NEET-CHEMISTRY-VOL-I ATOMIC STRUCTURE

Conceptual Atomic Models

9.
Ernest Rutherford’s model of the atom didn’t
Subatomic Particles specifically include the _____.
1. One of the fundamental particles is missing in 1) Proton 2) Electron
one of the isotopes of hydrogen atom. The 3) Nucleus 4) Neutron
particle and isotope are respectively 10. The conclusions of Rutherford scattering
1) Neutron, protium 2) Neutron, tritium experiment does not include:
3) Proton, protium 4) Electron, tritium 1)   particle can come within a distance of the
2. The charge of an electron is 1.6 10–19C what order of 1014 m of the nucleus.
will be the value of charge on Na+ ion.
2) The radius of the nucleus is less than 1014 m
1)1.6  10–19C 2)3.2  10–19C
3) 2.4  10–19C 4) 10  1.6  10–19C 3) Scattering follows Coulomb’s law
3. Which of the following is correct for cathode 4) The (+) vely charged particles of an atom move
rays in discharge tube with extremely high velocities.
1) Independent of the nature of the cathode Atomic Number & Mass Number
2) Independent of the nature of the gas 11. A neutral atom, with atomic number greater
3) Deflection is observed in presence of electric than one consists of
and magnetic field 1) Protons only 2) Protons and neutrons
4) All the above 3) Neutrons and electrons
4. The specific charge for a cathode ray. 4) Neutrons, electrons and protons
1) Has the smallest value when the discharge tube 12. The ratio between the neutrons present in
carbon atom and silicon atom with mass
is filled with H2
numbers 12 and 28 is
2) Is constant
1) 7 : 3 2) 3 : 7 3) 1 : 2 4) 2 : 1
3) Varies with the atomic number of gas in the
13. Many elements have non-integral masses.
discharge tube This is because
4) Varies with the atomic number of an element 1) Their isotopes have different atomic number
forming the cathode ray 2) Their isotopes have different masses
5. The specific charge for positive rays is much 3) Their isotopes have non-integral masses
less than the specific charge for cathode rays. 4) Their constituents, protons, electrons and
This is because: neutrons combine to give fractional masses
1) Positive rays are positively charged 14. Among the following which is not isoelectronic
2) Charge on positive rays is less with others
3) Positive rays comprise ionised atoms whose mass 1) HF 2) H2O 3) NH3 4) CO
is much higher 15. Set of iso electronic ions among the following is
4) Experimental method for determination is wrong. 1) Na+, Cl–, O–2 2) K+, Ca+2, F–
6. If S1 be the specific charge (e/m) of cathode 3) Cl–, K+, S–2 4) H+, Be+2, Na+
rays and S2 be that of positive ray then which
is true? Electromagnetic Radiation
1) S1 = S2 2) S1 > S2 16. All types of electromagnetic radiations possess
3) S1 < S2 4) Any one of these same
1) Wave length 2) Frequency 3)Energy
7. The massive particle among the following is
4) Velocity when they passed through vacuum
1)  - particle 2) Deuteron
17. The radiation having maximum wave length is
3) Proton 4)  - particle 1) Ultraviolet rays 2) Radio waves
8. Which of the following statements about the 3) X-rays 4) Infra-red rays
electron is incorrect? 18. Electromagnetic radiation, which of the
1) It is a negatively charged particle. following has greater wavelength than vis-
2) The mass of electron is equal to the mass of ible light
neutron. 1) U.V rays 2) I.R rays
3) It is a basic constituent of all atoms. 3) Gamma rays 4) X-rays
4) It is a constituent of cathode rays.
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19. The product of which of the following is equal 27. Transition of electron from M-shell to K-shell
to the velocity of light results in the emission of
1) Wave length and wave number 1) Cosmic rays 2) Infrared rays
2) Wave length and frequency 3) Ultraviolet rays 4) X-rays
3) Frequency and wave number 28. Which of the following transition is associated
4) Wave length and amplitude with coloured spectral line
1) n = 5 to n = 3 2) n = 4 to n = 2
Plank’s Quantum Theory And Photo
3) n = 2 to n = 1 4) n = 3 to n = 1
Electric Effect 29. Values of n1 and n2 for H spectral line in the
20. Which of the following relates to photons both hydrogen emission spectrum
as wave motion and as a stream of particles? 1) 1 and 2 2) 2 and 3 3) 3 and 2 4) 2 and 4
1) Interference 2) E = mc2 30. Rydberg constant is
3) Diffraction 4) E = hv 1) Same for all elements
21. The photoelectric emission from a surface 2) Different for different elements
starts only when the light incident upon the 3) A universal constant
surface has certain minimum 4) Is different for lighter elements but same for
1) Intensity 2) Wavelength heavier elements
3) Frequency 4) Velocity
Bohr’s Atomic Model
22. A surface ejects electrons when hit by green
light but not when hit by yellow light. Will 31. The value of the total energy of an electron in
electrons be ejected if the surface is hit by red the hydrogen atom is given by
light 1) mv2 2) 1/2 mv2 3) –e2/2r 4) - mv/r2
1) Yes 2) No 32. The ratio between potential energy and total
3) Yes, if the red bream is quite intense energy of an electron in H-atom according to
4) Yes, if the red beam continues to fall upon Bohr atom
23. Kinetic energy of photo electrons is 1) 1 : -1 2) 1 : 1 3) 1 : 2 4) 2: 1
independent on --------- of incident radiation. 33. The equation corresponding to the wave
1) Wavelength 2) Wave number number of spectral line in the Bracket series
3) Frequency 4) Intensity
1) R[(1 / 2 2 )  (1 / 42 )] 2) R[(1 / 4 2 )  (1 / 52 )]
Atomic Spectra
24. The best evidence that electrons are arranged 3) R[(1 / 32 )  (1 / 52 )] 4) R[(1 / 6 2 )  (1 / 4 2 )]
in definite orbits or energy levels is based on
34. The wave length of a spectral line for an
the observation that
1) Atomic spectra consist of discrete lines and not electronic transition is inversely related to
continuous bands 1) Velocity of electron undergoing transition
2) Electrons in the beta ray have high kinetic energy 2) Number of elctrons undergoing transaction
3) The penetrating power of cathode ray electrons 3) The difference in energy levels involved in the
depends upon the voltage used to produce them transition
4) Electrons revolve around the nucleus 4) None of these
25. The band spectrum is caused by 35. E value is maximum in
1) Molecules 2) Atoms 1) E2 - E1 = E 2) E3 - E2 = E
3) Any substance in solid state 3) E4 - E3 = E 4) E5 - E4 = E
4) Any substance in liquid state de-Broglie’s And Heisenberg
Hydrogen Spectrum Uncertainity Principle
26. The hydrogen spectrum from an incandescent 36. Diffraction of the electron beam is an evidence
source of hydrogen is: of the fact that
1) An emission band spectrum 1) Electrons repel each other
2) An emission line spectrum 2) Light has wave properties
3) An absorption band spectrum 3) Electron has wave property
4) An absorption line spectrum 4) Electron has momentum
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37. Wave properties are only important for magnetic quantum number
particles having 1) + 2 2) + 3 3) - 3 4) - 4
1) High mass and low velocities 48. The 2px, 2py and 2pz orbitals of an atom have
2) Low mass and no velocity identical shapes but differ in their
3) High mass and high velocities 1) Size 2) Shape 3) Orientation 4) Spin
4) Low mass and high velocities 49. The orbital with maximum number of possible
38. Which of the following is responsible to rule orientations
out the existence of definite paths or 1) s 2) p 3) d 4) f
trajectories of electrons? 50. The quantum number which cannot say any
1) Pauli’s exclusion principle. thing about an orbital is
2) Heisenberg’s uncertainty principle. 1) n 2) l 3) m 4) s
3) Hund’s rule of maximum multiplicity. 51. Which is not an atomic orbital?
4) Aufbau principle. 1) 2d 2) 5p 3) 3p 4) 4d
52. The quantum number in which the valence
Quantum Mechanical Model of Atom electrons of magnesium differs in
39.  2  psi  the wave function represents the 1) m 2) n 3) l 4) s
probability of finding electron. Its value 53. The set of quantum numbers not possible to
depends an electron is
1) Inside the nucleus 2) Far from the nucleus 1) 1,1,1, +1/2 2) 1,0,0, +1/2
3) Near the nucleus 3) 1, 0, 0, - 1/2 4) 2, 0,0, +1/2
4) Upon the type of orbital Electronic Configuration
40. In the Schrodinger wave equation  54. According to (n + l) rule after completing ‘np’
represents level the electron enters into
1) Orbitals 2) Wave function 1) (n – 1) d 2) (n + 1) s
3) Amplitude function 4) Both 2 & 3 3) nd 4) (n + 1) p
41. The electron density of 3dxy orbital in YZ 55. If Pauli’s exclusion principle is not known, the
plane is electronic arrangement of lithium atom is
1) 50 % 2) 95 % 3) 33.33 % 4) Zero 1) 1s2 2s1 2) 1s1 2s2
42. In an orbital, the signs of lobes indicate the 3) 1s3 4) 1s2 2s1 2p1
1) Sign of the wave function 56. Any p - orbital can accommodate upto
2) Sign of the probability distribution 1) Four electrons
3) Presence or absence or electron 2) Two electrons with parallel spins
4) Sign of charge 3) Six electrons
43. The number of radial nodes, nodal planes for 4) Two electrons with opposite spins
an orbital with n = 4 ; l = 1 is
57. Due to which of the following reasons the
1) 3, 1 2) 2, 1 3) 2, 0 4) 4, 0
nitrogen shows three unpaired electrons
Quantum Numbers
1) Hund’s rule 2) Aufbau principle
44. The quantum number which determines the
number of sub-energy levels in any main 3) Pauli's principle 4) Heisenberg’s principle
energy level is 58. Mg+2, Al+3 have identical _____
1) n 2) l 3) m 4) s 1) Configuration 2) Atoms
45. Among the various quantum numbers (n, l, m, 3) Ions 4) Molecules
s)describing an electron which can have the 59. The maximum number of electrons in an atom
largest value which can have (n + l) = 4
1) n 2) l 3) m 4) s 1) 2 2) 6 3) 8 4) 18
46 The angular momentum of an electron in an 60. The valency shell electron configuration of an
atom depends on atom is 4s2 4p5. The maximum no. of electrons
1) m 2) l 3) n 4) All having parallel spin in this configuration are
47. A 3d electron having s = + 1/2 can have a 1) 7 2) 4 3) 3 4) 5
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Key – Conceptual (C.W) 47. For 3d orbital l  2 ;m= -2 to+2.
01) 1 02) 1 03) 4 04) 2 05) 3 06) 2 49. f - orbitals has 7 orientations.
07) 1 08) 2 09) 4 10) 4 11) 4 12) 2 51. 2d orbital is not possible
13) 2 14) 4 15) 3 16) 4 17) 2 18) 2 Conceptual (H.W)
19) 2 20) 4 21) 3 22) 2 23) 4 24) 1
25) 1 26) 2 27) 3 28) 2 29) 4 30) 2 Subatomic Particles
31) 3 32) 4 33) 2 34) 3 35) 1 36) 2 1. Which of the following is not a fundamental
particle
37) 4 38) 2 39) 4 40) 4 41) 4 42) 1
1) Proton 2) Neutron
43) 2 44) 1 45) 1 46) 2 47) 1 48) 3
3)   particle 4) Electron
49) 4 50) 4 51) 1 52) 4 53) 1 54) 2
2. Magnitude of deflection of cathode rays
55) 3 56) 4 57) 1 58) 1 59) 3 60) 2 in discharge tube is more when
1) Magnitude of charge of the particle is more
Hints – Conceptual (C.W)
2) Greater interaction with the electric or
1. H11 (Pr otium ) number of neutrons = 1-1=0 magnetic field
6. mass of electron is less 3) Less mass of the particle
11. Electron,proton and neutron are the fundametal 4) All the above
particles 3. The constancy of e/m ratio for electron
12. n = A-Z shows that
1
14. HF, H2Oand NH3 have 10 electrons 1) Electrons mass is th of the mass of proton
1837
17. X  rays U .V rays I .R Radio 2) Electrons are universal particles of all matter
3) Electrons are produced in discharge tube only
  4) None of these
18.   rays X  rays U .V rays I .R Radio e
4. The value of electron is
  m
1) 1.76  10–11ckg–1 2) 1.76  1011ckg–1
12
3) 1.76  10 kg c–1 4) 1.76  1013kg–1c
c
19.    c   5. When the speed of the electron increases, the

