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CHEMISTRY

Q.82 (Code-A) (Wave and particle nature of light) 4. Which among the following has highest first
1. Wave nature of electromagnetic radiation is ionisation enthalpy?
manifested in (1) C (2) F
(3) O (4) N
(1) Photoelectric effect (2) Black body radiation
(3) Interference (4) Both (1) & (3) Q.82 (Code-B) (Orbitals and quantum numbers)
2. Consider the following statements about 1. Total number of electrons present in p subshell of
photoelectric effect a sulphur atom is
(a) There is no time lag between the striking of (1) 4 (2) 6
light beam and the ejection of electrons from
metal surface (3) 10 (4) 12
(b) Kinetic energy of ejected electron increases 2. In multielectronic species which of the given
with decreases in wavelength of light orbitals is filled first?
(c) The number of electrons ejected in (1) 5s (2) 4p
proportional to the frequency of the light used
the correct statements are (3) 3d (4) 4f
(1) (a) and (b) only (2) (b) and (c) only 3. Maximum possible electrons in Cl, for which n + l
(3) (a) and (c) only (4) (a), (b) and (c) + m = 2 is
3. Correct order of wavelengths of given radiation (1) 10 (2) 6
is
(3) 2 (4) 4
(1) Microwave > Radio wave > IR
(2) IR > Radio wave > Microwave 4. Maximum number of electrons present in a d
orbital is
(3) Radio wave > Microwave > IR
(4) Radio wave > IR > Microwave (1) 10

Q.64. (Code-B) (Periodic properties of elements) (2) 2

1. Most electronegative element among the following
(3) 5
is
(1) Si (2) P (4) 6
(3) C (4) B
79. (Code-A) (Shapes of atomic orbitals)
2. Correct order of electronegativity of the given
elements is 1. Which graph of probability density 2(r) as a
(1) Si > B > Al > Mg function of distance r of the electron from nucleus
(2) B > Si > Al > Mg is correct for 2s orbital of H-like atom?
(3) B > Al > Si > Mg
(4) Si > Mg > Al > B
3. Correct order of negative electron gain enthalpy of
the given element is
(1) O > S > Se > Te (2) Se > Te > S > O (1) (2)
(3) S > O > Se > Te (4) S > Se > Te > O

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CSS-01 Chemistry

Q.83 (Code-A) (Energy of orbitals)

1. For multielectronic species which of the following
(3) (4) orbitals is associated with maximum energy?
(1) 3d (2) 4p
(3) 5s (4) 4s

2. The shape of which d orbital is different from dxy? 2. In the 3rd shell of H-atom, how many degenerate
orbitals are present?
(1) dx2 –y2 (2) dyz
(1) 3 (2) 2
(3) dzx (4) dz 2
(3) 6 (4) 9
3. Consider the following statements 3. Which among the following has lowest energy of
(a) For d-orbital the minimum value of principal an electron?
quantum number is 3 (1) H-atom
(b) The orbital wave function () for an electron in
(2) Li2+ ion
an atom has no physical meaning
(3) Be3+ ion
(c) Number of radial nodes present in 5p orbital is
4 (4) He+ ion
The correct statements are 4. Energy of an electron in a multielectronic species
(1) (a) and (c) only (2) (a) and (b) only depends on
(3) (b) and (c) only (4) (a), (b) and (c) (1) n value only (2) l value only
(3) (n + l) value (4) m value

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 FTS-2
Code-(A + B)

