SARVSRESTHA INSTITUTE

ATOMIC STRUCTURE

1. The nucleus of the element having atomic number 25 and atomic weight 55 will
contain :
(1) 25 protons and 30 neutrons (2) 25 neutrons and 30 protons
(3) 55 protons (4) 55 neutrons
2. Which of the following constitutes a group of the isoelectronic species
(1) NO , C , CN , N (2) CN , N , O , C
(3) N , O , NO , CO (4) C , O , CO, NO
3. Isoelectronic species are
(1) 𝐾 , 𝐶𝑙 (2) 𝑁𝑎 , 𝐶𝑙 (3) 𝑁𝑎, 𝐴r (4) 𝑁𝑎 , 𝐴𝑟
4. An isostere is :
(1) 𝑁𝑂 and 𝑂 (2) 𝑁𝑂 and 𝑃𝑂
(3) 𝐶𝑂 , 𝑁 𝑂, 𝑁𝑂 (4) 𝐶𝑙𝑂 and 𝑂𝐶𝑁
5. The nitride ion is lithium nitride is composed of
(1) 7 protons + 10 electrons (2) 10 protons + 10 electrons
(3) 7 protons +7 protons (4) 10 protons + 7 electrons
6. An isotone of 𝐺𝑒 is
(1) 𝐺𝑒 (2) 𝐺𝑒 (3) 𝐺𝑒 (4) 𝐺𝑒
7. In special series of hydrogen, the series which does not come in infrared region is
(1) Pfund (2) Brackett (3) Paschen (4) Lyman
8. According to Bohr’s theory, the angular momentum of an electron in 5th orbit is
(1) 25/𝜋 (2) 1.0 h/ 𝜋 (3) 10h/ 𝜋 (4) 2.5h/ 𝜋
9. Splitting of spectral lines under the influence of magnetic field is called
(1) Zeeman Effect (2) Stark Effect
(3) Photoelectric Effect (4) None of these
10. The ratio of area covered by second orbit to the first orbit is
(1) 1:2 (2) 1:16 (3) 8:1 (4) 16:1
11. The radius of which of the following orbit is same as that of the first Bohr’s orbit of
hydrogen atom
(1) 𝐻𝑒 (𝑛 = 2) (2) 𝐿𝑖 (𝑛 = 2) (3) 𝐿𝑖 (𝑛 = 3) (4) 𝐵𝑒 (𝑛 = 2)
12. The energy equivalent of 2.0 mg mass defect is
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(1) 1.8 × 10 𝑒𝑟𝑔 (2) 9 × 10 𝑒𝑟𝑔 (3) 1.5 × 10 𝑒𝑟𝑔 (4) 1.8 × 10 𝑒𝑟𝑔
13. What is the maximum no. of emission lines obtained when the excited electrons of a
hydrogen atom in 𝑛 = 5 drop to ground state
(1) 10 (2) 5 (3) 12 (4) 15
14. In photoelectric effect, the kinetic energy of photoelectrons increases linearly with the
(1) Wavelength of incident light
(2) Frequency of incident light
(3) Velocity of incident light
(4) Atomic mass of an element
15. If Helium atom and Hydrogen molecule are moving with the same velocity, their
wavelength ratio will be
(1) 4: 1 (2) 1: 2 (3) 2: 1 (4) 1: 4
16. The correct ground state electronic configuration of chromium atom is
(1) [𝐴𝑟]3𝑑 4𝑠 (2) [𝐴𝑟]3𝑑 4𝑠 (3) [𝐴𝑟]3𝑑 4𝑠 (4) [𝐴𝑟]4𝑑 4𝑠
17. The electronic configuration of calcium ion (𝐶𝑎 ) is
(1) 1𝑠 , 2𝑠 2𝑝 , 3𝑠 3𝑝 , 4𝑠 (2) 1𝑠 , 2𝑠 𝑠𝑝 , 3𝑠 3𝑝 , 4𝑠
(3) 1𝑠 , 2𝑠 2𝑝 , 3𝑠 3𝑝 3𝑑 (4) 1𝑠 , 2𝑠 𝑠𝑝 , 3𝑠 3𝑝 3𝑑
(5) 1𝑠 , 2𝑠 2𝑝 , 3𝑠 3𝑝 , 4𝑠
18. Which of the following sequence is correct as per Aufbau principle
(1) 3𝑠 < 3𝑑 < 4𝑠 < 4𝑝 (2) 1𝑠 < 2𝑝 < 4𝑠 < 3𝑑
(3) 2𝑠 < 5𝑠 < 4𝑝 < 5𝑑 (4) 2𝑠 < 2𝑝 < 3𝑑 < 3𝑝
19. Which of the following ions is not having the configuration of neon
(1) 𝐹 (2) 𝑀𝑔 (3) 𝑁𝑎 (4) 𝐶𝑙
20. When 3d orbital is complete, the new electron will enter the
(1) 4𝑝-orbital (2) 4𝑓-orbital (3) 4𝑠-orbital (4) 4𝑑-orbital
21. There is no difference between a 2p and a 3p orbital regarding
(1) Shape (2) Size (3) Energy (4) Value of n
22. Which of the following represents the correct sets of four quantum number of 4d
electron
(1) 4, 3, 2, (2) 4,2,10 (3) 4, 3, − 2, + (4) 4, 2, 1, −

23. A 3p-orbital is
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(1) Two spherical nodes

(2) Two non-spherical nodes
(3) One spherical and one non-spherical nodes
(4) One spherical and two non-spherical nodes
24. Aufbau principle is obeyed in which of the following electronic configurations
(1) 1𝑠 2𝑠 2𝑝 (2) 1𝑠 3𝑝 3𝑠 (3) 1𝑠 3𝑠 3𝑝 (4) 1𝑠 2𝑠 3𝑠
25. Which of the following set of quantum numbers is possible
(1) 𝑛 = 3; 𝑙 = 2, 𝑚 = 2 and 𝑠 = +