specific charge
22. Red light has less frequency than green. So, it will
1) Decreases 2) Increases
not cause ejection of electrons
3) Remains same 4) None
27. Lyman series of line are observed in uv-region. 6. The nature of anode rays depends upon
28. n=4 to n=2 falls in visible region 1) Nature of gas filled in the discharge tube
29. For H  , n  n2  n1  2 2) Nature of electrode
3) Nature of metal 4) None of these
e 2 e
P.E 7. The value of proton is
 r 2 m
32. T .E e 2
e
2r 1) Less than value of electron
m
33. For bracket series n1  4, n2  5, 6, 7... e
35. On moving away from nucleus energy difference 2) Equal to value of electron
m
between successive orbit decrease e
43. No of radial nodes  n  l  1 3) Greater than value of electron
m
No of nodal planes= l 4) All the above.
44. No of sub energy levels=n
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Atomic models 17. The radiation with highest wave number
8. In Rutherford's alpha-ray scattering experiment, 1) Micro waves 2) X–rays
the alpha particles are detected using a screen 3) I.R.Radiations 4) Radiowaves
coated with 18. The energy of photon is inversely proportional
1) Carbon black 2) Platinum black to its
3) Zinc sulphide 4) Teflon 1) Wavelength 2) Frequency
9. Rutherford’s alpha-rays scattering experiments 3) Wavenumber 4) Valency
showed for the first time that the atom has Planck’s Quantum Theory & Photo
1) Nucleus 2) Proton 3) Electron 4)Neutron Electric Effect
10. When alpha particles are sent through a thin 19. The value of planck’s constant is
metal foil, most of them go straight through 1) 6.6256  10 27 J s 2) 6.6256  10 34 J s
the foil because 3) 6.023  10 23 J s 4)1.6  1019 J s
1) Alpha particles are much heavier than electron 20. The ratio of energy to frequency of
2) Alpha particles are positively charged electromagnetic radiation is called
3) Alpha particles move with high velocity 1) Bohr’s constant 2) Rydberg’s constant
4) Most part of the atom is empty 3) Planck’s constant 4) Ritz constant
11. For the atomic radius of the order of 10–8 cm 21. The minimum energy required to eject an
and nuclear radius of the order of 10–13 cm. electron from an atom is called
The fraction of atom occupied by the nucleus 1) Kinetic energy 2) Electrical energy
will be 3) Chemical energy 4) Work function
1) 10–13  atomic volume 22. In photoelectric effect the number of
2) 10–14  atomic volume photo-electrons emitted is proportional to
3) 10–15  atomic volume
4) 10–16  atomic volume 1) Intensity of incident beam
2) Frequency of incident beam
Atomic Number and Mass Number 3) Wavelength of incident beam
12. The lightest radioactive isotope in periodic 4) All
table is 23. The kinetic energy of the ejected electrons in
1) Tritium 2) Deuterium photoelectric effect is
3) Protium 4) All the above 1) Directly proportional to the frequency of the
13. Isotopes exhibits similar incident radiation
1) Physical properties 2) Chemical properties
2) Inversely proportional to the frequency of the
3) Physical and chemical
4) Neither physical nor chemical properties. incident radiation
14. Among 10A20 11B21 11C22 and 12D22 the isobar 3) Not related to the frequency of the incident
combination is radiation
1) A & B 2) B & C 3) C & D 4) A & D 4) All the above
15. The hydride ion is isoelectronic with 24. Photo electric effected is not observed in
1) H + 2) He + 3) He 4) Be case of
1) Potassium 2) Rubidium
Electromagnetic Radiation
3) Magnesium 4) Cesium
16. Which of the following statements is not correct
regarding electromagnetic spectrum?
Atomic Spectra
1) The velocity of X-rays is more than that of 25. The spectrum with all wavelengths may be
microwaves 1) Absorption spectrum 2) Emission spectrum
2) Infra-red radiations have larger wavelength than 3) Continuous spectrum 4) Discontinuous spectrum
cosmic rays 26. Line spectrum is characteristic of
3) The frequency of microwaves is less than that of 1) Atoms 2) Molecules
ultra - violet rays 3) Any substance in the solid state
4) X-rays have larger wave number than micro 4) Any substance in the liquid state
waves
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Hydrogen Spectrum de-Broglie’s And Heisenberg
27. Atoms can not give Uncertainity Principle
1) Absorption spectrum 2) Line spectrum 36. The momentum of electron is
3) Band spectrum 4) Atomic spectrum 1) Directly proportional to wave length
28. The hydrogen line spectrum provides 2) Inversly proportional to wave number
evidence for the 3) Inversly proportional to wave length
1) Heisenberg uncertainty principle 4) Unable to be determined
2) Wave-like properties of light 37. The de Broglie wavelength relates to applied
3) Diatomic nature of H2 voltage as :
4) Quantized nature of atomic energy states.
12.3 0 12.3 0
29. If RH is the Rydberg constant, then the energy 1)   A 2)   A
h V
of an electron in the ground state of Hydrogen
atom is 12.3 0
3)   A 4) Both (2) and (3)
E
hc
1) RH / C 2) RH h / C 3) 4) RH hc 38. According to de Broglie’s concept, the
RH circumference of each electron of which must
Bohr’s Atomic Model be equal to
30. According to Bohr's theory energy is ..... when 1) Diameter of a electron
an electron moves from a lower to a higher 2) The wave length of an electron
orbit. 3) The integral no of electron wavelength
1) Absorbed 2) Emitted 4) Planck’s constant divided by 2
3) No change 4) Both 1 and 2 Quantum Mechanical Model
31. The basic assumption of Bohrs Model of 39. The quantum no. not obtained from
hydrogen atom is that Schrodinger’s wave equation is
1) The energy of the electron is quantised 1) n 2) l 3) m 4) s
2) The angular momentum of the electron is 40. Which one of the following expressions
quantised represent the electron probability function (D)
3) The radial distance of the electron is quantised 1) 4r dr  2 2) 4r 2 dr 
4) The orbital velocity of the electron is quantised
3) 4r 2 dr  2 4) 4r dr 
32. The radius of an orbit in hydrogen atom is
equal to 41. The probability of finding an electron in an
orbital is approximately?
1) n2h2 / 4  2 m Ze2 2) 2  Ze2 / nh
2 2 4 2 2 1) 95% 2) 50% 3) 60% 4) 25%
3) 2  mZ e / n h 4) -2  2mZ2e2 / n2h2
42. Which one of the following atomic orbitals is
33. The total energy of the electron in any orbit
not directed along the axis?
of one electron containing species is given by
the expression 1) Px 2) d x 2  y 2 3) dxy 4) d z 2
1)  e 2 / r 2 2)  n 2 h 2 / 2 2 Z 2 e 4 m Quantum Numbers
3)  2 mZ e / n h
2 2 4 2 24) nh / 2  43. Total numebr of orbitals associated with third
shell will be _____.
34. The total energy of the electron revolving
1) 2 2) 4 3) 9 4) 3
round the nucleus is
44. The azimuthal quantum number of a non-
1) zero 2) less than zero directional orbital is
3) More than zero 1) 0 2) 1 3) -1 4) +1/2
4) In some atoms less than zero and in certain atoms 45. The shape of an orbital is decided by
more than zero 1) Radial wave function
35. Bohr’s model of atom can explain the 2) Angular wave function
spectrum of all except 3) Magnetic quantum number
1) H 2) He+ 3) Li+2 4) He 4) Spin quantum number
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46. The azimuthal quantum number of an electron 25) 3 26) 1 27) 3 28) 4 29) 4 30) 1
is one. The shape of the orbital is
1) Spherical 2) Dumb bell 31) 2 32) 1 33) 3 34) 2 35) 4 36) 3
3) Double dumb bell 4) Highly complicated 37) 2 38) 3 39) 4 40) 3 41) 1 42) 3
47. The m value not possible for a double 43) 3 44) 1 45) 2 46) 2 47) 3 48) 3
dumbell-shaped orbital is
1) 0 2) -2 3) +3 4) -1 49) 3 50) 1 51) 3 52) 1 53) 1 54) 1
48. The quantum number which determines the 55) 2 56) 3
energy of a sublevel is
1) n 2) l Hints Conceptual (H.W)
3) Both n and l 4) Neither n nor l 1 m0
m ,m
49. The sub-energy level having minimum 5. v 2
energy is  
1  
1) 3d 2) 5p 3) 4s 4) 4p C
50. The quantum number that was proposed to 4
explain the Zeeman effect is 11. volume   r 3
1) m 2) l 3) s 4) n 3
51. Orbital angular momentum depends on X  rays U .V rays I .R Radio
1) l 2) n and l 3) n and m 4) m and s 17.
52. The angular momentum of an electron due to  
its spin is given by hc 1
h h 18. E  h  ;E 
1) s  s  1 2) s  s  1  
2 2 E
h 2 20. E  h ; h 
3) 4) s  s  1 
2 h 24. Highly electropositive metals show photo electric
53. According to aufbau principle the electron has effect.
a tendency to occupy that subshell which R hc
has......... energy. 29. En  H 2
1) Lowest 2) Highest n
3) No energy 4) Both 1 and 2 e2
34. Total energy is negative value ( )
54. The statement “No two electrons in an atom can 2r
have all the four quantum numbers identical” is 35. It can explin the spectra of uni electronic species
known as the............. only.
1) Pauli's exclusion principle 2) Aufbau Principle h h 1
3) Hund's rule 4) Heisenberg’s principle 36.   ;p ;p
p  
55. The electronic configuration of an element Cr
is 1s2 2s2 2p6 3s2 3p6 3d5 4s1. This represents 1 2
its 37. K .E  V .e  mv
2
1) Excited state 2) Ground state 2V .e 2E h
3) Cationic form 4) Gnionic form v  
56. An atom Cr has one 4s electron and five 3d m m m
electrons. How many unpaired electrons would h h
be in Cr+3? or   
2mVe 2mE
1) 1 2) 2 3) 3 4) 4
h 12.3 1010
Key – Conceptual (H.W) or    m
01) 3 02) 4 03) 2 04) 2 05) 1 06) 1 eV
. .m V
38. 2 r  n
07) 1 08) 3 09) 1 10) 4 11) 3 12) 1
43. Total no.of orbital in a shell = n 2
13) 2 14) 3 15) 3 16) 1 17) 2 18) 1 44. s orbital
19) 2 20) 3 21) 4 22) 1 23) 1 24) 3 46. If l  1 , i.e p-subshell.

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47. For d-orbital l  2 ,so m  2, 1, 0, 1, 2 are 8. The electromagnetic radiations are,
possible a) Visible light b) IR light
49. Lower ( n  l ) indicates lower energy c) UV light d) Micro waves
The correct order of increasing energy from
56. Cr  4s1 3d 5 ; Cr   4 s 0 3d 3
lowest to highest is
1) a  b  c  d 2) a  b  c  d
Level-I (C.W) 3) d  b  a  c 4) b  c  d  a
Sub Atomic Particles Planck’s Quantum Theory & Photo
1. The value of charge on the oil droplets Electric Effect
experimentally observed were –1.6  10–19and 9. Energy levels A, B, C of a certain atoms
–4  10–19coulomb. The value of the electronic corresponding to increasing values of energy
charge, indicated by these results is level i.e., E A  EB  EC . If 1 , 2 and 3 are
1) 1.6  10–19 2) –2.4  10–19 the wavelengths of radiations corresponding
3) –4  10 –19 4) –0.8  10–19
to the transitions C to B, B to A and C to A
2. The charge to mass ratio of   particle is respectively which of the following statement
approximately two the charge to mass ratio of is correct?
proton is
1) Half 2) Twice 3) 4 times 4) 6 times 12
3. The increasing order of specific charge of 1) 3  1  2 2) 3 
1  2
electron (e), proton (p), alpha particle (  ) and
neutron (n) is 3) 1  2  3  0 4) 32  12  22
1) e, p, n,  2) n, p, e,  10. Planck’s constant has the same dimensions as
3) n,  , p, e 4) n, p,  , e that of
Atomic Number, Mass Number & EMR 1) Power 2) Work
4. The nitride ion in lithium nitride is composed of 3) Radiant energy 4) Angular momentum.
1) 7 protons + 7 electrons 11. The number of photons of light having wave
2) 10 protons + 7 electrons number x in 1 J of energy source is (Planck’s
3) 7 protons + 10 electrons constant = h, velocity of light = c)
4) 10 protons + 10 electrons x 1
5. The wrong statement among the following is 1) hcx 2) hc/x 3) 4)
1) Nitrogen atom, nitride ion have same atomic hc hcx
number 12. The work function of a photoelectric material
2) Aluminium atom and its ion have same mass is 3.3 eV. It threshold frequency will be
number 1) 4  1 0 1 1 H z 2) 7.96 1010 Hz
3) Iron atom, ferrous ion have same electron 3) 5  1033 Hz 4) 4  1011 Hz
configuration 13. In photo electric effect, the energy photon
4) Nuclear charge is same in both chlorine atom,
chloride ion striking a metallic surface is 5.6  1019 J . The
6. In which of the following species both cation kinetic energy of the ejected electrons is
and Anion have same number of electrons 12.0  1020 J . The work function is
1) CaO 2) KBr 3) NaF 4) MgS 1) 6.4  1019 J 2) 6.8  1019 J
7. An atom contains electrons, protons and
neutrons. If the mass of each neutrons is 3) 4.4  10 19 J 4) 6.4  1020 J
halved, and each electron is doubled, then the 14. The kinetic energy of electrons ejected by
atomic mass of 12Mg24 using light having frequency equal to thresh-
1) Gets doubled old frequency (v0)is :
2) Approximately remain same 1) hv0 2) Almost zero
3) Approximately get reduced by 5% 3) Very large 4) h/v0
4) Approximately get reduced by 25%

