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Topic Covered :
Instructions :
1. Duration of Test is 3 hrs.
2. The test booklet consists of 90 questions. The maximum marks are 300.
3. There are three parts in the questions paper A, B, C consisting of Physics, Chemistry and Mathematics
having 30 questions in each part of equal weightage. Each part has two sections.
(i) Section-I : This section contains 20 multiple choice questions which have only one correct answer. Each
questions carries +4 marks for correct answer and –1 mark for wrong answer.
(ii) Section-II : This section contains 10 questions. In Section II, attempt any five questions out of 10. The
answer to each of the questions is a numerical value. Each question carries 4 marks for
correct answer and there is –1 mark for wrong answer.
CHEMISTRY
depends on the gas taken in the tube. molarity of H2SO4 (approx.) in final solution is?
(1) 1.16 (2) 2.32
The correct statement(s) is/are:
(3) 3.48 (4) 1.12
(1) Only I
19. Consider the data.
(2) Only II
(3) Both I and II
(4) Neither I nor II
15. The correct set of quantum numbers for the last
electron of Sc (atomic number = 21) is
(1) n = 4, l = 0, m = 0, s = +1/2
(2) n = 4, l = 0, m = 0, s = – 1/2
(3) n = 3, l = 1, m = –1, s = +1/2
(Use hc = 1244 eV-nm)
(4) n = 3, l = 2, m = 0, s = – 1/2
Select correct statement.
16. The graph of radial distribution function
(1) When light 'P' is incident on metal A and B, the
2
r 4r 2
versus radial distance (r) for an kinetic energy of photoelectron of A is more
than B by 1 eV (approx.)
orbital of a unielectronic species is drawn as:
(2) Light 'P' can show photoelectric effect with B _____respectively. (Round off to the Nearest
and C Integer).
(3) Light 'Q' cannot show photoelectric effect with 24. The work function of sodium metal is
any metal A, B and C 4.41 × 10–19 J. If photons of wavelength 300 nm
(4) Light 'P' cannot show photoelectric effect with are incident on the metal, the kinetic energy of the
any metal A, B or C ejected electrons will be (h = 6.63 × 10–34 J s;
20. Ionisation energy of an element are c = 3 × 108 m/s) ________ × 10–20 J. (Round off to
IE1 = 800.6 kJ/mol, IE2 = 2427.1 kJ/mol, the nearest integer)
IE3 = 3659.7 kJ/mol, IE4 = 25025.8 kJ/mol, 25. A proton and a Li3+ nucleus are accelerated by the
IE5 = 32826.7 kJ/mol. The element may belongs to same potential. If Li and p denote the de Broglie
(1) 1st group (2) 15th group wavelengths of Li3+ and proton respectively, then
(3) 13th group (4) 14th group Li
the value of is x × 10–1.
SECTION - II p
Numerical Value Type Questions: This section The value of x is _____. (Rounded off to the
contains 10 questions. In Section II, attempt any five nearest integer)
questions out of 10. The answer to each question is a [Mass of Li3+ = 8.3 × mass of proton]
NUMERICAL VALUE. For each question, enter the 26. The Azimuthal quantum number for the valence
correct numerical value (in decimal notation, electrons of Ga+ ion is _______.
truncated/rounded‐off to the second decimal place; e.g. (Atomic number of Ga = 31)
06.25, 07.00, 00.33, 00.30, 30.27, 27.30) using the 27. 4.3 g of a hydrated salt MSO4 xH2O gives 3.4 g
mouse and the on-screen virtual numeric keypad in the anhydrous salt. If the molar mass of the hydrated
place designated to enter the answer. salt is 172 g/mol, then the value of X is
21. ________ grams of 3-Hydroxy propanal (MW = 28. On heating Ag2CO3 decomposes as :
74) must be dehydrated to produce 7.8 g of 1
Ag2CO3 (s) 2Ag(s)+ CO2 (g) O2 (g)
acrolein (MW = 56) (C3H4O) if the percentage yield 2
is 64. If 5.52 g of pure Ag2CO3(s) on heating left a
(Round off to the Nearest Integer). residue of 4.92 g, then % yield of the reaction is
[Given : Atomic masses : C : 12.0 u, H : 1.0 u, O : (Atomic mass : Ag = 108)
16.0 u] 29. In a sample of H-atoms, initially electrons are
22. A 6.50 molal solution of KOH (aq.) has a density present in 5th excited state. On de-excitation to
of 1.89 g cm–3. The molarity of the solution is ___ ground state the number of different wavelengths
mol dm–3. (Round off to the Nearest Integer). observed in infrared region is
[Atomic masses : K : 39.0 u; O : 16.0 u; H : 1.0 u] 30. A metal surface having threshold frequency
23. Complete combustion of 750 g of an organic 2 × 1016 Hz is irradiated using photons of frequency
compound provides 420 g of CO2 and 210 g of 1 = 11 × 1016 Hz and 2 = 5 × 1016 Hz. The ratio of
H2O. The percentage composition of carbon and maximum kinetic energy of the emitted
hydrogen in organic compound is 15.3 and photoelectrons from frequency 1 to 2 is?