogen ion in it.

iii. What is common ion effect? Explain its application in qualitative analysis of II group radicals.

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