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Hydrogen Spectrum 25. Each hydrogen atom is excited by giving 10.2
15. Which of the following transitions are not eV. The maximum number of spectral lines in
allowed in the normal electronic emission the emission is equal to
spectrum of an atom? 1) 1 2) 2 3) 3 4) 4
1) 2s  1s 2) 2 p  1s 26. Consider the following statements
I) Bohr’s theory can also be used to explain
3) 3d  4 p 4) 5 p  3s the spectra of He+ ion
16. In hydrogen spectrum, the spectral line of II) Energy of an electron in the first Bohr or-
Balmer series having lowest wavelength is bit of hydrogen atom is –13.6 eV
III) Bohr’s theory is only applicable to hydro-
1) H  – line 2) H  – line 3) H  – line 4) H  – line gen atom and not to any other species
IV) The energy of an electron in a hydrogen
17. In Hydrogen atom electron is present in the N
atom is quantised
shell. If it loses energy, a spectral line may be
The correct statements are
observed in the region
1) I, II, IV 2) II, III 3) II, IV 4) All
1) Infra-red 2) Visible
3) Ultra-violet 4) All the above 27. The ionisation potential of H-atom is 13.6 eV. It is
18. The electron present in 5th orbit in excited exposed to electromagnetic radiation of wavelength
hydrogen atoms returned back to ground state. 1028A0 and gives out induced radiations, then
The no. of lines which appear in Lyman series 1) Longest wavelength of induced is 6568A0
of hydrogen spectrum 2) Lowest wavelength of induced radiation is 102A0
1) 5 2) 10 3) 4 4) 6 3) Longest wavelength of induced radiation is
19. Which of the following gives neither emission 3252A0
spectrum nor absorption spectrum? 4.) Longest wavelength of induced is 1216A0
1) He+ 2) H2 3) H+ 4) He 28. Which of the following curves may represent
20. The following electronic transition corresponds the speed of electron in a H-atom as a function
to the shortest wave length (n = no. of orbit) of principal quantum number (n)
1) n5  n1 2) n5  n3 3) n5  n2 4) n5  n4
21. Which of the following electron transition in
hydrogen atom will require the energy 1) V 2) V
equivalent to its ionization energy ? n n

1) from n = 1 to n = 2 2) from n = 2 to n =3 n n
3) from n = 1 to n = 3 4)from n = 1 to n  
22. If the mass of the electron is reduced to half
the Rydberg constant 3) 4)
Vn Vn
1) Remains unchanged 2) Becomes half
3) Becomes double 4) Becomes one fourth n n
Bohr’s Atomic model 29. The difference in angular momentum
23. According to Bohr's theory, the angular associated with the electron in two successive
momentum for an electron of 5th orbit is; orbits of hydrogen atom is
1) 10h/  2) 5h / 2  3) 25h/  4) 5  /2h 1) h / 2 2) h /  3) h/2 4) (n - 1) h / 2
24. The change in velocity when hydrogen electron 30. Properties of electrons that are quantized in
jumps from K shell to L shell is Bohr’s atomic model are
1) One-half of its original velocity 1) Mass and energy
2) Twice to its original velocity 2) Energy and angular momentum
3) One-quarter of its original velocity 3) Angular momentum and mass
4) Equal to its original velocity 4) Mass and charge

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31. When greater number of excited hydrogen 39. The basis of quantum mechanical model of an
atoms reach the ground state, then atom is
1) More number of lines are found in Lyman series 1) Angular momentum of electron
2) The intensity of lines in Balmer series increase 2) Qantum numbers
3) The intensity of lines in Lyman series increase 3) Dual nature of electron
4) Both the intensity and number of lines in Lyman 4) Black body radiation
series increases
40. In the plots of radial distribution function for
32. To which of the following is Bohr’s theory
applicable the hydrogen 3s orbital versus ‘r’, the no. of
I) He+ II) Li+2 III) Tritium IV) Be+2 peaks are
The correct combination is 1) 3 2) 2 3) 1 4) 0
1) III, IV 2) I, II, III, IV 41. Which of the following conditions is
3) I, II 4) I, II, III incorrect for
1)  must be single valued at any particular point
de-Broglie’s & Heisenberg’s
2)  must be positive
33. Which of the following has the largest de
Broglie wavelength provided all have equal 3)  must be a continuous function of its
velocity? coordinates
1) Carbon dioxide molecule 2) Ammonia molecule 4) None of the above
3) Oxygen molecule 4) Nitrogen molecule 42. Consider the following statements :
34. Among the following particles, which will have 1) Electron density in XY plane in 3d x2  y 2
the shortest wavelength when accelerated by
orbital is zero
one million eV?
1) Neutron 2) Tritium atom 2) Electron density in XY plane in 3d z2 orbital
3)  -particle 4) Electron is zero
35. If the wavelength of the electron is 3) 2s orbital has only one spherical node
numerically equal to the distance travelled 4) For 2pz orbital YZ is the nodal plane
by it in 1 sec, then The correct statements are :
h h 1) 2 and 3 2) 1,2,3,4 3) Only 2 4) 1 & 3
1)   2)   43. Which of the following statements is correct?
p m
1) An orbital describes the path of an electron in
h an atom
h
3)   4)   2) An orbital is a region where the electron is not
m p located
36. When uncertainty in position and momentum 3) An orbital is a function which gives the
are equal, then uncertainty in velocity is : probabilities of finding the electron in a given
region
h 1 h 1 h h 4) All the above
1) 2) 3) 4) 2m
 2  2m   44. For an electron in a hydrogen atom, the wave
function  is proportional to exp, where a0 is
Quantum Mechanical Model of Atom
the Bohr’s radius. What is the ratio of the
37. The number of angular and radial nodes of 4d probability of finding the electron at the
orbital respectively are (EAM-2014) nucleus to the probability of finding it at a0 ?
1)3,1 2)1,2 3)3,0 4)2,1 1) e 2) e2 3) 1/e2 4) zero
38. The number of radial nodes of 3s and 2p 45. The electron density between 1s and 2s is
orbitals respectively are 1) High 2) Low
1)0,2 2)2,0 3)1,2 4)2,1 3) Zero 4) Abnormal

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46. Which of the following statement(s) is/are 3) A subshell in an atom can be designated with
correct about angular nodes two quantum numbers n and l.
1) They are independent from the radial wave 4) The maximum value of l is equal to n - 1 and that
function of m is l .
2) They are directional in nature 55. Which of the following sets of quantum
3) The number of angular nodes of orbital is equal numbers represents the highest energy of
to azimuthal quantum number. an atom?
4) All are correct 1) n = 3, l = 1, m = 1, s = + 1/2
2) n = 3, l = 2, m = 1, s = + 1/2
Quantum Numbers 3) n = 4, l = 0, m = 0, s = + 1/2
47. T he quant um number l and the number of 4) n = 3, l = 0, m = 0, s = + 1/2
electrons (n) in the sub level are related by 56. In an atom the order of increasing energy of
1) n = 2l + l 2) l = 2n + l elelctrons with quantum numbers
3) n = 4l + 2 4) n  2 l 2 (EAM- 2014) (AIEEE 2012 )
48. The set of quantum numbers n=3, l=2, m1= 0 i)n=4, l  1 ii)n=4,l =0
1) Describes an electron in a 2s orbital
iii)n=3,l =2 iv)n=3,l =1 is
2) Is not allowed
3) Describes an electron in a 3p orbital 1)iii< i < iv < ii 2)ii < iv <i < iii
4) Describes one of the five orbitals of a similar 3) i < iii < ii < iv 4) iv < ii < iii <i
type 57. The angular wave function depends upon
49. The orbital having minimum ‘m’ value quantum numbers.
1) Spherical in shape 2) Dumbell in shape 1) n and l 2) l and m 3) l and s 4) m and s
3) Double dumbell in shape 4) Tetrahedral 58. The minimum angular momentum of an electron
50. An orbital made of four lobes can have the with the magnetic quantum numbers –1 , 0 , +1
following quantum numbers
1) n = 2, l = 2, m = 0 2) n = 3, l = 1, m = -2 3h h 2h 3h
1) 2) 3) 4)
3) n = 3, l = 2, m = 0 4) n = 3, l = 3, m = -3 2π π π 2π
51. Number of electrons of manganese with 59. The electrons occupying the same orbital have
magnetic quantum number value ‘0’ is the same values for all the quantum number
1) 1 2) 8 3) 12 4) 13 except for
52. The total number of m values for n=4 is 1) n 2) l 3) m 4) s
1) 8 2) 16 3) 12 4) 20 60. In order to designate an orbital in an atom the
53. Choose the incorrect statement : no. of quantum no. required
1) The shape of an atomic orbital depends upon 1) One 2) Two 3) Three 4) Four
the azimuthal quantum number 61. The max. number of electron that can be
2) The orientation of an atomic orbitals depend accomodated in all the orbitals for which l = 3 is
upon the magnetic quantum number 1) 2 2) 6 3) 10 4) 14
3) The energy of an electron in an atomic orbital of 62. During ionisation of copper atom, the quantum
multi-electron atom depends on principal quantum numbers of electron removed maybe
number. 1
1) n  4 l  1 s  
4) The number of degenerate atomic orbitals of one 2
type depends on the value of azimuthal and magnetic
1
quantum numbers. 2) n  3 l  0 s  
54. Which of the following statements on quantum 2
numbers is not correct? 1
3) n  4 l  0 s  
1) Quantum numbers n, l, m and ms are needed to 2
describe an electron in an atom completely. 1
4) n  4 l  2 s  
2) Quantum numbers n, l, m and s are obtained by 2
solving the Schrodinger wave equation.
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Electronic Configurations Key - Level-I (C.W)