(2) 𝑛 = 3; 𝑙 = 4, 𝑚 = 0 and 𝑠 = −

(3) 𝑛 = 4; 𝑙 = 0, 𝑚 = 2 and 𝑠 = +

(4) 𝑛 = 4; 𝑙 = 4, 𝑚 = 3 and 𝑠 = +

26. The configuration 1𝑠 , 2𝑠 2𝑝 , 3𝑠 shows

(1) Excited state of 𝑂
(2) Excited state of neon
(3) Excited state of fluorine
(4) Ground state of fluorine atom
27. Number of orbitals in ℎ sub-shell is
(1) 11 (2) 15 (3) 17 (4) 19
28. Which of the following has the least energy
(1) 2𝑝 (2) 3𝑝 (3) 2𝑠 (4) 4𝑑
29. The set of quantum number of the outermost electron for copper in its ground state is
……
(1) 4,1,1,+1/2 (2) 3,2,2, +1/2 (3) 4,0,0, +1/2 (4) 4,2,2, +1/2
30. Which of the following orbitals has zero probability of finding the electron in the xy-
plane
(1) 𝑝 (2) 𝑝 (3) 𝑑 (4) 𝑑
31. The increasing order (lowest first) for the values of e/m (charge/mass) for
(1) 𝑒, 𝑝, 𝑛, 𝛼 (2) 𝑛, 𝑝, 𝑒, 𝛼 (3) 𝑛, 𝑝, 𝛼, 𝑒 (4) 𝑛, 𝛼, 𝑝, 𝑒
32. Which of the following electron transition in a hydrogen atom will require the largest
amount of energy

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(1) From 𝑛 = 1 to 𝑛 = 2 (2) From 𝑛 = 2 to 𝑛 = 3

(3) From 𝑛 = ∞ to 𝑛 = 1 (4) From 𝑛 = 3 to 𝑛 = 5
33. The correct set of quantum numbers for the unpaired electron of chlorine atom is
𝑛 𝑙 𝑚
(1) 2 1 0
(2) 2 1 1
(3) 3 1 1
(4) 3 0 0
34. The orbital diagram in which the Aufbau’s principle is violated is
2𝑠 2𝑝 2𝑝 2𝑝
(1) ↑↓ ↑↓ ↑ ↑
(2) ↑ ↑↓ ↑ ↑
(3) ↑↓ ↑ ↑ ↑
(4) ↑↓ ↑↓ ↑↓ ↑
35. The mass of neutron is nearly
(1) 10 𝑘𝑔 (2) 10 𝑘𝑔 (3) 10 𝑘𝑔 (4) 10 𝑘𝑔
36. Which electron level would allow the hydrogen atom to absorb a photon but not to
emit a photon
(1) 3𝑠 (2) 2𝑝 (3) 2𝑠 (4) 1𝑠
37. Which of the following is not correct for electron distribution in the ground state
4𝑠 3𝑑
(1) 𝐶𝑜(𝐴𝑟) ↑↓ ↑↓ ↑↓ ↑ ↑ ↑
(2) 𝑁𝑖(𝐴𝑟) ↑↓ ↑↓ ↑↓ ↑↓ ↑ ↑
(3) 𝐶𝑢(𝐴𝑟) ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑
(4) 𝑍𝑛(𝐴𝑟) ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓
38. The orbital angular momentum of an electron is 𝑠 orbital is

(1) + ∙ (2) Zero (3) (4) √2 ∙

39. Values of the four quantum numbers for the last electron in the atom are 𝑛 = 4, 𝑙 =
1, 𝑚 = +1 and 𝑠 = − . Atomic number of the atom will be

(1) 22 (2) 32 (3) 33 (4) 36

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40. The atomic weight of an element is 39. The number of neutrons in its nucleus is one
more than the number of protons. The number of protons, neutrons and electrons
respectively in its atom would be
(1) 19, 20, 19 (2) 19, 19, 20 (3) 20, 19, 19 (4) 20, 19, 20
41. The electrons identified by quantum numbers 𝑛 and 𝑙 (i) 𝑛 = 4, 𝑙 = 1 (ii) 𝑛 = 4, 𝑙 = 0
(iii) 𝑛 = 3, 𝑙 = 2, (iv) 𝑛 = 3, 𝑙 = 1 can be placed in order of increasing energy from the
lowest to highest, as
(1) (iv) < (ii) < (iii) < (i) (2) (ii) < (iv) < (i) < (iii)
(3) (i) < (iii) < (ii) < (iv) (4) (iii) < (i) < (iv) < (ii)
42. The total number of electrons present in all the 𝑠-orbitals, all the 𝑝-orbitals and all
the 𝑑-orbitals of cesium ion are respectively
(1) 8, 26, 10 (2) 10, 24, 20 (3) 8, 22, 24 (4) 12, 20, 22
43. The de-Broglie wavelength of a tennis ball of mass 60 g moving with a velocity of 10
metres per second is approximately
(1) 10 meters (2) 10 meters (3) 10 meters (4) 10 meters
44. The value of Planck’s constant is 6.63 × 10 𝐽𝑠. The velocity of light is 3.0 × 10 𝑚𝑠 .
Which value is closest to the wavelength in nanometres of a quantum of light with
frequency of 8 × 10 𝑠 .
(1) 3 × 10 (2) 2 × 10 (3) 5 × 10 (4) 4 × 10
45. If uncertainty in position and momentum are equal, then uncertainty in velocity is

(1) (2) (3) (4)

ROUGH WORK

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