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CONCEPT STRENGTHENING SHEET

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CHEMISTRY

Q.51 (Code-A) (VSEPR Theory) 2. Unit of van der Waals constant ‘a’ is
(1) atm L mol–2 (2) atm2 L2 mol–1
1. Shape of XeF4 molecule is
(3) atm L2 mol–1 (4) atm L2 mol–2
(1) Square planar
3. The van der Waals constant ‘a’ is a measure of
(2) Tetrahedral
magnitude of
(3) Trigonal pyramidal (1) Attractive forces between the gas
(4) Square pyramidal molecules
2. Sum of lone pair(s) and bond pair(s) of electrons (2) Effective size of gas molecule
on P atom in PH3 is (3) Volume of the container
(1) 4 (2) 3 (4) Volume of the gas molecules
(3) 5 (4) 6 78. (Code-A) (Kinetic theory of Gases)
3. In which of the following compounds, all the 1. Total kinetic energy of 16g He gas at 27° C is
bond lengths are not equal? (1) 450 R (2) 600 R
(1) SF4 (2) SF6 (3) 900 R (4) 1800 R
(3) BF3 (4) XeF2 2. Minimum average kinetic energy is of
Q.63. (Code-A) (Lattice Energy) (1) 10 mol Ne at 27°C
1. Which among the following has least lattice (2) 5 mol He at 47°C
enthalpy? (3) 2 mol Xe at 57°C
(1) LiF (2) NaF (4) 15 mol Ar at 17°C
(3) KF (4) RbF 3. Kinetic energy of ideal gas is proportional to
2. Magnitude of lattice energy depends upon (1) Molecular mass of gas
(1) Ionic charges (2) Temperature of gas
(3) Product of pressure and volume
(2) Size of the ions
(4) Both (2) and (3)
(3) Distance between the ions
(4) All of these 72. (Code-A) (Liquid state)
3. Correct order of melting point is 1. Vapour pressure depends on
(1) NaBr > NaCl > NaF (2) NaF > NaBr > (1) Surface area of liquid
NaCl
(2) Volume of liquid
(3) NaF > NaCl > NaBr (4) NaCl > NaF >
NaBr (3) Temperature of liquid
Q.82 (Code-A) (van der Waals constant) (4) All of these
1. Correct order of van der Waals constant ‘b’ for
2. Unit of coefficient of viscosity is
the following gases is
(1) NH3 > Cl2 > H2 (2) Cl2 > NH3 > H2 (1) N s m–2 (2) N m

(3) Cl2 > H2 > NH3 (4) H2 > NH3 > Cl2 (3) N m–1 (4) N m2 s–1

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CSS-02 Chemistry

3. The property of liquid by virtue of which it tries 4. Pressure cooker is used for cooking food at hilly
to minimize its surface area is known as areas because
(1) Viscosity (1) Water boils at high temperature on hills
(2) Surface tension (2) Water boils at low temperature on hills
(3) Aqueous tension (3) At hilly areas water shows hardness
(4) Compressibility factor (4) At hilly areas temperature is too low

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CSS-01 Chemistry

FTS-01
Code (A + B)

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CONCEPT STRENGTHENING SHEET

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CHEMISTRY
ANSWERS
Q.82 (Code-A) (Wave and particle nature of light) 3. (4)
1. (3) 4. (2)
2. (1) 79. (Code-A) (Shapes of atomic orbitals)
3. (3) 1. (2)
Q.64 (Code-B) (Periodic properties of elements) 2. (4)
1. (3)
3. (2)
2. (2)
Q.83 (Code-A) (Energy of orbitals)
3. (4)
1. (3)
4. (2)
2. (4)
Q.82 (Code-B) (Orbitals and quantum numbers)
3. (3)
1. (3)
4. (3)
2. (3)

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CSS-01 Chemistry

FTS-02
Code (A + B)

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CONCEPT STRENGTHENING SHEET

CSS-01
CHEMISTRY
ANSWERS
Q.51 (Code-A) (VSEPR Theory) 3. (1)
1. (1)
78. (Code-A) (Kinetic theory of Gases)
2. (1)
1. (4)
3. (1)
2. (4)
Q.63. (Code-A) (Lattice Energy)
3. (4)
1. (4)
2. (4) 72. (Code-A) (Liquid state)
3. (3) 1. (3)
2. (1)
Q.82 (Code-A) (van der Waals constant)
1. (2) 3. (2)
2. (4) 4. (2)

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