63. The rule that explains the reason for chromium 01) 4 02) 2 03) 3 04) 3 05) 3 06) 3
to have [Ar]3d5 4s1 configuration instead of
07) 4 08) 3 09) 2 10) 4 11) 4 12) 1
[Ar] 3d4s2?
1) Pauli's exclusion principle 2) Aufbau Principle 13) 3 14) 2 15) 3 16) 4 17) 4 18) 3
3) Hund's rule 4) Heisenberg principle 19) 3 20) 1 21) 4 22) 2 23) 2 24) 1
64. The orbital diagram in which the aufbau 25) 1 26) 1 27) 1 28) 1 29) 1 30) 2
principle is violated is
31) 3 32) 4 33) 2 34) 3 35) 2 36) 3
2s 2p 2s 2p
37) 4 38) 2 39) 3 40) 1 41) 2 42) 1
1) 2)
43) 3 44) 4 45) 3 46) 4 47) 3 48) 4
2s 2p 2s 2p
49) 3 50) 3 51) 4 52) 2 53) 3 54) 2
3) 4)
55) 2 56) 4 57) 2 58) 2 59) 4 60) 3
65. The electronic configuration of an element with 61) 4 62) 3 63) 3 64) 2 65) 1 66) 1
atomic number 64 is 67) 3 68) 3 69) 4 70) 2
1) 6s 2 5d 1 4 f 7 2) 6s 2 5d 0 4 f 8
Hints - Level-I (C.W)
3) 6s1 5d 0 4 f 7 4) 6s1 5d 2 4 f 7 1. q = ne
66. How many 'd' electrons are present in Cr2+ ion ?
1) 4 2) 5 3) 6 4) 3 magnitudeof ch arg e
67. Which of the following statements is 2. e/m value of ion  mass number 4. N 3
incorrect ? 5. Neutral atom and ions will have different no.of elec-
1) Extra stability of half filled and completely filled trons.
orbitals among s and p block elements is reflected
6. No.of electrons = atomic no  ch arg e
in trends of IE across a period.
2) Extra stability of half filled and completely filled 7. p n mass
orbitals among s and p block elements is reflected Initial 12 12 24
in E.A. trends across a period. Final 12 6 18
3) Aufbau principle is incorrect for cases where 6  100
energy difference between ns and (n – 1)d subshell  =25% reduced.
24
is larger
U .V visible I . R micro
4) Extra stability to half filled subshell is due to higher 8. 
E
exchange energies.
68. The ion that is most stable hc E
9. E 11. E  Nhc ; N 
1) Fe+ 2) Fe2+ 3) Fe3+ 4) Fe4+  hc
69. Which has the same number of s-electrons as
W
the d-electrons in Fe2+ ? 12. W  h 0 ; 0 
1) Li 2) Na 3) N 4) P h
70. Which of the following statements are incorrect 13. h  W  K .E ; W  h  K .E
I) There are five unpaired electrons in 15. Lower orbit to higher orbit
Fe+3(z=26)
1
II) Fe+3, Mn+ and Cr all having 24 electrons 16.   19. It has no electron
have same value of magnetic moment n
III) Copper (I) chloride is coloured salt 1 2 2 mZ 2e 4
IV) Every coloured ion is paramagnetic 20.   22. R  , Rm
1) I & II 2) II & III 3) III & IV 4) I & IV
n Ch3
nh v
23. mvr  24. Vn  1
2 n
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25. E2  E1  10.2ev ,so electron is excited to second 55. Higher ( n  l ) indicates higher energy
n( n  1) 56. The order of increase of energy can be calculated
orbit ,therefore no.of spectral lines  from (n+l ) rule. If two orbitals have same value of
2
26. Energy of given radiation = (n+l ) , the orbital with lower value of n will be
filled first.
hc 61. no.of electrons  4l  2
E   12.02ev
 68. Half filled d-orbital is stable
13.6 hc
E  eV
.  n  3  E  Level-I (H.W)
n2 
hc Sub Atomic Particles
a ) 1 induced 
E3  E1 1. An oil drop has 6.39 1019 charge. What will
be the number of electrons in this drop?
hc
b) 2 induced  1) 2 2) 4 3) 8 4) 16
E3  E2 2. Charge of one mole of alpha particle is
1) + 2 units 2) +1 units
hc 3) + 2 faraday 4) + 2 coulombs
c) 2 induced 
E2  E1 3. The ratio of e/m of proton and  - particle is
1) 2 : 1 2) 1 : 2 3) 1 : 1 4) 1 : 3
1 Atomic Number & Mass Number
28. V 
n 4. Charge of the species with 17 protons, 18
nh neutrons and 18 electrons is
29. mvr  , b/n two successive orbits n2  n1 = 1 1) + 1 2) - 1 3) - 2 4) None
2
76
h 1 5. An isotone of 32Ge is:
33.   ;  77 77
mv m a) 32 Ge b) 33 As c) 3477 Se d) 3478 Se
h 1 1) Only a and b 2) Only b and d
34.   ;  3) Only b and c 4) b, c and d.
2meV eV
6. The number of neutrons present in the
h h deuterium isotope of hydrogen is
35.   V ;    ; 
1) 2 2) 3 3) 5 4) 1
mV m
h h Electromagnetic Radiation
2   7. Identify the incorrectly matched set from the
m m
following
h 2 h h list I list II
36. x.p  ; x  ; x  1) Wavelength Nanometers
4 4 4
2) Frequency Hertz
h 1 h 3) Wavenumber m–1
v  ; v  4) Velocity ergs
4 .m.x 2m 
8. If  1 a n d  2 a re t h e w av e le n g t h o f
37. No.of angular nodes = l =2
characteristic X-rays and gamma rays
No.of radial nodes  n  l  1 = 4  2  1  1 respectively, then the relation between
38. No.of spherical/radial nodes = n-l -1 them is
for s = orbital, l =0.
40. No.of peaks= n l
1
1) 1  2) 1  2
2
51. 1s 2 2s 2 2 p 6 3s 2 4 s 2 3d 5 in each sub energy level one
orbital is with m = 0 3) 1  2 4) 1  2
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Planck’s Quantum Theory and 17. The electronic transition that emits maximum
Photo Electric Effect energy is [n = represents orbit]
1) n5  n4 2) n4  n3
9. The characteristic not associated with Planck’s
theory is : 3) n2  n1 4) n3  n2
1) Radiations are associated with energy Bohr’s Atomic Model
2) The magnitude of energy associated with a 18. With increasing atomic number of a single
quantum is proportional to frequency electron species, the energy difference
3) Radiation energy is neither emitted nor absorbed between two orbits
continuously.
1) Increases 2) Decreases
4) Radiation energy is neither emitted nor absorbed
3) Remains constant
discontinuously
4) First increases followed by a decrease
10. Ultraviolet light of 6.2 eV falls on Caesium sur-
19. The ratio of the radius of the Bohr orbit for
face (work function = 1.2 eV). The kinetic en- the electron orbiting the hydrogen nucleus that
ergy (in electron volts) of the fastest electron of the electron orbiting the deuterium nucleus
emitted is approximately is approximately
1) 1:1 2) 1 : 2 3) 2 : 1 4) 1 : 4
1) 5 eV 2) 4 eV 3) 3 eV 4) 2 eV
20. Which of the following curves may represent
11. Visible light photons do not show Compton the radius of orbit (rn) in a H-atoms as a func-
effect because they tion of principal quantum number (n)
1) Move very slowly 2) Have no momentum
3) Have very less mass 4) Have larger
wavelength
12. As the frequency of the light increases, the
momentum of its Photon
1) Increases 2) Decreases
3) Remains same 4) Cannot be predicted
H-Spectrum
13. The line spectra of two elements are not
identical because :
1) The elements do not have the same number of
neutrons
2) They have different mass numbers 21. How much energy is required to ionise a H
3) Their outermost electrons are at different energy atom if the electron occupies n = 5 orbit?
levels 1) 5.44 ev 2) 10.8 ev
4) All of the above. 3) 0.544 ev 4) 1.08 ev
14. Among the first lines of Lyman, Balmer, 22. If the speed of electron in the Bohr’s first orbit
Paschen and Brackett series in hydrogen of hydrogen in x, the speed in the third orbit is
atomic spectra which has higher energy? 1) x/9 2) x/3 3) 3x 4) 9x
1) Lyman 2) Balmer de-Broglie’s & Heisenberg’s
3) Paschen 4) Brackett 23. If moving with equal speeds, the longest
15. When the atomic electron is at infinite distance wavelength of the following matter waves is
from the nucleus, its energy is that for a (an)
1) infinity 2) zero 3) negative 4) positive 1) Electron 2)  -particle
16. The wave number of the H- line in Balmer 3) Proton 4) Neutron
series of hydrogen spectrum is 24. The momentum of radiation of wavelength 0.33
1) 5R / 36 2) 3R / 16 nm is ……. kgm sec–1
3) 21R / 100 4) 3R / 4 1) 2  10–24 2) 2  10–12
3) 2  10–6 4) 2  10–48
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Quantum Mechanical Model of Atom Quantum Numbers
25. Which of the following statements is not 31. What is the full degeneracy of the n  3 state
correct? of a H-atom in the absence of a magnetic field?
1) The wave function depicting the dependence on 1) 4 2) 10 3) 8 4) 18
r involves two quantum numbers n and l. 32. For the azimuthal quantum number ‘l’ the
2) The wave function depicting the angular dependence total number of magnetic quantum numbers
involves two quantum numbers l and m. is given by
3) The spin quantum number is not the outcome of ( m  1) m 1
the Schrodinger equation. 1) l  2) l 
2 2
4) The lowest energy state of an atom corresponds
to n = 0 2m  1 2m  1
3) l  4) l 
26. In a main energy level, the orbital with more 2 2
number of nodal planes will be ...... 33. How many sets of four quantum numbers are
1) Higher energy 2) Lower energy possible for electrons present in He2- anion
3) Either 1 or 2 4) Neither 1 nor 2 1) 2 2) 4 3) 5 4) 7
34. The set of quantum numbers n = 2, l = 2,
27. Choose the correct statement among the
m1 = 0
following :
1) Describes an electron in a 2s orbital
1)  2 represents the atomic orbital 2) Describes one of the five orbitals of a similar type
2) The number of peaks in radial distribution is n-1 3) Describes an electron in a 2p orbital
3) A node is a point in space around nucleus where 4) Is not allowed.
the wave function  has zero value 35. The sub-energy level which can accommodate
maximum number of electrons with parallel
4) All of the these
spin values is
28. The maximum probability of finding electron
1) 4p 2) 6s 3) 3d 4) 6p
in the dxy orbital is
36. The azimuthal quantum number and the
1) Along with x - axis 2) Along the y - axis principal quantum number of the 17th
0
3) At an angle of 45 from the X and Y axis electron are
4) At an angle of 900 from the x and y axis 1) l = 1, n = 3 2) l = 3, n = 2
29. Which of the following statements regarding 3) l = 1, n = 17 4) l = 2, n = 1
an orbital are correct 37. The lowest orbital in which an electron with
1) An orbital is a definite trajectory around the Azimuthal quantum no. value 3 is
nucleus in which electron can move 1) 4 2) 5 3) 1 4) 6
2) An orbital always has spherical trajectory 38. The quantum numbers n = 3, l = 1, m = + 1
3) An orbital is the region around the nucleus where and s = +1/2 represent the unpaired
there is a 90 – 95% probability of finding all the electron present in
electrons of an atom 1) Sodium atom 2) Aluminium atom
4) An orbital is characterized by 3 quantum numbers 3) Fluorine atom 4) Potassium atom
n, l and m 39. The magnetic quantum number m for the
30. Which of the following statements on the outermost electron in the Na atom,is
atomic wave function  is not correct? 1)0 2)2 3)3 4)1
1)  may be a real valued wave function 40. Which of the following quantum numbers
2)  may be in some cases be a complex function is correct for an electron in 4f-orbital
3)  has a mathematical significance only 1) n = 4, l = 3, m = +1, s = +1/2
4)  is proportional to the probability of finding an 2) n = 4, l = 3, m = +4, s = +1/2
electron 3) n = 4, l = 4, m = +1, s = +1/2
4) n = 4, l = 2, m = –2, s = +1/2
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Electronic Configurations 3) The principal quantum number (n) indicates

41. Which of the following arrangements of elec- the shape of the orbital
trons is most likely to be stable? 4) The electronic configuration of phosphorous is
given by [Ne] 3s2 3p1x 3p1y 3p1z
3d 4s 50. Which of the following has maximum number
1) of unpaired electrons ?
1) Zn 2) Fe2+ 3) Ni3+ 4) Cu+
2) 51. The successive elements belonging to the
3d-series have the same number of electrons
3) in the d-sub-shell. The elements are
1) Ti & V 2) V & C
4) 3) Cr & Mn 4) Mn & F
52. The electronic configuration in the valence
42. Aufbau principle fails to explain the 3s 3p
configuration of element with atomic number shell of silicon is . The rule
1) 18 2) 21 3) 24 4) 27 violated is
43. Total number of electrons in any energy level 1) Auf-bau principle 2) Pauli’s rule
is 3) Hund’s rule 4) All
l  n 1 l n
53. In potassium, the order of energy levels is
1)  2  2l  1 2)  2  2l  1
l 0 l 0
1) 3s > 3d 2) 4s < 3d
l  n 1 l  n 1
3) 4s > 4p 4) 4s = 3d
3)  2  2l  1
l 0
4)  2  2l  1
l 1
Key-Level–I (H.W)
44. The atomic number at which filling of a g- 01) 2 02) 3 03) 1 04) 2 05) 2 06) 4
orbital is likely to begin is : 07) 4 08) 3 09) 4 10) 1 11) 4 12) 1
1) 121 2) 116 3) 106 4) 124 13) 3 14) 1 15) 2 16) 1 17) 3 18) 1
45. n and l values of an orbital A are 3 and 2 and 19) 1 20) 2 21) 3 22) 2 23) 1 24) 1
another orbital B are 5 and 0. The energy of
25) 4 26) 1 27) 4 28) 3 29) 3 30) 4
1) B is more than A 2) A is more than B
3) A and B are same 4) A is four times than B 31) 4 32) 2 33) 2 34) 4 35) 3 36) 1
46. Number of unpaired electrons of neutral 37) 1 38) 2 39) 1 40) 1 41) 3 42) 3
manganese atom and its divalent ion are in 43) 1 44) 1 45) 1 46) 1 47) 1 48) 1
the ratio (the atomic number of manganese is 49) 4 50) 2 51) 3 52) 3 53) 2
25 and it loses two electrons to form the
divalent ion) Hints - Level–I (H.W)
1) 1 : 1 2) 25 : 23 3) 5 : 3 4) 3 : 5 1. q = ne
47. Which of the following electrons is most tightly 2. 1 mole of positive charge = 1F
bound by the nucleus 3. specific charge = e/m
1) 4p 2) 5s 3) 4d 4) 5d 4. 1 electron is more
2 2 6 2 6 5
48. 1s 2s 2p 3s 3p 3d is not the electron 10. K.E = E-W
configuration of
1) Mn3+ 2) Fe3+ 3) Cr+ 4) Co4+ 2 2 mZ 2e 4
15. En  ; if n   then E  0
49. Which one of the following statements is n2h2
correct? 1 1 1
1) 2's' orbital is spherical with two nodal planes 16.     R[ n 2  n 2 ]
1 2
2) The de Broglie wavelength (  ) of a particle of 17. The energy difference b/n first and second orbits is
mass 'm' and velocity 'V' is equal to mV/h more.
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1 1 5. The mass numbers of three isotopes of an
2
18. E  RhC  n 2  n 2   Z element are 10,12,14 units.Thier percentage
 1 2 
abundance is 80,15, and5 respectively.What is
E  Z 2 the atomic weight of the element?
n2 n2 1)10.5 2)11.5 3)12.5 4)13.5
19. r  20. r
z z 6. An ion with mass number 56 contains 3 units
13.6 2 V1 of positive charge and 30.4% more neutrons
21.  En  I .E  z 22. Vn  than electrons. Assign the symbol to this ion
n2 n
1 h 1) 55
26 Fe3 2) 57
26 Fe3 3) 59
26 Fe
3
4) 56
26 Fe3
23.  24. p
m  Electromagnetic Radiation
25. n=0 is not possible.
The frequency of a wave light is 1.0×106 sec–1.
26. The orbital with more no.of nodal planes will have 7.
more energy. The wave length for this wave is
32. m  2l  1 1) 3  10 4 cm 2) 3  104 cm
33. no.of sets = no.of electrons
35. 3d has 5 parallel spin values. 3) 6  104 cm 4) 6  106 cm
45. If n  l is same, small n value indicate lower 8. The energy per quantum associated with light
energy level of wave length 250  10–9 m is
1) 7.95  10-19 J 2) 7.95  10 -26 J
Level–II (C.W)
3) 3.93  10 -26 J 4) 3.93  10-19 J
Atomic Models Atomic Number & 9. What is the energy of photons that corresponds
Mass Number to a wave number of 2.5 ×10-5 cm -1
1. The e/m ratio of cathode rays is x unit, when
hydrogen is filled in the discharge tube. What 1) 2.5 1020 erg 2) 5.1 1023 erg
will be its value when deuterium (D2) is filled
3) 4.97 1021 erg 4) 8.5  102 erg
in it?
1) x unit 2) x/2 unit 3) 2x unit 4) x/4 unit Planck’s Quantum Theory & Photo
2. –particles are projected towards the Electric Effect
following metals, with the same kinetic 10. Nitrogen laser produces a radiation at a
e n e rg y. To w a rd s w h i c h m e t a l , t h e wavelength of 337.1 nm. If the number of
distance of closest approach is minimum? photons emitted is 5.6  1024 . Calculate the
1) Cu  Z  29  2) Ag  Z  47  power of this laser
1) 3.33  106 J 2) 3.33  105 J
3) Au  Z  79  4) Ca  Z  20 
3) 1.56  106 J 4) 15.6  108 J
3. Which of the following nuclear reactions will
generate an isotope 11. The ratio of energies of photons with
wavelengths 2000A0 and 4000A0 is
1)Neutron particle emission 2) Positron emission
1) 1/4 2) 4 3) 1/2 4) 2
3)   particle emission 4)   particle emission 12. An Electro magnetic radiation of wavelength
4. Chlorine exists in two forms, Cl – 37 and 242nm is just sufficient to ionise a sodium atom.
Cl – 35 but its atomic mass is 35.5. This Calculate the ionisation energy of sodium in
indicates the ratio of Cl – 37 and Cl – 35 kJ/mol?
is approximately. 1) 494.5 2) 594.5 3) 694.5 4) 794.5
1) 1:2 2) 1:1 3) 1:3 4) 3:1
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13. When a metal is irradiated with light of m  m  1  n m  n  1  m

