DELHI PUBLIC SCHOOL JODHPUR

TERM II EXAMINATION-2020-21
CLASS-11
CHEMISTRY (Theory)
Duration: 2.5 Hrs MM:50

General Instructions:
(1) All questions are compulsory.
(2) Marks against each question are indicated.
(3) Questions from one to 15 are MCQ type questions carrying one mark each
(4) In each of the questions from one to twelve, only one option is correct. Write the
correct option
(5) Questions from 16 to 20 are very short answer type questions carrying one mark
each.
(6) Questions from 21 to25 are short answer type questions carrying two marks each.

(7) Questions from 26 to 30 are short answer type questions carrying three marks each.
(8) Questions 31 is a long answer type questions carrying five mark .

1. 1

2.
1

1
 3. 1

4. The probability density plots of 1s and 2s orbitals are

1
given in Fig. 2.1:The density of dots in a region
represents the probability density of finding electrons in
the region. On the basis of above diagram which of the
following statements is incorrect?

(a) 1s and 2s orbitals are (b) The probability density of electrons for 2s orbital
spherical in shape. decreases uniformly as distance from the nucleus
increases.

(c) The probability of (d) The probability of finding the electron at a given
distance is equal in all directions
finding the electron is
maximum near the nucleus

5. In an atom maximum number of electron associated with n+l = 6 can be

__________.

(a) 4 (b) 9

(c) 18 (d) 12

6. Which of the following is incorrect about Orbitals: 1

(a) angular momentum of (b) in H atom energy of electron in

electron in : 2S orbital is : 2s orbital is same as in 2p orbital
not equal to 3s orbital

(c) size of 2p orbital is (d) shape of 3p orbital is same as that of 4p orbital

not same as that of 3p
orbital

7. The pair of ions having same value of total spin 1

(a) Cr3+, Fe3+ (b) Cr3+, Mn2+

(c) Fe2+, Mn2+ (d) Cr3+, Co2+

2
 8. What will be the molality of the solution containing 1 mole glucose is dissolved
0.58kg of its aqueous solution ? 1

(a) 1.72molal (b) 2.5

(c) 1m (d)1.5

9. The types of hybrid orbitals of Sulphur in SO2, SO3 and SF4 respectively are
expected to be 1

(a) sp, sp3 and sp2 (b) sp2, sp2 and sp3d

(c) sp2, sp2 and sp3 (d) sp2, sp3 and sp2

10. In which of the following pairs I molecule is more polar than ii molecule 1

(a) SnCl2 or BeCl2 (b) CO2 Or CO

(c) BF-4 , BCl3 (d) XeF4, XeF2

11. Which of the following species has tetrahedral geometry 1

(a) SF4 (b) XeF4

(c) XeO2F2 (d) SiCl4

12.
1

13.
1

3
 14. 1

In the following questions from 15 to 17

a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct
option out of the choices given below each question.
(a) Assertion is correct statement and reason is wrong statement.
(b) Assertion and reason both are correct statement and reason is correct explanation of assertion.
(c) Assertion and reason both are correct statements.
(d) Assertion is wrong statement and reason is correct statement.
15. 1

16. Assertion (A) : Electron gain enthalpy becomes less negative as we go down a group. 1
Reason (R) : Size of the atom increases on going down the group and the added electron
would be farther from the nucleus

17. Assertion : Atomic radius in general decreases along a period. 1

Reason : In a period, effective nuclear charge decreases

Molecular orbital theory as developed by Hund and Mulliken concerns with the formation of
molecular orbitals formed by
linear combination of atomic orbitals. The electrons are present in these molecular orbitals. The
molecular orbitals are filled exactly in the same way as atomic orbitals are filled. The molecular
orbital configuration helps us to calculate bond order which gives information about the number of
bonds present between atoms. The bond order is related to bond length and bond strength.
Answer the question 18 to 20

4
18. 1

19.
1

20.
1

21. What is the number of photons of light with a wavelength of 4000 pm that provide 1J of 2
energy ?

22. Assign oxidation number to the underlined elements in each of the following species :
(i) (ii)

OR 2
Identify the substance oxidised, reduced, oxidising agent and reducing agent for each of
the following
reactions :

23. (i) What do you mean by disproportionation redox reaction ?. 2

(ii) Which out of HNO2 and HNO3 can have disproportionation and why ?

24.
2

5
25. 2

OR

26. 3
Hydrogen gas is prepared in the laboratory by reacting dilute HCl with granulated zinc.
Following reaction takes place. Zn + 2HCl ZnCl2 + H2
Calculate the volume of hydrogen gas liberated at STP when 32.65 g of zinc reacts with
42.65g of HCl. Find limiting reagent in reaction and If 1 mol of a gas occupies 22.7 L
volume at STP; Atomic mass of Zn = 65.3 u.

27. Balance the following ionic equations 3

OR

3
28. 2L of an ideal gas at a pressure of 10 atm expands isothermally into a vacuum until its total
volume is 10L.
(i) How much heat is absorbed and how much work is done in the expansion ?
(ii) How much heat is absorbed if this system expands against a constant external pressure
of 1 atm ? (iii) How much heat is absorbed if the expansion is conducted reversibly at 298 K.

29. Pressure of 1 g of an ideal gas A at 27°C is found to be 2 bar. When 2 g of another ideal gas
B is introduced in the same flask at same temperature the pressure becomes 3 bar. Find a
relationship between their molecular masses.
3

OR

At 273 K, the density of a gaseous oxide at 2 bar is same as that of nitrogen at 5 bar. Calculate
the molecular mass of oxide.

6
30. 3

5
31. Define the following terms
(i) Enthalpy of formation (ii)Enthalpy of atomistaion
Calculate C–C bond enthalpy from the following data :

Assume 416 kJ as the C–H bond enthalpy.

OR
Define the following
(i) Lattice enthalpy (ii) Enthalpy of Fusion