VISWASAI IIT ACADEMY NELLORE & TIRUPATI

SENIOR MPC (VJOI & JOI) REVISION ASSIGNMENTS

CHEMISTRY ASSIGNMENT-3 DATE:09.11.2023
1. The correct set of four quantum numbers for the 8. Of the following sets, which one does not contain
valence electrons of rubidium atom [Z = 37] is isoelectronic species ?
1 1 1) BO33 , CO 32  , NO 3
1) 5,0,0,  2) 5,1,0, 
2 2
2) SO 32  ,CO 32  , NO 3

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1 1
3) 5,1,1,  4) 5,0,1, 
2 2 3) CN  , N 2 ,C 2 2  4) PO 43 , SO 4 2 , ClO4 
2. The electrons identified by quantum numbers n and 9. Which of the following sets of quantum numbers is
 correct for an electron in 4f orbital ?
1) n = 4,   1 2) n = 4,   0
3) n = 3,   2 4) n = 3,   1 1
1) n  4,   3, m  4,s  
can be placed in the order of increasing energy is 2
1) 3 < 4 < 2 < 1 2) 4 < 2 < 3 < 1
1
3) 2 < 4 < 1 < 3 4) 1 < 3 < 2 < 4 2) n  4,   4,m  4,s  
3. A gas obsorbs photon of 355 nm and emits at two 2
wavelengths. If one of the emission is at 680 nm, the 1
other is at 3) n  4,   3, m  1,s  
2
1) 1035 nm 2) 325 nm 3) 743 nm 4) 518 nm
4. Which of the following sets of quantum numbers 1
represents the highest energy of an atom ? 4) n  3,   2,m  2,s  
2
1 10. Consider the ground state of Cr atom (Z = 24(. The
1) n  3,   1, m  1,s  
2 numbers of electrons with the azimuthal quantum
1 numbers,   1 and 2 are, respectively
2) n  3,   2, m  1,s   1) 12 and 4 2) 12 and 5 3) 16 and 4 4) 16 and 5
2
11. Which one of the following sets of ions represents
1
3) n  3,   0,m  0,s   the collection of isoelectronic species ?
2 (Atomic numbers of F = 9, Cl = 17, Na = 11, Mg = 12,
1 Al = 13, K = 19, Ca = 20, Sc = 21)
4) n  3,   0,m  0,s   1) K+, Ca2+, Sc3+, Cl– 2) Na+, Ca2+, Sc3+, F–
2
5. Which of the following nuclear reactions will generate 3) K+, Cl–, Mg2+, Sc3+ 4) Na+, Mg2+, Al3+, Cl–
an isotope ? 12. In Bohr series of lines of hydrogen spectrum, the third
1) Neutron particle emission line from the red end corresponds to which one of the
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2) Positron emission following inner-orbit jumps of the electron for bohr

3)   particle emission 4)   particle emission orbits in an atom of hydrogen ?
6. According to Bohr's theory, the anglar momentum of 1) 3  2 2) 5  2 3) 4  1 4) 2  5
an electron in 5th orbit is 13. The number of d-electrons retained in Fe2+ (atomic
h h h h number Fe = 26) ion is
1) 25 2) 1.0 3) 10 4) 2.5 1) 3 2) 4 3) 5 4) 6
   
7. In a multielectron atom, which of the following orbitals 14. The orbital angular momentum for an electron
described by the three quantum numbers will have h
the same energy in the absence of magnetic and revolving in an orbit is given by     1 . This
2
electric fields ?
momentum for s-electron will be given by
A) n  1,   0,m  0 B) n  2,   0,m  0
C) n  2,   1, m  1 D) n  3,   2,m  1 1 h h h
1)  . 2) zero 3) 4) 2.
2 2 2 2
E) n  3,   2,m  0
1) D and E 2) C and D 3) B and C 4) A and B
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15. Energy of H-atom in the ground state is –13.6 eV 26. The correct IUPAC name of the compound is
hence energy in the second excited state is
1) –6.8 eV 2) – 3.4 eV 3) –1.51 eV4) –4.53 eV
16. But-2-ene exhibits cls-trans-isomerism due to is
1) Rotation around C3 – C4 bonds
2) Restricted rotation arond C = C bond 1) 3-(1-ethyl propyl)hex-1-ene
3) Rotation around C1 – C2 bond 2) 3, 4-Diethyl hex-1-ene
4) Rotation around C2 – C3 double bond 3) 3-ethyl-4-ethenyl heptane
17. Which of the folowing cannot exhibit geometrical 4) 3-ethyl-4-propyl hex-5-ene
isomerism 27. Structure of the compound whose IUPAC name is
3-Ethyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid is
1) a2C = Cb2 2) abC=Cde

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3) adC-Cab 4) AbC=Cda
18. Which of the following exhibit cis-trans isomerism 1) 2)
1) Propene 2) 1-butene 3) 2-butene 4) benzene
19. Geometrical isomerism is shown by
1) CH2=C(Br)I 2) CH3CH=C(Br)I
3) (CH3)2C=C(Br)I 4) CH3CH=CCl2 3) 4)
20. The E-isomer is
28 Given

A) B)

C) D)

21. Which among the following compound show Which of the given compounds can exhibit
geometrical isomerism tautomerism ?
1) II and III 2) I, II and III 3) I and II 4) I and III
I) 1-butene II) 2-butene
29. Among the following the aromatic compound is
III) 2-emthyl-2-butene IV) 2-pentene
1) II, III 2) II, III, IV3) II, IV 4) I, II, IV
22. No. of geometrical isomers possible for the compound 1) 2) 3) 4)

CH 3  CH  CH  CH  CH  C 2 H5 30. The IUPAC anem of the compound

1) 2 2) 3 3) 4 4) 5
23. Geometrical isomerism is not shown by

1) 2)
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3) 4)
24. The IUPAC name of 1) 3-keto-2methylhex-4-enal
CH 3 O 2) 5-formylhex-2-en-3-one
| || 3) 5-methyl-4-oxohex-2-en-5-al
CH 3  C  C  CH 2  CH 2 OH 4) 3-keto-2-methylhex-5-enal
1) 1-hydroxy-4-methyl pentan-3-one KEY
2) 2-methyl-5-hydroxy pentan-3-one 1) 1 2) 2 3) 3 4) 2 5) 1
3) 4-methyl-3-oxopentan-1-ol 6) 4 7) 1 8) 2 9) 3 10) 2
4) hexan-1-ol-3-one
25. The number of structural iosmers possible from the
11) 1 12) 2 13) 4 14) 2 15) 3
moleculear formula C3H9N 16) 2 17) 1 18) 3 19) 2 20) 2
1) 2 2) 3 3) 4 4) 5 21) 3 22) 3 23) 1 24) 1 25) 3
26) 2 27) 4 28) 2 29) 1 30) 1

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