2 2 2 2

frequency 4.0 ×1016 s -1 the photo electrons 1)   2 2)   2

n  n  1  m2 n  m  1  n2
emitted had six times the K.E as the K.E
2 2
of photo electron emitted when the metal m  m  1  n  1  1
was irradiated with light of frequency 3)   2
 2
n  n  1  m  1  1
2.0 ×1016 s -1 . The calculate the critical
2 2
frequency of the metal. m  n  1  m  1  1
1) 2.0  1016 s 1 2)1.6  1016 s 1 4)   2
 2
n  m  1  n  1  1
3) 3.0  1016 s 1 4) 4.2  1016 s 1 21. Which of the following relationship is correct
14. In photo electric effect,if the energy required
1 1
to over come the attractive forces on the 1) E1 of H  E2 of He  E3 of
electron(work function) of Li, Na and Rb are 2 3
2.41eV, 2.3eV and 2.09eV respectively, the 1
Li 2  of E4 of Be 3
work function of “K” could approximately be 4
in eV (EAM 2012) 2) E1 of H  E2 of He +  E3 of
1) 2.52 2) 2.2 3) 2.35 4) 2.01
Li +2  E4 of Be +3
H-Spectrum
3) E1 of H  2 E2 of He  3E3
15. The ratio of highest possible wavelength
to lowest possible wavelength of Lyman of Li 2  4 E4 of Be 3
series is
2 4
1) 4/3 2) 9/8 3) 27/5 4) 16/5 4) E1 of H  E2 of He   E3
3 3
16. If the wave number of the first line in the Balmer
series of hydrogen atom is 15000 cm–1, the 5
of Li 2  E4 of Be 3
wave number of the first line of the Balmer 4
series of Li2+ is 22. What is the wavelength of a photon emitted
during a transition from n = 5 state to the
1) 1.35 105 cm 1 2) 1.66 109 cm 1 n = 2 state in the hydrogen atom
3) 13.5 105 cm 1 4) 1.43 104 cm 1 1) 434nm 2) 234nm 3) 476nm 4) 244nm
23. Which one of the following transitions of an
17. What is the lowest energy of the spectral electrons in hydrogen atom emits radiation of
line emitted by the hydrogen atom in the the lowest wavelength (EAM 2010)
Lyman series? (h=Planck’s constant;
C=Velocity of light; R=Rydberg constant). 1) n2   to n1  2 2) n2  4 to n1  3
3) n2  2 to n1  1 4) n2  5 to n1  3
5hcR 4hcR 3hcR 7hcR
1) 2) 3) 4)
36 3 4 144 Bohr’s Atomic Model
18. The ionization energy of H atom is x kJ. The 24. The velocity of electron in first orbit of H-atom
energy required for the electron to jump from as compared to the velocity of light is :
n = 2 to n =3 will be : 1 1 1
1) 5x 2) 36x/5 3) 5x/36 4) 9x/4 1) th 2) th 3) th 4) Same
10 100 1000
19. When the electron of 5th orbit jumps into the
25. In a collection of H-atoms, all the electrons
first orbit, the number of spectral lines
jump from n = 5 to ground level finally ( directly
produced in hydrogen spectrum is or indirectly), without emitting any line in
1) 5 2) 10 3) 20 4) 1 Balmer series. The number of possible
20. The Ratio of m to n wavelength of Lyman
th th different radiations is
series in H-spectrum is equal to 1) 10 2) 8 3) 7 4) 6
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26. What is likely to be principal quantum number 34. Calculate the wavelength (in nm) associated
for a circular orbit of diameter 20.6 nm of the with a proton moving at 1.0×103 m / s . The
hydrogen atom. If we assume Bohr orbit to be
the same as that represented by the principal mass of proton is 1.67 × 10 -27 kg and h is
quantum number? 6.63 × 10 -34 Js (Aieee2009)
1) 10 2) 14 3) 12 4)16 1)0.032 nm 2) 2.5 nm 3) 14.0 nm 4) 0.4 nm
27. If the radius of the first Bohr orbit of Hydrogen 35. The de-Broglie wavelength for a proton with a
atom is ‘x’, then the de-Broglie wavelength of velocity 15% of the speed of light is :
electron in third orbit is nearly.
1) 8.8  1012 m 2) 8.8  1015 cm
1) 2x 2) 6x 3) 9x 4) x/3
28. A single electron in an ion has ionization energy 3) 8.8  1015 m 4) 4.4  10 15 cm
equal to 217.6eV. What is the total number of 36. The velocities of two particles A and B are 0.05
neutrons present in one ion of it? and 0.02m/s respectively. The mass of B is five
1) 2 2) 4 3) 5 4) 9 times the mass of A. The ratio of their
29. The ionisation energy for the Hydrogen atom
de-Broglies wavelength is (EAM 2008)
in the ground state is 2.18 ×10 -18 Jatom -1 . The
energy required for the following process 1) 2 : 1 2) 1 : 4 3) 1 : 1 4) 4 : 1
37. The mass of an electron is m, its charge e and
He   g   He 2  g   e  is
it is accelerated from rest through a potential
1) 8.72  1018 Jatom 1 2) 8.72  1019 Jatom 1 difference V. The velocity of electron will be
3) 4.35  10 Jatom 4) 2.62  10 Jatom
18  1  19  1 calculated by formula :
30. If the diameter of carbon atom is 0.15nm , the 1) V / m 2) eV / m
number of carbon atoms which can be placed
side by side is a straight line across length of 3)  2eV / m  4) None of these
20 cm is 38. The uncertainity in the positions of an electron
1) 13.3  109 2) 1.33  109 and proton is equal, the ratio of the uncertainities
3) 6.2  109 4) 1.33  107 in the velocity of an electron and proton is
31. An electronic transition in hydrogen atom 1) 103 :1 2) 1:1836 3) 3672:1 4) 1836:1
results in the formation of H line of hydrogen
in lyman series the energies associated with 39. A ball of mass 200 gm is moving with velocity
-1 . If the error in measurement of
the electrons in each of the orbits involved in of 10 m.s
velocity is 0.1%, the uncertainity in its
the transition(in kal/mol) are (EAM 08) position is
1) 313.6, 34.84 2) 313.6, 78.4 1) 3.3.  10-31 m 2) 3.3  10-27 m
3) 5.3  10 m-25 4) 2.64  10-32 m
3) 78.4, 34.84 4) 78.4, 19.6
32. The wavelength of a spectral line emitted by 40. The kinetic energy of an electron accelerated
hydrogen atom in the lyman series is 16/5R from rest through a potential difference of 5V
will be
cm. What is the value of n2
1) 5J 2) 5erg
1) 2 2) 3 3) 4 4)1
3)5eV 4) 8  1010 eV
de-Broglie’s & Heisenberg’s
33. If Ee , E , and E p represents the kinetic Quantum Mechanics & Numbers
energies of an electron alpha particle and a 41. Which one of the following conditions is
proton respectively, each moving with same incorrect for a well behaved wave function ( )
deBroglie wavelength then :
(EAM 2010)
1) Ee  E  E p 2) Ee  E  E p 1)  must be finite 2)  must be single valued
3) E  EP  Ee 4) Ee  EP  En 3)  must be infinite 4)  must be continuous

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42. The spin magnetic momentum of electrons in 52. Which one of the following sets correctly
an ion is 4.84 BM. Its total spin will be represents the in case in the paramagnetic
h property of the ions. (EAM 2008)
1) 1 2) 2 3)  4) 2.5 1) Cu  V  Cr  Mn
 2 2  2  2
4
43. The maximum number of sub levels,orbitals 2) Cu 2  Cr 2  V 2  Mn 2
and electrons in N shell of an atom are 3) Cu 2  V 2  Cr 2  Mn 2
respectively
4) V 2  Cu 2  Cr 2  Mn 2
1) 4, 12, 32 2) 4, 16, 30
3) 4, 16, 32 4) 4, 32, 64 Key Level–II (C.W)
44. In multi electron atom, which of the following 01) 1 02) 4 03) 1 04) 3 05) 1 06) 4
orbitals described by the three quantum 07) 1 08) 1 09) 3 10) 1 11) 4 12) 1
numbers will have the same energy in the 13) 2 14) 2 15) 1 16) 1 17) 3 18) 3
absence of magnetic and electric fields. 19) 2 20) 2 21) 2 22) 1 23) 3 24) 2
a) n = 1, l = 0, m = 0 b) n = 2, l = 0, m = 0
25) 4 26) 2 27) 2 28) 3 29) 1 30) 2
c) n = 2, l = 1, m = 1 d) n = 3, l = 2, m = 1
e) n = 3, l = 2, m = 0 31) 2 32) 3 33) 3 34) 4 35) 3 36) 1
1) a & c 2) b & c 3) c & d 4) d & e 37) 3 38) 4 39) 4 40) 3 41) 3 42) 2
45. The values of four quantum numbers of valence 43) 3 44) 4 45) 1 46) 1 47) 1 48) 2
electron of an element X is n = 4, l = 0, m = 0,
49) 3 50) 4 51) 3 52) 3
s = 1/2 The element is
1) K 2) Ti 3) Na 4) Sc Hints Level–II (C.W)
K L M N 1. e/m value of cathode rays independent on the nature
46. Given 2
8 11 2 of gas
The number of electrons present in l  2 is 3. Isotopes are species are having same number of
1) 3 2) 6 3) 5 4) 4 protons but different number of neutrons
47. Sum of electronic spins of all electrons with  %abundance  Atomicweight
the configuration 3d7 is 4. Avg.at.wt 
Totalratio
1) + 3/2 2) + 5/2 3) + 7/2 4) 9/2
48. Which one of the following pairs of ions have  %abundance  Atomicweight
the same electronic configuration? 5. Avg.at.wt 
Totalratio
1) Cr+3, Fe+3 2) Fe+3, Mn+2
3) Fe+3, CO+3 4) Sc+3, Cr+3 6. Let the number of electrons in A3  x
49. An impossible set of four quantum number of 56 = x+3+1.304x
an electron is (AIEEE-2009) c hC
7.  8. E
1) n = 4, l = 2, m = -2, s = + 1/2  
2) n = 4, l = 0, m = 0, s = +1/2
Nhc
3) n = 3, l = 2, m = -3, s = + 1/2 9. E  hc 10. E
4) n = 5, l = 3, m = 0, s = - 1/2 
Electronic Configurations E1 2
50. How many electrons are present in the M-shell 11. E  
2 1
of an atom of the element with atomic number
Z=24? (E-2000) hc
12. E 
1) 5 2) 6 3) 12 4) 13 
51. The atomic numbers of elements X,Y and Z  E  NA
are 19, 21 and 25 respectively. The number
of electrons present in the M shells of these K .E2  2  0
elements follow the order. 13. K .E   
1 1 0
1) Z>X>Y 2) X>Y>Z 3) Z>Y>X 4)Y>Z>X
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14. As the size of atom increases, energy required to 28. Ionization energy
over come the attractive forces on the outer most
electron decreases. Z2
217.6  13.6  2 ; Z  4m
1
hc 1 1 1
15. E   ;   R[ n 2  n 2 ] So, it is 94 Be3 ; no. of neutrons 9 - 4 = 5
1 2

16.    H  z 2 z2
29.  IE  z   IE H
n2
1 1
17. E  Rhc  n 2  n 2  30. No. of carbon items that can be placed in a straight
 1 2 
length
18. Eionisation   E1 line =
diameter
E1   x 313.52 2

x 31. En  2
Z
E2   n
4
1 1 1 15R 1 1
E3  
x 32.   R[ n 2  n 2 ]  16  R[12  n 2 ]
1 2 2
9
x x h
E   33.  
9 4 2mkE
x x 5x
=  = h h
4 9 36 34.   35. 
mv mv
n  n  1
19. Number of spectral lines = h  A mB .vB
2 36.   ; 
mv B mA .v A
1 1 1 Z2
20.     R[ n 2  n 2 ] 21. E
1 2
1 2 n2 mv  ev
37.
1 1 1 2
22.     R[ n 2  n 2 ]
1 2 xe .me .ve
23. For any series the first line have lowest wave length 38. 1
x p .m p .vp
and highest energy
24. C  3  1010 cm / sec; ve m p
8 
V  2.18  10 cm / sec; vp me

5 h
39. x.m.v 
4 4
25. 3 h
x 
1
4 .m.v
diameter 1 2
26. rn  0.529  n2 A0 ; diameter = 2r ; r  40. mv  e.v
2 2
2
27. rn  n r1; 2eV
V2 
nh m
mvn rn 
2 2eV
h V 
 m
mvn
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42.   4S  S  1 8. Suppose 10 17 J of energy is needed by the
43. no.of sub shell = n,no.of orbitals  n 2 , interior of human eye to see an object. How
no.of electrons  2n 2 many photons of green light ( =550nm) are
44. Same (n+l) value indicates same energy level. needed to generate this minimum amount of
energy?
1  1 1) 14 2) 28 3) 39 4) 42
47. sum of spin quantum no = 5   2    9. The ratio of the energies of two different
2  2
52. paramagnetic property depends upon the number radiations whose frequencies are 3 x 1014 Hz
of unpaired electrons ,higher the no.of unpaired and 5 x 1014 Hz is
electrons , higher the paramagnetic property. 1) 3 : 5 2) 5 : 3 3) 3 : 1 4) 5 : 1
10. Which one of the following frequency of
Level–II (H.W) radiation(in Hz) has a wavelength of 600nm
(EAM 2011)
Atomic Models & Electromagnetic
1) 2  1013 2) 5  1016 3) 2  1014 4) 5  1014
Radiation
1. Which has highest specific charge? Plank’s Quantum Theory and Photo
1) Na  (A =23) 2) Mg 2  (A=24) Electric Effect
11. In photoelectric effect, the energy of the photon
3) Al 3 (A =27) 4) Si 4 (A =28) striking a metallic surface is 5.6 × 10–19 J. The
2. -particles are projected towards the following kinetic energy of the ejected electrons is
metals, with the same kinetic energy. Towards 12.0 × 10–20J. The work function is :
which metal, the distance of closest approach is
minimum? 1) 6.4  10 19 J 2) 6.8  1019 J
1) Zn( z  30) 2) Cd ( Z  48) 3) 4.4  10 19 J 4) 6.4  1020 J
12. An Electro magnetic radiation of wavelength
3) Hg (Z  80) 4) Al ( Z  13)
484nm is just sufficient to ionise a sodium
3. The mass numbers of three isotopes of an atom.Calculate the ionisation energy of sodium
element are 11,12,13 units.Thier percentage in kJ/mol approximately?
abundance is 80, 15, and 5 respectively.What 1) 494.5 2) 246.9 3) 989.0 4) 794.5
is the atomic wieght of the element? H-Spectrum
1)10.25 2)11.25 3)12.25 4)13.25 13. Which of the following lines will have a wave
4. 10 11
Boron has two istopes B & B whose relative no. equal in magnitude to the value of R in the
abudances are 20% & 80% respectively H - Spectral series
avg.atomic wieght of Boron is? 1) Limiting line of Balmer series
1)10 2)11 3)10.5 4)10.8 2) Limiting line of Lyman series
5. If the wavelength of green light is about 3) First line of Lyman series
5000A0, then the frequency of its wave is 4) First line of Balmer series
1) 16  1014 sec 1 2) 16  1014 sec 1 14. The wave number of first line in Balmer series
3) 6  1014 sec 1 4) 6 1014 sec1 of H ydr ogen is 15,200 cm-1 the wave number of
first line in Balmer series of Be 3+
6. The energy of photon of light having frequency
1) 2.43  10 5cm-1 2) 3.43 105cm-1
of 3  1015S–1 is
3) 4.43  10 5cm-1 4) 5.43  10 5cm-1
1) 1.99  10 18 J 2) 1.99  1017 J 15. What transition in the hydrogen spectrum
3) 1.99  1017 ergs 4) 1.99  1018 ergs would have the same wavelength as the
7. What is the energy of photons that corresponds Balmer transition n = 4 to n = 2 of He +
to a wave number of 5  10–5m–1 spectrum ?
1) 99.384  1030 J 2) 993.84  1030 J 1) n1 = 1 ; n2 = 2 2) n1 = 2 , n2 = 3
3) n1 = 3 , n2 = 2 4) n1 = 2 , n2 = 4
3) 9.9384  1030 J 4) 0.99384  1030 J
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16. The wave number for the longest wavelength 25. According to Bohr’s theory of hydrogen atom
transition in the Balmer series of atomic 1) There is only fixed set of allowed orbitals for the
hydrogen is electron
1) 15.2  106 m 1 2) 13.6  106 m 1 2) The allowed orbitals of the electrons are elliptical
3) 1.5  106 m 1 4) 1.3 106 m 1 . in shape
17. The ionization potential of hydrogen atom is 13.6 3) The moment of an electron from one allowed
eV. The wavelength of the energy radiation toanother allowed orbital is forbidden
required for the ionization of H-atom 4) No light is emitted as long as the electron remains
1) 1911 nm 2) 912 nm 3) 68 nm 4)91.2 nm in an allowed orbital
18. A gas of mono atomic hydrogen is excited by 26. The ratio of radius of 2nd and 3rd Bohr orbit is
an energy of 12.75 eV/atom. Which spectral 1) 3 : 2 2) 9 : 4 3) 2 : 3 4) 4 : 9
lines of the following are formed in Lyman, 27. According to Bohr’s theory, which one of the
Balmer and Paschen series respectively. following values of angular momentum of
1) 3, 2, 1 2) 2, 3, 1 3) 1, 3, 2 4)1, 2, 3 hydrogen atom is not permitted. (EAM-11)
19. The wave length of the radiation emitted by
1.25h h 1.5h 0.5h
Hydrogen when compared to He+ ion is 1) 2) 3) 4)
1) 2 times that of He+ ion    
2) 3 times that of He+ ion de-Broglie’s and Heisenberg’s
3) 4 times that of He+ ion 28. The mass of the electrons 9.8  10–28gram and
4) Same as He+ uncertainty in the velocity equal to 210–3cm/sec.
Bohr’s Atomic Model The uncertainty in the position of an electron is
20. The energy of the second Bohr orbit of (h=6.6210–27ergsec)
hydrogen atom is - 3.41 eV. The energy of the
second orbit of He+ would be 1) 2.9 102 cm 2) 2.9 10 2 cm
1) – 0.85eV 2) –13.6eV 3) 2.9 1012 cm 1 4) 2.9 1012 cm 1
3) –1.70eV 4) -6.82eV
29. The velocity of an electron with de Broglie
21. If the diameter of carbon atom is 0.15nm , the
wavelength of 1.0102 nm is :
number of carbon atoms which can be placed
side by side is a straight line across length of 1) 7.2  105 cm / sec 2) 72  105 cm / sec
10.0 cm is 3) 7.2  104 cm / sec 4) 3.6  105 cm / sec
1) 66.66  107 2) 66.66  108 30. The wave length of a electron with mass
3) 6.2  10 9 4) 1.33  10 7
9.1× 10 -31 kg and kinetic energy 3.0 ×10 -25 J is
22. The ionization energy of the ground state of 1) 89.67nm 2) 8.96nm
hydrogen atom is 2.18 1018 J . The energy of 3) 456.7nm 4) 896.7nm
an electron in its second orbit would be 31. A cricket ball of 0.5 Kg is moving with a
1) 1.09 10 18 J 2) 2.18 1018 J velocity of 100m per sec. the wavelength
associated with its motion is
3) 4.36 10 18 J 4) 5.45 1019 J
1) 1/100 m 2) 6.6 1034 m
23. The velocity of an electron in the first Bohr
orbit of hydrogen atom is 2.19 106 ms 1 .Its 3) 1.321035 m 4) 6.6 1028 m
velocity in the second orbit would be 32. A microscope using suitable photons is employed
1) 1.10 106 ms 1 2) 4.38 106 ms 1 to locate an electron in an atom within a distance
of 0.1A0. What is the uncertainty involved in the
3) 5.5 105 ms1 4) 8.76 106 ms 1 measurement of its velocity?
24. Energy of electron moving in the second orbit
1) 2.69  106 ms 1 2) 5.79  105 ms 1
of He+ion is
1) -13.6ev 2) -3.4 ev 3) 5.79  106 ms 1 4) 4.62  106 ms 1
3) -1.51 ev 4) -0.84 ev

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33. The mass of photon with wave length 3.6A0 is 40. Which one of the following set of quantum
1) 6.135  1033 kg 2) 6.135  10 27 kg numbers is not possible for a 4p electron?
1) n =4, l = 1, m = +1, ms =  12
3) 4.126 1029 kg 4) 4.126  1025 kg
34. If the velocity of electron in Bohr’s first orbit is 2) n =4, l = 1, m = 0, ms =  12
2.19 × 10 6 ms -1 . The de-Broglie’s wavelength is 3) n = 4, l = 1, m = 2, ms =  12
1) 332 pm 2) 313 pm 3) 3.32 pm 4)3.13 pm 4) n = 4, l = 1, m = -1, ms =  12
35. Uncertainity in position of a particle of 25 gram
41. The total number of electrons present in all
in space is 10–5 m. Hence uncertainity in
the s orbitals, all the P orbitals and all the d
velocity (m/sec) is ( h = 6.6 ×10 -34 J - sec ) orbitals of caesium ion are respectively.
1) 2.11028 2) 2.11034 1) 6, 26, 10 2) 10,24,20
3) 8, 22, 24 4) 12, 20, 23
3) 0.5 1034 4) 5 1024 42. The quantum numbers + 1/2 and - 1/2 for the
36. An electron, a proton and an alpha particle electron spin represent
have K.E. of 16E, 4E and E respectively. What 1) rotation of electron in clockwise and anti
is the qualitative order of their de-Broglie clockwise direction respectively
wavelengths: 2) rotation of electron in anti-clockwise and
clockwise direction respectively
1) e   p   2)  p    e 3) magnetic moment of the electron pointing up and
down respectively
3)  p  c   4)   e   p 4) two quantum mechanical spin states which have
37. The wavelengths of electron waves in two no classical analogue
orbits is 3 : 5. The ratio of kinetic energy of 43. The correct set of quantum numbers for the
electrons will be (EAM 2009) unpaired electron of Chlorine atom
1) 25:9 2)5:3 3)9:25 4)3:5 1) 2,0,0,+1/2 2) 2,1,-1,+1/2
Quantum Mechanics & Numbers 3) 3,0,0,+1/2 4) 3,1,-1,  1/2
38. The probability density plots of 1s and 2s 44. The quantum number which explain the line
orbitals are given in figure spectra observed as doublets in case of hydrogen
and alkali metals and doublets & triplets in case
of alkaline earth metals is
(EAM 2012)
1) Spin 2) Azimuthal 3) Magnetic 4) Principle
1s 2s Electronic Configurations
The density of dots in region represents the 45. An element has 2 electrons in K shell, 8
probability density of finding electrons in electrons in L shell, 13 electrons in M shell and
the region.On the basis of above diagram one electron in N shell. The element is
which of the following statements is incor- 1) Cr 2) Fe 3) V 4) Ti
rect? 46. A compound Vanadium has a magnetic moment
1) 1s and 2s orbitals are spherical in shape of 1.73BM. The electronic configuration of
2) The probability of finding the electron is Vanadium ion in the compound is______.
maximum near the nucleus. 1) [ Ar ]3d 2 2) [ Ar ]3d1 4s 0
3) The probability of finding the electron at a given
distance is equal in all directions. 3) [ Ar ]3d 3 4) [ Ar ]3d 0 4s1
4) The probability density of electrons for 2s 47. A transition metal 'X' has a configuration [Ar] 3d4
orbitals decreases uniformly as distance from in its +3 oxidation state, its atomic number is
the nucleus increases. 1) 25 2) 26 3) 22 4) 19
39. The maximum number of electrons with spin 48. Which one of the following ions has same
value +1/2 in the orbital with azimuthal quantum number of unpaired electrons as those present
number value l = 2 and magnetic quantum in V+3 ion. (Eam–2014)
number m = +2 is ....... 1) Fe  3 2) Ni  2 3) Mn  2 4) Cr 3
1) 5 2) 6 3) 3 4) 1
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21. No. of carbon atoms items that can be placed in a
Key Level–II (H.W)
01) 4 02) 4 03) 2 04) 4 05) 3 06) 1 length
straight line =
07) 3 08) 2 09) 1 10) 4 11) 3 12) 2 diameter
13) 2 14) 1 15) 1 16) 3 17) 4 18) 1  E1 v1
19) 3 20) 2 21) 1 22) 4 23) 1 24) 1 22. En  23. vn 
n2 n
25) 4 26) 4 27) 1 28) 1 29) 1 30) 4
13.6 r1 n12
31) 3 32) 3 33) 1 34) 1 35) 1 36) 1 24. En  Z2 26. 
n2 r2 n22
37) 1 38) 4 39) 4 40) 3 41) 2 42) 4
43) 4 44) 1 45) 1 46) 2 47) 1 48) 2 nh
27. mvr  where n  1, 2,3...
Hints Level–II (H.W) 2
magnitude of ch arg e h h
1. e/m= 28. x.m.v  29. 
mass number 4 mv
h h
3. Avg .at .wt 
 % abundance  Atomicweight 30 &36.   31. 
Totalratio 2mkE mv

4. Avg .at .wt 

 % abundance  Atomicweight h

h
Totalratio
32. x.m.v  33 & 34.
4 mv
c
5.  6. E  h h 1 KE2
 35. x.m.v  37. 
4 2 KE1
nhc
7. E  hc 8. E
 46. Magnetic momentum = n(n  2) BM
E1  1 c
9.  10.  Level – III
E2  2 
Electromagnetic Radiation
11. E  w0  K .E 1. Calculate the wavelength of photon having
hc energy 5 e.V.
12. E 
 1) 2.47  106 cm 2) 2.47  105 cm
 E  NA 3) 24.7  105 cm 4) 24.7  106 cm
2. The energy required to break one mole of
1 1
13.   R[ n 2  n 2 ] 14.   H  Z 2 Cl–Cl bonds in Cl2 is 242 kJmol–1. The longest
1 2 wavelength of light capable of breaking a single
Cl–Cl bond is
2  1 1 1 1 1) 594nm 2) 640nm 3) 700nm 4) 494nm
15. R  Z  n 2  n 2   R  n 2  n 2 
 1 2   1 2  3. A photon of 300 nm is absorbed by a gas and
then reemitted two photons. One of the remitted
1 1 1 hc photon has wavelength 496 nm, then the other
16.     RH  2  2 17. E 
 n1 n2   photon has

18. E  E4  E1  12.75ev / atom ,then the electron 1) 2.625  1019 erg 2) 2.625  1019 J
is excited to fourth orbit. 3) 2.625 J 4) 2.625Cal

E1 Z12 4. The time period of a light is 2.0 × 10 -10 s . The

1
19.  Z2 20.  wavelength for this wave is
 E2 Z 22
1) 0.06m 2) 6m 3) 0.03m 4) 0.3m
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5. A 100 watt bulb emits monochromatic light Planck’s Quantum Theory &Photo
of wavelength 400nm. Calculate the number Electric Effect
of photons emitted per second by the bulb.
13. A gas absorbs photon of 355nm and emits at
1) 20.12  1020 S 1 2) 2.012  1020 S 1 two wavelength if one of the emission is at
3) 4.969  1019 S 1 4) 49.69  1019 S 1 680nm, the order is at
6. Neon gas emits at 616 nm. The distance 1)1035nm 2)325nm 3)743nm 4)518nm
travelled by this radiaton in 30 sec is. 14. The threshold frequency for a metal is
1) 9  107 m 2) 9  109 m
7.0 ×1014 S -1 . What is the kinetic energy of an
3) 4.5  109 m 4) 7  109 m electron emitted when radiation of frequency
7. A quantum of light having energy E has 1.0×1015 S -1 hits the metal
wavelength equal to 7200A0 . The frequency
of light which corresponds to energy equal 1) 1.988 1017 J 2) 1.9881019 J
to 3E, is
3) 3.988 1019 J 4) 1.988 1019 J
1) 1.25 1014 s 1 2) 1.25 1015 s 1
15. Iodine molecule dissociates into atoms after
3) 1.25 1013 s 1 4) 1.25  1014 s 1
absorbing light of 4500 0A. If one quantum
8. Bond dissociation energy of AB molecules is of radiation is absorbed by each molecule,
300 kJ/mole. The number of moles of photons calculate the kinetic energy of Iodine
of wavelength 6625A0 requires to dissociate atoms.(Bond energy of I2 = 240 kJ mol-1 )
3 moles of AB molecules is 1) 2.16  10-20 J 2) 4.1  10-20J
1)1 2) 2 3) 4 4) 5 3) 3.12  10-14 J 4) 2.16  10-22 J
9. A certain dye absorbs light of = 4530A0 and 16. A photon of wavelength 4 ×10 -7 m strikes on
wavelength of fluoroscence light is 5080A0. metal surface, The work function of the metal
Assuming that under given condition 47% of is 2.13eV . The velocity of the photo electron is
the absorbed energy is reemited out as
1) 5.67  106 ms 1 2) 5.67  105 ms 1
fluoroscence the ratio of quanta emitted out
to the number of quanta absorbed. 3) 5.67  105 ms 1 4) 5.67  106 ms 1
1) 0.527 2) 1.5 3) 52.7 4) 3 17. When electromagnetic radiation of wavelength
10. A 25 watt bulb emits monochromatic yellow 300nm falls on the surface of sodium, electrons
light of wavelength of 0.57  m . Calculate the are emitted with a Kinetic energy of
rate of emission of quanta per second. 1.68 ×105 Jmol -1 . The maximum wave length
that will cause a photo electron to be emitted is
1) 7.16  10 19 2) 7.16  1019
1) 51.7nm 2) 517nm 3) 427nm 4) 62nm
3) 3.5  1015 4) 6.5  1019
18. Photo electric emission is observed from a surface
11. An electromagnetic radiation of wavelength for frequencies v1 and v2 the KE in two cases are
484nm is just sufficient to ionise a sodium atom. in ratio 1 : K, then the threshold frequency v0 is
Calculate the ionisation energy of sodium in
given by
kJ/mol?
1)246.9 2)594.5 3)694.5 4)794.5 v2  v1 Kv1  v2
12. If the radiation source has the duration of 2 1) 2)
K 1 K 1
nano seconds and the number of photons emit-
ted is 2.5  1015. The energy of the source is Kv2  v2 v2  v2
3) 4)
K 1 K
1) 8.282  1010 J 2) 4.141 10 10 J
3) 6.262  109 J 4) 8.282  10 10 J
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 NEET-CHEMISTRY-VOL-I ATOMIC STRUCTURE
19. Light of certain wavelength strikes on a metal spectrum.
surface with intensity x and the metal emits y 1) n2 = 3 to n1 = 2 ; E = 182.8 KJ
electrons per second of average energy, z. 2) n2 = 2 to n1 = 1 ; E = 155.8 KJ
What will happen to y and z if x is doubled? 3) n2 = 3 to n1 = 1 ; E = 180.8 KJ
1) y will be doubled and z will become half 4) n2 = 4 to n1 = 2 ; E = 182.5 KJ
2) y will remian same and z will be doubled 25. In Bohr series of lines of hydrogen spectrum,
3) Both y and z will be doubled the third line from the red end corresponds
4) y will be doubled but z will remain same to which one of the following inter-orbit jumps
20. Threshold frequency of metal is f0.When light of the electron for Bohr orbits is an atom of
of frequency  = 2f 0 is incident on the metal hydrogen. [AIEEE-02]
plate, velocity of electron emitted in V1. When 1) 52 2) 4 1 3) 2  5 4) 3  2
a plate frequency of incident radiation is 5f0, 26. The energy difference between the states of
V 2 is velocity of emitted electron , then n = 2 and n = 3 is ‘E’ eV in Hydrogen atom.
V1:V2 is The ionization potential of H atom is
1) 1: 4 2) 1: 2 3) 2 :1 4) 4 :1 1) 3.2 E 2) 7.2 E 3) 5.6 E 4) 13.2 E
21. I f  0 is the threshold wavelength for 27. In a certain electronic transition in the
photoelectric emission,  the wavelength of hydrogen atom from an initial state (1) to a
light falling on the surface of a metal and m is final state (2), the difference in the orbital
the mass of the electron, then the velocity of radius (r1 –r2) is 24 times the first Bohr radius.
ejected electron is given by Identify the transition.
1) 5  1 2) 25  1 3) 8  3 4) 1  5
1/ 2 1/ 2
 2h   2hc 28. I.E of He is 19.6  10 –18 J atom –1 . The
+
1)        2)   0    energy of the Ist stationary state (n=1) of
m   m 
Li +2 is (AIEEE–10)
1/ 2 1/ 2 –16 –1
 2hc  0     2hc  1 1  1) 4.41 10 J atom
3)    4)     2) –4.4110–17 J atom–1
 m      m     
0 0
3) –2.2 10–15 J atom–1
22. The ejection of the photo electron from the silver 4) –8.8310–17 J atom–1
metal in the photo electric effect experiment can 29. When a hydrogen atom emits a photon of
be stopped by applying the voltage of 0.35 vol. energy 12.1 eV, the orbital angular momentum
When the radiation 256.7 nm is used. The work changes by
function for silver metal is h 3h h 2h
1) 4.48 ev 2) 3.35 ev 3) 44.8 ev 4) 22.4 ev 1) 2) 3) 4)
2 2  
H-Spectrum Bohr’s Atomic Model
23. 1.8 gm of H-atom sample are excited to 30. Energy of an electron is given by
radiations. The study of spectra indicates that
27% of the atoms are in 3rd energy level, 15% -18 z2
E= -2.178 × 10 J( ) wavelength of light
of atoms in 2nd energy level and rest in ground n2
state required to excite an electron in an hydrogen
1) Number of atoms in 2nd energy level is atom from level n=1to n=2 will be
23 atoms
1.626 10 m
2) Number of atoms in 3rd energy level is [h = 6.62×10-34 J s&c = 3×108 ] (Mains-13)
s
2.9268 1023 atoms 1) 1.214  10 m  7 2) 2.816  107 m
3) Number of at oms in Ground st ate is
3) 6.5  10 7 m 4) 8.5  107 m
6.2872 1023 atoms 31. According to Bohr’s thoery ,the angular
4) All are correct momentum of electron in the fifth Bohr
24. Calculate the energy emitted when electrons orbit is? (AIEE–06)
of 1.0 gram atom of hydrogen undergo
transition giving the spectral line of lowest 25h 1.0h 10h 2.5h
1) 2) 3) 4)
wave energy in the visible region of its atomic    
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32. In an atom, two electrons move around the 39. Which of the following sets of quantum
nucleus in circular orbits of radii R and 4R. numbers represents the highest energy of an
The ratio of the time taken by them to atom
complete one revolution is 1) n = 3, l = 1, m = 1, s = +1/2
1) 1:4 2) 4:1 3) 1:8 4) 8:1 2) n = 3, l = 2, m = 1, s = +1/2
33. The ionisation energy of hydrogen atom is 3) n = 4, l = 0, m = 0, s = +1/2
1.312  106 J mol–1. The energy required to 4) n = 3, l = 0, m = 0, s = +1/2
excite the electron in the atom from n1 = 1, 40. The spin only magnetic moment [in BM] of Ni 2
n2 = 2 is (AIEEE 2008) in aqueous solution would be (atomic no of
5
1)8.51 10 J mol –1 2) 6.56 105 J mol–1 Ni=28)
3) 7.56 105 J mol–1 4) 9.84 105 J mol–1 1) 2.84 2) 4.9 3) 0 4) 1.73
de-Broglie’s and Heisenberg’s Key Level - III
34. In an atom, an electron is moving with a speed 01) 2 02) 4 03) 2 04) 1 05) 2 06) 2
of 600m/s with an accuracy of 0.005% 07) 2 08) 4 09) 1 10) 2 11) 1 12) 4
certainity with which the position of the 13) 3 14) 4 15) 2 16) 2 17) 2 18) 2
electron can be located is (AIEEE-09) 19) 4 20) 2 21) 3 22) 1 23) 4 24) 1
[h = 6.6 × 10 -34 J s,m = 9.1× 10 -31 kg] 25) 1 26) 2 27) 1 28) 2 29) 3 30) 1
1) 1.52  104 m 2) 5.1 103 m 31) 4 32) 3 33) 4 34) 3 35) 2 36) 3
37) 2 38) 1 39) 2 40) 1
3) 1.92  103 m 4) 3.84  103 m Hints Level – III
35. The kinetic energy of electron is 3.0  10 J . 25
12375 0
1.  A
The wave length of the electron is E
1) 7965A0 2) 4625A0 hc
3) 91A0 4) 8967A0 2. E

36. Uncertainity in the position of an electron
(mass = 9.1   10 –31 kg) moving with 1 1
3. E2  hc[  ]
velocity 300m–1 , accurate upto 0.001%,  1
will be (h = 6.6310 –34 JS) c 1
(AIEEE2006) 4.   
-2  t
1) 19.2  10 m 2) 5.76  10-2 m
3) 1.92  10-2 m 4) 3. 83  10-2 m    ct
37. An electron of a velocity ‘x’ is found to have a Nhc E
5. E N 
certain wavelength. The velocity to be  hc
possessed by the neutron to have half the de d
Broglie wavelength possessed by electron is : 6. v  d  v  t [ v  3  108 m / sec]
t
1) x/1840 2) x/920 3) 3680x 4) x/3680
c c
Quantum Mechanical Model of Atom 7. 1  ; 2 
1 2
38. In  321 the sum of angular momentum,
E1 v1
spherical nodes and angular mode is: 
E2 v2
6h  4 6h
1) 2) 3 Nhc
2 2 8. E

6 h  2 6 h  8 Nhc E1   2
3) 4) 9. E ; E
2 2  1
2

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 NEET-CHEMISTRY-VOL-I ATOMIC STRUCTURE
Nhc 1
10. E  K.E = h(ν - ν0 )Þ mv 2 = h(ν - ν0 )
 2
hc 2h(ν - ν )
0 ;v 2 = 2h(2f0 - f0 ) - - - - - (1)
20. v2 =
11. E  m 1 m

2h(5f0 - f0 )
Energy of one mole= E  N A v2 2 = - - - - - - - -2
m
1 Nh hc c 1
12. E  Nh (   ); E   h  mv 2
t t 21.  0 2
13. Etotal  E1  E2
1 1  1
hc hc hc 1 1 1 hc     mv 2
       0  2
 1 2  1 2
1
2
1 1 1  2hc  0    
  V     
353 680 2  m  0  
14. h  h 0  kE ; K .E  h(   0 ) 22.
h  w  K .E ; w  h  K .E
240 103
15. B.E for 1 molecule = = 40  10 20 J hc 6.625  1034  3  108
6 1023   K .E   0.35
= 4  10 19 J  256.7  109
hc %
Energy of incident light E   4.41 1019 J 23. No.of atoms  n  N 0 
 100
K .E  E  W 24. Balmer series - visible region,for the line of balmer
series energy is maximum
K .E  0.41 1019 25. Balmer series - visible region
= 4.1 10 20 J for 3rd line n1  2, n2  5
1 2 hC 1 E1 E1
16. h  W  mv ;  W  mv 2  E
2  2 26.
32 22
19
(1eV  1.6  10 J ) 5E1
 E
W  2.13  1.6  1019 J 36
hc E1  7.2 E
17. h  W  K .E ;W   K .E
 I .E   E1
hc hc  7.2 E
W  0 
0 W
27. r1  r2  0.529  n12  n22 
18. hv1  hv0  1  h  v1  v0   1 -------------(1)
28. I .E   E1
hv2  hv0  k  h  v2  v0   k ----------- (2) ( E1 ) He ( z He )2
z2
(1) 1 v1  v0 En   
n2 ( E1 ) Li 2 ( z Li 2 )2
= K  v v
(2) 2 0
29. E  E3  E1  12.1eV
v2  v0  Kv1  Kv0 Electron jumps from 3rd orbit to 1st orbit
Kv0  v0  Kv1  v2 3h h
mvr  
v0  K  1  Kv1  v2 2 2
Kv1  v2 hc 18 1 1
v0  30. E    2.178  10 ( n 2  n 2 )
K 1 1 2
19. no. of photo electrons ejected  intensity of radia- 6.6256  10 34  3 108 1 1
tion but KE is independent of intensity of radiation.  2.178 1018 ( 2  2 )
 1 2
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 ATOMIC STRUCTURE NEET-CHEMISTRY-VOL-I
nh 1. Assertion(A): The energy of ultraviolet radiation
31. mvr  is greater than the energy of infrared radiation
2
Reason(R): The velocity of ultraviolet radiation
32. According to Kepler’s law t 2  R 3 is greater than the velocity of infrared radiation.
33. E  E2  E1 [ I .E   E1 ] 2. A : Fe 3 ion is more stable than Fe 2
R : Fe 3 ion has more number of unpaired electrons
1.312  106 1.312  106
 ( ) than Fe 2
22 1
3. A : The kinetic energy of the photo electron ejected
h increases with increase in intensity of incident light.
34. x.m.v 
4 R: Increase in intensity of incident light increases
h the rate of emission.
x  4 A : Threshold frequency is a characteristic for a
4 .m.v
metal
6.6256  1034 R : Threshold frequency is a maximum frequency
x 
600  0.005 required for the ejection of electron from the metal
4  3.14  9.1 1031 
100 surface.
h 5. A : Line spectrum of Li 2 and He  are identical
35.   R : Isoelectronic species produce identical
2mkE
spectrum
h 6. A : Hydrogen has only one electron in its orbit but
36. x 
4 m.V produces several spectral lines.
1 mn vn R : There are many excited energy levels available
 2  me  ve in a sample of Hydrogen gas.
37. 1 me.ve , Vn  7. A : It is not essential that all the lines available in
2 mn
the emission spectrum will also be available in the
38.  321 : n  3, l  2, m  1 absorption spectrum
R : The spectrum of hydrogen atom is only
h 6h
absorption spectrum
Angular momentum  l  l  1  8. A : In an atom, the velocity of electrons in the higher
2 2 orbits keeps on decreasing
Spherical nodes  3  2  1  0 ; R : Velocity of electron is inversely proportional to
Angular node = 2 the radius of the orbit
6h 6h  4 9. A : The radial probability of 1s electron first
Sum of all the above  2 increases, till it is maximum at 0.53A0 , and then
2 2
decreases.
40.  B  n(n  2) Ni 2  3d 8 R : Bohr’s radius for the first orbit is 0.53A0
Number of unpaired electrons (n) = 2 10. A : Wavelength of limiting line of lyman series is
less than wavelength of limiting line of Balmer series.
Level–IV
R : Rydberg constant value is same for all elements
In the questions that follows two statements 11. A : The faster a particle moves, the greater its
are given. Reason is supported to be the
momentum and the shorter is the wave length that
explanation for Assertion. Study both the is associated with it.
statements and then mark your answers.
R : Because  = hp–1 and p = mv
according to the codes given below. Mark
12. A : An electron cannot exist in the nucleus
your answer as
R : The deBroglie wavelength of an electron is much
1) Both (A) and (R) are true and (R) is the correct smaller than the diameter of the nucleus
explanation of (A)
13. A : The position of electron can be determined with
2) Both (A) and (R) are true and (R) is not the
the help of an electronic microscope
correct explanation of (A) R : The product of uncertainty in momentum and
3) (A) is true but (R) is false
the uncertainty in the position of an electron cannot
4) (A) is false but (R) is true
be less than a finite limit
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 NEET-CHEMISTRY-VOL-I ATOMIC STRUCTURE
14. A : It is not possible to predict position and the C) Wave number 3) 3  108m / sec
velocity of an electron exactly and simultaneously D) Photon 4) 6.625  10–34J–sec
R : Electron moving with high speed possesses both 5) cm–1
the particle nature and the wave nature The correct match is
15. A : deBroglie equation has significance for any A B C D A B C D
microscopic or submicroscopic particles 1) 2 3 4 5 2) 1 2 3 4
R : deBroglie wavelength is inversely proportional 3) 2 4 5 1 4) 3 4 5 1
to the mass of the object. 26. List - I List - II
16. A : There are two nodal regions in 3s-orbital. I) hν  W  K.E a) Quantization of
R : There is no nodal plane in 3s-orbital. angular momentum
17. A : A spectral line will be observed for a 2px–2py
II) E  hν b)Wave numbers of
transition
R : The energy of 2px and 2py orbitals is the same Balmer series
18. A : The Px orbital has maximum electron density 1 1
III) ν  R  2  2  c) Quantum theory
along the x axis and its nodal plane is yz plane 2 n 
R : For a given atom, for all values of n, the p- h
orbitals have the same shape, but the overall size IV) m.v.r  d) Photoelectric effect
increase as n increases 2π
19. A : Electrons may be considered as particles and The correct match is
waves I II III IV I II III IV
R : An electron in an atom may be described as 1) a b c d 2) c d b a
occupying at atomic orbital or by a wave function 3) d c b a 4) b d a c
ψ , which is a solution to the schrodinger wave 27. List - I List - II
equation I) Wave number a) ms 1
20. A : ψ indicates the amplitude of electron - wave II) Frequency b) nm
R : ψ2 denotes probability of finding an electron in III) Wavelength c) s 1
the space around the nucleus IV) Velocity d) m 1
21. A : The electronic configurations in which all of the The correct match is
orbitals of the same sub shell are either completely I II III IV I II III IV
filled or are exactly half filled are more stable 1) a b c d 2) d c b a
R : The completely filled or exactly half filled shells 3) b c d a 4) c d b a
possess a symmetrical distribution of electrons and 28. List - I List - II
allow their maximum number of exchanges 2πze 2
22. A : An orbital cannot have more than two electrons A) Energy 1)
R : The two electrons in an orbital create opposite nh
magnetic field 2π 2 mz 2 e 4
23. A : P – orbital can accomadate 6 electrons B) Velocity 2)
n 2h2
R : No two electrons in atom can have same set of
four quantum numbers 2π 2 mz 2 e 4
C) Rydberg constant 3)
24. A : Ground state electronic configuration of h 3c
chromium atom is (A r) 4s 3d 1 5

R : Exchange energy is more wtih(Ar) 4s13d5than n2 h 2

D) Radius 4)
(Ar) 4s23d4 4π 2 mz e 2
Matrix Match Type 4π 2 mz 2 e 4
Following questions contains statements given 5)
in two columns. Which have to be matched. n2 h 2
Statements (A,B,C,D) in column I have to be The correct match is
matched with statements (P,Q,R,S)in column II 1) A = 2 B = 4 C = 5 D = 1
25. List - I List - II 2) A = 2 B = 1 C = 3 D = 4
A) Velocity of light 1) Energy particle 3) A = 3 B = 2 C = 1 D = 4
B) Plank’s constant 2) Energy packet 4) A = 4 B = 3 C = 1 D = 5
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Velammal Bodhi NEET Academy
 ATOMIC STRUCTURE NEET-CHEMISTRY-VOL-I
29. List - I List - II 33. List - I List - II
I) Radial probability a) 1.1A 0 I) The electrons of same a) Hund’s rule
distribution curve of orbital differ in ‘s’ value
3s orbital II) Order of orbitals is b) Stability of
II) Distance of maximum b)1s orbital 2s,2p,3s,3p,4s completely
probability of 1s electron filled sublevel
III) Radial node for a c) 3 peaks, III) E.C of N is c) Pauli’s principle
2 2 1 1
1s 2s 2px 2py 2pz 1
2s electron 2 radial nodes
IV) E.C of Cu is d) Aufbau principle
IV) No spherical nodes d) 0.53A 0 [Ar] 4s13d10
The correct match is The correct match is
I II III IV I II III IV I II III IV I II III IV
1) a b c d 2) c d a b 1) a b c d 2) d c b a
3) b a d c 4) d a b c 3) c d a b 4) c b d a
30. List - I List - II 34. Column-I Column-II
Ze 2 A) 7s P) Maximum energy
A) nodal plane 1) B) 4d Q) Maximum
2r
number of electrons
h C) 5d R) 3 sub shells
B) p-orbital 2) λ 
mv D) 4p S) Minimum number
C) deBroglie 3) Spherical of orbitals
D) Kinetic energy 4) Probability of e– is zero 35. Column-I Column-II
5) Dumb bell A) Radial function (R) P) n
The correct match is B) Angular function( ) Q) l
A B C D A B C D
1) 4 5 2 1 2) 2 4 3 5 C) Angular function (  ) R) m
3) 1 5 3 2 4) 3 1 4 2 D) Quantised angular momentum S) s
31. List - I List - II Key Level – IV
2 01) 3 02) 2 03) 4 04) 3 05) 1 06) 1
I) ψ depends only a) p–orbitals
07) 3 08) 1 09) 2 10) 3 11) 1 12) 3
upon distance 13) 4 14) 1 15) 1 16) 2 17) 4 18) 2
II) ψ2 depends upon b) d–orbital 19) 2 20) 2 21) 1 22) 3 23) 4 24) 1
distance and on one 25) 4 26) 3 27) 2 28) 2 29) 2 30) 1
direction 31) 3 32) 3 33) 3
34) A-P,S; B-Q; C-Q; D-R
III) ψ2 depends upon c) f –orbital
35) A-P,Q; B-Q,R; C-R; D-Q,S
distance and on two
directions Hints Level – IV
IV) ψ 2 depends upon d) s –orbitals 7. The minimum frequency required to eject an
electron from the surface of metal is called
distance and on three threshold frequency.
directions 8. Due to same electronic configuration.
The correct match is 10. H-spectrum can be both emission and
I II III IV I II III IV absorption
1) d c b a 2) c b a d
3) d a b c 4) d a c b h
15. 
32. List - I List- mv
II 21. 2P orbitals are degenerate.
A) No of electrons present in an orbit 1) 2 22. The two lobes are oriented along x-axis.
B) Number of orbitals in an orbit 2) n 24.  2 is the probability function
C) Number of electrons in an orbital 3) n2  is the wave function.
D) Number of sub shells in an orbit 4) 2n2
The correct match is 34. no. of electrons in an orbit = 2n 2
A B C D A B C D no. of orbitals in an orbit = n 2
1) 4 2 1 3 2) 1 2 3 4 no. of electrons in an orbital = 2
3) 4 3 1 2 4) 2 1 3 4 no. of subshells = n
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Velammal Bodhi NEET Academy